arXiv subjects

J. Honolka

Publications and source records attributed to J. Honolka.

At least 19 recordsLinked to original sources

arXiv2021

Single crystal studies and electronic structure investigation of a room-temperature semiconductor NaMnAs

We report synthesis of single crystalline NaMnAs, confirm its antiferromagnetic order and characterise the sample by photoemission spectroscopy. The electronic structure was studied using optical transmittance, x-ray and ultraviolet spectroscopy and by theoretical modeling using local density approximation (LDA) extended to LDA+U when Heisenberg model parameters were determined. Optical transmittance measurement have confirmed the theoretical predictions that NaMnAs is a semiconductor. Also the Néel temperature was closer determined for the first time from temperature dependence of magnetization, in agreement with our Monte Carlo simulations.

cond-mat.mtrl-sci↗

arXiv2020

Spin-spiral state of a Mn monolayer on W(110) studied by soft x-ray absorption spectroscopy at variable temperatures

The noncollinear magnetic state of epitaxial Mn monolayers on tungsten (110) crystal surfaces is investigated by means of soft x-ray absorption spectroscopy, to complement earlier spin-polarized STM experiments. X-ray absorption spectra (XAS), x-ray linear dichroism (XLD) and x-ray magnetic circular dichroism (XMCD) Mn L23-edge spectra were measured in the temperature range from 8 to 300 K and compared to results of fully-relativistic ab initio calculations. We show that antiferromagnetic (AFM) helical and cycloidal spirals give rise to significantly different Mn L23-edge XLD signals, enabling thus to distinguish between them. It follows from our results that the magnetic ground state of a Mn monolayer on W(110) is an AFM cycloidal spin spiral. Based on temperature-dependent XAS, XLD and field-induced XMCD spectra we deduce that magnetic properties of the Mn monolayer on W(110) vary with temperature, but this variation lacks a clear indication of a phase transition in the investigated temperature range up to 300 K - even though a crossover exists around 170 K in the temperature dependence of XAS branching ratios and in XLD profiles.

cond-mat.mtrl-sci↗

arXiv2020

Magnetic properties of Mn-doped Bi$_2$Se$_3$ topological insulators: ab initio calculations

Doping Bi$_2$Se$_3$ by magnetic ions represents an interesting problem since it may break the time reversal symmetry needed to maintain the topological insulator character. Mn dopants in Bi$_2$Se$_3$ represent one of the most studied examples here. However, there is a lot of open questions regarding their magnetic ordering. In the experimental literature different Curie temperatures or no ferromagnetic order at all are reported for comparable Mn concentrations. This suggests that magnetic ordering phenomena are complex and highly susceptible to different growth parameters, which are known to affect material defect concentrations. So far theory focused on Mn dopants in one possible position, and neglected relaxation effects as well as native defects. We have used ab initio methods to calculate the Bi$_2$Se$_3$ electronic structure influenced by magnetic Mn dopants, and exchange interactions between them. We have considered two possible Mn positions, the substitutional and interstitial one, and also native defects. We have found a sizable relaxation of atoms around Mn, which affects significantly magnetic interactions. Surprisingly, very strong interactions correspond to a specific position of Mn atoms separated by van der Waals gap. Based on the calculated data we performed spin dynamics simulations to examine systematically the resulting magnetic order for various defect contents. We have found under which conditions the experimentally measured Curie temperatures ${T_{\rm{C}}}$ can be reproduced, noticing that interstitial Mn atoms appear to be important here. Our theory predicts the change of ${T_{\rm{C}}}$ with a shift of Fermi level, which opens the way to tune the system magnetic properties by selective doping.

cond-mat.mtrl-sci↗

arXiv2018

Influence of an anomalous temperature-dependence of the phase coherence length on the conductivity of magnetic topological insulators

Magnetotransport constitutes a useful probe to understand the interplay between electronic band topology and magnetism in spintronics devices based on topological materials. A recent theory of Lu and Shen [Phys. Rev. Lett. 112, 146601 (2014)] on magnetically doped topological insulators predicts that quantum corrections $Δκ$ to the temperature-dependence of the conductivity can change sign during the Curie transition. This phenomenon has been attributed to a suppression of the Berry phase of the topological surface states at the Fermi level, caused by a magnetic energy gap. Here, we demonstrate experimentally that $Δκ$ can reverse its sign even when the Berry phase at the Fermi level remains unchanged, provided that the inelastic scattering length decreases with temperature below the Curie transition.

cond-mat.mtrl-sci↗

arXiv2017

Local moment formation and magnetic coupling of Mn guest atoms in Bi$_2$Se$_3$: a low-temperature ferromagnetic resonance study

We compare the magnetic and electronic configuration of single Mn atoms in molecular beam epitaxy (MBE) grown Bi$_2$Se$_3$ thin films, focusing on electron paramagnetic (ferromagnetic) resonance (EPR and FMR, respectively) and superconducting quantum interference device (SQUID) techniques. X-ray diffraction (XRD) and electron backscatter diffraction (EBSD) reveal the expected increase of disorder with increasing concentration of magnetic guest atoms, however, Kikuchi patterns show that disorder consists majorly of mum-scale 60deg twin domains in the hexagonal Bi$_2$Se$_3$ structure, which are promoted by the presence of single unclustered Mn impurities. Ferromagnetism below T$_C$ ~ (5.4 +/- 0.3) K can be well described by critical scaling laws M(T) ~ (1-T/T$_C$)$^β$ with a critical exponent $β$ = (0.34 +/- 0.2)), suggesting 3D Heisenberg class magnetism instead of e.g. 2D-type coupling between Mn-spins in van der Waals gap sites. From EPR hyperfine structure data we determine a Mn$^{2+}$ (d$^5$, S = 5/2) electronic configuration with a g-factor of 2.002 for -1/2 --> +1/2 transitions. In addition, from the strong dependence of the low temperature FMR fields and linewidth on the field strength and orientation with respect to the Bi$_2$Se$_3$ (0001) plane, we derive magnetic anisotropy energies of up to K1 = -3720 erg/cm3 in MBE-grown Mn-doped Bi$_2$Se$_3$, reflecting the first order magneto-crystalline anisotropy of an in-plane magnetic easy plane in a hexagonal (0001) crystal symmetry. Across the ferromagnetic-paramagnetic transition the FMR intensity is suppressed and resonance fields converge the paramagnetic limit of a Mn$^{2+}$ (d$^5$, S = 5/2).

cond-mat.mtrl-sci↗

arXiv2016

Electronic and transport properties of the Mn-doped topological insulator Bi$_{2}$Te$_{3}$: A first-principles study

We present a first-principles study of the electronic, magnetic, and transport properties of the topological insulator Bi$_{2}$Te$_{3}$ doped with Mn atoms in substitutional (Mn$_{\rm Bi}$) and interstitial van der Waals gap positions (Mn$_{\rm i}$), which act as acceptors and donors, respectively. The effect of native Bi$_{\rm Te}$- and Te$_{\rm Bi}$-antisite defects and their influence on calculated electronic transport properties is also investigated. We have studied four models representing typical cases, namely (i) Bi$_{2}$Te$_{3}$ with and without native defects, (ii) Mn$_{\rm Bi}$ defects with and without native defects, (iii) the same but for Mn$_{\rm i}$ defects, and (iv) the combined presence of Mn$_{\rm Bi}$ and Mn$_{\rm i}$. It was found that lattice relaxations around Mn$_{\rm Bi}$ defects play an important role for both magnetic and transport properties. The resistivity is strongly influenced by the amount of carriers, their type, and by the relative positions of the Mn-impurity energy levels and the Fermi energy. Our results indicate strategies to tune bulk resistivities, and also help to uncover the location of Mn atoms in measured samples. Calculations indicate that at least two of the considered defects have to be present simultaneously in order to explain the experimental observations, and the role of interstitials may be more important than expected.

cond-mat.mtrl-sci↗

arXiv2016

Nanofaceting as a stamp for periodic graphene charge carrier modulations

The exceptional electronic properties of monoatomic thin graphene sheets triggered numerous original transport concepts, pushing quantum physics into the realm of device technology for electronics, optoelectronics and thermoelectrics. At the conceptual pivot point is the particular twodimensional massless Dirac fermion character of graphene charge carriers and its volitional modification by intrinsic or extrinsic means. Here, interfaces between different electronic and structural graphene modifications promise exciting physics and functionality, in particular when fabricated with atomic precision. In this study we show that quasiperiodic modulations of doping levels can be imprinted down to the nanoscale in monolayer graphene sheets. Vicinal copper surfaces allow to alternate graphene carrier densities by several 10^13 carriers per cm^2 along a specific copper high-symmetry direction. The process is triggered by a self-assembled copper faceting process during high-temperature graphene chemical vapor deposition, which defines interfaces between different graphene doping levels at the atomic level.

cond-mat.mtrl-sci↗

arXiv2016

Non-magnetic ground state of Ni adatoms on Te-terminated bismuth chalcogenide topological insulators

We report on the quenching of single Ni adatom moments on Te-terminated Bi2Te2Se and Bi2Te3 topological insulator surfaces. The effect becomes manifested as a missing X-ray magnetic circular dichroism for resonant L3,2 transitions into partially filled Ni 3d states of occupancy n_d = 9.2. On the basis of a comparative study of Ni and Fe using scanning tunneling microscopy and ab initio calculations we are able to relate the element specific moment formation to a local Stoner criterion. While Fe adatoms form large spin moments of m_s = 2.54 mu_B with out-of-plane anisotropy due to a sufficiently large density of states at the Fermi energy, Ni remains well below an effective Stoner threshold for local moment formation. With the Fermi level remaining in the bulk band gap after adatom deposition, non-magnetic Ni and preferentially out-of-plane oriented magnetic Fe with similar structural properties on Bi2Te2Se surfaces constitute a perfect platform to study off-on effects of time-reversal symmetry breaking on topological surface states.

cond-mat.mtrl-sci↗

arXiv2016

Topological insulator homojunctions including magnetic layers: the example of n-p type ($n$-QLs Bi$_2$Se$_3$/Mn-Bi$_2$Se$_3$) heterostructures

Homojunctions between Bi$_2$Se$_3$ and its Mn-doped phase are investigated as a sample geometry to study the influence of spin degrees of freedom on topological insulator properties. $n$ quintuple layers (QLs) of Bi$_2$Se$_3$ are grown ontop of Mn-doped Bi$_2$Se$_3$ by molecular beam epitaxy for $0\le n \le 30\,$QLs, allowing to unhamperedly monitor the development of electronic and topological properties by surface sensitive techniques like angle resolved photoemission spectroscopy. With increasing $n$, a Mn-induced gap at the Dirac point is gradually filled in an "hourglass" fashion to reestablish a topological surface state at $n \sim 9\,$QLs. Our results suggest a competition of upwards and downwards band bending effects due to the presence of an n-p type interface, which can be used to tailor topological and quantum well states independently.

cond-mat.mtrl-sci↗

arXiv2015

Temperature dependent behavior of localized and delocalized electrons in nitrogen-doped 6H SiC crystals as studied by electron spin resonance

We have studied the temperature behavior of the electron spin resonance (ESR) spectra of nitrogen (N) donors in n-type 6H SiC crystals grown by Lely and sublimation sandwich methods (SSM) with donor concentration of 10^17 cm^(-3) at T=60-150 K. A broad signal in the ESR spectrum was observed at T>=80 K with Lorentzian lineshape and gpar=2.0043(3), gper=2.0030(3), which was previously assigned in the literature to the N donors in the 1s(E) excited state. Based on the analysis of the ESR lineshape, linewidth and g-tensor we attribute this signal to the conduction electrons (CE). The emergence of the CE ESR signal at T>80 K was explained by the ionization of electrons from the 1s(A) ground and 1s(E) excited states of N donors to the conduction band while the observed reduction of the hyperfine (hf) splitting for the Nk1,k2 donors with the temperature increase is attributed to the motion narrowing effect of the hf splitting. The temperature dependence of CE ESR linewidth is described by an exponential law (Orbach process) with the activation energy corresponding to the energy separation between 1s(A1) and 1s(E) energy levels for N residing at quasi-cubic sites (Nk1,k2). The theoretical analysis of the temperature dependence of microwave conductivity measured by the contact-free method shows that due to the different position of the Fermi level in two samples the ionization of free electrons occurs from the energy levels of Nk1,k2 donors in Lely grown samples and from the energy level of Nh residing at hexagonal position in 6H SiC grown by SSM

cond-mat.mtrl-sci↗

arXiv2014

Single 3$d$ transition metal atoms on multi-layer graphene systems: electronic configurations, bonding mechanisms and role of the substrate

The electronic configurations of Fe, Co, Ni, and Cu adatoms on graphene and graphite have been studied by x-ray magnetic circular dichroism and charge transfer multiplet theory. A delicate interplay between long-range interactions and local chemical bonding is found to influence the adatom equilibrium distance and magnetic moment. The results for Fe and Co are consistent with purely physisorbed species having, however, different 3$d$-shell occupancies on graphene and graphite ($d^{n+1}$ and $d^n$, respectively). On the other hand, for the late 3$d$ metals Ni and Cu a trend towards chemisorption is found, which strongly quenches the magnetic moment on both substrates.

cond-mat.mtrl-sci↗

arXiv2014

Complex trend of magnetic order in Fe clusters on 4$d$ transition-metal surfaces

We demonstrate the occurrence of compensated spin configurations in Fe clusters and monolayers on Ru(0001) and Rh(111) by a combination of X-ray magnetic circular dichroism experiments and first-principles calculations. Our results reveal complex intra-cluster exchange interactions which depend strongly on the substrate 4$d$-band filling, the cluster geometry as well as lateral and vertical structural relaxations. The importance of substrate 4$d$-band filling manifests itself also in small nearest-neighbor exchange interactions in Fe dimers and in an nearly inverted trend of the Ruderman-Kittel-Kasuya-Yosida coupling constants for Fe adatoms on the Ru and Rh surface.

cond-mat.mtrl-sci↗

arXiv2011

In-plane magnetic anisotropy of Fe atoms on Bi$_2$Se$_3$(111)

The robustness of the gapless topological surface state hosted by a 3D topological insulator against perturbations of magnetic origin has been the focus of recent investigations. We present a comprehensive study of the magnetic properties of Fe impurities on a prototypical 3D topological insulator Bi$_2$Se$_3$ using local low temperature scanning tunneling microscopy and integral x-ray magnetic circular dichroism techniques. Single Fe adatoms on the Bi$_2$Se$_3$ surface, in the coverage range $\approx 1%$ are heavily relaxed into the surface and exhibit a magnetic easy axis within the surface-plane, contrary to what was assumed in recent investigations on the opening of a gap. Using \textit{ab initio} approaches, we demonstrate that an in-plane easy axis arises from the combination of the crystal field and dynamic hybridization effects.

cond-mat.mes-hall↗

arXiv2010

Manipulation of electrical and ferromagnetic properties of photo-sensitized (Ga,Mn)As

We present the manipulation of magnetic and electrical properties of (Ga,Mn)As by the adsorption of dye-molecules as a first step towards the realization of light-controlled magnetic-semiconductor/dye hybrid devices. A significant lowering of the Curie temperature with a corresponding increase in electrical resistance and a higher coercive field is found for the GaMnAs/fluorescein system with respect to (Ga,Mn)As. Upon exposure to visible light a shift in Curie temperature towards higher values and a reduction of the coercive field can be achieved in photo-sensitized (Ga,Mn)As. A mayor change in the XPS spectrum of (Ga,Mn)As indicates the appearance of occupied levels in the energy range corresponding to the (Ga,Mn)As valence band states upon adsorption of fluorescein. This points towards a hole quenching effect at the molecule-(Ga,Mn)As interface which is susceptible to light exposure.

cond-mat.mtrl-sci↗

arXiv2009

Cobalt nano-clusters on metal supported Xe monolayers: influence of the substrate on cluster formation kinetics and magnetism

The growth dynamics of submonolayer coverages of Cobalt during buffer layer assisted growth on Ag(111) and Pt(111) substrates is investigated by variable temperature scanning tunneling microscopy in the temperature range between 80 and 150 Kelvin. It is found that attractive cluster-substrate interactions can govern the cluster formation on the Xe buffer layer, if the Xe layer is sufficiently thin. The interpretation of the microscopy results are supported by x-ray magnetic circular dichroism which monitors the effect of cluster-substrate interactions on the formation of magnetic moments and magnetic anisotropy of Co nanocluster during the different stages of growth. {\it Ab-initio} calculations show that the cluster magnetism is controlled by the interface anisotropy, leading to perpendicular magnetization for Co on Pt(111). Limits of and new potential for nanocluster fabrication by buffer layer assisted growth are discussed.

cond-mat.mes-hall↗

arXiv2009

Temperature dependent Neel wall dynamics in GaMnAs/GaAs

Extensive Kerr microscopy studies reveal a strongly temperature dependent domain wall dynamics in Hall-bars made from compressively strained GaMnAs. Depending on the temperature magnetic charging of domain walls is observed and nucleation rates depend on the Hall-geometry with respect to the crystal axes. Above a critical temperature where a biaxial-to-uniaxial anisotropy transition occurs a drastic increase of nucleation events is observed. Below this temperature, the nucleation of domains tends to be rather insensitive to temperature. This first spatially resolved study of domain wall dynamics in patterned GaMnAs at variable temperatures has important implications for potential single domain magneto-logic devices made from ferromagnetic semiconductors.

cond-mat.mtrl-sci↗

arXiv2008

Complex domain wall dynamics in compressively strained GaMnAs epilayers

The domain wall induced reversal dynamics in compressively strained GaMnAs was studied employing the magneto-optical Kerr effect and Kerr microscopy. Due to the influence of an uniaxial part in the in-plane magnetic anisotropy (90+/-Delta) domain walls with considerably different dynamic behavior are observed. While the (90+Delta) reversal is identified to be propagation dominated with a small number of domain walls, the case of (90-Delta) reversal includes the nucleation of many domain walls. The domain wall nucleation/propagation energy for both transitions are estimated using model calculations from which we conclude that single domain devices can be achievable using the (90+Delta) mode.

cond-mat.other↗

arXiv2007

Absence of local magnetic moments in Ru and Rh impurities and clusters on Ag(100) and Pt(997)

The magnetism of quench-condensed Ru and Rh impurities and metal films on Ag(100) and Pt(997) has been studied using x-ray magnetic circular dichroism. In the coverage range between 0.22 ML and 2.0 ML no dichroic signal was detected at the M3,2 absorption edges of Ru on Ag(100) at a temperature of 5 K in the presence of an applied magnetic field. The same was found for coverages between 0.12 ML and 0.5 ML of Rh on Ag(100) and Pt(997). It is concluded that the magnetic moments of single impurities, small clusters of various shape and monolayers of the 4d metals are below the detection limit of 0.04 muB per atom. These results provide an unambiguous determination of the local magnetic moment of Ru and Rh deposited on nonmagnetic transition-metal surfaces, which are in contrast with theoretical predictions.

cond-mat.other↗