arXiv subjects

J. Tong

Publications and source records attributed to J. Tong.

7 recordsLinked to original sources

arXiv2026

Electrostatic control of Li+ density and transport rate in double-gated van der Waals devices

Ion transport in crystalline hosts is controlled by an applied potential that simultaneously sets ionic distribution and transport rate, restricting operation to a one-dimensional control space. Here we show that the transport rate of Li+ ions in double-gated van der Waals devices can be modulated while the system occupies fixed ionic-density states. We measure the ionic current along the van der Waals interfaces between hexagonal boron nitride and graphene or MoS2 while simultaneously monitoring the in-plane electronic response. The ionic current exhibits pronounced hysteresis, with plateaus marking discrete ionic-density states balanced by electronic charge, while an independently tuneable electrochemical-potential drop controls the ionic transport rate. The devices sustain over 1,000 switching cycles and function as hybrid ionic-electronic transistors capable of logic operations and memory retention, with ON/OFF ratios exceeding two orders of magnitude. This work demonstrates a two-dimensional control space for ions intercalated in layered materials.

cond-mat.mes-hall↗

arXiv2026

Layer-selective hydrogenation and proton transport in twisted bilayer graphene

Recent work investigated graphene's hydrogenation with independent control of the electric field, E, and charge density, n, in the crystal and showed that the process is controlled by n. Here, we demonstrate layer-selective conductor-insulator transitions in twisted bilayer graphene, driven by hydrogenation at fixed n under strong E. This process is accompanied by proton transport through the bilayer, enabling several parallel and configurable logic gates in the devices. Selectivity arises because the large twist angle decouples the two layers' electronic systems, enabling independent control of their charge densities. Polarisation by the field then induces a charge imbalance at fixed total n, triggering hydrogenation when one of the layers' charge densities reaches the threshold for monolayer hydrogenation. Our results introduce a new type of electrode-electrolyte interface in which electrochemical processes are controlled with two decoupled 2D electron gases, opening new design opportunities for energy and information processing devices.

cond-mat.mes-hall↗

arXiv2025

Mechanism of the electrochemical hydrogenation of graphene

The electrochemical hydrogenation of graphene induces a robust and reversible conductor-insulator transition, of strong interest in logic-and-memory applications. However, its mechanism remains unknown. Here we show that it proceeds as a reduction reaction in which proton adsorption competes with the formation of H2 molecules via an Eley-Rideal process. Graphene's electrochemical hydrogenation is up to $10^6$ times faster than alternative hydrogenation methods and is fully reversible via the oxidative desorption of protons. We demonstrate that the proton reduction rate in defect-free graphene can be enhanced by an order of magnitude by the introduction of nanoscale corrugations in its lattice, and that the substitution of protons for deuterons results both in lower potentials for the hydrogenation process and in a more stable compound. Our results pave the way to investigating the chemisorption of ions in 2D materials at high electric fields, opening a new avenue to control these materials' electronic properties.

physics.chem-ph↗

arXiv2024

Control of proton transport and hydrogenation in double-gated graphene

The basal plane of graphene can function as a selective barrier that is permeable to protons but impermeable to all ions and gases, stimulating its use in applications such as membranes, catalysis and isotope separation. Protons can chemically adsorb on graphene and hydrogenate it, inducing a conductor-insulator transition that has been explored intensively in graphene electronic devices. However, both processes face energy barriers and various strategies have been proposed to accelerate proton transport, for example by introducing vacancies, incorporating catalytic metals or chemically functionalizing the lattice. However, these techniques can compromise other properties, such as ion selectivity or mechanical stability. Here we show that independent control of the electric field, E, at around 1 V nm-1, and charge-carrier density, n, at around 1 x 10^14 cm-2, in double-gated graphene allows the decoupling of proton transport from lattice hydrogenation and can thereby accelerate proton transport such that it approaches the limiting electrolyte current for our devices. Proton transport and hydrogenation can be driven selectively with precision and robustness, enabling proton-based logic and memory graphene devices that have on-off ratios spanning orders of magnitude. Our results show that field effects can accelerate and decouple electrochemical processes in double-gated 2D crystals and demonstrate the possibility of mapping such processes as a function of E and n, which is a new technique for the study of 2D electrode-electrolyte interfaces.

cond-mat.mes-hall↗

arXiv2023

Gate-controlled suppression of light-driven proton transport through graphene electrodes

Recent experiments demonstrated that proton transport through graphene electrodes can be accelerated by over an order of magnitude with low intensity illumination. Here we show that this photo-effect can be suppressed for a tuneable fraction of the infrared spectrum by applying a voltage bias. Using photocurrent measurements and Raman spectroscopy, we show that such fraction can be selected by tuning the Fermi energy of electrons in graphene with a bias, a phenomenon controlled by Pauli blocking of photo-excited electrons. These findings demonstrate a dependence between graphene's electronic and proton transport properties and provide fundamental insights into molecularly thin electrode-electrolyte interfaces and their interaction with light.

cond-mat.mes-hall↗

arXiv2022

Inductive Matrix Completion and Root-MUSIC-Based Channel Estimation for Intelligent Reflecting Surface (IRS)-Aided Hybrid MIMO Systems

This paper studies the estimation of cascaded channels in passive intelligent reflective surface (IRS)- aided multiple-input multiple-output (MIMO) systems employing hybrid precoders and combiners. We propose a low-complexity solution that estimates the channel parameters progressively. The angles of departure (AoDs) and angles of arrival (AoAs) at the transmitter and receiver, respectively, are first estimated using inductive matrix completion (IMC) followed by root-MUSIC based super-resolution spectrum estimation. Forward-backward spatial smoothing (FBSS) is applied to address the coherence issue. Using the estimated AoAs and AoDs, the training precoders and combiners are then optimized and the angle differences between the AoAs and AoDs at the IRS are estimated using the least squares (LS) method followed by FBSS and the root-MUSIC algorithm. Finally, the composite path gains of the cascaded channel are estimated using on-grid sparse recovery with a small-size dictionary. The simulation results suggest that the proposed estimator can achieve improved channel parameter estimation performance with lower complexity as compared to several recently reported alternatives, thanks to the exploitation of the knowledge of the array responses and low-rankness of the channel using low-complexity algorithms at all the stages.

eess.SP↗

arXiv2015

Geometric distortion of area in medical ultrasound images

Medical ultrasound scanners are typically calibrated to the soft tissue average of 1540 m s$^{-1}$. In regions of different sound speed, for example, organs and tumours, the $B$-scan image then becomes a distortion of the true tissue cross-section, due to the misrepresentation of length and refraction. To quantify this distortion we develop a general geometric ray model for an object with an atypical speed of sound embedded in an ambient medium. We analyse the ensuing area distortion for circular and elliptical objects, mapping it out as a function of the key parameters, including the speed of sound mismatch, the object size and its elongation. We find that the area distortion can become significant, even for small-scale speed of sound mismatches. Our findings are verified by ultrasound imaging of a test object.

physics.med-ph↗