SO2, silicate clouds, but no CH4 detected in a warm Neptune

Abstract

WASP-107b is a warm (~740 K) transiting planet with a Neptune-like mass of ~30.5 Earth masses and Jupiter-like radius of ~0.94 Jupiter radius, whose extended atmosphere is eroding. Previous observations showed evidence for water vapour and a thick high-altitude condensate layer in WASP-107b's atmosphere. Recently, photochemically produced sulphur dioxide (SO2) was detected in the atmosphere of a hot (~1200 K) Saturn-mass planet from transmission spectroscopy near 4.05 microns, but for temperatures below 1000 K sulphur is predicted to preferably form sulphur allotropes instead of SO2. Here we report the 9-sigma detection of two fundamental vibration bands of SO2, at 7.35 microns and 8.69 microns, in the transmission spectrum of WASP-107b using the Mid-Infrared Instrument (MIRI) of the JWST. This discovery establishes WASP-107b as the second irradiated exoplanet with confirmed photochemistry, extending the temperature range of exoplanets exhibiting detected photochemistry from ~1200 K down to ~740 K. Additionally, our spectral analysis reveals the presence of silicate clouds, which are strongly favoured (~7-sigma) over simpler cloud setups. Furthermore, water is detected (~12-sigma), but methane is not. These findings provide evidence of disequilibrium chemistry and indicate a dynamically active atmosphere with a super-solar metallicity.