arXiv subjects

J. M. Riley

Publications and source records attributed to J. M. Riley.

At least 19 recordsLinked to original sources

arXiv2021

Spectroscopic view of ultrafast charge carrier dynamics in single- and bilayer transition metal dichalcogenide semiconductors

The quasiparticle spectra of atomically thin semiconducting transition metal dichalcogenides (TMDCs) and their response to an ultrafast optical excitation critically depend on interactions with the underlying substrate. Here, we present a comparative time- and angle-resolved photoemission spectroscopy (TR-ARPES) study of the transient electronic structure and ultrafast carrier dynamics in the single- and bilayer TMDCs MoS$_2$ and WS$_2$ on three different substrates: Au(111), Ag(111) and graphene/SiC. The photoexcited quasiparticle bandgaps are observed to vary over the range of 1.9-2.3 eV between our systems. The transient conduction band signals decay on a sub-100 fs timescale on the metals, signifying an efficient removal of photoinduced carriers into the bulk metallic states. On graphene, we instead observe two timescales on the order of 200 fs and 50 ps, respectively, for the conduction band decay in MoS$_2$. These multiple timescales are explained by Auger recombination involving MoS$_2$ and in-gap defect states. In bilayer TMDCs on metals we observe a complex redistribution of excited holes along the valence band that is substantially affected by interactions with the continuum of bulk metallic states.

cond-mat.mtrl-sci↗

arXiv2020

The faint radio source population at 15.7 GHz -- IV. The dominance of core emission in faint radio galaxies

We present 15-GHz Karl G. Jansky Very Large Array observations of a complete sample of radio galaxies selected at 15.7 GHz from the Tenth Cambridge (10C) survey. 67 out of the 95 sources (71 per cent) are unresolved in the new observations and lower-frequency radio observations, placing an upper limit on their angular size of ~2 arcsec. Thus compact radio galaxies, or radio galaxies with very faint jets, are the dominant population in the 10C survey. This provides support for the suggestion in our previous work that low-luminosity ($L<10^{25} \, \textrm{W Hz}^{-1}$) radio galaxies are core-dominated, although higher-resolution observations are required to confirm this directly. The 10C sample of compact, high-frequency selected radio galaxies is a mixture of high-excitation and low-excitation radio galaxies and displays a range of radio spectral shapes, demonstrating that they are a mixed population of objects.

astro-ph.GA↗

arXiv2019

Weyl-like points from band inversions of spin-polarised surface states in NbGeSb

Band inversions are key to stabilising a variety of novel electronic states in solids, from topological surface states in inverted bulk band gaps of topological insulators to the formation of symmetry-protected three-dimensional Dirac and Weyl points and nodal-line semimetals. Here, we create a band inversion not of bulk states, but rather between manifolds of surface states. We realise this by aliovalent substitution of Nb for Zr and Sb for S in the ZrSiS family of nonsymmorphic semimetals. Using angle-resolved photoemission and density-functional theory, we show how two pairs of surface states, known from ZrSiS, are driven to intersect each other in the vicinity of the Fermi level in NbGeSb, as well as to develop pronounced spin-orbit mediated spin splittings. We demonstrate how mirror symmetry leads to protected crossing points in the resulting spin-orbital entangled surface band structure, thereby stabilising surface state analogues of three-dimensional Weyl points. More generally, our observations suggest new opportunities for engineering topologically and symmetry-protected states via band inversions of surface states.

cond-mat.mtrl-sci↗

arXiv2018

Ubiquitous formation of bulk Dirac cones and topological surface states from a single orbital manifold in transition-metal dichalcogenides

Transition-metal dichalcogenides (TMDs) are renowned for their rich and varied properties. They range from metals and superconductors to strongly spin-orbit-coupled semiconductors and charge-density-wave systems, with their single-layer variants one of the most prominent current examples of two-dimensional materials beyond graphene. Their varied ground states largely depend on the transition metal d-electron-derived electronic states, on which the vast majority of attention has been concentrated to date. Here, we focus on the chalcogen-derived states. From density-functional theory calculations together with spin- and angle- resolved photoemission, we find that these generically host type-II three-dimensional bulk Dirac fermions as well as ladders of topological surface states and surface resonances. We demonstrate how these naturally arise within a single p-orbital manifold as a general consequence of a trigonal crystal field, and as such can be expected across a large number of compounds. Already, we demonstrate their existence in six separate TMDs, opening routes to tune, and ultimately exploit, their topological physics.

cond-mat.mtrl-sci↗

arXiv2018

Fermiology and Superconductivity of Topological Surface States in PdTe$_2$

We study the low-energy surface electronic structure of the transition-metal dichalcogenide superconductor PdTe$_2$ by spin- and angle-resolved photoemission, scanning tunneling microscopy, and density-functional theory-based supercell calculations. Comparing PdTe$_2$ with its sister compound PtSe$_2$, we demonstrate how enhanced inter-layer hopping in the Te-based material drives a band inversion within the anti-bonding p-orbital manifold well above the Fermi level. We show how this mediates spin-polarised topological surface states which form rich multi-valley Fermi surfaces with complex spin textures. Scanning tunneling spectroscopy reveals type-II superconductivity at the surface, and moreover shows no evidence for an unconventional component of its superconducting order parameter, despite the presence of topological surface states.

cond-mat.supr-con↗

arXiv2018

9C spectral-index distributions and source-count estimates from 15 to 93 GHz - a re-assessment

In an earlier paper (2007), we used follow-up observations of a sample of sources from the 9C survey at 15.2 GHz to derive a set of spectral-index distributions up to a frequency of 90 GHz. These were based on simultaneous measurements made at 15.2 GHz with the Ryle telescope and at 22 and 43 GHz with the Karl G. Jansky Very Large Array (VLA). We used these distributions to make empirical estimates of source counts at 22, 30, 43, 70 and 90 GHz. In a later paper (2013), we took data at 15.7 GHz from the Arcminute Microkelvin Imager (AMI) and data at 93.2 GHz from the Combined Array for Research in Millimetre-wave Astronomy (CARMA) and estimated the source count at 93.2 GHz. In this paper, we re-examine the data used in both papers and now believe that the VLA flux densities we measured at 43 GHz were significantly in error, being on average only about 70 per cent of their correct values. Here, we present strong evidence for this conclusion and discuss the effect on the source-count estimates made in the 2007 paper. The source-count prediction in the 2013 paper is also revised. We make comparisons with spectral-index distributions and source counts from other telescopes, in particular with a recent deep 95 GHz source count measured by the South Pole Telescope. We investigate reasons for the problem of the low VLA 43-GHz values and find a number of possible contributory factors, but none is sufficient on its own to account for such a large deficit.

astro-ph.GA↗

arXiv2017

Maximal Rashba-like spin splitting via kinetic energy-driven inversion symmetry breaking

Engineering and enhancing inversion symmetry breaking in solids is a major goal in condensed matter physics and materials science, as a route to advancing new physics and applications ranging from improved ferroelectrics for memory devices to materials hosting Majorana zero modes for quantum computing. Here, we uncover a new mechanism for realising a much larger energy scale of inversion symmetry breaking at surfaces and interfaces than is typically achieved. The key ingredient is a pronounced asymmetry of surface hopping energies, i.e. a kinetic energy-driven inversion symmetry breaking, whose energy scale is pinned at a significant fraction of the bandwidth. We show, from spin- and angle-resolved photoemission, how this enables surface states of 3d and 4d-based transition-metal oxides to surprisingly develop some of the largest Rashba-like spin splittings that are known. Our findings open new possibilities to produce spin textured states in oxides which exploit the full potential of the bare atomic spin-orbit coupling, raising exciting prospects for oxide spintronics. More generally, the core structural building blocks which enable this are common to numerous materials, providing the prospect of enhanced inversion symmetry breaking at judiciously-chosen surfaces of a plethora of compounds, and suggesting routes to interfacial control of inversion symmetry breaking in designer heterostructures.

cond-mat.str-el↗

arXiv2017

Narrow-band anisotropic electronic structure of ReS$_2$

We have used angle resolved photoemission spectroscopy to investigate the band structure of ReS$_2$, a transition-metal dichalcogenide semiconductor with a distorted 1T crystal structure. We find a large number of narrow valence bands, which we attribute to the combined influence of the structural distortion and spin-orbit coupling. We further image how this leads to a strong in-plane anisotropy of the electronic structure, with quasi-one-dimensional bands reflecting predominant hopping along zig-zag Re chains. We find that this does not persist up to the top of the valence band, where a more three-dimensional character is recovered with the fundamental band gap located away from the Brillouin zone centre along $k_z$. These experiments are in good agreement with our density-functional theory calculations, shedding new light on the bulk electronic structure of ReS$_2$, and how it can be expected to evolve when thinned to a single layer.

cond-mat.mtrl-sci↗

arXiv2016

Multiband one-dimensional electronic structure and spectroscopic signature of Tomonoga-Luttinger liquid behavior in K$_2$Cr$_3$As$_3$

We present Angle-Resolved Photoemission Spectroscopy measurements of the quasi-one dimensional superconductor K$_2$Cr$_3$As$_3$. We find that the Fermi surface contains two Fermi surface sheets, with linearly dispersing bands not displaying any significant band renormalizations. The one-dimensional band dispersions display a suppression of spectral intensity approaching the Fermi level according to a linear power law, over an energy range of ~200 meV. This is interpreted as a signature of Tomonoga-Luttinger liquid physics, which provides a new perspective on the possibly unconventional superconductivity in this family of compounds.

cond-mat.supr-con↗

arXiv2016

GMRT 610-MHz observations of the faint radio source population - and what these tell us about the higher-radio-frequency sky

We present 610-MHz Giant Metrewave Radio Telescope observations of 0.84 deg$^2$ of the AMI001 field (centred on $00^{\rm h} 23^{\rm m} 10^{\rm s}$, $+31^{\circ} 53'$) with an r.m.s. noise of 18 $μ$Jy beam$^{-1}$ in the centre of the field. 955 sources are detected, and 814 are included in the source count analysis. The source counts from these observations are consistent with previous work. We have used these data to study the spectral index distribution of a sample of sources selected at 15.7 GHz from the recent deep extension to the Tenth Cambridge (10C) survey. The median spectral index, $α$, (where $S \propto ν^{-α}$) between $0.08 < S_{15.7~\rm GHz} / \rm mJy < 0.2$ is $0.32 \pm 0.14$, showing that star-forming galaxies, which have much steeper spectra, are not contributing significantly to this population. This is in contrast to several models, but in agreement with the results from the 10C ultra-deep source counts; the high-frequency sky therefore continues to be dominated by radio galaxies down to $S_{15.7~\rm GHz} = 0.1$ mJy.

astro-ph.GA↗

arXiv2016

Spin-valley locking in the normal state of a transition-metal dichalocogenide superconductor

The metallic transition-metal dichalcogenides (TMDCs) are benchmark systems for studying and controlling intertwined electronic orders in solids, with superconductivity developing upon cooling from a charge density wave state. The interplay between such phases is thought to play a critical role in the unconventional superconductivity of cuprates, Fe-based, and heavy-fermion systems, yet even for the more moderately-correlated TMDCs, their nature and origins have proved highly controversial. Here, we study a prototypical example, $2H$-NbSe$_2$, by spin- and angle-resolved photoemission and first-principles theory. We find that the normal state, from which its hallmark collective phases emerge, is characterised by quasiparticles whose spin is locked to their valley pseudospin. This results from a combination of strong spin-orbit interactions and local inversion symmetry breaking. Non-negligible interlayer coupling further drives a rich three-dimensional momentum-dependence of the underlying Fermi surface spin texture. Together, these findings necessitate a fundamental re-investigation of the nature of charge order and superconducting pairing in NbSe$_2$ and related TMDCs.

cond-mat.supr-con↗

arXiv2016

10C continued: a deeper radio survey at 15.7 GHz

We present deep 15.7-GHz observations made with the Arcminute Microkelvin Imager Large Array in two fields previously observed as part of the Tenth Cambridge (10C) survey. These observations allow the source counts to be calculated down to 0.1 mJy, a factor of five deeper than achieved by the 10C survey. The new source counts are consistent with the extrapolated fit to the 10C source count, and display no evidence for either steepening or flattening of the counts. There is thus no evidence for the emergence of a significant new population of sources (e.g. starforming) at 15.7 GHz flux densities above 0.1 mJy, the flux density level at which we expect starforming galaxies to begin to contribute. Comparisons with the de Zotti et al. model and the SKADS Simulated Sky show that they both underestimate the observed number of sources by a factor of two at this flux density level. We suggest that this is due to the flat-spectrum cores of radio galaxies contributing more significantly to the counts than predicted by the models.

astro-ph.GA↗

arXiv2015

Nearly-free electrons in a 5d delafossite oxide metal

Understanding the role of electron correlations in strong spin-orbit transition-metal oxides is key to the realisation of numerous exotic phases including spin-orbit assisted Mott insulators, correlated topological solids, and prospective new high-temperature superconductors. To date, most attention has been focussed on the $5d$ iridium-based oxides. Here, we instead consider the Pt-based delafossite oxide PtCoO$_2$. Our transport measurements, performed on single-crystal samples etched to well-defined geometries using focussed ion-beam techniques, yield a room-temperature resistivity of only 2.1~$μΩ$cm, establishing PtCoO$_2$ as the most conductive oxide known. From angle-resolved photoemission and density-functional theory, we show that the underlying Fermi surface is a single cylinder of nearly hexagonal cross-section, with very weak dispersion along k$_z$. Despite being predominantly composed of $d$-orbital character, the conduction band is remarkably steep, with an average effective mass of only 1.14$m_e$. Moreover, the sharp spectral features observed in photoemission remain well-defined with little additional broadening for over 500~meV below E$_F$, pointing to suppressed electron-electron scattering. Together, our findings establish PtCoO$_2$ as a model nearly-free electron system in a $5d$ delafossite transition-metal oxide.

cond-mat.str-el↗

arXiv2015

The faint radio source population at 15.7 GHz - II. Multi-wavelength properties

A complete, flux density limited sample of 96 faint ($> 0.5$ mJy) radio sources is selected from the 10C survey at 15.7 GHz in the Lockman Hole. We have matched this sample to a range of multi-wavelength catalogues, including SERVS, SWIRE, UKIDSS and optical data; multi-wavelength counterparts are found for 80 of the 96 sources and spectroscopic redshifts are available for 24 sources. Photometric reshifts are estimated for the sources with multi-wavelength data available; the median redshift of the sample is 0.91 with an interquartile range of 0.84. Radio-to-optical ratios show that at least 94 per cent of the sample are radio loud, indicating that the 10C sample is dominated by radio galaxies. This is in contrast to samples selected at lower frequencies, where radio-quiet AGN and starforming galaxies are present in significant numbers at these flux density levels. All six radio-quiet sources have rising radio spectra, suggesting that they are dominated by AGN emission. These results confirm the conclusions of Paper I that the faint, flat-spectrum sources which are found to dominate the 10C sample below $\sim 1$ mJy are the cores of radio galaxies. The properties of the 10C sample are compared to the SKADS Simulated Skies; a population of low-redshift starforming galaxies predicted by the simulation is not found in the observed sample.

astro-ph.GA↗

arXiv2015

Hierarchical spin-orbital polarisation of a giant Rashba system

The Rashba effect is one of the most striking manifestations of spin-orbit coupling in solids, and provides a cornerstone for the burgeoning field of semiconductor spintronics. It is typically assumed to manifest as a momentum-dependent splitting of a single initially spin-degenerate band into two branches with opposite spin polarisation. Here, combining polarisation-dependent and resonant angle-resolved photoemission measurements with density-functional theory calculations, we show that the two "spin-split" branches of the model giant Rashba system BiTeI additionally develop disparate orbital textures, each of which is coupled to a distinct spin configuration. This necessitates a re-interpretation of spin splitting in Rashba-like systems, and opens new possibilities for controlling spin polarisation through the orbital sector.

cond-mat.mtrl-sci↗

arXiv2014

Direct observation of spin-polarised bulk bands in an inversion-symmetric semiconductor

Methods to generate spin-polarised electronic states in non-magnetic solids are strongly desired to enable all-electrical manipulation of electron spins for new quantum devices. This is generally accepted to require breaking global structural inversion symmetry. In contrast, here we present direct evidence from spin- and angle-resolved photoemission spectroscopy for a strong spin polarisation of bulk states in the centrosymmetric transition-metal dichalcogenide WSe$_2$. We show how this arises due to a lack of inversion symmetry in constituent structural units of the bulk crystal where the electronic states are localised, leading to enormous spin splittings up to $\sim\!0.5$ eV, with a spin texture that is strongly modulated in both real and momentum space. As well as providing the first experimental evidence for a recently-predicted `hidden' spin polarisation in inversion-symmetric materials, our study sheds new light on a putative spin-valley coupling in transition-metal dichalcogenides, of key importance for using these compounds in proposed valleytronic devices.

cond-mat.mtrl-sci↗

arXiv2012

The faint source population at 15.7 GHz - I. The radio properties

We have studied a sample of 296 faint (> 0.5 mJy) radio sources selected from an area of the Tenth Cambridge (10C) survey at 15.7 GHz in the Lockman Hole. By matching this catalogue to several lower frequency surveys (e.g. including a deep GMRT survey at 610 MHz, a WSRT survey at 1.4 GHz, NVSS, FIRST and WENSS) we have investigated the radio spectral properties of the sources in this sample; all but 30 of the 10C sources are matched to one or more of these surveys. We have found a significant increase in the proportion of flat spectrum sources at flux densities below approximately 1 mJy - the median spectral index between 15.7 GHz and 610 MHz changes from 0.75 for flux densities greater than 1.5 mJy to 0.08 for flux densities less than 0.8 mJy. This suggests that a population of faint, flat spectrum sources is emerging at flux densities below 1 mJy. The spectral index distribution of this sample of sources selected at 15.7 GHz is compared to those of two samples selected at 1.4 GHz from FIRST and NVSS. We find that there is a significant flat spectrum population present in the 10C sample which is missing from the samples selected at 1.4 GHz. The 10C sample is compared to a sample of sources selected from the SKADS Simulated Sky by Wilman et al. and we find that this simulation fails to reproduce the observed spectral index distribution and significantly underpredicts the number of sources in the faintest flux density bin. It is likely that the observed faint, flat spectrum sources are a result of the cores of FRI sources becoming dominant at high frequencies. These results highlight the importance of studying this faint, high frequency population.

astro-ph.CO↗

arXiv2010

Further GMRT observations of the Lockman Hole at 610 MHz

We present further observations of the Lockman Hole field, made with the Giant Metrewave Radio Telescope at 610 MHz with a resolution of 6 x 5 arcsec^2. These complement our earlier observations of the central approx 5 deg^2 by covering a further approx 8 deg^2, with an r.m.s. noise down to ~80 microJy beam^-1. A catalogue of 4934 radio sources is presented.

astro-ph.CO↗