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J. Martín-Pintado

Publications and source records attributed to J. Martín-Pintado.

At least 19 recordsLinked to original sources

Excitation and spatial study of a prestellar cluster towards G+0.693-0.027 in the Galactic centre

Star formation in the central molecular zone (CMZ) is suppressed with respect to that of the Galactic disk, and this is likely related to its high turbulent environment. This turbulence impedes the potential detection of prestellar cores. We present the temperature, density, and spatial structure of the CMZ molecular cloud G+0.693-0.027, which has been proposed to host a prestellar cluster in the Sgr B2 region. We analysed multiple HC$_{3}$N rotational transitions that were observed with the IRAM 30m, APEX, Yebes 40m, and GBT radio telescopes, together with SMA+APEX spatially resolved maps. The spectral shape of HC$_{3}$N lines shows three velocity components: a broad component with a line width of 23 km s$^{-1}$ (C1), and two narrow components with line widths of 7.2 and 8.8 km s$^{-1}$ (C2 and C3). This suggests that a fraction of the molecular gas in this cloud is undergoing turbulence dissipation. From a non-local thermodynamic equilibrium analysis we have found H$_{2}$ densities of 2$\times$10$^{4}$ cm$^{-3}$, 5$\times$10$^{4}$ cm$^{-3}$, and 4$\times$10$^{5}$ cm$^{-3}$ and kinetic temperatures of 140 K, 30 K, and 80 K for C1, C2, and C3, respectively. The spatially resolved maps confirm that the colder and high-density condensations C2 and C3, which peak in the 70-85 km s$^{-1}$ velocity range, are embedded in a more diffuse and warmer gas (C1). The larger-scale structure of the Sgr B2 region shows a hole at 40-50 km s$^{-1}$ that is likely due to a small cloud that shocked the Sgr B2 region and is spatially related with a massive cloud at 60-80 km s$^{-1}$. We propose that the impacting small cloud sequentially triggered the formation of Sgr B2(M), (N), and (S) and the condensations in G+0.693-0.027 during its passage. Based on the analysis of the masses of the two condensations and on the virial parameters, C2 might expand, while C3 might further fragment or collapse.

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The first detection of SiC$_2$ in the interstellar medium

We report the first detection of SiC$_2$ in the interstellar medium. The molecule was identified through six rotational transitions toward G\,+0.693$-$0.027, a molecular cloud located in the Galactic center. The detection is based on a line survey carried out with the GBT, the Yebes 40m, and the IRAM 30m telescopes covering a range of frequencies from 12 to 276 GHz. We fit the observed spectra assuming local thermodynamic equilibrium and derive a column density of ($1.02\pm0.04)\times10^{13}$ cm$^{-2}$, which gives a fractional abundance of $7.5\times10^{-11}$ with respect to H$_2$, and an excitation temperature of $5.9\pm0.2$ K. We conclude that SiC$_2$ can be formed in the shocked gas by a reaction between the sputtered atomic silicon and C$_2$H$_2$, or it can be released directly from the dust grains due to disruption. We also search for other Si-bearing molecules and detect eight rotational transitions of SiS and four transitions of Si$^{18}$O. The derived fractional abundances are $3.9\times10^{-10}$ and $2.1\times10^{-11}$, respectively. All Si-bearing species toward G\,+0.693$-$0.027 show fractional abundances well below what is typically found in late-type evolved stars.

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Rotation-tunneling spectrum and astrochemical modeling of dimethylamine, CH$_3$NHCH$_3$, and searches for it in space

Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunneling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to $J = 61$ and $K_a = 21$, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array toward the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693$-$0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report nondetections of dimethylamine toward the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693$-$0.027 which imply that dimethylamine is at least 14, 4.5 and 39 times less abundant than methylamine toward these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modeled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

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A high-resolution spectroscopic analysis of aminoacrylonitrile and an interstellar search towards G+0.693

Cyanides, ranging from three carbon atoms to PAHs, and alkenyl compounds are abundant in the interstellar medium (ISM). Aminoacrylonitrile (3-Amino-2-propenenitrile, H$_{2}$N-CH=CH-CN), an alkenyl cyanide, thus represents a promising candidate for new interstellar detection. A comprehensive spectroscopic laboratory investigation of aminoacrylonitrile in its rotational ground vibrational state has been herein performed. The measurements carried out up to the THz regime made it possible to generate a precise set of reliable rest frequencies for its search in space up to sub-millimetre wavelengths. The $Z$-aminoacrylonitrile ($Z$-apn) isomer spectrum has been recorded employing a source-modulated sub-millimetre spectrometer, from 80 GHz to 1 THz. A combination of Doppler and sub-Doppler measurement regimes allowed to record 600 new lines. The collected data have enabled the characterisation of a set of spectroscopic parameters up to decic centrifugal distortion constants. The catalogue generated from the improved spectral data has been used for the search of $Z$-apn in the spectral survey of the G+0.693-0.027 molecular cloud located in the central molecular zone, in the proximity of the Galactic centre.

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Amides inventory towards the G+0.693-0.027 molecular cloud

Interstellar amides have attracted significant attentions as they are potential precursors for a wide variety of organics essential to life. However, our current understanding of their formation in space is heavily based on observations in star-forming regions and hence the chemical networks lack the constraints on their early origin. In this work, unbiased sensitive spectral surveys with IRAM 30m and Yebes 40m telescopes are used to systematically study a number of amides towards a quiescent Galactic Centre molecular cloud, G+0.693-0.027. We report the first detection of acetamide (CH3C(O)NH2) and trans-N-methylformamide (CH3NHCHO) towards this cloud. In addition, with the wider frequency coverage of the survey, we revisited the detection of formamide (NH2CHO) and urea (carbamide; NH2C(O)NH2), which had been reported previously towards G+0.693-0.027. Our results are compared with those present in the literature including recent laboratory experiments and chemical models. We find constant abundance ratios independently of the evolutionary stages, suggesting that amides related chemistry is triggered in early evolutionary stages of molecular cloud and remain unaffected by the warm-up phase during the star formation process. Although a correlation between more complex amides and NH2CHO have been suggested, alternative formation routes involving other precursors such as acetaldehyde (CH3CHO), methyl isocyanate (CH3NCO) and methylamine (CH3NH2) may also contribute to the production of amides. Observations of amides together with these species towards a larger sample of sources can help to constrain the amide chemistry in the interstellar medium.

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On the thermal structure of the proto-Super Star Cluster 13 in NGC 253

Using high angular resolution ALMA observations ($0.02^{\prime\prime}\approx0.34$ pc), we study the thermal structure and kinematics of the proto super star cluster $13$ in the central region of NGC253 through their continuum and vibrationally excited HC$_3$N emission from $J=24-23$ and $J=26-25$ lines arising from vibrational states up to $v_4=1$. We have carried 2D-LTE and non-local radiative transfer modelling of the radial profile of the HC$_3$N and continuum emission in concentric rings of $0.1$ pc width. From the 2D-LTE analysis, we found a Super Hot Core (SHC) of $1.5$ pc with very high vibrational temperatures ($>500$ K), and a jump in the radial velocity ($21$ km s$^{-1}$) in the SE-NW direction. From the non-local models, we derive the HC$_3$N column density, H$_2$ density and dust temperature ($T_\text{dust}$) profiles. Our results show that the thermal structure of the SHC is dominated by the greenhouse effect due to the high dust opacity in the IR, leading to an overestimation of the LTE $T_\text{dust}$ and its derived luminosity. The kinematics and $T_\text{dust}$ profile of the SHC suggest that star formation was likely triggered by a cloud-cloud collision. We compare proto-SSC $13$ to other deeply embedded star-forming regions, and discuss the origin of the $L_\text{IR}/M_{\text{H}_2}$ excess above $\sim100$ L$_\odot$ M$_\odot^{-1}$ observed in (U)LIRGs.

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Toward the limits of complexity of interstellar chemistry: Rotational spectroscopy and astronomical search for n- and i-butanal

In recent times, large organic molecules of exceptional complexity have been found in diverse regions of the interstellar medium. In this context, we aim to provide accurate frequencies of the ground vibrational state of two key aliphatic aldehydes, n-butanal and its branched-chain isomer, i-butanal, to enable their eventual detection in the interstellar medium. We employ a frequency modulation millimeter-wave absorption spectrometer to measure the rotational features of n- and i-butanal. We use the spectral line survey ReMoCA performed with the Atacama Large Millimeter/submillimeter Array to search for n- and i-butanal toward the star-forming region Sgr B2(N). We also search for both aldehydes toward the molecular cloud G+0.693-0.027 with IRAM 30 m and Yebes 40 m observations. Several thousand rotational transitions belonging to the lowest-energy conformers have been assigned in the laboratory spectra up to 325 GHz. A precise set of the relevant rotational spectroscopic constants has been determined for each structure. We report non-detections of n- and i-butanal toward both sources, Sgr B2(N1S) and G+0.693-0.027. We find that n- and i-butanal are at least 2-6 and 6-18 times less abundant than acetaldehyde toward Sgr B2(N1S), respectively, and that n-butanal is at least 63 times less abundant than acetaldehyde toward G+0.693-0.027. Comparison with astrochemical models indicates good agreement between observed and simulated abundances (where available). Grain-surface chemistry appears sufficient to reproduce aldehyde ratios in G+0.693-0.027; gas-phase production may play a more active role in Sgr B2(N1S). Our astronomical results indicate that the family of interstellar aldehydes in the Galactic center region is characterized by a drop of one order of magnitude in abundance at each incrementation in the level of molecular complexity.

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Deuterium fractionation as a multi-phase component tracer in the Galactic Centre

The Central Molecular Zone (CMZ) contains most of the mass of our Galaxy but its star formation rate is one order of magnitude lower than in the Galactic disc. This is likely related to the fact that the bulk of the gas in the CMZ is in a warm ($>$100 K) and turbulent phase with little material in the pre-stellar phase. We present in this Letter observations of deuterium fractionation (D/H ratios) of HCN, HNC, HCO$^{+}$, and N$_{2}$H$^{+}$ towards the CMZ molecular cloud G+0.693-0.027. These observations clearly show, for the first time, the presence of a colder, denser, and less turbulent narrow component, with a line width of $\sim$9 km s$^{-1}$, in addition to the warm, less dense and turbulent broad component with a line width of $\sim$20 km s$^{-1}$. The very low D/H ratio $\le$6$\times$10$^{-5}$ for HCO$^{+}$ and N$_{2}$H$^{+}$, close to the cosmic value ($\sim$2.5$\times$10$^{-5}$), and the high D/H ratios $>$4$\times$10$^{-4}$ for HCN and HNC derived for the broad component, confirm the presence of high-temperatures deuteration routes for nitriles. For the narrow component we have derived D/H ratios $>$10$^{-4}$ and excitation temperatures of $7$ K for all molecules, suggesting kinetic temperatures $\le$30 K and H$_2$ densities $\ge$5$\times$10$^{4}$ cm$^{-3}$, at least one order of magnitude larger than for the broad component. The method presented in this Letter allows to identify clouds on the verge of star formation, i.e. under pre-stellar conditions, towards the CMZ. This method can also be used for the identification of such clouds in external galaxies.

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Radio emission in a nearby ultracool dwarf binary: a multi-frequency study

The substellar triple system VHS J125601.92$-$125723.9 is composed by an equal-mass M7.5 brown dwarf binary and a L7 low-mass substellar object. In this work, we aim to identify the origin of the radio emission occurring in the central binary of VHS 1256$-$1257 while discussing the expected mechanisms involved in the radio emission of ultracool dwarfs (UCDs). We observed this system with the Karl G. Jansky Very Large Array, the European very-long-baseline interferometry (VLBI) Network, the enhanced Multi Element Remotely Linked Interferometer Network, the NOrthern Extended Millimeter Array, and the Atacama Large Millimetre Array at frequencies ranging from 5 GHz up to 345 GHz in several epochs during 2017, 2018, and 2019. We have found radio emission at 6 GHz and 33 GHz coincident with the expected position of the central binary of VHS~1256$-$1257. The Stokes I density flux detected were 73 $\pm$ 4 $μ$Jy and 83 $\pm$ 13 $μ$Jy, respectively, with no detectable circular polarisation or pulses. No emission is detected at higher frequencies (230 GHz and 345 GHz) nor at 5 GHz with VLBI arrays. The emission appears to be stable over almost 3 years at 6 GHz. To explain the constraints obtained both from the detections and non-detections we considered multiple scenarios including thermal and non-thermal emission, and different contributions from each component of the binary. Our results can be well explained by non-thermal gyrosynchrotron emission originating at radiation belts with a low plasma density (n$_e$ = 300$-$700 cm$^{-3}$), a moderate magnetic field strength (B $\approx$ 140 G), and an energy distribution of electrons following a power-law ($d N / d E \propto E^{- δ}$) with $δ$ fixed at 1.36. These radiation belts would need to be present in both components and also be viewed equatorially.

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Negative and Positive Feedback from a Supernova Remnant with SHREC: A detailed Study of the Shocked Gas in IC443

Supernova remnants (SNRs) contribute to regulate the star formation efficiency and evolution of galaxies. As they expand into the interstellar medium (ISM), they transfer vast amounts of energy and momentum that displace, compress and heat the surrounding material. Despite the extensive work in galaxy evolution models, it remains to be observationally validated to what extent the molecular ISM is affected by the interaction with SNRs. We use the first results of the ESO-ARO Public Spectroscopic Survey SHREC, to investigate the shock interaction between the SNR IC443 and the nearby molecular clump G. We use high sensitivity SiO(2-1) and H$^{13}$CO$^+$(1-0) maps obtained by SHREC together with SiO(1-0) observations obtained with the 40m telescope at the Yebes Observatory. We find that the bulk of the SiO emission is arising from the ongoing shock interaction between IC443 and clump G. The shocked gas shows a well ordered kinematic structure, with velocities blue-shifted with respect to the central velocity of the SNR, similar to what observed toward other SNR-cloud interaction sites. The shock compression enhances the molecular gas density, n(H$_2$), up to $>$10$^5$ cm$^{-3}$, a factor of >10 higher than the ambient gas density and similar to values required to ignite star formation. Finally, we estimate that up to 50\% of the momentum injected by IC443 is transferred to the interacting molecular material. Therefore the molecular ISM may represent an important momentum carrier in sites of SNR-cloud interactions.

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The trans/cis ratio of formic, HCOOH, and thioformic, HC(O)SH, acids in the Interstellar Medium

We studied theoretically the cis-trans isomerization reactions of two astrophysically relevant acids, formic acid (HCOOH) and thioformic acid (HC(O)SH), where the latter has recently been discovered in space. We also searched for these molecules towards the hot core G31.41+0.31 to compare their abundances with the expected theoretical isomerization results. Our results demonstrate that these isomerizations are viable in the conditions of the ISM due to ground-state tunneling effects, which allow the system to reach the thermodynamic equilibrium at moderately low temperatures. At very low temperatures (Tkin 10 K), the reaction rate constants for the cis to trans isomerizations are very small, which implies that the cis isomers should not be formed under cold ISM conditions. This is in disagreement with observations of the cis/trans isomers of HCOOH in cold cores where the cis isomer is found to be 5-6% the trans isomer. At high temperatures (150-300 K), our theoretical data not only match the observed behaviour of the trans/cis abundance ratios for HCOOH (the cis form is undetected), but they support our tentative detection of the trans and, for the first time in the insterstellar medium, of the cis isomer of HC(O)SH towards the hot molecular core G31.41+0.31 (with a measured trans/cis abundance ratio of 3.7). While the trans/cis ratio for HC(O)SH in the ISM depends on the relative stability of the isomers, the trans/cis ratio for HCOOH cannot be explained by isomerization, and it is determined by other competitive chemical processes

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First detection of C$_2$H$_5$NCO in the ISM and search of other isocyanates towards the G+0.693-0.027 molecular cloud

Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated isocyanic acid (H$_2$NCO$^+$) and methyl isocyanate (CH$_3$NCO). The molecular cloud G+0.693-0.027, located in the Galactic Centre, represents an excellent candidate to search for new isocyanates since it exhibits high abundances of the simplest ones, HNCO and CH$_3$NCO. After CH$_3$NCO, the next complex isocyanates are ethyl isocyanate (C$_2$H$_5$NCO) and vinyl isocyanate (C$_2$H$_3$NCO). Their detection in the ISM would enhance our understanding of the formation of these compounds in space. We have detected C$_2$H$_5$NCO and H$_2$NCO$^+$ towards G+0.693-0.027 (the former for the first time in the interstellar medium) with molecular abundances of (4.7$-$7.3)$\times$10$^{-11}$ and (1.0$-$1.5)$\times$10$^{-11}$, respectively. A ratio CH$_3$NCO / C$_2$H$_5$NCO = 8$\pm$1 is obtained; therefore the relative abundance determined for HNCO:CH$_3$NCO:C$_2$H$_5$NCO is 1:1/55:1/447, which implies a decrease by more than one order of magnitude going progressively from HNCO to CH$_3$NCO and to C$_2$H$_5$NCO. This is similar to what has been found for e.g. alcohols and thiols and suggests that C$_2$H$_5$NCO is likely formed on the surface of dust grains. In addition, we have obtained column density ratios of HNCO / NCO > 269, HNCO / H$_2$NCO$^+$ $\sim$ 2100 and C$_2$H$_3$NCO / C$_2$H$_5$NCO~<~4. A comparison of the Methyl~/~Ethyl ratios for isocyanates (-NCO), alcohols (-OH), formiates (HCOO-), nitriles (-CN) and thiols (-SH) is performed and shows that ethyl-derivatives may be formed more efficiently for the N-bearing molecules than for the O- and S-bearing molecules.

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Detection of the cyanomidyl radical (HNCN): a new interstellar species with the NCN backbone

We report here the first detection in the interstellar medium of the cyanomidyl radical (HNCN). Using the Yebes 40m and the IRAM 30m telescopes, we have targeted the doublets of the $N$=2$-$1, 4$-$3, 5$-$4, 6$-$5, and 7$-$6 transitions of HNCN toward the molecular cloud G+0.693-0.027. We have detected three unblended lines of HNCN, these are the $N$=6$-$5 doublet and one line of the $N$=4$-$3 transition. Additionally we present one line of the $N$=5$-$4 transition partially blended with emission from other species. The Local Thermodynamic Equilibrium best fit to the data gives a molecular abundance of (0.91$\pm$0.05)$\times$10$^{-10}$ with respect to H$_2$. The relatively low abundance of this species in G+0.693-0.027, and its high reactivity, suggest that HNCN is possibly produced by gas-phase chemistry. Our work shows that this highly reactive molecule is present in interstellar space, and thus it represents a plausible precursor of larger prebiotic molecules with the NCN backbone such as cyanamide (NH$_2$CN), carbodiimide (HNCNH) and formamidine (NH$_2$CHNH).

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On the effects of UV photons/X-rays on the chemistry of the Sgr B2 cloud

The lines of HOC$^+$, HCO and CO$^+$ are considered good tracers of photon-dominated regions (PDRs) and X-ray dominated regions. We study these tracers towards regions of the Sgr B2 cloud selected to be affected by different heating mechanisms. We find the lowest values of the column density ratios of HCO$^+$ versus HOC$^+$, HCO and CO$^+$ in dense HII gas, where UV photons dominate the heating and chemistry of gas. HOC$^+$, HCO and CO$^+$ abundances and the above ratios are compared with those of chemical modeling, finding that high temperature chemistry, a cosmic-ray ionization rate of 10$^{-16}$ s$^{-1}$ and timescales $>$10$^{5.0}$ years explain well the HOC$^+$ abundances in quiescent Sgr B2 regions, while shocks are also needed to explain the highest HCO abundances derived for these regions. CO$^+$ is mainly formed in PDRs since the highest CO$^+$ abundances of $\sim$(6-10)$\times$10$^{-10}$ are found in HII regions with electron densities $>$540 cm$^{-3}$ and that CO$^+$ emission is undetected in quiescent gas. Between the ratios, the HCO$^+$/HCO ratio is sensitive to the electron density as it shows different values in dense and diffuse HII regions. We compare SiO J=2-1 emission maps of Sgr B2 with X-ray maps from 2004 and 2012. One known spot shown on the 2012 X-ray map is likely associated with molecular gas at velocities of 15-25 km s$^{-1}$. We also derive the X-ray ionization rate of $\sim$10$^{-19}$ s$^{-1}$ for Sgr B2 regions pervaded by X-rays in 2004, which is quite low to affect the chemistry of the molecular gas.

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Spectral Line Identification and Modelling (SLIM) in the MAdrid Data CUBe Analysis (MADCUBA) package: An interactive software for data cube analysis

In this paper we present the detailed formalism at the core of the Spectral Line Identification and Modelling (SLIM) within the MAdrid Data CUBe Analysis (MADCUBA) package and their main data handling functionalities. These tools have been developed to visualize, analyze and model large spectroscopic data cubes. We present the highly interactive on-the-fly visualization and modelling tools of MADCUBA and SLIM, which includes an stand-alone spectroscopic database. The parameters stored therein are used to solve the full radiative transfer equation under Local Thermodynamic Equilibrium (LTE). SLIM provides tools to generate synthetic LTE model spectra based on input physical parameters of column density, excitation temperature, velocity, line width and source size. SLIM also provides an automatic fitting algorithm to obtain the physical parameters (with their associated errors) better fitting the observations. Synthetic spectra can be overlayed in the data cubes/spectra to easy the task of multi-molecular line identification and modelling.We present the Java-based MADCUBA and its internal module SLIM packages which provide all the necessary tools for manipulation and analysis of spectroscopic data cubes. We describe in detail the spectroscopic fitting equations and make use of this tool to explore the breaking conditions and implicit errors of commonly used approximations in the literature. Easy-to-use tools like MADCUBA allow the users to derive the physical information from spectroscopic data without the need of resourcing to simple approximations. SLIM allows to use the full radiative transfer equation, and to interactively explore the space of physical parameters and associated uncertainties from observational data.

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A rotating fast bipolar wind and disk system around the B[e]-type star MWC 922

We present interferometric observations with the Atacama Large Millimeter Array (ALMA) of the free-free continuum and recombination line emission at 1 and 3mm of the "Red Square Nebula" surrounding the B[e]-type star MWC922. The unknown distance to the source is usually taken to be d=1.7-3 kpc. The unprecedented angular resolution (up to ~0.02arcsec) and exquisite sensitivity of these data unveil, for the first time, the structure and kinematics of the emerging, compact ionized region at its center. We imaged the line emission of H30a and H39a, previously detected with single-dish observations, as well as of H51epsilon, H55gamma, and H63delta, detected for the first time in this work. The line emission is seen over a full velocity range of ~180 km/s arising in a region of diameter <0.14arcsec (less than a few hundred au) in the maser line H30a, which is the most intense transition reported here. We resolve the spatio-kinematic structure of a nearly edge-on disk rotating around a central mass of ~10Msun (d=1.7 kpc) or ~18Msun (d=3 kpc), assuming Keplerian rotation. Our data also unveil a fast (~100 km/s) bipolar ejection (a jet?) orthogonal to the disk. In addition, a slow (<15km/s) wind may be lifting off the disk. Both, the slow and the fast winds are found to be rotating in a similar manner to the ionized layers of the disk. This represents the first empirical proof of rotation in a bipolar wind expanding at high velocity (~100 km/s). (abridged)

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Herschel water maps towards the vicinity of the black hole Sgr A*

Aims: We study the spatial distribution and kinematics of water emission in a ~64 pc$^2$ region of the Galactic Center (GC) around Sgr A*. We also analyze the water excitation to derive the physical conditions and water abundances in the CND and the `quiescent clouds'. Methods: We presented the integrated intensity maps of the ortho 1$_{10}-1_{01}$, and para 2$_{02}-1_{11}$ and 1$_{11}-0_{00}$ water transitions observed with the HIFI instrument on board Herschel. To study the water excitation we used ground state ortho and para H$_2^{18}$O transitions. In our study, we also used SPIRE continuum measurements of the CND. Using a non-LTE radiative transfer code, the water line profiles and dust continuum were modeled. We also used a rotating ring model to reproduce the CND kinematics represented by the PV diagram. Results: We identify the water emission arising from the CND, the Western Streamer, and the 20 and 50 km s$^{-1}$ clouds. The ortho water maps show absorption structures in the range of [-220,10] km s$^{-1}$. The PV diagram shows that the 2$_{02}-1_{11}$ H$_2$O emission traces the CND. We derive high X$_{H_2O}$ of $\sim$(0.1-1.3)$\times$10$^{-5}$, V$_t$ of 14-23 km s$^{-1}$ and T$_d$ of 15-45 K for the CND, and the lower X$_{\rm H_2O}$ of 4$\times$10$^{-8}$ and V$_t$ of 9 km s$^{-1}$ for the 20 km s$^{-1}$ cloud. Collisional excitation and dust effects are responsible for the water excitation in the southwest lobe of the CND and the 20 km s$^{-1}$ cloud, whereas only collisions can account for the water excitation in the northeast lobe of the CND. We propose that the water vapor in the CND is caused by grain sputtering by shocks of 10-20 km s$^{-1}$, with some contribution of high temperature and cosmic-ray chemistries plus a PDR chemistry. The low X$_{\rm H_2O}$ derived for the 20 km s$^{-1}$ cloud could be partially a consequence of the water freeze-out on grains.

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First detection of the pre-biotic molecule glycolonitrile (HOCH2CN) in the interstellar medium

Theories of a pre-RNA world suggest that glycolonitrile (HOCH$_2$CN) is a key species in the process of ribonucleotide assembly, which is considered as a molecular precursor of nucleic acids. In this Letter, we report the first detection of this pre-biotic molecule in the interstellar medium (ISM) by using ALMA data obtained at frequencies between 86.5$\,$GHz and 266.5$\,$GHz toward the Solar-type protostar IRAS16293-2422 B. A total of 15 unblended transitions of HOCH$_2$CN were identified. Our analysis indicates the presence of a cold (T$\rm _{ex}$=24$\pm$8$\,$K) and a warm (T$\rm _{ex}$=158$\pm$38$\,$K) component meaning that this molecule is present in both the inner hot corino and the outer cold envelope of IRAS16293 B. The relative abundance with respect to H$_2$ is (6.5$\pm$0.6)$\times$10$^{-11}$ and $\geq$(6$\pm$2)$\times$10$^{-10}$ for the warm and cold components respectively. Our chemical modelling seems to underproduce the observed abundance for both the warm and cold component under various values of the cosmic-ray ionisation rate ($ζ$). Key gas phase routes for the formation of this molecule might be missing in our chemical network.

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