arXiv subjects

Jesús Martín-Pintado

Publications and source records attributed to Jesús Martín-Pintado.

34 records · Page 2Linked to original sources

arXiv2021

Probing the chemical complexity of amines in the ISM: detection of vinylamine (C$_2$H$_3$NH$_2$) and tentative detection of ethylamine (C$_2$H$_5$NH$_2$)

Amines, in particular primary amines (R-NH$_2$) are closely related to the primordial synthesis of amino acids since they share the same structural backbone. However, only limited number of amines has been identified in the ISM which prevents us from studying their chemistry as well as their relation to pre-biotic species that could lead to the emergence of life. In this letter, we report the first interstellar detection of vinylamine (C$_2$H$_3$NH$_2$) and tentative detection of ethylamine (C$_2$H$_5$NH$_2$) towards the Galactic Centre cloud G+0.693-0.027. The derived abundance with respect to H$_2$ is (3.3$\pm$0.4)$\times$10$^{-10}$ and (1.9$\pm$0.5)$\times$10$^{-10}$, respectively. The inferred abundance ratios of C$_2$H$_3$NH$_2$ and C$_2$H$_5$NH$_2$ with respect to methylamine (CH$_3$NH$_2$) are $\sim$0.02 and $\sim$0.008 respectively. The derived abundance of C$_2$H$_3$NH$_2$, C$_2$H$_5$NH$_2$ and several other NH$_2$-bearing species are compared to those obtained towards high-mass and low-mass star-forming regions. Based on recent chemical and laboratory studies, possible chemical routes for the interstellar synthesis of C$_2$H$_3$NH$_2$ and C$_2$H$_5$NH$_2$ are discussed.

astro-ph.GA↗

arXiv2021

Discovery in space of ethanolamine, the simplest phospholipid head group

Cell membranes are a key element of life because they keep the genetic material and metabolic machinery together. All present cell membranes are made of phospholipids, yet the nature of the first membranes and the origin of phospholipids are still under debate. We report here the first detection in space of ethanolamine, NH$_2$CH$_2$CH$_2$OH, which forms the hydrophilic head of the simplest and second most abundant phospholipid in membranes. The molecular column density of ethanolamine in interstellar space is $N$=(1.51$\pm$0.07)$\times$10$^{13}$ cm$^{-2}$, implying a molecular abundance with respect to H$_2$ of (0.9-1.4)$\times$10$^{-10}$. Previous studies reported its presence in meteoritic material but they suggested that it is synthesized in the meteorite itself by decomposition of amino acids. However, we find that the proportion of the molecule with respect to water in the interstellar medium is similar to the one found in the meteorite (10$^{-6}$). These results indicate that ethanolamine forms efficiently in space and, if delivered onto early Earth, it could have contributed to the assembling and early evolution of primitive membranes.

astro-ph.GA↗

arXiv2021

Thiols in the ISM: first detection of HC(O)SH and confirmation of C$_2$H$_5$SH

The chemical compounds carrying the thiol group (-SH) have been considered essential in recent prebiotic studies regarding the polymerization of amino acids. We have searched for this kind of compounds toward the Galactic Centre quiescent cloud G+0.693-0.027. We report the first detection in the interstellar space of the trans-isomer of monothioformic acid (t-HC(O)SH) with an abundance of $\sim\,$1$\,\times\,$10$^{-10}$. Additionally, we provide a solid confirmation of the gauche isomer of ethyl mercaptan (g-C$_2$H$_5$SH) with an abundance of $\sim\,$3$\,\times\,$10$^{-10}$, and we also detect methyl mercaptan (CH$_3$SH) with an abundance of $\sim\,$5$\,\times\,$10$^{-9}$. Abundance ratios were calculated for the three SH-bearing species and their OH-analogues, revealing similar trends between alcohols and thiols with increasing complexity. Possible chemical routes for the interstellar synthesis of t-HC(O)SH, CH$_3$SH and C$_2$H$_5$SH are discussed, as well as the relevance of these compounds in the synthesis of prebiotic proteins in the primitive Earth.

astro-ph.GA↗

arXiv2021

The origin of the E/Z isomer ratio of imines in the interstellar medium

Recent astronomical observations of both isomers E and Z of imines such as cyanomethanimine, ethanimine and 2-propyn-1-imine, have revealed that the abundances in the ISM of these isomers differ by factors of ~3-10. Several theories have been proposed to explain the observed behavior, but none of them successfully explains the [E]/[Z] ratios. In this work we present a detailed study of the kinetics of the one-step E-Z isomerization reactions of cyanomethanimine, ethanimine and 2-propyn-1-imine under interstellar conditions (in the 10-400 K temperature range). This reaction was previously thought to be non-viable in the ISM due to its associated high-energy barrier (about 13,000 K). In this Letter, we show that considering the multidimensional small curvature tunneling approximation, the tunneling effect enables the isomerization even at low temperatures. This is due to the fact that the representative tunneling energy lies in the vibrational ground state of the least stable isomer up to approximately 150 K, making the reaction constants of the isomerization from the least stable to the most stable isomer basically constant. The predicted [E]/[Z] ratios are almost the same as those reported from the astronomical observations for all imines observed. This study demonstrates that the [E]/[Z] ratio of imines in the ISM strongly depends on their relative stability.

physics.chem-ph↗

arXiv2021

Vibrationally excited HC3N emission in NGC1068: Tracing the recent star formation in the starburst ring

Using ALMA data, we have studied the HC$_3$N and continuum emission in the starburst ring (SB ring) and the circumnuclear disc (CND) of the SB/AGN composite galaxy NGC 1068. We have detected emission from vibrationally excited HC$_3$N (HC$_3$N*) only towards one star-forming region of the SB ring. Remarkably, HC$_3$N* was not detected towards the CND despite its large HC$_3$N $v=0$ column density. From LTE and non-LTE modelling of HC$_3$N*, we obtained a dust temperature of $ T_\text{dust} \sim 250$ K and a density of $n_{\text{H}_2}=6\times10^5$ cm$^{-3}$ for this star-forming region. The estimated IR luminosity of $5.8\times10^8$ L$_\odot$ is typical of proto-Super Star Clusters (proto-SSC) observed in the SB galaxy NGC 253. We use the continuum emissions at $147$ GHz and $350$ GHz, along with CO and Pa $α$, to estimate the ages of other $14$ SSCs in the SB ring. We find the youngest SSCs to be associated with the region connecting the nuclear bar with the SB ring, supporting the scenario of sequential star formation. For the CND, our analysis yields $T_\text{dust} \leqslant 100$ K and $n_{\text{H}_2}\sim(3-6)\times10^5$cm$^{-3}$. The very different dust temperatures found for the CND and the proto-SSC indicates that, while the dust in the proto-SSC is being efficiently heated from the inside by the radiation from massive proto-stars, the CND is being heated externally by the AGN, which in the IR optically thin case can only heat the dust to $56$ K. We discuss the implications of the non-detection of HC$_3$N* near the luminous AGN in NGC 1068 on the interpretation of the HC$_3$N* emission observed in the SB/AGN composite galaxies NGC 4418 and Arp 220.

astro-ph.GA↗

arXiv2020

A proto-pseudobulge in ESO 320-G030 fed by a massive molecular inflow driven by a nuclear bar

Galaxies with nuclear bars are believed to efficiently drive gas inward, generating a nuclear starburst and possibly an active galactic nucleus (AGN). We confirm this scenario for the isolated, double-barred, luminous infrared galaxy ESO 320-G030 based on an analysis of Herschel and ALMA spectroscopic observations. Herschel/PACS and SPIRE observations of ESO 320-G030 show absorption/emission in 18 lines of H2O, which we combine with the ALMA H2O 423-330 448 GHz line (Eupper~400 K) and continuum images to study the nuclear region. Radiative transfer models indicate that 3 nuclear components are required to account for the H2O and continuum data. An envelope, with R~130-150 pc, T_dust~50 K, and N_H2~2x10^{23} cm^{-2}, surrounds a nuclear disk with R~40 pc and tau_100um~1.5-3 (N_H2~2x10^{24} cm^{-2}) and an extremely compact (R~12 pc), warm (~100 K), and buried (tau_100um>5, N_H2>~5x10^{24} cm^{-2}) core component. The three nuclear components account for 70% of the galaxy L_IR (SFR~16-18 Msun yr^{-1}). The nucleus is fed by a molecular inflow observed in CO 2-1 with ALMA, which is associated with the nuclear bar. With decreasing radius (r=450-225 pc), the mass inflow rate increases up to ~20 Msun yr^{-1}, which is similar to the nuclear SFR, indicating that the starburst is sustained by the inflow. At lower r, the inflow is best probed by the far-infrared OH ground-state doublets, with an estimated inflow rate of ~30 Msun yr^{-1}. The short timescale of ~20 Myr for nuclear gas replenishment indicates quick secular evolution, and indicates that we are witnessing an intermediate stage (<100 Myr) proto-pseudobulge fed by a massive inflow that is driven by a strong nuclear bar. We also apply the H2O model to the Herschel far-infrared spectroscopic observations of H2^{18}O, OH, $^{18}OH, OH+, H2O^+, H3O^+, NH, NH2, NH3, CH, CH^+, ^{13}CH^+, HF, SH, and C3, and estimate their abundances.

astro-ph.GA↗

arXiv2020

Structure and kinematics of shocked gas in Sgr B2: further evidence of a cloud-cloud collision from SiO emission maps

We present SiO J=2-1 maps of the Sgr B2 molecular cloud, which show shocked gas with a turbulent substructure comprising at least three cavities at velocities of [10,40] km s$^{-1}$ and an arc at velocities of [-20,10] km s$^{-1}$. The spatial anti-correlation of shocked gas at low and high velocities, and the presence of bridging features in position-velocity diagrams suggest that these structures formed in a cloud-cloud collision. Some of the known compact HII regions spatially overlap with sites of strong SiO emission at velocities of [40,85] km s$^{-1}$, and are between or along the edges of SiO gas features at [100,120] km s$^{-1}$, suggesting that the stars responsible for ionizing the compact HII regions formed in compressed gas due to this collision. We find gas densities and kinetic temperatures of the order of $n_{\rm H_2}\sim 10^5\rm cm^{-3}$ and $\sim$30 K, respectively, towards three positions of Sgr B2. The average values of the SiO relative abundances, integrated line intensities, and line widths are $\sim$10$^{-9}$, $\sim$11 K km s$^{-1}$, and $\sim$31 km s$^{-1}$, respectively. These values agree with those obtained with chemical models that mimic grain sputtering by C-type shocks. A comparison of our observations with hydrodynamical simulations shows that a cloud-cloud collision that took place $\lesssim$ 0.5 Myr ago can explain the density distribution with a mean column density of $\bar{N}_{\rm H_2}\gtrsim 5\times10^{22}$ cm$^{-2}$, and the morphology and kinematics of shocked gas in different velocity channels. Colliding clouds are efficient at producing internal shocks with velocities $\sim$5-50 km $s^{-1}$. High-velocity shocks are produced during the early stages of the collision and can readily ignite star formation, while moderate- and low-velocity shocks are important over longer timescales and can explain the widespread SiO emission in Sgr B2.

astro-ph.GA↗

arXiv2020

Prebiotic precursors of the primordial RNA world in space: Detection of NH$_{2}$OH

One of the proposed scenarios for the origin of life is the primordial RNA world, which considers that RNA molecules were likely responsible for the storage of genetic information and the catalysis of biochemical reactions in primitive cells, before the advent of proteins and DNA. In the last decade, experiments in the field of prebiotic chemistry have shown that RNA nucleotides can be synthesized from relatively simple molecular precursors, most of which have been found in space. An important exception is hydroxylamine, NH$_2$OH, which, despite several observational attempts, it has not been detected in space yet. Here we present the first detection of NH$_2$OH in the interstellar medium towards the quiescent molecular cloud G+0.693-0.027 located in the Galactic Center. We have targeted the three groups of transitions from the $J$=2$-$1, 3$-$2, and 4$-$3 rotational lines, detecting 5 transitions that are unblended or only slightly blended. The derived molecular abundance of NH$_2$OH is (2.1$\pm$0.9)$\times$10$^{-10}$. From the comparison of the derived abundance of NH$_2$OH and chemically related species, with those predicted by chemical models and measured in laboratory experiments, we favor the formation of NH$_2$OH in the interstellar medium via hydrogenation of NO on dust grain surfaces, with possibly a contribution of ice mantle NH$_3$ oxidation processes. Further laboratory studies and quantum chemical calculations are needed to completely rule out the formation of NH$_2$OH in the gas phase.

astro-ph.GA↗

arXiv2020

The multi-phase ISM in the nearby composite AGN-SB galaxy NGC 4945: large (parsecs) scale mechanical heating

We aim at carrying out a comprehensive study of the nearby composite AGN-SB galaxy, NGC 4945, using spectroscopic and photometric data from the Herschel satellite. In particular, we want to characterize the thermal structure in this galaxy by a multi-transitions analysis of the spatial distribution of the 12^CO emission at different spatial scales using HIFI, PACS, SPIRE as well as APEX data. We combined the 12^CO/IR flux ratios and the LTE analysis of the 12^CO images to derive the thermal structure of the Interstellar Medium (ISM) for spatial scales raging from <200 pc to 2 kpc. From the 12^CO analysis we found clear trend in the distribution of the derived temperatures and the 12^CO/IR ratios. It is remarkable that at intermediate scales (360 pc-1 kpc) we see large temperatures in the direction of the X-ray outflow while at smaller scales (<200 pc-360 pc), the highest temperature, derived from the high-J lines, is not found toward the nucleus, but toward the galaxy plane. The thermal structure derived from the 12CO multi-transition analysis suggests that mechanical heating, like shocks or turbulence, dominates the heating of the ISM in the nucleus of NGC 4945 located beyond 100 pc from the center of the galaxy. This result is further supported by the Kazandjian et al. 2015 models, which are able to reproduce the emission observed at high-J (PACS) 12^CO transitions when mechanical heating mechanisms are included. Shocks and/or turbulence are likely produced by the barred potential and the outflow, observed in X-rays.

astro-ph.GA↗

arXiv2018

Evidence for the First Extragalactic Hydrogen Recombination Line Maser in NGC 253

We present the first detection of extragalactic hydrogen recombination line maser emission in the H26alpha transition toward the inner 13.5 pc nuclear region of the starburst galaxy NGC 253 using ALMA data. In regions with complex continuum emission (dust, free-free and synchrotron) we propose to use the recombination line spectral index, $α_\mathrm{L}$ ($S_\mathrm{L}\cdot Δv \propto ν^{α_\mathrm{L}}$), between the H30alpha and the H26alpha lines to study the structure of ultra-compact HII regions and to identify maser emission ($α_\mathrm{L}> 2.1$) from ionized winds. The measured values of $α_\mathrm{L}$ ranged from 1.0 to 2.9. The largest $α_\mathrm{L}$ can only be explained by maser emission. The measured flux density in the H26$α$ maser in NGC 253 suggests that we are observing hundreds of stars like MWC349A, a prototypical stellar wind where maser emission arises from its circumstellar disk. We briefly discuss the implication of the detection of maser emission in starburst galaxies like NGC 253.

astro-ph.GA↗

arXiv2018

The first detections of the key prebiotic molecule PO in star-forming regions

Phosphorus is a crucial element in prebiotic chemistry, especially the P$-$O bond, which is key for the formation of the backbone of the deoxyribonucleic acid. So far, PO had only been detected towards the envelope of evolved stars, and never towards star-forming regions. We report the first detection of PO towards two massive star-forming regions, W51 e1/e2 and W3(OH), using data from the IRAM 30m telescope. PN has also been detected towards the two regions. The abundance ratio PO/PN is 1.8 and 3 for W51 and W3(OH), respectively. Our chemical model indicates that the two molecules are chemically related and are formed via gas-phase ion-molecule and neutral-neutral reactions during the cold collapse. The molecules freeze out onto grains at the end of the collapse and desorb during the warm-up phase once the temperature reaches $\sim$35 K. The observed molecular abundances of 10$^{-10}$ are predicted by the model if a relatively high initial abundance of phosphorus, 5$\times$10$^{-9}$, is assumed.

astro-ph.GA↗

arXiv2015

Lambda = 3 mm line survey of nearby active galaxies

We used the IRAM 30m telescope to observe the frequency range [86-116]GHz towards the central regions of the starburst galaxies M83, M82, and NGC253, the AGNs M51, NGC1068, and NGC7469, and the ULIRGs Arp220 and Mrk231. Assuming LTE conditions, we calculated the column densities of 27 molecules and 10 isotopologues. Among others, we report the first tentative detections of CH3CHO, HNCO, and NS in M82 and, for the first time in the extragalactic medium, HC5N in NGC253. Halpha recombination lines were only found in M82 and NGC253. Vibrationally excited lines of HC3N were only detected in Arp220. CH3CCH emission is only seen in the starburst-dominated galaxies. By comparison of the fractional abundances among the galaxies, we looked for the molecules that are best suited to characterise the chemistry of starbursts, AGNs and ULIRGs, as well as the differences among galaxies within the same group.

astro-ph.GA↗

arXiv2014

Origin of the ionized wind in MWC 349A

The UC-HII region of MWC 349A is the prototype of an ionized wind driven by a massive star surrounded by a disk. Recent high angular resolution observations of the millimeter recombination lines have shown that the disk rotates with a Keplerian law in its outer parts. However, the kinematics of innermost regions in the UC-HII region of MWC 349A is still unknown, in particular the radius where the wind is launched from the disk. We performed hydrogen recombination line observations with the Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory to study the kinematics of its innermost regions by studying their spectral features. In addition to the two laser peaks, we report the first detection of two new components that are blueshifted with respect to the laser peaks for all the recombination lines with principal quantum number n<22. These new spectral features originate from the region where the wind is ejected from the disk. We used our 3D non-LTE radiative transfer model for recombination lines (MORELI) to show that these features are consistent with the wind being ejected at a radius of about 24 AU from the star, which supports magnetohydrodynamic wind models.

astro-ph.SR↗

arXiv2013

A non-LTE radiative transfer model to study ionized outflows and disks. The case of MWC349A

Context. The best example of a massive star with an ionized outflow launched from its photoevaporating disk is MWC349A. The large amount of reported radio-continuum and radio-recombination line observations toward this galactic UC-HII region offers a unique possibility to build a model of the ionized envelope of this source. Aims. To understand the physical conditions and kinematics of the ionized region of the circumstellar disk and also of the outflow of MWC349A. Methods. We compared the bulk of radio-continuum maps, radio-recombination line profiles, and the H30alpha centroid map published to date with the predictions of our non-LTE 3D radiative transfer model, MORELI (MOdel for REcombination LInes), which we describe here in detail. Results. Our non-LTE 3D radiative transfer model provides new evidence that the UC-HII region of MWC349A is composed of an ionized circumstellar disk rotating in Keplerian fashion around a star of 38 solar mass, and an ionized outflow expanding with a terminal velocity of 60 km/s and rotating in the same sense as the disk. The model shows that while maser amplification is the dominant process involved for Hnαradio-recombination line (RRL) emission with quantum numbers n<41, stimulated emission is relevant for the emission of RRLs with n>41 up at least the H76alpha line. Conclusions. For the first time, we present a model of MWC349A which satisfactorily explains the vast amount of reported observational data for a very wide range of frequencies and angular resolutions.

astro-ph.SR↗

arXiv2011

A lambda = 1.3 mm and 2 mm molecular line survey towards M82

We study the chemical complexity towards the central parts of the starburst galaxy M82, and investigate the role of certain molecules as tracers of the physical processes in the galaxy circumnuclear region. We carried out a spectral line survey with the IRAM-30m telescope towards the northeastern molecular lobe of M82. It covers the frequency range between 129.8 GHz and 175.0 GHz in the 2 mm atmospheric window, and between 241.0 GHz and 260.0 GHz in the 1.3 mm atmospheric window. Sixty-nine spectral features corresponding to 18 different molecular species are identified. In addition, three hydrogen recombination lines are detected. The species NO, H2S, H2CS, NH2CN, and CH3CN are detected for the first time in this galaxy. Assuming local thermodynamic equilibrium, we determine the column densities of all the detected molecules. We also calculated upper limits to the column densities of fourteen other important, but undetected, molecules, such as SiO, HNCO, or OCS. We compare the chemical composition of the two starburst galaxies M82 and NGC253. This comparison enables us to establish the chemical differences between the products of the strong photon-dominated regions (PDRs) driving the heating in M82, and the large-scale shocks that influence the properties of the molecular clouds in the nucleus of NGC253. Overall, both sources have different chemical compositions. Some key molecules highlight the different physical processes dominating both central regions. Examples include CH3CCH, c-C3H2, or CO+, the abundances of which are clearly higher in M82 than in NGC253, pointing at photodissociating regions. On the other hand, species such as CH2NH, NS, SiO, and HOCO+ have abundances of up to one order of magnitude higher in NGC253 than in M82.

astro-ph.CO↗

arXiv2010

The magnetic precursor of L1448-mm: Excitation differences between ion and neutral fluids

Shock modelling predicts an electron density enhancement within the magnetic precursor of C-shocks. Previous observations of SiO, H13CO+, HN13C and H13CN toward the young L1448-mm outflow showed an over-excitation of the ion fluid that was attributed to an electron density enhancement in the precursor. We re-visit this interpretation and test if it still holds when we consider different source morphologies and kinetic temperatures for the observed molecules, and also give some insight on the spatial extent of the electron density enhancement around L1448-mm. We estimate the opacities of H13CO+ and HN13C by observing the J=3\to2 lines of rarer isotopologues to confirm that the emission is optically thin. To model the excitation of the molecules, we use the large velocity gradient (LVG) approximation with updated collisional coefficients to i) re- analyse the observations toward the positions where the over-excitation of H13CO+ has previously been observed [i.e. toward L1448- mm at offsets (0,0) and (0,-10)], and ii) to investigate if the electron density enhancement is still required for the cases of extended and compact emission, and for kinetic temperatures of up to 400 K. We also report several lines of SiO, HN13C and H13CO+ toward new positions around this outflow, to investigate the spatial extent of the over-excitation of the ions in L1448-mm. From the isotopologue observations, we find that the emission of H13CO+ and HN13C from the precursor is optically thin if this emission is extended. Using the new collisional coefficients, an electron density enhancement is still needed to explain the excitation of H13CO+ for extended emission and for gas temperatures of\le 400 K toward L1448-mm (0,-10), and possibly also toward L1448-mm (0,0). For compact emission the data cannot be fitted. We do not find any evidence for the over-excitation of the ion fluid toward the newly observed positions around L1448-mm. The observed line emission of SiO, H13CO+ and HN13C toward L1448-mm (0,0) and (0,-10) is consistent with an electron density enhancement in the precursor component, if this emission is spatially extended. This is also true for the case of high gas temperatures (\le400 K) toward the (0,-10) offset. The electron density enhancement seems to be restricted to the southern, redshifted lobe of the L1448-mm outflow. Interferometric images of the line emission of these molecules are needed to confirm the spatial extent of the over-excitation of the ions and thus, of the electron density enhancement in the magnetic precursor of L1448-mm.

astro-ph.SR↗