arXiv subjects

J. Martín-Pintado

Publications and source records attributed to J. Martín-Pintado.

At least 37 records · Page 2Linked to original sources

arXiv2018

Abundant Z-cyanomethanimine in the interstellar medium: paving the way to the synthesis of adenine

We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Center quiescent molecular cloud G+0.693. The Z-isomer has a column density of (2.0$\pm$0.6)$\times$10$^{14}$ cm$^{-2}$ and an abundance of 1.5$\times$10$^{-9}$. The relative abundance ratio between the isomers is [Z/E]$\sim$6. This value cannot be explained by the two chemical formation routes previously proposed (gas-phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed [Z/E] ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130$-$210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM.

astro-ph.GA↗

arXiv2018

Complex organic molecules in the Galactic Centre: the N-bearing family

We present an unbiased spectral line survey toward the Galactic Centre (GC) quiescent giant molecular cloud (QGMC), G+0.693 using the GBT and IRAM 30$\,$ telescopes. Our study highlights an extremely rich organic inventory of abundant amounts of nitrogen (N)-bearing species in a source without signatures of star formation. We report the detection of 17 N-bearing species in this source, of which 8 are complex organic molecules (COMs). A comparison of the derived abundances relative to H$_2$ is made across various galactic and extragalactic environments. We conclude that the unique chemistry in this source is likely to be dominated by low-velocity shocks with X-rays/cosmic rays also playing an important role in the chemistry. Like previous findings obtained for O-bearing molecules, our results for N-bearing species suggest a more efficient hydrogenation of these species on dust grains in G+0.693 than in hot cores in the Galactic disk, as a consequence of the low dust temperatures coupled with energetic processing by X-ray/cosmic ray radiation in the GC.

astro-ph.GA↗

arXiv2018

Study of diffuse HII regions potentially forming part of the gas streams around Sgr A*

We present a study of diffuse extended ionised gas toward three clouds located in the Galactic Centre (GC). One line of sight (LOS) is toward the 20 km s$^{-1}$ cloud (LOS$-$0.11) in the Sgr A region, another LOS is toward the 50 km s$^{-1}$ cloud (LOS$-$0.02), also in Sgr A, while the third is toward the Sgr B2 cloud (LOS+0.693). The emission from the ionised gas is detected from H$nα$ and H$mβ$ radio recombination lines (RRLs). He$nα$ and He$mβ$ RRL emission is detected with the same $n$ and $m$ as those from the hydrogen RRLs only toward LOS+0.693. RRLs probe gas with positive and negative velocities toward the two Sgr A sources. The H$mβ$ to H$nα$ ratios reveal that the ionised gas is emitted under local thermodynamic equilibrium conditions in these regions. We find a He to H mass fraction of 0.29$\pm$0.01 consistent with the typical GC value, supporting the idea that massive stars have increased the He abundance compared to its primordial value. Physical properties are derived for the studied sources. We propose that the negative velocity component of both Sgr A sources is part of gas streams considered previously to model the GC cloud kinematics. Associated massive stars with what are presumably the closest HII regions to LOS$-$0.11 (positive velocity gas), LOS$-$0.02 and LOS+0.693 could be the main sources of UV photons ionising the gas. The negative velocity components of both Sgr A sources might be ionised by the same massive stars, but only if they are in the same gas stream.

astro-ph.GA↗

arXiv2017

Phosphorus-bearing molecules in the Galactic Center

Phosphorus (P) is one of the essential elements for life due to its central role in biochemical processes. Recent searches have shown that P-bearing molecules (in particular PN and PO) are present in star-forming regions, although their formation routes remain poorly understood. In this Letter, we report observations of PN and PO towards seven molecular clouds located in the Galactic Center, which are characterized by different types of chemistry. PN is detected in five out of seven sources, whose chemistry is thought to be shock-dominated. The two sources with PN non-detections correspond to clouds exposed to intense UV/X-rays/cosmic-ray radiation. PO is detected only towards the cloud G+0.693$-$0.03, with a PO/PN abundance ratio of $\sim$1.5. We conclude that P-bearing molecules likely form in shocked gas as a result of dust grain sputtering, while are destroyed by intense UV/X-ray/cosmic ray radiation.

astro-ph.GA↗

arXiv2017

First detection of the 448 GHz H2O transition in space

We present the first detection of the ortho-H2O 4_23-3_30 transition at 448 GHz in space. We observed this transition in the local (z = 0.010) luminous infrared (IR) galaxy ESO 320-G030 (IRAS F11506-3851) using the Atacama Large Millimeter/submillimeter Array (ALMA). The water 4_23-3_30 emission, which originates in the highly obscured nucleus of this galaxy, is spatially resolved over a region of ~65 pc in diameter and shows a regular rotation pattern compatible with the global molecular and ionized gas kinematics. The line profile is symmetric and well fitted by a Gaussian with an integrated flux of 37.0 +- 0.7 Jy km s-1 . Models predict this water transition as a potential collisionally excited maser transition. On the contrary, in this galaxy, we find that the 4_23-3_30 emission is primarily excited by the intense far-IR radiation field present in its nucleus. According to our modeling, this transition is a probe of deeply buried galaxy nuclei thanks to the high dust optical depths (tau_100μm > 1, N_H > 1e24 cm-2) required to efficiently excite it.

astro-ph.GA↗

arXiv2017

Detection of methylisocyanate (CH3NCO) in a solar-type protostar

We report the detection of the prebiotic molecule CH3NCO in a solar-type protostar, IRAS16293-2422 B. A significant abundance of this species on the surface of the comet 67P/Churyumov-Gerasimenko has been proposed, and it has recently been detected in hot cores around high-mass protostars. We observed IRAS16293-2422 B with ALMA in the 90 GHz to 265 GHz range, and detected 8 unblended transitions of CH3NCO. From our Local Thermodynamic Equilibrium analysis we derived an excitation temperature of 110+-19 K and a column density of (4.0+-0.3)x10^15 cm^-2 , which results in an abundance of <=(1.4+-0.1)x10^-10 with respect to molecular hydrogen. This implies a CH3NCO/HNCO and CH3NCO/NH2CHO column density ratios of ~0.08. Our modelling of the chemistry of CH3NCO suggests that both ice surface and gas phase formation reactions of this molecule are needed to explain the observations.

astro-ph.SR↗

arXiv2016

On the chemical ladder of esters. Detection and formation of ethyl formate in the W51 e2 hot molecular core

The detection of organic molecules with increasing complexity and potential biological relevance is opening the possibility to understand the formation of the building blocks of life in the interstellar medium. One of the families of molecules with astrobiological interest are the esters, whose simplest member, methyl formate, is rather abundant in star-forming regions. The next step in the chemical complexity of esters is ethyl formate, C$_2$H$_5$OCHO. Only two detections of this species have been reported so far, which strongly limits our understanding of how complex molecules are formed in the interstellar medium. We have searched for ethyl formate towards the W51 e2 hot molecular core, one of the most chemically rich sources in the Galaxy and one of the most promising regions to study prebiotic chemistry, especially after the recent discovery of the P$-$O bond, key in the formation of DNA. We have analyzed a spectral line survey towards the W51 e2 hot molecular core, which covers 44 GHz in the 1, 2 and 3 mm bands, carried out with the IRAM 30m telescope. We report the detection of the trans and gauche conformers of ethyl formate. A Local Thermodynamic Equilibrium analysis indicates that the excitation temperature is 78$\pm$10 K and that the two conformers have similar source-averaged column densities of (2.0$\pm$0.3)$\times$10$^{16}$ cm$^{-2}$ and an abundance of $\sim$10$^{-8}$. We compare the observed molecular abundances of ethyl formate with different competing chemical models based on grain surface and gas-phase chemistry. We propose that grain-surface chemistry may have a dominant role in the formation of ethyl formate (and other complex organic molecules) in hot molecular cores, rather than reactions in the gas phase.

astro-ph.GA↗

arXiv2016

First detections of the key prebiotic molecule PO in star-forming regions

Phosphorus is a crucial element in biochemistry, especially the P-O bond, which is key for the formation of the backbone of the deoxyribonucleic acid. So far, PO has only been detected towards the envelope of evolved stars, and never towards star-forming regions. We report the first detections of PO towards two massive star-forming regions, W51 e1/e2 and W3(OH), using data from the IRAM 30m telescope. PN has also been detected towards the two regions. The abundance ratio PO/PN is 1.8 and 3 for W51 and W3(OH), respectively. Our chemical model indicates that the two molecules are chemically related and are formed via gas-phase ion-molecule and neutral-neutral reactions during the cold collapse. The molecules freeze out onto grains at the end of the collapse and desorb during the warm-up phase once the temperature reaches 35 K. Similar abundances of the two species are expected during a period of 5x10^{4} yr at the early stages of the warm-up phase, when the temperature is in the range 35-90 K. The observed molecular abundances of 10^{-10} are predicted by the model if a relatively high initial abundance of 5x10^{-9} of depleted phosphorus is assumed.

astro-ph.GA↗

arXiv2016

The unbearable opaqueness of Arp 220

We explore the potential of imaging vibrationally excited molecular emission at high angular resolution to better understand the morphology and physical structure of the dense gas in Arp~220 and to gain insight into the nature of the nuclear powering sources. Vibrationally excited emission of HCN is detected in both nuclei with a very high ratio relative to the total $L_{FIR}$, higher than in any other observed galaxy and well above what is observed in Galactic hot cores. HCN $v_2=1f$ is observed to be marginally resolved in $\sim60\times50$~pc regions inside the dusty $\sim100$~pc sized nuclear cores. Its emission is centered on our derived individual nuclear velocities based on HCO$^+$ emission ($V_{WN}=5342\pm4$ and $V_{EN}=5454\pm8$~\kms, for the western and eastern nucleus, respectively). With virial masses within $r\sim25-30$~pc based on the HCN~$v_2=1f$ line widths, we estimate gas surface densities (gas fraction $f_g=0.1$) of $3\pm0.3\times10^4~M_\odot~\rm pc^{-2}$ (WN) and $1.1\pm0.1\times10^4~M_\odot~\rm pc^{-2}$ (EN). The $4-3/3-2$ flux density ratio could be consistent with optically thick emission, which would further constrain the size of the emitting region to $>15$~pc (EN) and $>22$~pc (WN). The absorption systems that may hide up to $70\%$ of the HCN and HCO$^+$ emission are found at velocities of $-50$~\kms~(EN) and $6$, $-140$, and $-575$~\kms (WN) relative to velocities of the nuclei. Blueshifted absorptions are the evidence of outflowing motions from both nuclei. The bright vibrational emission implies the existence of a hot dust region radiatively pumping these transitions. We find evidence of a strong temperature gradient that would be responsible for both the HCN $v_2$ pumping and the absorbed profiles from the vibrational ground state as a result of both continuum and self-absorption by cooler foreground gas.

astro-ph.GA↗

arXiv2015

Short- and long-term variability of young stars in the Orion Nebula Cluster and Molecular Cloud

We used the Very Large Array to carry out a multi-epoch radio continuum monitoring of the Orion Nebula Cluster and Orion Molecular Cloud. Our observations reveal the presence of 19 sources. With the exception of the sources BN and C the sources show variability between the different epochs. We have found tentative evidence of variability in the massive object related with source I. Our observations also confirm radio flux density variations of a factor >2 on timescales of hours to days in 5 sources. One of these flaring sources, OHC-E, has been detected for the first time. We conclude that the radio emission arises from: i) highly-variable non-thermal gyrosynchrotron emission produced by electrons accelerated in the magnetospheres of pre-main sequence stars; ii) thermal emission from ionized gas and/or heated dust around massive objects and proplyds. Combining our sample with other radio monitoring and a X-ray catalog, we have studied the properties of 51 radio/X-ray stars. We have found severals hints of a direct relation between the X-ray activity and the mechanisms responsible for (at least some fraction of) the radio emission. We have estimated a radio flaring rate of 0.14 flares day-1 in the densest stellar cluster of the region, suggesting that radio flares from young stars are more common events than previously thought.

astro-ph.SR↗

arXiv2014

High-lying OH absorption, [C II] deficits, and extreme $L_{\mathrm{FIR}}/M_{\mathrm{H2}}$ ratios in galaxies

Herschel/PACS observations of 29 local (Ultra-)Luminous Infrared Galaxies, including both starburst and AGN-dominated sources as diagnosed in the mid-infrared/optical, show that the equivalent width of the absorbing OH 65 um Pi_{3/2} J=9/2-7/2 line (W_{eq}(OH65)) with lower level energy E_{low}~300 K, is anticorrelated with the [C ii]158 um line to far-infrared luminosity ratio, and correlated with the far-infrared luminosity per unit gas mass and with the 60-to-100 um far-infrared color. While all sources are in the active L_{IR}/M_{H2}>50 Lsun/Msun mode as derived from previous CO line studies, the OH65 absorption shows a bimodal distribution with a discontinuity at L_{FIR}/M_{H2}~100 Lsun/Msun. In the most buried sources, OH65 probes material partially responsible for the silicate 9.7 um absorption. Combined with observations of the OH 71 um Pi_{1/2} J=7/2-5/2 doublet (E_{low}~415 K), radiative transfer models characterized by the equivalent dust temperature, Tdust, and the continuum optical depth at 100 um, tau_{100}, indicate that strong [C ii]158 um deficits are associated with far-IR thick (tau_{100}>~0.7, N_{H}>~10^{24} cm^{-2}), warm (Tdust>~60 K) structures where the OH 65 um absorption is produced, most likely in circumnuclear disks/tori/cocoons. With their high L_{FIR}/M_{H2} ratios and columns, the presence of these structures is expected to give rise to strong [C ii] deficits. W_{eq}(OH65) probes the fraction of infrared luminosity arising from these compact/warm environments, which is >~30-50% in sources with high W_{eq}({OH65}). Sources with high W_{eq}({OH65}) have surface densities of both L_{IR} and M_{H2} higher than inferred from the half-light (CO or UV/optical) radius, tracing coherent structures that represent the most buried/active stage of (circum)nuclear starburst-AGN co-evolution.

astro-ph.GA↗

arXiv2014

3 mm spectral line survey of two lines of sight toward two typical cloud complexes in the Galactic Center

We present the results of two Mopra 3-mm spectral line surveys of the Lines of Sight (LOS) toward the Galactic Center (GC) molecular complexes Sgr B2 (LOS+0.693) and Sgr A (LOS-0.11). The spectra covered the frequency ranges of ~77-93 GHz and ~105-113 GHz. We have detected 38 molecular species and 25 isotopologues. The isotopic ratios derived from column density ratios are consistent with the canonical values, indicating that chemical isotopic fractionation and/or selective photodissociation can be considered negligible (<10%) for the GC physical conditions. The derived abundance and rotational temperatures are very similar for both LOSs, indicating very similar chemical and excitation conditions for the molecular gas in the GC. The excitation conditions are also very similar to those found for the nucleus of the starburst galaxy NGC 253. We report for the first time the detection of HCO and HOC+ emission in LOS+0.693. Our comparison of the abundance ratios between CS, HCO, HOC+ and HCO+ found in the two LOSs with those in typical Galactic photodissociation regions (PDRs) and starbursts galaxies does not show any clear trend to distinguish between UV and X-ray induced chemistries. We propose that the CS/HOC+ ratio could be used as a tracer of the PDR components in the molecular clouds in the nuclei of galaxies.

astro-ph.GA↗

arXiv2011

Surviving the hole I: Spatially resolved chemistry around Sgr A*

The interstellar region within the few central parsecs around the super-massive black hole, Sgr A* at the very Galactic center is composed by a number of overlapping molecular structures which are subject to one of the most hostile physical environments in the Galaxy. We present high resolution (4"x3"~0.16x0.11 pc) interferometric observations of CN, 13CN, H2CO, SiO, c-C3H2 and HC3N emission at 1.3 mm towards the central ~4 pc of the Galactic center region. Strong differences are observed in the distribution of the different molecules. The UV resistant species CN, the only species tracing all previously identified circumnuclear disk (CND) structures, is mostly concentrated in optically thick clumps in the rotating filaments around Sgr A*. H2CO emission traces a shell-like structure that we interpret as the expansion of Sgr A East against the 50 km/s and 20 km/s giant molecular clouds (GMCs). We derive isotopic ratios 12C/13C~15-45 across most of the CND region. The densest molecular material, traced by SiO and HC3N, is located in the southern CND. The observed c-C3H2/HC3N ratio observed in the region is more than an order of magnitude lower than in Galactic PDRs. Toward the central region only CN was detected in absorption. Apart from the known narrow line-of-sight absorptions, a 90 km/s wide optically thick spectral feature is observed. We find evidences of an even wider (>100 km/s) absorption feature. Around 70-75% of the gas mass, concentrated in just the 27% densest molecular clumps, is associated with rotating structures and show evidences of association with each of the arcs of ionized gas in the mini-spiral structure. Chemical differentiation has been proven to be a powerful tool to disentangle the many overlapping molecular components in this crowded and heavily obscured region.

astro-ph.GA↗

arXiv2010

Mapping photodissociation and shocks in the vicinity of Sgr A*

We have obtained maps of the molecular emission within the central five arcminutes (12 pc) of the Galactic center (GC) in selected molecular tracers: SiO(2-1), HNCO(5_{0,5}-4_{0,4}), and the J=1-->0 transition of H^{13}CO+, HN^{13}C, and C^{18}O at an angular resolution of 30" (1.2 pc). The mapped region includes the circumnuclear disk (CND) and the two surrounding giant molecular clouds (GMCs) of the Sgr A complex, known as the 20 and 50 km s^{-1} molecular clouds.Additionally, we simultaneously observed the J=2-1 and 3-2 transitions of SiO toward selected positions to estimate the physical conditions of the molecular gas. The SiO(2-1) and H^{13}CO+(1-0) emission covers the same velocity range and presents a similar distribution. In contrast, HNCO(5-4) emission appears in a narrow velocity range mostly concentrated in the 20 and 50 km s^{-1} GMCs. The HNCO column densities and fractional abundances present the highest contrast, with difference factors of $\geq$60 and 28, respectively. Their highest values are found toward the cores of the GMCs, whereas the lowest ones are measured at the CND. SiO abundances do not follow this trend, with high values found toward the CND, as well as the GMCs. By comparing our abundances with those of prototypical Galactic sources we conclude that HNCO, similar to SiO, is ejected from grain mantles into gas-phase by nondissociative C-shocks. This results in the high abundances measured toward the CND and the GMCs. However, the strong UV radiation from the Central cluster utterly photodissociates HNCO as we get closer to the center, whereas SiO seems to be more resistant against UV-photons or it is produced more efficiently by the strong shocks in the CND. Finally, we discuss the possible connections between the molecular gas at the CND and the GMCs using the HNCO/SiO, SiO/CS, and HNCO/CS intensity ratios as probes of distance to the Central cluster.

astro-ph.GA↗

arXiv2010

Herschel/HIFI measurements of the ortho/para ratio in water towards Sagittarius B2(M) and W31C

We present Herschel/HIFI observations of the fundamental rotational transitions of ortho- and para-H$_2^{16}$O and H$_2^{18}$O in absorption towards Sagittarius~B2(M) and W31C. The ortho/para ratio in water in the foreground clouds on the line of sight towards these bright continuum sources is generally consistent with the statistical high-temperature ratio of 3, within the observational uncertainties. However, somewhat unexpectedly, we derive a low ortho/para ratio of $2.35 \pm 0.35$, corresponding to a spin temperature of $\sim$27~K, towards Sagittarius~B2(M) at velocities of the expanding molecular ring. Water molecules in this region appear to have formed with, or relaxed to, an ortho/para ratio close to the value corresponding to the local temperature of the gas and dust.

astro-ph.GA↗

arXiv2010

Excitation of the molecular gas in the nuclear region of M82

We present high resolution HIFI spectroscopy of the nucleus of the archetypical starburst galaxy M82. Six 12CO lines, 2 13CO lines and 4 fine-structure lines are detected. Besides showing the effects of the overall velocity structure of the nuclear region, the line profiles also indicate the presence of multiple components with different optical depths, temperatures and densities in the observing beam. The data have been interpreted using a grid of PDR models. It is found that the majority of the molecular gas is in low density (n=10^3.5 cm^-3) clouds, with column densities of N_H=10^21.5 cm^-2 and a relatively low UV radiation field (GO = 10^2). The remaining gas is predominantly found in clouds with higher densities (n=10^5 cm^-3) and radiation fields (GO = 10^2.75), but somewhat lower column densities (N_H=10^21.2 cm^-2). The highest J CO lines are dominated by a small (1% relative surface filling) component, with an even higher density (n=10^6 cm^-3) and UV field (GO = 10^3.25). These results show the strength of multi-component modeling for the interpretation of the integrated properties of galaxies.

astro-ph.CO↗

arXiv2010

Herschel observations of water vapour in Markarian 231

The Ultra Luminous InfraRed Galaxy Mrk 231 reveals up to seven rotational lines of water (H2O) in emission, including a very high-lying (E_{upper}=640 K) line detected at a 4sigma level, within the Herschel/SPIRE wavelength range, whereas PACS observations show one H2O line at 78 microns in absorption, as found for other H2O lines previously detected by ISO. The absorption/emission dichotomy is caused by the pumping of the rotational levels by far-infrared radiation emitted by dust, and subsequent relaxation through lines at longer wavelengths, which allows us to estimate both the column density of H2O and the general characteristics of the underlying far-infrared continuum source. Radiative transfer models including excitation through both absorption of far-infrared radiation emitted by dust and collisions are used to calculate the equilibrium level populations of H2O and the corresponding line fluxes. The highest-lying H2O lines detected in emission, with levels at 300-640 K above the ground state, indicate that the source of far-infrared radiation responsible for the pumping is compact (radius=110-180 pc) and warm (T_{dust}=85-95 K), accounting for at least 45% of the bolometric luminosity. The high column density, N(H2O)~5x10^{17} cm^{-2}, found in this nuclear component, is most probably the consequence of shocks/cosmic rays, an XDR chemistry, and/or an "undepleted chemistry" where grain mantles are evaporated. A more extended region, presumably the inner region of the 1-kpc disk observed in other molecular species, could contribute to the flux observed in low-lying H2O lines through dense hot cores, and/or shocks. The H2O 78 micron line observed with PACS shows hints of a blue-shifted wing seen in absorption, possibly indicating the occurrence of H2O in the prominent outflow detected in OH (Fischer et al., this volume).

astro-ph.CO↗

arXiv2008

Using SPICA Space Telescope to characterize Exoplanets

We present the 3.5m SPICA space telescope, a proposed Japanese-led JAXA-ESA mission scheduled for launch around 2017. The actively cooled (<5 K), single aperture telescope and monolithic mirror will operate from ~3.5 to ~210 um and will provide superb sensitivity in the mid- and far-IR spectral domain (better than JWST at lambda > 18 um). SPICA is one of the few space missions selected to go to the next stage of ESA's Cosmic Vision 2015-2025 selection process. In this White Paper we present the main specifications of the three instruments currently baselined for SPICA: a mid-infrared (MIR) coronagraph (~3.5 to ~27 um) with photometric and spectral capabilities (R~200), a MIR wide-field camera and high resolution spectrometer (R~30,000), and a far-infrared (FIR ~30 to ~210 um) imaging spectrometer - SAFARI - led by a European consortium. We discuss their capabilities in the context of MIR direct observations of exo-planets (EPs) and multiband photometry/high resolution spectroscopy observations of transiting exo-planets. We conclude that SPICA will be able to characterize the atmospheres of transiting exo-planets down to the super-Earth size previously detected by ground- or space-based observatories. It will also directly detect and characterize Jupiter/Neptune-size planets orbiting at larger separation from their parent star (>5-10 AU), by performing quantitative atmospheric spectroscopy and studying proto-planetary and debris disks. In addition, SPICA will be a scientific and technological precursor for future, more ambitious, IR space missions for exo-planet direct detection as it will, for example, quantify the prevalence exo-zodiacal clouds in planetary systems and test coronographic techniques, cryogenic systems and lightweight, high quality telescopes. (abridged)

astro-ph↗