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Jinlong Zhu

Publications and source records attributed to Jinlong Zhu.

At least 19 recordsLinked to original sources

Phase amplification microscopy with femtometer-level accuracy

We demonstrate a major breakthrough in laser interferometry and microscopy achieving femtometer-level measurement accuracy and beyond, termed Phase Amplification microscopy (Φ-Amp). By exploiting the native silicide substrate as a phase cavity, our phase-gain theory predicts that weak sub-atomic phase signals can be magnified over 1000-fold, thus bypassing the shot-noise limit. We experimentally achieved a 158.2-fold phase gain for graphene in ambient air, corresponding ~ 730 femtometer accuracy. To fully unleash the potential of Φ-Amp for atomic fabrication and quantum measurement, we quantified interlayer spacing differences between AB-stacked and 30-degree-twisted bilayer graphene to be ~ 0.77 Angstroms and further detected atomic impurities and defects on large atomic structures. As the first wide-field metrology tool, we envision Φ-Amp may accelerate the scaling up of atomic quantum devices.

physics.optics

ScoutVLA: UAV-Centric Active Perception via a Dual-Expert VLA Model for Open-World Embodied Question Answering

Aerial Embodied Question Answering (EQA) requires Unmanned Aerial Vehicles (UAVs) to actively perceive the environment and answer natural language questions. Existing outdoor EQA systems usually stop once the target enters the UAV's field of view, leaving the fine-grained viewpoint adjustment needed for evidence-seeking questions largely unresolved. To address this issue, we introduce FG-EQA, a fine-grained active perception EQA benchmark with more than 40K simulated trajectories and 1K real-world trajectories. Drawing inspiration from the ``waggle dance'' of scout bees, which iteratively adjust their flight paths to verify target information, we propose ScoutVLA, an evidence-driven Vision-Language-Action model for outdoor EQA. To emulate this active exploration behavior, ScoutVLA features a decoupled dual-expert architecture: a vision-language expert infers the semantic intent to identify missing evidence, while an independent action expert employs high-DoF flow matching to generate continuous viewpoint-refinement trajectories. To balance the competing demands of continuous control and semantic reasoning, we devise a decoupled training strategy with a knowledge insulation mechanism that prevents the action gradients from erasing the model's multimodal reasoning ability. Extensive simulated experiments and a qualitative real-world field study both verify the superiority of ScoutVLA over the state-of-the-art baselines, demonstrating a 10.48$\boldsymbol{\times}$ higher average strict success rate and a 7.72$\boldsymbol{\times}$ higher average QA correctness.

cs.CV

Modern Solid Electrolytes for All-Solid-State Batteries: Materials Chemistry, Structure, and Transport

In this review, from crystallographic symmetry to amorphous local polyhedra arrangement and combinations, we examine inorganic solid state electrolytes through the lens of structure property relationships, with oxides, sulfides, and halides representing three major framework chemistries. Halide solid electrolytes and their derivatives, including mixed anion halides and antiperovskite related materials, have expanded this landscape further by introducing new ways to regulate local coordination chemistry, defect populations, and transport active frameworks. Across these families, fast ion conduction depends not simply on composition or crystallographic diffusion pathways, but on the coupled effects of framework topology, site energy distribution, defect chemistry, bottleneck response, and local anion flexibility. Oxides illustrate transport within chemically robust but geometrically constrained frameworks. Sulfides demonstrate that a soft, easily polarizable lattice can broaden the array of low energy migration pathways. Halides occupy an intermediate state, in which the closely packed anion sublattices, an approximately degenerate lithium environment, and mixed anion coordination enable effective transport while simultaneously enhancing oxidation stability and compatibility with cathodes. Building on these comparisons, we argue that long range ion transport is increasingly understood not as motion along a single idealized pathway, but as the macroscopic outcome of statistically connected low barrier local migration events distributed across the structure. We further discuss the experimental and computational approaches required to establish such multiscale structure property relationships and outline future strategies for designing transport active frameworks in which conductivity, stability, and processability are optimized together.

cond-mat.mtrl-sci

Pressure Induced 18 K Superconductivity and Two Superconducting Phases in CuIr2S4

We report pressure-induced superconductivity in the spinel CuIr$_{2}$S$_{4}$ with a transition temperature ($T_{\text{c}}$) reaching \textbf{18.2 K}, establishing a new record for this class of materials and surpassing the decades-old limit of 13.7 K. Our electrical transport and synchrotron X-ray diffraction studies up to 224 GPa reveal the emergence of \textbf{two distinct superconducting phases} from a charge-ordered insulating state. The first phase (SC-I) appears around 18 GPa, and forms a dome-shaped superconducting region in which the resistivity exhibits a pronounced, field- and current-sensitive drop without reaching strict zero above our base temperature. Above 111.8 GPa, a second, lower-$T_{\text{c}}$ phase (SC-II) emerges and coexists with SC-I over a broad pressure range, and SC-II ultimately develops a true zero-resistance state above 122.2 GPa. These superconducting phases are intimately linked to a cascade of structural transitions that systematically distort the frustrated pyrochlore lattice of Ir atoms. Our results expand the potential for superconductivity in spinels and demonstrate a pathway to high-$T_{\text{c}}$ pairing directly from a correlated insulating state driven by lattice tuning.

cond-mat.supr-con

Nitrogen-Triggered Amorphization Enables High-Performance Solid-State Electrolytes

Amorphous solid-state electrolytes (SSEs) hold great promise for advancing the application of all-solid-state batteries (ASSBs), owing to their favorable ionic conductivity, structural tunability, and promising electrochemical performance. However, the absence of universal design principles for amorphous SSEs limits their development. By fundamentally re-evaluating the amorphization-forming ability of amorphous SSE systems, this study establishes a nitrogen-driven universal strategy to convert diverse metal chlorides into amorphous xLi3N-MCly (0.3 < 3x < 1.9; M denotes a metal element; 2 < y < 5) SSE. Nitrogen synergistically disrupts crystalline order via distorted coordination polyhedra and N-bridged networks, while dynamic bond reorganization enables rapid Li+ migration, achieving ionic conductivity of 2.02 mS cm-1 for 0.533Li3N-HfCl4 at 25 °C. Structural-property relationships reveal that high charge density and bridging capability of N3- enhance network disorder, shorten metal coordinating atom distances, and optimize Li+ diffusion pathway connectivity. ASSBs employing 0.533Li3N-HfCl4 retain 81.87% capacity after 2000 cycles at 1000 mA g-1 with high cathode loading (6.24 mg cm-2), demonstrating engineering viability. This work provides a paradigm for rational design of high-performance amorphous SSEs.

cond-mat.mtrl-sci

Orthorhombic nitride perovskite CeTaN3-δ with switchable and robust ferroelectric polarization

Perovskite-type ternary nitrides with predicted exciting ferroelectricity and many other outstanding properties hold great promise to be an emerging class of advanced ferroelectrics for manufacturing diverse technologically important devices. However, such nitride ferroelectrics have not yet been experimentally identified, mainly due to the challenging sample synthesis by traditional methods at ambient pressure. Here we report the successful high-pressure synthesis of a high-quality ferroelectric nitride perovskite of CeTaN3-δ with nitrogen deficiency, adopting an orthorhombic Pmn21 polar structure. This material is electrically insulating and exhibits switchable and robust electric polarization for producing ferroelectricity. Furthermore, a number of other extraordinary properties are also revealed in this nitride such as excellent mechanical properties and chemical inertness, which would make it practically useful for many device-relevant applications and fundamentally important for the study of condensed-matter physics.

cond-mat.mtrl-sci

Bose-Einstein condensation of a two-magnon bound state in a spin-one triangular lattice

In ordered magnets, the elementary excitations are spin waves (magnons), which obey Bose-Einstein statistics. Similarly to Cooper pairs in superconductors, magnons can be paired into bound states under attractive interactions. The Zeeman coupling to a magnetic field is able to tune the particle density through a quantum critical point (QCP), beyond which a "hidden order" is predicted to exist. Here we report direct observation of the Bose-Einstein condensation (BEC) of the two-magnon bound state in Na$_2$BaNi(PO$_4$)$_2$. Comprehensive thermodynamic measurements confirmed the two-dimensional BEC-QCP at the saturation field. Inelastic neutron scattering experiments were performed to establish the microscopic model. An exact solution revealed stable 2-magnon bound states that were further confirmed by electron spin resonance and nuclear magnetic resonance experiments, demonstrating that the QCP is due to the pair condensation and the phase below saturation field is likely the long-sought-after spin nematic phase.

cond-mat.str-el

Processes and characteristics of methane hydrate formation and decomposition: a microfluidic experimental study

The formation and decomposition of methane hydrates, particularly in porous media such as subsea sediments, have attracted significant research interest due to their implications for energy production, storage, and safety in deep-sea environments. This study explores the process and characteristics of methane hydrates formation and decomposition using microfluidic technology to mimic natural conditions. By incorporating methylene blue, we enhanced phase differentiation, identifying five hydrate types: block, vein, point, membrane, and shell. These forms were influenced by the presence and movement of free gas, which shaped their development. Block and vein hydrates mainly formed in water-filled pores, while point and membrane hydrates appeared as coatings related to gas migration. Shell hydrates formed after gas relocation, filling pores. During dissociation, the presence of free gas accelerated the process significantly, with a dissociation rate approximately 12 times faster than with water alone. Gas migration was key in accelerating hydrate breakdown and fragment formation. This research offers critical insights into methane hydrate behavior, aiding in optimizing natural gas extraction and preventing deep-sea pipeline blockages.

physics.app-ph

MMT-BERT: Chord-aware Symbolic Music Generation Based on Multitrack Music Transformer and MusicBERT

We propose a novel symbolic music representation and Generative Adversarial Network (GAN) framework specially designed for symbolic multitrack music generation. The main theme of symbolic music generation primarily encompasses the preprocessing of music data and the implementation of a deep learning framework. Current techniques dedicated to symbolic music generation generally encounter two significant challenges: training data's lack of information about chords and scales and the requirement of specially designed model architecture adapted to the unique format of symbolic music representation. In this paper, we solve the above problems by introducing new symbolic music representation with MusicLang chord analysis model. We propose our MMT-BERT architecture adapting to the representation. To build a robust multitrack music generator, we fine-tune a pre-trained MusicBERT model to serve as the discriminator, and incorporate relativistic standard loss. This approach, supported by the in-depth understanding of symbolic music encoded within MusicBERT, fortifies the consonance and humanity of music generated by our method. Experimental results demonstrate the effectiveness of our approach which strictly follows the state-of-the-art methods.

cs.SD

Direct visualization of molecular stacking in quasi-2D hexagonal ice

The structure and properties of water or ice are of great interest to researchers due to their importance in the biological, cryopreservation and environmental fields. Hexagonal ice (Ih) is a common ice phase in nature and has been extensively studied; however, microstructural investigations at the atomic or molecular scale are still lacking. In this paper, the fine structure of quasi-2-dimensional ice Ih films was directly examined using cryogenic transmission electron microscopy. Two types of thin Ih films were observed: perfect single crystals growing along the [0001] direction and crystals with stacking faults, including both basal (BSF) and prismatic (PSF) ones, along the orientation of [11-20]; these results were further confirmed by theoretical calculations. Importantly, for the first time, the stacking faults in ice Ih were directly visualized and resolved. In light of the extension behavior of the chair conformation composed of the water molecules, we elucidated the formation mechanism of BSF in Ih, namely, the Ic phase. This study not only determined the structural characteristics of ice structure at the molecular scale but also provided important concepts for researchers to more fully understand the growth kinetics of ice crystals at the atomic scale.

cond-mat.mtrl-sci

Pressure Tuned 2D Superconductivity in Black Phosphorus

This paper examines the micro-parameters of superconductors. It studies the modulations from weak van der Waals interaction to strong covalence bonding of superconductors. In particular, we studied layered black phosphorus (BP) as a function of pressure. These results reveal a rich scenario of phase transitions and related quantum phenomena, which show that the phases exhibit superconducting states at a pressure higher than 5.0 GPa. In addition, they indicate an angle-dependent upper critical field that demonstrates the dimensional characteristics of superconductivities. This result suggests that the A17 and cubic phases are three-dimensional (3D). The A7 phase shows a two-dimensional (2D) character. The 2D behavior is related to a weakened, distorted, entangled interlayer coupling.

cond-mat.supr-con

Magnetic phase diagram and multiple field-induced states in the intermetallic triangular-lattice antiferromagnet NdAuAl$_4$Ge$_2$ with Ising-like spins

Geometrical frustration and the enhancement of strong quantum fluctuations in two-dimensional triangular antiferromagnets can lead to various intriguing phenomena. Here, we studied the spin-1/2 triangular lattice antiferromagnet NdAuAl$_4$Ge$_2$. Thermodynamic and transport properties, such as magnetization and specific heat together with the resistivity measurements were performed. In zero field, two successive phase transitions were observed at $T_{\rm N1}=1.75\pm 0.02$ K and $T_{\rm N2}=0.49\pm 0.02$ K, respectively. Under magnetic field, $\rm XXZ$-type anisotropy was revealed, with the moments pointing along the easy $c$ axis. For $B\parallel c$, multiple field-induced states were observed, and the magnetic phase diagram was established based on the specific heat and magnetization data. The temperature-dependent resistivity measurements indicate that NdAuAl$_4$Ge$_2$ is a good metal. It is very likely that both the long-range RKKY interactions and the geometrical frustration play an important roles in this case.

cond-mat.str-el

Ferroelectricity driven by magnetism in quasi-one-dimensional Ba9Fe3Se15

The spin-induced ferroelectricity in quasi-1D spin chain system is little known, which could be fundamentally different from those in three-dimensional (3D) system. Here, we report the ferroelectricity driven by a tilted screw spin order and its exotic dynamic in the spin-chain compound Ba9Fe3Se15. It is found that the spin-induced polarization has already occurred and exhibits magnetoelectric coupling behavior far above the long-range spin order (LRSO) at TN = 14 K. The polarized entities grow and their dynamic responses slow down gradually with decreasing temperature and permeate the whole lattice to form 3D ferroelectricity at TN. Our results reveal that the short-range spin orders (SRSOs) in the decoupled chains play a key role for the exotic dynamic in this dimension reduced system. Ba9Fe3Se15 is the only example so far which exhibits electric polarization above LRSO temperature because of the formation of SRSOs.

cond-mat.str-el

Transmission-matrix Quantitative Phase Profilometry for Accurate and Fast Thickness Mapping of 2D Materials

The physical properties of two-dimensional (2D) materials may drastically vary with their thickness profiles. Current thickness profiling methods for 2D material (e.g., atomic force microscopy and ellipsometry) are limited in measurement throughput and accuracy. Here we present a novel high-speed and high-precision thickness profiling method, termed Transmission-Matrix Quantitative Phase Profilometry (TM-QPP). In TM-QPP, picometer-level optical pathlength sensitivity is enabled by extending the photon shot-noise limit of a high sensitivity common-path interferometric microscopy technique, while accurate thickness determination is realized by developing a transmission-matrix model that accounts for multiple refractions and reflections of light at sample interfaces. Using TM-QPP, the exact thickness profiles of monolayer and few-layered 2D materials (e.g., MoS2, MoSe2 and WSe2) are mapped over a wide field of view within seconds in a contact-free manner. Notably, TM-QPP is also capable of spatially resolving the number of layers of few-layered 2D materials.

physics.optics

Crystal structure and properties of iron-based spin-chain compound Ba9Fe3Se15

We report the synthesis of a new quasi one-dimensional (1D) iron selenide. Ba9Fe3Se15 was synthesized at high temperature and high pressure of 5.5 GPa and systematically studied via structural, magnetic and transport measurements at ambient and at high-pressures. Ba9Fe3Se15 crystallizes in a monoclinic structure and consists of face-sharing FeSe6 octahedral chains along the c axis. At ambient pressure it exhibits an insulating behavior with a band gap ~460 meV and undergoes a ferrimagnet-like phase transition at 14 K. Under high pressure, a complete metallization occurs at ~29 GPa, which is accompanied by a spin state crossover from high spin (HS) state to low spin (LS) state. The LS appears for pressures P >36 GPa.

cond-mat.supr-con

Towards new forms of particle sensing and manipulation and 3D imaging on a smartphone for healthcare applications

Close to half of the world population have smartphones, while a typical flagship smartphone today has been integrated with more than 20 smart components and sensors, making a smartphone a highly integrated platform that can potentially mimic the five senses of humans. Recent advancement in achieving high compactness, high performance computing, high flexibility, and multiplexed functionality in smartphones have enabled them for many cutting-edge healthcare applications, such as single-molecule imaging, medical diagnosis, and biosensing, which were conventionally done with bulky and sophisticated devices. Most of the current healthcare applications are developed based on using the photon-sensitive components, such as CMOS sensors, flash & fill lights, lens modules, and LED lights in the screen, leaving the rest of the smart and high-performance sensors rarely explored. In this Perspective, we review recent progresses in advanced sensors in modern smartphones and discuss how those sensors have great, as yet unmet, promise to offer widespread and easy-to-implement solutions to many emerging healthcare applications, including nanoscale sensing, point-of-care testing, pollution monitoring, etc.

eess.IV

A New Quasi One-Dimensional Compound Ba3TiTe5 and Superconductivity Induced by Pressure

We report systematical studies of a new quasi-one-dimensional (1D) compound Ba3TiTe5 and the high-pressure induced superconductivity therein. Ba3TiTe5 was synthesized at high pressure and high temperature. It crystallizes into a hexagonal structure (P63/mcm), which consists of infinite face-sharing octahedral TiTe6 chains and Te chains along the c axis, exhibiting a strong 1D characteristic structure. The first-principles calculations demonstrate that Ba3TiTe5 is a well-defined 1D conductor and thus, it can be considered a starting point to explore the exotic physics induced by pressure via enhancing the interchain hopping to move the 1D conductor to a high dimensional metal. For Ba3TiTe5, high-pressure techniques were employed to study the emerging physics dependent on interchain hopping, such as the Umklapp scattering effect, spin/charge density wave (SDW/CDW), superconductivity and non-Fermi Liquid behavior. Finally, a complete phase diagram was plotted. The superconductivity emerges from 8.8 GPa, near which the Umklapp gap is mostly suppressed. Tc is enhanced and reaches the maximum ~6 K at about 36.7 GPa, where the spin/charge density wave (SDW/CDW) is completely suppressed, and a non-Fermi Liquid behavior appears. Our results suggest that the appearance of superconductivity is associated with the fluctuation due to the suppression of Umklapp gap and the enhancement of Tc is related with the fluctuation of the SDW/CDW.

cond-mat.supr-con

Visualizable Detection of Nanoscale Perturbations

Using light to non-destructively detect nanoscale perturbations is vital to many fields including material characterization, human disease diagnosis, and semiconductor electronics. In this work, we introduce the concepts of electromagnetic canyons and non-resonance amplification and apply them on a conventional diffraction-limited optical microscope to directly view individual perturbations (25-nm radius = wavelength/31) in a nanoscale volume. Considering the extensive impact of microscopy on scientific discovery and technology development, our noninvasive imaging-based method with deep subwavelength footprint will have far-reaching consequences that will affect our everyday lives.

physics.optics