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Jiangfeng Du

Publications and source records attributed to Jiangfeng Du.

At least 19 recordsLinked to original sources
arXiv2026

Molecular chiral discrimination through symmetry-breaking spin dynamics

Molecular chirality plays a crucial role in physics, chemistry, life sciences and pharmacology. Nowadays, the chiral discrimination and control at the single-molecule level is urgently needed to reveal the origin of the chirality-relevant phenomena by recovering the information disturbed by the ensemble averaging. The method of magnetic resonance (MR), as one of powerful tools for structure analysis, is blind to the molecular chirality in the absence of a chiral reagent. Here we propose and experimentally demonstrate a direct MR-based method for determining the chirality at the single-molecule level through constructing the symmetry-breaking dynamics of nearby nuclear spins. In principle, the mirror asymmetry of two enantiomers in real space is manifested by breaking the joint symmetry of the mirror reflection and time reversal in spin space under spin dynamics. Experimentally, two enantiomers are indistinguishable from the dynamics of strongly-coupled but unpolarized nuclear spins, but diverge evidently in the dynamical results that break the field-inversion symmetry after spins are polarized. Our method and results will benefit the study of chirality-induced properties in the fields of chemistry and biology.

quant-ph↗
arXiv2025

Single-molecule Scale Nuclear Magnetic Resonance Spectroscopy using a Robust Near-Infrared Spin Sensor

Nuclear magnetic resonance (NMR) at the single-molecule level with atomic resolution holds transformative potential for structural biology and surface chemistry. Near-surface solid-state spin sensors with optical readout ability offer a promising pathway toward this goal. However, their extreme proximity to target molecules demands exceptional robustness against surface-induced perturbations. Furthermore, life science applications require these sensors to operate in biocompatible spectral ranges that minimize photodamage. In this work, we demonstrate that the PL6 quantum defect in 4H silicon carbide (4H-SiC) can serve as a robust near-infrared spin sensor. This sensor operates at tissue-transparent wavelengths and exhibits exceptional near-surface stability even at depth of 2 nm. Using shallow PL6 centers, we achieve nanoscale NMR detection of proton ($\mathrm{^{1}H}$) spins in immersion oil and fluorine ($\mathrm{^{19}F}$) spins in Fomblin, attaining a detection volume of $\mathrm{(3~nm)^3}$ and a sensitivity reaching the requirement for single-proton spin detection. This work establishes 4H-SiC quantum sensors as a compelling platform for nanoscale magnetic resonance, with promising applications in probing low-dimensional water phases, protein folding dynamics, and molecular interactions.

quant-ph↗
arXiv2025

Parallel accelerated electron paramagnetic resonance spectroscopy using diamond sensors

The nitrogen-vacancy (NV) center can serve as a magnetic sensor for electron paramagnetic resonance (EPR) measurements. Benefiting from its atomic size, the diamond chip can integrate a tremendous amount of NV centers to improve the magnetic-field sensitivity. However, EPR spectroscopy using NV ensembles is less efficient due to inhomogeneities in both sensors and targets. Spectral line broadening induced by ensemble averaging is even detrimental to spectroscopy. Here we show a kind of cross-relaxation EPR spectroscopy at zero field, where the sensor is tuned by an amplitude-modulated control field to match the target. The modulation makes detection robust to the sensor's inhomogeneity, while zero-field EPR is naturally robust to the target's inhomogeneity. We demonstrate an efficient EPR measurement on an ensemble of roughly 30000 NV centers. Our method shows the ability to not only acquire unambiguous EPR spectra of free radicals, but also monitor their spectroscopic dynamics in real time.

quant-ph↗
arXiv2025

Single-cell identification with quantum-enhanced nuclear magnetic resonance

Identification of individual cells within heterogeneous populations is essential for biomedical research and clinical diagnostics. Conventional labeling-based sorting methods, such as fluorescence-activated cell sorting and magnetic-activated cell sorting, enable precise sorting when reliable markers are available. However, their applicability is limited in cells lacking defined markers or sensitive to labeling, as labeling can compromise cellular viability and function. We present a single-cell identification approach using quantum-enhanced NMR with diamond nitrogen-vacancy centers for label-free detection of intracellular proton ($^1$H) signals. Using this method, we distinguish two human tumor cell lines by their proton spin-lattice ($T_1$) relaxation times, which serve as a cell-intrinsic physicochemical signature. It lays the groundwork for label-free sorting applications in rare cell analysis, personalized medicine, and single-cell diagnostics.

quant-ph↗
arXiv2025

High-Accuracy Temporal Prediction via Experimental Quantum Reservoir Computing in Correlated Spins

Physical reservoir computing provides a powerful machine learning paradigm that exploits nonlinear physical dynamics for efficient information processing. By incorporating quantum effects, quantum reservoir computing offers superior potential for machine learning applications, as quantum dynamics are exponentially costly to simulate classically. Here, we present a novel quantum reservoir computing approach based on correlated quantum spin systems, exploiting natural quantum many-body interactions to generate reservoir dynamics, thereby circumventing the practical challenges of deep quantum circuits. Our experimental implementation supports nontrivial quantum entanglement and exhibits sufficient dynamical complexity for high-performance machine learning. We achieve state-of-the-art performance in experiments on standard time-series benchmarks, reducing prediction error by 1 to 2 orders of magnitude compared to previous quantum reservoir experiments. In long-term weather forecasting, our 9-spin quantum reservoir delivers greater prediction accuracy than classical reservoirs with thousands of nodes. This represents the first experimental demonstration of quantum machine learning outperforming large-scale classical models on real-world tasks.

quant-ph↗
arXiv2025

Observation of hierarchy of Hilbert space ergodicities in the quantum dynamics of a single spin

Ergodicity, the property that all allowed configurations are explored over time, plays a pivotal role in explaining the equilibrium behavior of classical dynamical systems. Yet, such a property is typically precluded in quantum systems owing to the presence of energy eigenstates, which are stationary states in dynamics. However, recent theoretical works have argued that ergodic explorations of the Hilbert space, occurring at varying levels as measured by statistical pseudorandomness of the time-evolved quantum states, may be exhibited for quantum systems driven by Hamiltonians with aperiodic time dependencies, which do not face such obstacles. Here, we experimentally investigate the hierarchy of Hilbert-space ergodicities (HSE) achievable in the dynamics of a single quantum spin realized by a solid-state defect in diamond, upon subjecting it to various time-dependent modulations. Through continuous monitoring of spin trajectories with full state tomography, different degrees of HSE were observed, ranging from no HSE in a time-periodic (Floquet) drive, to partial HSE in a smoothly kicked time-quasiperiodic drive, to complete HSE in a drive composed of a sequence of kicks generated by the Fibonacci word. We formulate a theoretical understanding of the increasing levels of HSE observed by attributing them to increasing levels of complexities associated with the drive sequences, whose notions we elucidate. Our work constitutes the first unambiguous experimental evidence of Hilbert space ergodicity and promotes deeper investigations into the mechanisms and fine-grained levels with which closed quantum systems reach equilibrium.

quant-ph↗
arXiv2025

Error-resilient Reversal of Quantum Chaotic Dynamics Enabled by Scramblons

The emergence of the arrow of time in quantum many-body systems stems from the inherent tendency of Hamiltonian evolution to scramble quantum information and increase entanglement. While, in principle, one might counteract this temporal directionality by engineering a perfectly inverted Hamiltonian to reverse entanglement growth, such a scenario is fundamentally unstable because even minor imperfections in the backward evolution can be exponentially amplified, a hallmark of quantum many-body chaos. Therefore, successfully reversing quantum many-body dynamics demands a deep understanding of the underlying structure of quantum information scrambling and chaotic dynamics. In this letter, by using solid-state nuclear magnetic resonance on a macroscopic ensemble of randomly interacting spins, we measure the out-of-time-ordered correlator (OTOC) and validate key predictions of scramblon theory, a universal theoretical framework for information scrambling. Crucially, this theory enables us to isolate and mitigate errors in the OTOC caused by imperfections in the backward evolution. As a result, this protocol uncovers the anticipated exponential behavior of quantum many-body chaos and extracts the quantum Lyapunov exponent in a many-body experimental system for the first time. Our results push the fundamental limits of dynamical reversibility of complex quantum systems, with implications for quantum simulation and metrology.

cond-mat.str-el↗
arXiv2025

Time-Reversal Symmetry Protected Transport at Correlated Oxide Interfaces

Time-reversal symmetry (TRS) protection is core to topological physics, yet its role in correlated oxides-typically non-topological-remains underexplored. This limit hampers the potential in engineering exotic quantum states by fusing TRS protection and the rich emergent phenomena in the oxide platform. Here, we report evidence of a TRS-protected subband at oxygen vacancy-free LaAlO3/SrTiO3 interfaces. This subband causes a low-field quantum oscillation with anomalous characters: exceptionally light electron mass, aperiodicity, and susceptibility to magnetic fields. All findings align with a Rashba model in which TRS-protected transport occurs along quasi-1D ferroelastic domain walls, which possess a Dirac band topology and a giant Rashba spin-orbit coupling, two orders stronger than the 2D interface. Our results deepen the understanding of SrTiO3-based electron systems, unveiling an appealing new platform for quantum engineering.

cond-mat.mes-hall↗
arXiv2025

Entanglement-Enhanced Nanoscale Single-Spin Sensing

Detecting individual spins--including stable and metastable states--represents a fundamental challenge in quantum sensing with broad applications across condensed matter physics, quantum chemistry, and single-molecule magnetic resonance imaging. While nitrogen-vacancy (NV) centers in diamond have emerged as powerful nanoscale sensors, their performance for single-spin detection remains constrained by substantial environmental noise and restricted sensing volume. Here, we propose and demonstrate an entanglement-enhanced sensing protocol that overcomes these limitations through the strategic use of entangled NV pairs. Our approach achieves a 3.4-fold enhancement in sensitivity and a 1.6-fold reduction in spatial resolution relative to single NV centers under ambient conditions. The protocol employs carefully engineered entangled states that amplify target spin signals through quantum interference while suppressing environmental noise. Crucially, we extend these capabilities to resolve metastable single-spin dynamics, directly observing stochastic transitions between different spin states by identifying state-dependent coupling strengths. This dual functionality enables simultaneous detection of static and dynamic spin species for studying complex quantum systems. The achieved performance establishes entanglement-enhanced sensing as a viable pathway toward atomic-scale characterization of quantum materials and interface.

quant-ph↗
arXiv2025

Beating the break-even point with autonomous quantum error correction

Quantum error correction (QEC) is essential for practical quantum computing, as it protects fragile quantum information from errors by encoding it in high-dimensional Hilbert spaces. Conventional QEC protocols typically require repeated syndrome measurements, real-time feedback, and the use of multiple physical qubits for encoding. Such implementations pose significant technical complexities, particularly for trapped-ion systems, with high demands on precision and scalability. Here, we realize autonomous QEC with a logical qubit encoded in multiple internal spin states of a single trapped ion, surpassing the break-even point for qubit lifetime. Our approach leverages engineered spin-motion couplings to transfer error-induced entropy into motional modes, which are subsequently dissipated through sympathetic cooling with an ancilla ion, fully eliminating the need for measurement and feedback. By repetitively applying this autonomous QEC protocol under injected low-frequency noise, we extend the logical qubit lifetime to approximately 11.6 ms, substantially outperforming lifetime for both the physical qubit ($\simeq$0.9 ms) and the uncorrected logical qubit ($\simeq$0.8 ms), thereby beating the break-even point with autonomous protection of quantum information without measurement or post-selection. This work presents an efficient approach to fault-tolerant quantum computing that harnesses the intrinsic multi-level structure of trapped ions, providing a distinctive path toward scalable architectures and robust quantum memories with reduced overhead.

quant-ph↗
arXiv2025

Experimental realization and synchronization of a quantum van der Pol oscillator

Classical self-sustained oscillators, that generate periodic motion without periodic external forcing, are ubiquitous in science and technology. The realization of nonclassical self-oscillators is an important goal of quantum physics. We here present the experimental implementation of a quantum van der Pol oscillator, a paradigmatic autonomous quantum driven-dissipative system with nonlinear damping, using a single trapped atom. We demonstrate the existence of a quantum limit cycle in phase space in the absence of a drive and the occurrence of quantum synchronization when the nonlinear oscillator is externally driven. We additionally show that synchronization can be enhanced with the help of squeezing perpendicular to the direction of the drive and, counterintuitively, linear dissipation. We also observe the bifurcation to a bistable phase-space distribution for large squeezing. Our results pave the way for the exploration of self-sustained quantum oscillators and their application to quantum technology.

quant-ph↗
arXiv2025

New Constraints on Dark Photon Dark Matter with a Millimeter-Wave Dielectric Haloscope

Dark matter remains one of the most profound and unresolved mysteries in modern physics. To unravel its nature, numerous haloscope experiments have been implemented across various mass ranges. However, very few haloscope experiments conducted within millimeter-wave frequency range, which is in the favored mass region for well-motivated dark matter candidates. Here we designed and constructed a millimeter-wave dielectric haloscope featuring a dark matter detector composed of dielectric disks and a mirror. Using this setup, we conducted a search for randomly polarized dark photon dark matter and found no evidence for its existence. Our results established new constraints on the kinetic mixing parameter in the mass range from $387.72$ to $391.03$ $\mu eV$, improving the existing limits by two orders of magnitude. With future enhancements, our system has the potential to explore new parameter space for dark photon as well as axion dark matter within the millimeter-wave frequency range.

astro-ph.CO↗
arXiv2025

Constraints on Velocity and Spin Dependent Exotic Interaction at the Millimeter Scale with a Diamagnetic-levitated Force Sensor

Light bosons, beyond the standard model and as prominent candidates for dark matter, can mediate velocity and spin dependent exotic interaction between electron spins and nucleons. At short ranges, it remains an open challenge to test this exotic interaction with high precision. Here, we present a method based on diamagnetic-levitated force sensor to detect the exotic interaction at the millimeter scale. Improved constraints for the coupling $g_A^e g_V^N$ are established, within the force range spanning from 0.15 mm to 1.5 mm. And the constraint $|g_A^e g_V^N| \leq 4.39 \times10^{-26}$ at $\lambda$ = 0.5 mm at the $95 \%$ confidence level, significantly surpasses previous results by more than three orders of magnitude. The diamagnetic levitation force measurement system developed here can also be repurposed to probe other exotic spin-dependent interactions, such as the exotic spin-spin interaction. This system provides a platform for the exploration of dark matter.

hep-ph↗
arXiv2025

Scalable architecture for dark photon searches: Superconducting-qubit proof of principle

The dark photon is a well-motivated candidate of dark matter due to its potential to open the window of new physics beyond the Standard Model. A fundamental mass-range-sensitivity dilemma is always haunting the dark photon searching experiments: The resonant haloscopes have excellent sensitivity but are narrowband, and vice versa for the non-resonant ones. A scalable architecture integrating numerous resonant haloscopes will be a desirable solution to this dilemma. However, even the concept of scalable searching remains rarely explored, due to the size limitation of conventional haloscopes imposed by the dark photon wavelength. Here we propose and demonstrate a novel architecture using superconducting qubits as sub-wavelength haloscope units. By virtue of the scalability of superconducting qubits, it is possible to integrate multiple qubits with different frequencies on a chip-scale device. Furthermore, the frequencies of the qubits can be tuned to extend the searching mass range. Thus, our architectures allow for searching for dark photons in a broad mass range with high sensitivity. As a proof-of-principle experiment, we designed and fabricated a three-qubit chip and successfully demonstrated a scalable dark-photon searching. Our work established constraints on dark photons in the mass range of 15.632 $\mu$eV$\sim$15.638 $\mu$eV, 15.838 $\mu$eV$\sim$15.845 $\mu$eV, and 16.463 $\mu$eV$\sim$16.468 $\mu$eV, simultaneously, and the constraints are much more stringent than the cosmology constraints. Our work can be scaled up in the future to boost the scrutiny of new physics and extended to search for more dark matter candidates, including dark photons, axions and axion-like particles.

hep-ph↗
arXiv2025

Non-Hermitian non-Abelian topological transition in the S=1 electron spin system of a nitrogen vacancy centre in diamond

Topological phases and transitions are of fundamental importance in physics, which provide a deep insight into the understanding of materials. Recently, non-Abelian topological transitions have been investigated in Hermitian systems, revealing important topological features. With non-Hermiticity introduced, non-Hermitian non-Abelian topological transitions bring about more intriguing topological features, yet has not been experimentally explored. In this work, we report the observation of the non-Hermitian non-Abelian topological transition at the atomic scale utilizing a nitrogenvacancy center in diamond. While the well-established topological numbers, failed to recognize this transition, we successfully characterized such a transition with the measurement of the complex eigenvalue braids. We obtained the braid invariants from the measured relative phases between eigenvalues. The observed change in braid invariants provides a clear signature of the non-Abelian topological transition. Furthermore, we experimentally revealed an intriguing consequence of this transition, which is the creation of a third-order exceptional point through the collision of two second-order exceptional points with opposite charges. Our experimental findings shed light on the abundant non-Abelian topological phenomena involving non-Hermiticity, and provide insights into manipulating the spectral topology in atomic scale systems to achieve exotic functionalities arising from non-Abelian band braiding.

quant-ph↗
arXiv2025

Experimental observation of Dirac exceptional point

The energy level degeneracies, also known as exceptional points (EPs), are crucial for comprehending emerging phenomena in materials and enabling innovative functionalities for devices. Since EPs were proposed over half a century age, only two types of EPs have been experimentally discovered, revealing intriguing phases of materials such as Dirac and Weyl semimetals. These discoveries have showcased numerous exotic topological properties and novel applications, such as unidirectional energy transfer. Here we report the observation of a novel type of EP, named the Dirac EP, utilizing a nitrogen-vacancy center in diamond. Two of the eigenvalues are measured to be degenerate at the Dirac EP and remain real in its vicinity. This exotic band topology associated with the Dirac EP enables the preservation of the symmetry when passing through, and makes it possible to achieve adiabatic evolution in non-Hermitian systems. We examined the degeneracy between the two eigenstates by quantum state tomography, confirming that the degenerate point is a Dirac EP rather than a Hermitian degeneracy. Our research of the distinct type of EP contributes a fresh perspective on dynamics in non-Hermitian systems and is potentially valuable for applications in quantum control in non-Hermitian systems and the study of the topological properties of EP.

quant-ph↗
arXiv2025

Experimental observation of parity-symmetry-protected phenomena in the quantum Rabi model with a trapped ion

Symmetry is crucial for gaining insights into the fundamental properties of physical systems, bringing possibilities in studying exotic phenomena such as quantum phase transitions and ground state entanglement. Here, we experimentally simulate a highly controllable extended quantum Rabi model, capable of tuning into the ultra-strong or deep coupling regime, in a spin-motion-coupled trapped ion. We observe that the phonon driven by such a model with parity symmetry preserved (broken) would experience double (single) excitation in the ultra-strong coupling regime. Quantum phenomena such as strong ground state entanglement and quantum superposition in systems occur with parity symmetry, and these phenomena disappear following the symmetry breaking. We also find sensitive responses for the two-level system entropy and phonon Wigner function in the deep coupling regime, depending on the parameter across the symmetry transition point. This work offers the prospect of exploring symmetry-controlled quantum phenomena and their applications in high-precision quantum technologies.

quant-ph↗