arXiv subjects

Jan Cami

Publications and source records attributed to Jan Cami.

At least 19 recordsLinked to original sources

arXiv2026

PDRs4All XXII. Near-Infrared continuum in the Orion Bar

Conspicuous excess emission is present in the near-infrared (NIR) region in various objects, including reflection nebulae, planetary nebulae, and nearby galaxies. However, the spatial distribution and spectral shape of the excess emission remain poorly understood. We studied the NIR continuum emission spectroscopically and obtained its spatial distribution relative to the aromatic infrared band (AIB) at 3.3um in the Orion Bar prototypical photodissociation region (PDR). We aim to characterize its spectral shape and discuss its origin. We employed 3D spectroscopic data of the Orion Bar taken with the integrated field unit of NIRSpec on JWST from the Early Release Science program "PDRs4All." Contribution from the foreground ionized gas was estimated using the Cloudy code and subtracted. The observed regions were divided into nine physically distinct regions and an average spectrum was derived for each region. The nine regions, including the ionized gas, atomic PDR, and molecular PDR, clearly show remaining continuum in the region 1--4.5um. The continuum at wavelengths longer than 2.7um shows good correlations with the 3.3um AIB, while the correlation of the continuum at 1.2um is not significant. We further find that the NIR continuum in the Orion Bar can be approximated by a summation of two blackbodies. The low-temperature component correlates with the AIB well, while the high-temperature component does not. The average spectra also show absorption features at 3.0 and 4.27um, which are attributed to the presence in the spectra of water ice and CO2 ice. We discuss possible origins of the NIR continuum, among which recurrent fluorescence from carbon clusters better explains the observed low-temperature component. The presence of ice species suggests a contribution from a deeper layer of the PDR along the line of sight producing characteristic ice absorption features.

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arXiv2026

Detection of C$_{60}$ Combination Bands in the Near-IR Spectrum of Tc 1

We report the detection of a set of new near-infrared emission features between 3.5 and 5.2 ${\mu}$m in JWST/NIRSpec observations of Tc 1, the planetary nebula known for displaying the cleanest and most prominent mid-infrared cosmic fullerene spectrum. These broad features share the same spatial distribution as the well-known C$_{60}$ and C$_{70}$ mid-infrared emission bands, peaking in an asymmetric ring approximately 5-6" from the central star. Through comparison with new anharmonic quantum chemical calculations, we demonstrate that these features arise from C$_{60}$ combination bands, marking their first detection in an astrophysical environment. The total energy radiated in the combination bands amounts to ~17% of the total energy emitted from all C$_{60}$ modes, with direct implications for fullerene cooling models. These near-infrared combination bands offer a promising new window for identifying and studying the molecular astrophysics of C$_{60}$ in sources where mid-infrared spectra are more complex.

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arXiv2026

Detection of CO$_2$ ice in the planetary nebula NGC 6302

Using JWST/MIRI observations, we report the detection of CO$_2$ ice in the dusty torus of the planetary nebula NGC 6302, an environment generally considered hostile to fragile molecular species and ices due to intense UV irradiation. This detection accompanies cold (20-50 K) gas-phase CO$_2$ along the same sightlines. The ice absorption profile exhibits a double-peak profile, a characteristic of pure, crystalline CO$_2$ ice. The CO$_2$ gas-to-ice ratio is more than an order of magnitude higher than in young stellar objects, pointing to distinct ice formation or processing mechanisms in evolved stellar environments. This discovery demonstrates that the dusty torus provides sufficient shielding to harbour ice chemistry, and that ice-mediated surface reactions must be incorporated into chemical models of planetary nebulae.

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arXiv2026

PDRs4All: XVIII. The evolution of the PAH ionisation and PAH size distribution across the Orion Bar

We investigate the evolution of the PAH population's charge state and size across key physical zones in the Orion Bar, which include the HII region, the atomic PDR (APDR), and three HI/H2 dissociation fronts (DF1, DF2, and DF3). Utilising the NASA Ames PAH Infrared Spectroscopic Database (PAHdb) and the pyPAHdb spectral modelling tool, we analysed the MIRI-MRS observations of the Orion Bar from the "PDRs4All" ERS Program. pyPAHdb modelling reveals the fractional contribution of the different PAH charge states and sizes to the total PAH emission across the Orion Bar. Cationic PAH emission peaks in the APDR region, where neutral PAHs have minimal contribution. Emission from neutral PAHs peaks in the HII region that consists of emission from a face-on PDR associated to the background OMC-1 molecular cloud, and in the molecular cloud regions past DF2. PAH anions are observed deep within the DF2 and DF3 zones. The average PAH size ranges between ~$60-74$ Nc. The modelling reveals regions of top-down PAH formation at the ionisation front, and bottom-up PAH formation within the molecular cloud region. The PAH ionisation parameter $\gamma$ ranges between ~$2-9 x 10^4$. Intensity ratios tracing PAH ionisation scale well with $\gamma$ in regions encompassing edge-on or face-on PDR emission, but their correlation weakens within the molecular cloud zone. Modelling of the $5-15$ $\mu$m PAH spectrum with pyPAHdb achieves comprehensive characterization of the net contribution of neutral and cationic PAHs across different environments, whereas empirical PAH proxy intensity ratio tracers can be highly variable and unreliable outside regions dominated by PDR emission. The derived average PAH size in the different physical zones is consistent with a view of PAHs being more extensively subjected to ultraviolet processing closer to the ionisation front, and less affected within the molecular cloud.

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arXiv2025

PDRs4All XIX. The 6 to 9 $\mu$m region as a probe of PAH charge and size in the Orion Bar

Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of molecular clouds. We aim to investigate the distribution and sizes of charged PAHs across the key zones of the Orion Bar PDR. We employ JWST MIRI-MRS observations of the Orion Bar from the Early Release Science program ''PDRs4All'' and synthetic images in the JWST MIRI filters. We investigate the spatial morphology of the AIBs at 6.2, 7.7, 8.6, and 11.0 $\mu$m that commonly trace PAH cations, and the neutral PAH-tracing 11.2 $\mu$m AIB, their (relative) correlations, and the relationship with existing empirical prescriptions for AIBs. The 6.2. 7.7, 8.6, 11.0, and 11.2 $\mu$m AIBs are similar in spatial morphology, on larger scales. Analyzing three-feature intensity correlations, two distinct groups emerge: the 8.6 and 11.0 $\mu$m vs. the 6.2 and 7.7 $\mu$m AIBs. We attribute these correlations to PAH size. The 6.2 and 7.7 $\mu$m AIBs trace cationic, medium-sized PAHs. Quantum chemical calculations reveal that the 8.6 $\mu$m AIB is carried by large, compact, cationic PAHs, and the 11.0 $\mu$m AIB's correlation to it implies, so is this band. The 6.2/8.6 and 7.7/8.6 PAH band ratios thus probe PAH size. We conclude that the 6.2/11.2 AIB ratio is the most reliable proxy for charged PAHs, within the cohort. We outline JWST MIRI imaging prescriptions that serve as effective tracers of the PAH ionization fraction as traced. This study showcases the efficacy of the 6-9 $\mu$m AIBs to probe the charge state and size distribution of the emitting PAHs, offering insights into the physical conditions of their host environments. JWST MIRI photometry offers a viable alternative to IFU spectroscopy for characterizing this emission in extended objects.

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arXiv2025

Searching for Corannulene with ALMA: Observations of the Red Rectangle Nebula

Polycyclic Aromatic Hydrocarbons (PAHs) are organic molecules responsible for the Aromatic Infrared Bands (AIBs), observed across a multitude of astrophysical environments. Despite their ubiquity, the precise formation mechanisms of PAHs remain unclear. One of the possible way for PAHs to form is in the outflows of evolved stars, such as HD 44179, which produces the Red Rectangle nebula - a known emitter of AIBs. However, no specific PAH molecules have been detected in such environments, complicating the understanding of PAH formation and evolution. This study aimed to detect the PAH molecule corannulene C20H10, a viable candidate for radio detection due to its large dipole moment of 2.07D. We analyzed high-resolution band 4 ALMA observations of the Red Rectangle nebula, collected over almost 9 hrs. Although corannulene emission was not detected, we estimated a firm upper limit on its abundance compared to hydrogen (5x10^-13) and we discuss the lack of detection in the context of our current understanding of PAH formation and destruction mechanisms. Additionally, we report tentative detection of signals at 139.612 GHz, 139.617 GHz, and 139.621 GHz, potentially originating from cyclopropenyledine c-C3H2 and the 140 GHz H2O maser.

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arXiv2025

Detection of CH3+ in the O-rich planetary nebula NGC 6302

Planetary nebulae are sites where ejected stellar material evolves into complex molecules, but the precise physical conditions and chemical routes that govern these processes are unclear. The presence of abundant carbon-rich molecules in O-rich environments poses particular challenges. Here we report the first detection of methyl cation (CH3+) in any planetary nebula, observed in the O-rich nebula NGC 6302 using JWST MIRI/MRS observations. CH3+ is a key driver of organic chemistry in UV-irradiated environments. Spatially resolved observations reveal that CH3+ is co-located with 12CO, H2, H II, HCO+, and Polycyclic aromatic hydrocarbons (PAHs). LTE modelling of the CH3+ emission yields excitation temperatures of 500-800K in the inner bubble and torus, rising to 1000-2000K in the outer bubble of NGC 6302, with column densities ranging from ~10^11 to 10^13 cm^-2. This detection demonstrates that hydrocarbon radical chemistry must be incorporated into planetary nebulae chemical models. Further near-IR observations are crucial to map different chemical networks operating in these environments.

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arXiv2025

Observation of an Accreting Planetary-Mass Companion with Signs of Disk-Disk Interaction in Orion

Young ($\lesssim 10$ Myr) planetary-mass companions (PMCs) provide valuable insights into the formation and early evolution of planetary systems. To date, only a dozen such objects have been identified through direct imaging. Using JWST/NIRCam observations towards the Orion Nebula, obtained as part of the \textit{PDRs4All} Early Release Science program, we have identified a faint point source near the M-type star V2376 Ori. Follow-up spectroscopic observations with the MUSE instrument on the VLT confirm that the source, V2376 Ori b, is indeed a young planetary-mass companion. It is a member of Orion D, around 80\,pc in the foreground of the Trapezium cluster of Orion and with an age of approximately $7 \pm 3$ Myr. We fit the SED of V2376 Ori b to infer a mass of $ \sim 20~M_{\rm Jup}$. The MUSE spectrum reveals several accretion tracers. Based on the H$\alpha$ line intensity, we estimate an accretion rate of $\sim$10$^{-6.5 \pm 0.7}~\rm M_{Jup}\,yr^{-1}$, which is comparable to that of young PMCs such as PDS~70b. In addition, the MUSE data cube reveals extended emission in the [O\,\textsc{ii}] doublet at 7320 and 7330~\AA, which is interpreted as evidence of a dynamical interaction between the two sources that, potentially, involves mass transfer between their individual accretion disks. These results demonstrate that JWST/NIRCam imaging surveys of young stellar associations can uncover new PMCs, which can then be confirmed and characterized through ground-based spectroscopic follow-up.

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arXiv2025

The JWST/MIRI view of the planetary nebula NGC 6302 I.: a UV irradiated torus and a hot bubble triggering PAH formation

NGC 6302 is a spectacular bipolar planetary nebula (PN) whose spectrum exhibits fast outflows and highly ionized emission lines, indicating the presence of a very hot central star (~220,000 K). Its infrared spectrum reveals a mixed oxygen and carbon dust chemistry, displaying both silicate and polycyclic aromatic hydrocarbon (PAH) features. Using the JWST Mid-Infrared Instrument (MIRI) and Medium Resolution Spectrometer, a mosaic map was obtained over the core of NGC 6302, covering the wavelength range of 5--28 micron and spanning an area of ~18.5 arcsec x15 arcsec. The spatially resolved spectrum reveals ~200 molecular and ionized lines from species requiring ionisation potentials of up to 205 eV. The spatial distributions highlight a complex structure at the nebula's centre. Highly ionized species such as Mg VII and Si VII show compact structures, while lower-ionization species such as H^+ extend much farther outwards, forming filament-defined rims that delineate a bubble. Within the bubble, the H^+ and H_2 emission coincide, while the PAH emission appears farther out, indicating an ionization structure distinct from typical photodissociation regions, such as the Orion Bar. This may be the first identification of a PAH formation site in a PN. This PN appears to be shaped not by a steady, continuous outflow, but by a series of dynamic, impulsive bubble ejections, creating local conditions conducive to PAH formation. A dusty torus surrounds the core, primarily composed of large (micron-sized) silicate grains with crystalline components. The long-lived torus contains a substantial mass of material, which could support an equilibrium chemistry and a slow dust-formation process.

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arXiv2025

JWST observations of the Ring Nebula (NGC 6720) -- II. PAH emission

Polycyclic aromatic hydrocarbons (PAHs) and carbonaceous dust have been observed in clumpy circumstellar environments, yet their formation and evolutionary pathways in such environments remain elusive. We aim to characterize the PAH emission in a clumpy planetary nebula to decipher their formation and evolution pathways. We obtained JWST Near-Infrared Spectrograph (NIRSpec) and Mid-Infrared Instrument (MIRI) integral field unit spectroscopic observations of two individual knots in the Ring Nebula (NGC 6720), a clumpy planetary nebula, and determine the PAH spectral characteristics. We detect the 3.3 and 11.2 um PAH emission bands in both knots but do not detect PAH emission in the 6-9 um range. We supplement our data with Spitzer Infrared Spectrograph (IRS) Short-Low 1 (SL1) and SL2 data, containing 11.2, weak 6.2, and weak 7.7 um PAH emission bands. The JWST data confirm the unusual profile of the 11.2 um band, which is very broad and redshifted with respect to typical 11.2 um PAH profiles. We estimate the PAH population to be largely neutral. The relative integrated surface brightness of the 3.3 and 11.2 um bands indicates the presence of small-sized PAHs, consisting of 35 +/- 6 carbon atoms. We find that the PAH emission is concentrated outside of the clumps, in the inter-clump medium, and confirm the existence of enhanced PAH emission in a narrow 'PAH ring' centred on the central star. This morphology suggests that PAHs formed during the Ring Nebula's asymptotic giant branch phase, in the central star's dust-driven wind.

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arXiv2025

PDRs4All XVI. Tracing aromatic infrared band characteristics in photodissociation region spectra with PAHFIT in the JWST era

Photodissociation regions (PDRs) exhibit emission between 3-20 um known as the Aromatic Infrared Bands (AIBs), originating from small carbonaceous species such as polycyclic aromatic hydrocarbons (PAHs). The AIB spectra observed in Galactic PDRs, such as the Orion Bar observations by the PDRs4All JWST program, are considered a local analog for those seen in extragalactic star-forming regions. We present the Python version of PAHFIT, a spectral decomposition tool that separates the contributions by AIB subcomponents, thermal dust emission, gas lines, stellar light, and dust extinction. By fitting segments of the Orion Bar spectra, we provide a configuration to decompose JWST spectra of PDRs in detail. The resulting central wavelengths and FWHM of the AIB subcomponents are compiled into a "PDR pack" for PAHFIT. We applied PAHFIT with this PDR pack and the default continuum model to spectra of the central star forming ring of the galaxy NGC7469. We introduce an alternate dust continuum model to fit the Orion Bar spectra, as the default PAHFIT continuum model mismatches the intensity at 15-26 um. Using the PDR pack and the alternate continuum model, PAHFIT reproduces the Orion Bar spectra with residuals of a few percent, and similar performance is achieved for the NGC7469 spectra. We provide PAHFIT-based diagnostics that trace the profile variations of the 3.3, 3.4, 5.7, 6.2, and 7.7 um AIBs, and thus the photochemical evolution of the AIB carriers. The 5.7 um AIB emission originates from at least two subpopulations, one more prominent in highly irradiated environments and one preferring more shielded environments. Smaller PAHs as well as very small grains or PAH clusters both thrive in the more shielded environments of the molecular zone in the Orion Bar. Based on these new diagnostics, we quantify the similarities between the AIB profiles observed in the Orion Bar and NGC7469.

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arXiv2025

Solar C/O ratio in planet-forming gas at 1 au in a highly irradiated disk

The chemical composition of exoplanets is thought to be influenced by the composition of the disks in which they form. JWST observations have unveiled a variety of species in numerous nearby disks, showing significant variations in the C/O abundance ratio. However, little is known about the composition and C/O ratio of disks around young stars in clusters exposed to strong ultraviolet (UV) radiation from nearby massive stars, which are representative of the environments where most planetary systems form, including ours. We present JWST spectroscopy of d203-504, a young 0.7 $\rm M_{\odot}$ star in the Orion Nebula with a 30 au disk irradiated by nearby massive stars. These observations reveal spectroscopic signatures of CO, H$_2$O, CH$_3^+$, and PAHs. Water and CO are detected in absorption in the inner disk ($r\lesssim 1$ au), where the estimated gas-phase C/O ratio is 0.48, consistent with the Solar value and that of the Orion Nebula. In contrast, \ch{CH3+} and PAHs are found in the extended surface layers of the disk. These results suggest that gas in the inner disk is chemically shielded from UV radiation while the surface layers of the disk experience UV-induced chemistry, potentially depleting their carbon content.

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arXiv2025

JWST observations of the Ring Nebula (NGC 6720): III. A dusty disk around its Central Star

The planetary nebula NGC 6720, also known as the ``Ring Nebula", is one of the most iconic examples of nearby planetary nebulae whose morphologies present a challenge to our theoretical understanding of the processes that govern the deaths of most stars in the Universe that evolve on a Hubble time. We present new imaging with JWST of the central star of this planetary nebula (CSPN) and its close vicinity, in the near- to mid-IR wavelength range. We find the presence of a dust cloud around the CSPN, both from the spectral energy distribution at wavelengths >~5 micron, as well as radially-extended emission in the 7.7, 10 and 11.3 micron images. From modeling of these data, we infer that the CSPN has a luminosity of 310 Lsun and is surrounded by a dust cloud with a size of ~2600 au, consisting of relatively small amorphous silicate dust grains (radius ~0.01 micron) with a total mass of 1.9 x 10^(-6) M_earth. However, our best-fit model shows a significant lack of extended emission at 7.7 micron -- we show that such emission can arise from a smaller (7.3 x 10^(-7) M_earth) but uncertain mass of (stochastically-heated) ionized PAHs. However, the same energetic radiation also rapidly destroys PAH molecules, suggesting that these are most likely being continuously replenished, via the outgassing of cometary bodies and/or the collisional grinding of planetesimals. We also find significant photometric variability of the central source that could be due to the presence of a close dwarf companion of mass < ~0.1 Msun.

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arXiv2024

PDRs4All XIII. Empirical prescriptions for the interpretation of JWST imaging observations of star-forming regions

(Abridged) JWST continues to deliver incredibly detailed infrared (IR) images of star forming regions in the Milky Way and beyond. IR emission from star-forming regions is very spectrally rich due to emission from gas-phase atoms, ions, and polycyclic aromatic hydrocarbons (PAHs). Physically interpreting IR images of these regions relies on assumptions about the underlying spectral energy distribution in the imaging bandpasses. We aim to provide empirical prescriptions linking line, PAH, and continuum intensities from JWST images, to facilitate the interpretation of JWST images in a wide variety of contexts. We use JWST PDRs4All Near-Infrared Camera (NIRCam) and Mid-Infrared Instrument (MIRI) imaging and Near-Infrared Spectrograph (NIRSpec) integral field unit (IFU) and MIRI Medium Resolution Spectrograph (MRS) spectroscopic observations of the Orion Bar photodissociation region (PDR), to directly compare and cross-calibrate imaging and IFU data at ~100 AU resolution over a region where the radiation field and ISM environment evolves from the hot ionized gas to the cold molecular gas. We measure the relative contributions of line, PAH, and continuum emission to the NIRCam and MIRI filters as functions of local physical conditions. We provide empirical prescriptions based on NIRCam and MIRI images to derive intensities of emission lines and PAH features. Within the range of the environments probed in this study, these prescriptions accurately predict Pa-$\alpha$, Br-$\alpha$, PAH 3.3 $\mu$m and 11.2 $\mu$m intensities, while those for FeII 1.644 $\mu$m, H$_2$ 1--0 S(1) 2.12 $\mu$m and 1--0 S(9) 4.96 $\mu$m, and PAH 7.7 $\mu$m show more complicated environmental dependencies. Linear combinations of JWST NIRCam and MIRI images provide effective tracers of ionized gas, H$_2$, and PAH emission in PDRs. We expect these recipes to be useful for both the Galactic and extragalactic communities.

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arXiv2024

A Study of Polycyclic Aromatic Hydrocarbon Emission in 30 Dor as seen by JWST

Polycyclic aromatic hydrocarbons (PAHs) are responsible for strong mid-IR emission features near star-forming regions. It is well known that low-metallicity environments exhibit weaker PAH emission, but it is not clear how the metallicity affects the properties of the emitting PAH population. We present a detailed study of the PAH emission in the low-metallicity regime represented by 30 Dor in the Large Magellanic Cloud (LMC) and we compare it to the PAH emission in the Orion Bar to investigate the characteristics of the PAH population and how the environments affects the resulting IR emission. We analyze JWST observations of 30 Dor that include imaging (NIRCam, MIRI) and spectroscopy (NIRSpec/IFU, MIRI/MRS). We extracted NIRSpec/IFU and MIRI/MRS spectra from 18 apertures that cover the morphological structures of 30 Dor. We characterize the profiles and relative intensities of PAH emission in these apertures. The detailed profiles of the PAH emission bands in 30 Dor are all very similar, and compare well to those from one of the dissociation fronts (DF2) in the Orion Bar. The relative band ratios on the other hand show a much larger range than in the Orion Bar. The PAH emission in 30 Dor originates from a population with a higher ionization fraction than in the Orion Bar, and a size distribution that has more smaller PAHs. Since smaller PAHs typically photo-fragment before larger PAHs, our findings support the hypothesis that the lower PAH emission for lower metallicities is the result of inhibition of growth toward larger PAHs rather than photo-fragmentation.

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arXiv2024

PDRs4All VIII: Mid-IR emission line inventory of the Orion Bar

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations.

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arXiv2024

A far-ultraviolet-driven photoevaporation flow observed in a protoplanetary disk

Most low-mass stars form in stellar clusters that also contain massive stars, which are sources of far-ultraviolet (FUV) radiation. Theoretical models predict that this FUV radiation produces photo-dissociation regions (PDRs) on the surfaces of protoplanetary disks around low-mass stars, impacting planet formation within the disks. We report JWST and Atacama Large Millimetere Array observations of a FUV-irradiated protoplanetary disk in the Orion Nebula. Emission lines are detected from the PDR; modelling their kinematics and excitation allows us to constrain the physical conditions within the gas. We quantify the mass-loss rate induced by the FUV irradiation, finding it is sufficient to remove gas from the disk in less than a million years. This is rapid enough to affect giant planet formation in the disk.

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arXiv2024

Formation of the Methyl Cation by Photochemistry in a Protoplanetary Disk

Forty years ago it was proposed that gas phase organic chemistry in the interstellar medium was initiated by the methyl cation CH3+, but hitherto it has not been observed outside the Solar System. Alternative routes involving processes on grain surfaces have been invoked. Here we report JWST observations of CH3+ in a protoplanetary disk in the Orion star forming region. We find that gas-phase organic chemistry is activated by UV irradiation.

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