arXiv subjects

Jeroen Bouwman

Publications and source records attributed to Jeroen Bouwman.

At least 19 recordsLinked to original sources

arXiv2026

First detection of HDO ice in a protoplanetary disk

Protoplanetary disks are the birthplace of planets and planetary systems. Investigating the molecular inventory of disks is key to linking the chemical evolution of the interstellar medium and the makeup of planets and their atmospheres. In particular, tracing the history of the deuterium enrichment of water along the journey from interstellar clouds through protoplanetary disks to planetary systems provides critical insights into the chemical inheritance. We aim to investigate the chemical composition of ices in protoplanetary disks; specifically, the presence of HDO ice that ought to be present, but has not been detected in disks thus far. We analyzed JWST/NIRSpec observations of the 132-1832 edge-on disk located in the Orion Nebula Cluster using the ENIIGMA fitting tool and unique laboratory data. We report on the first detections of HDO ice in a protoplanetary disk. The estimated upper limit for the HDO/H$_2$O ratio for 132-1832 is much higher, compared to HDO/H$_2$O ratios obtained for chondrites, comets, and embedded young stellar objects. In the disk ices, beyond HDO, we detected H$_2$O, CO$_2$, $^{13}$CO$_2$, CO, OCN$^-$, and OCS, species, whose presence has also been detected in other disks. The HDO ice detection may point to the efficient ice processing in the disk and confirm the findings of laboratory experiments on deuterated ices.

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arXiv2025

A Tale of Two Sightlines: Comparison of Hydrocarbon Dust Absorption Bands toward Cygnus OB2-12 and the Galactic Center

Infrared spectra of hydrocarbon dust absorption bands toward the bright hypergiant Cygnus OB2-12 are compared to published spectra of the Quintuplet Cluster, a sightline to the Galactic center. The Cyg OB2-12 data include a new ground-based 2.86-3.70 microns spectrum and a previously published, but here further analyzed, spectrum of the 5.50-7.34 microns region. Higher spectral resolution data for the Cyg OB2-12 sightline in the 3 micron region allows a detailed comparison of the 3.4 micron aliphatic bands to those observed toward the Quintuplet. Despite differences in interstellar environments along each sightline, strong similarities are observed in the central wavelengths and relative strengths for bands at 3.3, 3.4, 5.85, 6.2, and 6.85 microns. Analysis of these bands, produced by aromatic, aliphatic, olefinic, hydrogenated, and oxygenated components, shows that carbonaceous dust is a significant component of the diffuse interstellar medium, second in abundance only to silicates, and is primarily aromatic in nature. The grains producing these bands likely consist of large aromatic carbon cores with thin aliphatic mantles composed of hydrogenated amorphous carbon (HAC). Laboratory analog spectra reproduce the observed aliphatic absorption bands well, supporting the presence of such mantles. We present evidence that the carriers of both the 3.4 micron aliphatic and the 3.3 micron aromatic bands reside exclusively in the diffuse ISM, and that the 3.3 micron bands observed in the diffuse ISM differ from the 3.25 micron band seen in dense clouds, implying chemically distinct carriers.

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arXiv2025

SO2, silicate clouds, but no CH4 detected in a warm Neptune

WASP-107b is a warm (~740 K) transiting planet with a Neptune-like mass of ~30.5 Earth masses and Jupiter-like radius of ~0.94 Jupiter radius, whose extended atmosphere is eroding. Previous observations showed evidence for water vapour and a thick high-altitude condensate layer in WASP-107b's atmosphere. Recently, photochemically produced sulphur dioxide (SO2) was detected in the atmosphere of a hot (~1200 K) Saturn-mass planet from transmission spectroscopy near 4.05 microns, but for temperatures below 1000 K sulphur is predicted to preferably form sulphur allotropes instead of SO2. Here we report the 9-sigma detection of two fundamental vibration bands of SO2, at 7.35 microns and 8.69 microns, in the transmission spectrum of WASP-107b using the Mid-Infrared Instrument (MIRI) of the JWST. This discovery establishes WASP-107b as the second irradiated exoplanet with confirmed photochemistry, extending the temperature range of exoplanets exhibiting detected photochemistry from ~1200 K down to ~740 K. Additionally, our spectral analysis reveals the presence of silicate clouds, which are strongly favoured (~7-sigma) over simpler cloud setups. Furthermore, water is detected (~12-sigma), but methane is not. These findings provide evidence of disequilibrium chemistry and indicate a dynamically active atmosphere with a super-solar metallicity.

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arXiv2025

Investigating silicate, carbon, and water in the diffuse interstellar medium: the first shots from WISCI

The dusty interstellar medium (ISM) of the Milky Way is distributed in a complex, cloudy structure. It is fundamental to the radiation balance within the Milky Way, provides a reaction surface to form complex molecules, and is the feedstock for future generations of stars and planets. The life cycle of interstellar dust is not completely understood, and neither are its structure nor composition. The abundance, composition, and structure of dust in the diffuse ISM can be determined by combining infrared, optical and ultraviolet spectroscopy. JWST enables measurement of the faint absorption of ISM dust grains against bright stars at kiloparsec distances across the infrared spectrum. Here we present an overview of the project `Webb Investigation of Silicates, Carbons, and Ices' (WISCI) along with interpretation of two targets, GSC 08152-02121 and CPD-59 5831. Observations of 12 WISCI target stars were taken by JWST, the Hubble Space Telescope, Himalayan Chandra Telescope, and the Very Large Telescope. We use these to characterize the targets' spectral types and calculate their line-of-sight extinction parameters, $A_{\rm V}$ and $R_{\rm V}$. We find absorption in the JWST spectra of GSC 08152-02121, and CPD-59 5831 associated with carbonaceous dust around 3.4 and 6.2 micron and amorphous silicates at 9.7 micron. In GSC 08152-02121 we also find indications of absorption by trapped water around 3 micron. This first look from WISCI demonstrates the line-of-sight variability within the sample, and the program's potential to identify and correlate features across ultraviolet to mid-infrared wavelengths.

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arXiv2025

JWST's sharper view of EX Lup: cold water from ice sublimation during accretion outbursts

The unstable accretion phases during pre-main-sequence evolution of T Tauri stars produce variable irradiation and heating of planet-forming regions. A strong accretion outburst was observed with Spitzer-IRS in 2008 in EX Lup, the prototype of EXor variables, and found to increase the mid-infrared water and OH emission and decrease organic emission, suggesting large chemical changes. We present here two JWST-MIRI epochs of quiescent EX Lup in 2022 and 2023 obtained over a decade after the 2008 outburst and several months after a moderate burst in 2022. With JWST's sharper spectral view, we can now analyze water emission as a function of temperature in the two MIRI epochs and, approximately, also in the previous Spitzer epochs. This new analysis shows a strong cold water vapor ``burst" in low-energy lines during the 2008 outburst, which we consider clear evidence for enhanced ice sublimation due to a recession of the snowline, as found in protostellar envelopes. JWST shows that EX Lup still has an unusually strong emission from cold water in comparison to other T Tauri disks, suggesting > 10-yr-long freeze-out timescales in the inner disk surface. EX Lup demonstrates that outbursts can significantly change the observed organic-to-water ratios and increase the cold water reservoir, providing chemical signatures to study the recent accretion history of disks. This study provides an unprecedented demonstration of the chemical evolution triggered by accretion outbursts in the Class II phase and of the high potential of time-domain experiments to reveal processes that may have fundamental implications on planet-forming bodies near the snowline.

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arXiv2025

MIRI-LRS spectrum of a cold exoplanet around a white dwarf: water, ammonia, and methane measurements

The study of the atmosphere of exoplanets orbiting white dwarfs is a largely unexplored field. With WD\,0806-661\,b, we present the first deep dive into the atmospheric physics and chemistry of a cold exoplanet around a white dwarf. We observed WD 0806-661 b using JWST's Mid-InfraRed Instrument Low-Resolution Spectrometer (MIRI-LRS), covering the wavelength range from 5 -- 12~$μ\rm{m}$, and the Imager, providing us with 12.8, 15, 18 and 21\,$μ$m photometric measurements. We carried the data reduction of those datasets, tackling second-order effects to ensure a reliable retrieval analysis. Using the \textsc{TauREx} retrieval code, we inferred the pressure-temperature structure, atmospheric chemistry, mass, and radius of the planet. The spectrum of WD 0806-661 b is shaped by molecular absorption of water, ammonia, and methane, consistent with a cold Jupiter atmosphere, allowing us to retrieve their abundances. From the mixing ratio of water, ammonia and methane we derive $\rm{C/O} = 0.34 \pm 0.06$, $\rm{C/N} = 14.4 ^{+2.5}_{-1.8}$ and $\rm{N/O} = 0.023 \pm 0.004$ and the ratio of detected metals as proxy for metallicity. We also derive upper limits for the abundance of CO and $\rm{CO_2}$ ($1.2\cdot10^{-6} \rm{\,and\,} 1.6\cdot10^{-7}$ respectively), which were not detected by our retrieval models. While our interpretation of WD\,0806-661\,b's atmosphere is mostly consistent with our theoretical understanding, some results -- such as the lack of evidence for water clouds, an apparent increase in the mixing ratio of ammonia at low pressure, or the retrieved mass at odds with the supposed age -- remain surprising and require follow-up observational and theoretical studies to be confirmed.

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arXiv2025

Simple molecules and complex chemistry in a protoplanetary disk: A JWST investigation of the highly inclined disk d216-0939

While the number of detected molecules, particularly complex organic molecules, in the solid-state in astrophysical environments is still rather limited, laboratory experiments and astrochemical models predict many potential candidates. Detection of molecules in protoplanetary disks provides a bridge between the chemical evolution of the interstellar medium and the chemistry of planets and their atmospheres. The excellent spectral sensitivity, broad wavelength coverage and high spatial resolution of the James Webb Space Telescope (JWST) allows for making progress in exploring chemical compositions of various astrophysical environments including planet-forming disks. They are a prerequisite for probing the disk content by means of sensitive absorption studies. In this paper, we present initial results of the JWST Cycle 1 GO program 1741 on d216-0939, a highly inclined TTauri disk located in the outskirts of the Orion Nebula Cluster. We utilise the NIRSpec and MIRI integral field unit spectrographs to cover its spectrum from 1.7 to 28~$μ$m. In the d216-0939 disk, we give assignments of the composition of silicate grains. We unambiguously detect solid-state features of H$_2$O, CO$_2$, $^{13}$CO$_2$, CO, OCN$^-$, and tentatively OCS; species that had been detected recently also in other circumstellar disks. For the first time in disks, we provide unique detections of ices carrying NH$_4^+$ and the complex organic molecule ammonium carbamate (NH$_4^+$NH$_2$COO$^-$). The latter detections speak for a very efficient NH$_3$ chemistry in the disk. We also show the very important role of scattering in the analysis of observational spectra of highly inclined disks.

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arXiv2024

Combined analysis of the 12.8 and 15 $μm$ JWST/MIRI eclipse observations of TRAPPIST-1 b

The first JWST/MIRI photometric observations of TRAPPIST-1 b allowed for the detection of the thermal emission of the planet at 15 $μm$, suggesting that the planet could be a bare rock with a zero albedo and no redistribution of heat. These observations at 15 $μm$ were acquired as part of GTO time that included a twin program at 12.8 $μm$ in order to have a measurement in and outside the CO$_2$ absorption band. Here we present five new occultations of TRAPPIST-1 b observed with MIRI in an additional photometric band at 12.8 $μm$. We perform a global fit of the 10 eclipses and derive a planet-to-star flux ratio and 1-$σ$ error of 452 $\pm$ 86 ppm and 775 $\pm$ 90 ppm at 12.8 $μm$ and 15 $μm$, respectively. We find that two main scenarios emerge. An airless planet model with an unweathered (fresh) ultramafic surface, that could be indicative of relatively recent geological processes fits well the data. Alternatively, a thick, pure-CO2 atmosphere with photochemical hazes that create a temperature inversion and result in the CO2 feature being seen in emission also works, although with some caveats. Our results highlight the challenges in accurately determining a planet's atmospheric or surface nature solely from broadband filter measurements of its emission, but also point towards two very interesting scenarios that will be further investigated with the forthcoming phase curve of TRAPPIST-1 b.

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arXiv2024

Toward Exoplanet Transit Spectroscopy Using JWST/MIRI's Medium Resolution Spectrometer

The Mid-Infrared Instrument (MIRI)'s Medium Resolution Spectrometer (the MRS) on JWST has potentially important advantages for transit and eclipse spectroscopy of exoplanets, including lack of saturation for bright host stars, wavelength span to longward of 20 microns, and JWST's highest spectral resolving power. We here test the performance of the MRS for time series spectroscopy by observing the secondary eclipse of the bright stellar eclipsing binary R Canis Majoris. Our observations push the MRS into saturation at the shortest wavelength, more than for any currently known exoplanet system. We find strong charge migration between pixels that we mitigate using a custom data analysis pipeline. Our data analysis recovers much of the spatial charge migration by combining detector pixels at the group level, via weighting by the point spread function. We achieve nearly photon-limited performance in time series data at wavelengths longward of 5.2 microns. In 2017, Snellen et al. suggested that the MRS could be used to detect carbon dioxide absorption from the atmosphere of the temperate planet orbiting Proxima Centauri. We infer that the relative spectral response of the MRS versus wavelength is sufficiently stable to make that detection feasible. As regards the secondary eclipse of this Algol-type binary, we measure the eclipse depth by summing our spectra over the wavelengths in four channels, and also measuring the eclipse depth as observed by TESS. Those eclipse depths require a temperature for the secondary star that is significantly hotter than previous observations in the optical to near-IR, probably due to irradiation by the primary star. At full spectral resolution of the MRS, we find atomic hydrogen recombination emission lines in the secondary star, from principal quantum levels n = 7, 8, 10, and 14.

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arXiv2024

MINDS: The JWST MIRI Mid-INfrared Disk Survey

The study of protoplanetary disks has become increasingly important with the Kepler satellite finding that exoplanets are ubiquitous around stars in our galaxy and the discovery of enormous diversity in planetary system architectures and planet properties. High-resolution near-IR and ALMA images show strong evidence for ongoing planet formation in young disks. The JWST MIRI mid-INfrared Disk Survey (MINDS) aims to (1) investigate the chemical inventory in the terrestrial planet-forming zone across stellar spectral type, (2) follow the gas evolution into the disk dispersal stage, and (3) study the structure of protoplanetary and debris disks in the thermal mid-IR. The MINDS survey will thus build a bridge between the chemical inventory of disks and the properties of exoplanets. The survey comprises 52 targets (Herbig Ae stars, T Tauri stars, very low-mass stars and young debris disks). We primarily obtain MIRI/MRS spectra with high S/N (~100-500) covering the complete wavelength range from 4.9 to 27.9 μm. For a handful of selected targets we also obtain NIRSpec IFU high resolution spectroscopy (2.87-5.27 μm). We will search for signposts of planet formation in thermal emission of micron-sized dust - information complementary to near-IR scattered light emission from small dust grains and emission from large dust in the submillimeter wavelength domain. We will also study the spatial structure of disks in three key systems that have shown signposts for planet formation, TW Hya and HD 169142 using the MIRI coronagraph at 15.5 μm and 10.65 μm respectively and PDS70 using NIRCam imaging in the 1.87 μm narrow and the 4.8 μm medium band filter. ...

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arXiv2024

Transiting exoplanets with the Mid-InfraRed Instrument on board the James Webb Space Telescope: From simulations to observations

The James Webb Space Telescope (JWST) has now started its exploration of exoplanetary worlds. In particular, the Mid-InfraRed Instrument (MIRI) with its Low-Resolution Spectrometer (LRS) carries out transit, eclipse, and phase-curve spectroscopy of exoplanetary atmospheres with unprecedented precision in a so far almost uncharted wavelength range. The precision and significance in the detection of molecules in exoplanetary atmospheres rely on a thorough understanding of the instrument itself and accurate data reduction methods. This paper aims to provide a clear description of the instrumental systematics that affect observations of transiting exoplanets through the use of simulations. We carried out realistic simulations of transiting-exoplanet observations with the MIRI LRS instrument that included the model of the exoplanet system, the optical path of the telescope, the MIRI detector performances, and instrumental systematics and drifts that could alter the atmospheric features we are meant to detect in the data. After introducing our pipeline, we show its performance on the transit of L168-9b, a super-Earth-sized exoplanet observed during the commissioning of the MIRI instrument. This paper provides a better understanding of the data themselves and of the best practices in terms of reduction and analysis through comparisons between simulations and real data. We show that simulations validate the current data-analysis methods. Simulations also highlight instrumental effects that impact the accuracy of our current spectral extraction techniques. These simulations are proven to be essential in the preparation of JWST observation programs and help us assess the detectability of various atmospheric and surface scenarios.

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arXiv2023

15NH3 in the atmosphere of a cool brown dwarf

Brown dwarfs serve as ideal laboratories for studying the atmospheres of giant exoplanets on wide orbits as the governing physical and chemical processes in them are nearly identical. Understanding the formation of gas giant planets is challenging, often involving the endeavour to link atmospheric abundance ratios, such as the carbon-to-oxygen (C/O) ratio, to formation scenarios. However, the complexity of planet formation requires additional tracers, as the unambiguous interpretation of the measured C/O ratio is fraught with complexity. Isotope ratios, such as deuterium-to-hydrogen and 14N/15N, offer a promising avenue to gain further insight into this formation process, mirroring their utility within the solar system. For exoplanets only a handful of constraints on 12C/13C exist, pointing to the accretion of 13C-rich ice from beyond the disks' CO iceline. Here we report on the mid-infrared detection of the 14NH3 and 15NH3 isotopologues in the atmosphere of a cool brown dwarf with an effective temperature of 380 K in a spectrum taken with the Mid-InfraRed Instrument of the James Webb Space Telescope. As expected, our results reveal a 14N/15N value consistent with star-like formation by gravitational collapse, demonstrating that this ratio can be accurately constrained. Since young stars and their planets should be more strongly enriched in the 15N isotope, we expect that 15NH3 will be detectable in a number of cold, wide-separation exoplanets.

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arXiv2023

MINDS. Abundant water and varying C/O across the disk of Sz 98 as seen by JWST/MIRI

MIRI/MRS on board the JWST allows us to probe the inner regions of protoplanetary disks. Here we examine the disk around the classical T Tauri star Sz 98, which has an unusually large dust disk in the millimetre with a compact core. We focus on the H$_2$O emission through both its ro-vibrational and pure rotational emission. Furthermore, we compare our chemical findings with those obtained for the outer disk from Atacama Large Millimeter/submillimeter Array (ALMA) observations. In order to model the molecular features in the spectrum, the continuum was subtracted and LTE slab models were fitted. The spectrum was divided into different wavelength regions corresponding to H$_2$O lines of different excitation conditions, and the slab model fits were performed individually per region. We confidently detect CO, H$_2$O, OH, CO$_2$, and HCN in the emitting layers. The isotopologue H$^{18}_2$O is not detected. Additionally, no other organics, including C$_2$H$_2$, are detected. This indicates that the C/O ratio could be substantially below unity, in contrast with the outer disk. The H$_2$O emission traces a large radial disk surface region, as evidenced by the gradually changing excitation temperatures and emitting radii. The OH and CO$_2$ emission are relatively weak. It is likely that H$_2$O is not significantly photodissociated; either due to self-shielding against the stellar irradiation, or UV-shielding from small dust particles. The relative emitting strength of the different identified molecular features point towards UV-shielding of H$_2$O in the inner disk of Sz 98, with a thin layer of OH on top. The majority of the organic molecules are either hidden below the dust continuum, or not present. In general, the inferred composition points to a sub-solar C/O ratio (<0.5) in the inner disk, in contrast with the larger than unity C/O ratio in the gas in the outer disk found with ALMA.

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arXiv2023

The Brighter-Fatter Effect in the JWST MIRI Si:As IBC detectors I. Observations, impact on science, and modelling

The Mid-Infrared Instrument (MIRI) on board the James Webb Space Telescope (JWST) uses three Si:As impurity band conduction (IBC) detector arrays. The output voltage level of each MIRI detector pixel is digitally recorded by sampling-up-the-ramp. For uniform or low-contrast illumination, the pixel ramps become non-linear in a predictable way, but in areas of high contrast, the non-linearity curve becomes much more complex. The origin of the effect is poorly understood and currently not calibrated. We provide observational evidence of the Brighter-Fatter Effect (BFE) in MIRI conventional and high-contrast coronographic imaging, low-resolution spectroscopy, and medium-resolution spectroscopy data and investigate the physical mechanism that gives rise to the effect on the MIRI detector pixel raw voltage integration ramps. We use public data from the JWST MIRI commissioning and Cycle 1 phase. We also develop a numerical electrostatic model of the MIRI detectors using a modified version of the public Poisson_CCD code. We find that the physical mechanism behind the BFE manifesting in MIRI data is fundamentally different to that of CCDs and photodiode arrays such as the Hawaii-XRG (HXRG) near-infrared detectors used by the NIRISS, NIRCam, and NIRSpec instruments on board JWST. Observationally, the BFE makes the JWST MIRI data yield 10-25 % larger point sources and spectral line profiles as a function of the relative level of debiasing of neighboring detector pixels. This broadening impacts the MIRI absolute flux calibration, time-series observations of faint companions, and PSF modeling and subtraction. We also find that the intra-pixel 2D profile of the shrinking Si:As IBC detector depletion region directly impacts the accuracy of the pixel ramp non-linearity calibration model.

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arXiv2023

The Chemical Inventory of the Inner Regions of Planet-forming Disks -- The JWST/MINDS Program

The understanding of planet formation has changed recently, embracing the new idea of pebble accretion. This means that the influx of pebbles from the outer regions of planet-forming disks to their inner zones could determine the composition of planets and their atmospheres. The solid and molecular components delivered to the planet-forming region can be best characterized by mid-infrared spectroscopy. With Spitzer low-resolution (R=100, 600) spectroscopy, this approach was limited to the detection of abundant molecules such as H2O, C2H2, HCN and CO2. This contribution will present first results of the MINDS (MIRI mid-IR Disk Survey, PI: Th. Henning) project. Due do the sensitivity and spectral resolution (R~1500-3500) provided by JWST we now have a unique tool to obtain the full inventory of chemistry in the inner disks of solar-types stars and brown dwarfs, including also less abundant hydrocarbons and isotopologues. The Integral Field Unit (IFU) capabilities enable at the same time spatial studies of the continuum and line emission in extended sources such as debris disks, the flying saucer and also the search for mid-IR signatures of forming planets in systems such as PDS70. These JWST observations are complementary to ALMA and NOEMA observations of the outer disk chemistry; together these datasets provide an integral view of the processes occurring during the planet formation phase.

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arXiv2023

Characterising a World Within the Hot Neptune Desert: Transit Observations of LTT 9779 b with HST WFC3

We present an atmospheric analysis of LTT 9779 b, a rare planet situated in the hot Neptune desert, that has been observed with HST WFC3 G102 and G141. The combined transmission spectrum, which covers 0.8 - 1.6 $μ$m, shows a gradual increase in transit depth with wavelength. Our preferred atmospheric model shows evidence for H$_{\rm 2}$O, CO$_{\rm 2}$ and FeH with a significance of 3.1 $σ$, 2.4 $σ$ and 2.1 $σ$, respectively. In an attempt to constrain the rate of atmospheric escape for this planet, we search for the 1.083 $μ$m Helium line in the G102 data but find no evidence of excess absorption that would indicate an escaping atmosphere using this tracer. We refine the orbital ephemerides of LTT 9779 b using our HST data and observations from TESS, searching for evidence of orbital decay or apsidal precession, which is not found. The phase-curve observation of LTT 9779 b with JWST NIRISS should provide deeper insights into the atmosphere of this planet and the expected atmospheric escape might be detected with further observations concentrated on other tracers such as Lyman $α$.

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arXiv2023

MINDS. The detection of $^{13}$CO$_{2}$ with JWST-MIRI indicates abundant CO$_{2}$ in a protoplanetary disk

We present JWST-MIRI MRS spectra of the protoplanetary disk around the low-mass T Tauri star GW Lup from the MIRI mid-INfrared Disk Survey (MINDS) GTO program. Emission from $^{12}$CO$_{2}$, $^{13}$CO$_{2}$, H$_{2}$O, HCN, C$_{2}$H$_{2}$, and OH is identified with $^{13}$CO$_{2}$ being detected for the first time in a protoplanetary disk. We characterize the chemical and physical conditions in the inner few au of the GW Lup disk using these molecules as probes. The spectral resolution of JWST-MIRI MRS paired with high signal-to-noise data is essential to identify these species and determine their column densities and temperatures. The $Q$-branches of these molecules, including those of hot-bands, are particularly sensitive to temperature and column density. We find that the $^{12}$CO$_{2}$ emission in the GW Lup disk is coming from optically thick emission at a temperature of $\sim$400 K. $^{13}$CO$_{2}$ is optically thinner and based on a lower temperature of $\sim$325 K, may be tracing deeper into the disk and/or a larger emitting radius than $^{12}$CO$_{2}$. The derived $N_{\rm{CO_{2}}}$/$N_{\rm{H_{2}O}}$ ratio is orders of magnitude higher than previously derived for GW Lup and other targets based on \textit{Spitzer}-IRS data. This high column density ratio may be due to an inner cavity with a radius in between the H$_{2}$O and CO$_{2}$ snowlines and/or an overall lower disk temperature. This paper demonstrates the unique ability of JWST to probe inner disk structures and chemistry through weak, previously unseen molecular features.

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arXiv2023

The Science Performance of JWST as Characterized in Commissioning

This paper characterizes the actual science performance of the James Webb Space Telescope (JWST), as determined from the six month commissioning period. We summarize the performance of the spacecraft, telescope, science instruments, and ground system, with an emphasis on differences from pre-launch expectations. Commissioning has made clear that JWST is fully capable of achieving the discoveries for which it was built. Moreover, almost across the board, the science performance of JWST is better than expected; in most cases, JWST will go deeper faster than expected. The telescope and instrument suite have demonstrated the sensitivity, stability, image quality, and spectral range that are necessary to transform our understanding of the cosmos through observations spanning from near-earth asteroids to the most distant galaxies.

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