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Joachim Krug

Publications and source records attributed to Joachim Krug.

108 records · Page 6Linked to original sources
arXiv2001

Effects of adsorbates on submonolayer growth

The effects of adsorbates on nucleation and growth of two-dimensional islands is investigated by kinetic Monte Carlo simulations and rate equation theory. The variation of island morphology with adsorbate parameters is discussed and the temperature-dependence of island density in the case of immobile adsorbates is studied in detail. A set of rate equations for the description of nucleation in the presence of predeposited mobile and immobile adsorbates is developed.

cond-mat.mtrl-sci↗
arXiv2001

Coarsening of vortex ripples in sand

The coarsening of an array of vortex ripples prepared in an unstable state is discussed within the framework of a simple mass transfer model first introduced by K.H. Andersen et al. [Phys. Rev. E 63, 066308 (2001)]. Two scenarios for the selection of the final pattern are identified. When the initial state is homogeneous with uniform random perturbations, a unique final state is reached which depends only on the shape of the interaction function $f(λ)$. A potential formulation of the dynamics suggests that the final wavelength is determined by a Maxwell construction applied to $f(λ)$, but comparison with numerical simulations shows that this yields only an upper bound. In contrast, the evolution from a perfectly homogeneous state with a localized perturbation proceeds through the propagation of wavelength doubling fronts. The front speed can be predicted by standard marginal stability theory. In this case the final wavelength depends on the initial wavelength in a complicated manner which involves multiplication by factors of 2 and rational ratios such as 4/3.

cond-mat.stat-mech↗
arXiv2001

Tempo and mode in quasispecies evolution

Evolutionary dynamics in an uncorrelated rugged fitness landscape is studied in the framework of Eigen's molecular quasispecies model. We consider the case of strong selection, which is analogous to the zero temperature limit in the equivalent problem of directed polymers in random media. In this limit the population is always localized at a single temporary master sequence $σ^\ast(t)$, and we study the statistical properties of the evolutionary trajectory which $σ^\ast(t)$ traces out in sequence space. Numerical results for binary sequences of length N=10 and exponential and uniform fitness distributions are presented. Evolution proceeds by intermittent jumps between local fitness maxima, where high lying maxima are visited more frequently by the trajectories. The probability distribution for the total time $T$ required to reach the global maximum shows a $T^{-2}$-tail, which is argued to be universal and to derive from near-degenerate fitness maxima. The total number of jumps along any given trajectory is always small, much smaller than predicted by the statistics of records for random long-ranged evolutionary jumps.

cond-mat.stat-mech↗
arXiv2000

Scaling regimes for second layer nucleation

Nucleation on top of two-dimensional islands with step edge barriers is investigated using scaling arguments. The nucleation rate is expressed in terms of three basic time scales: The time interval between deposition events, the residence time of atoms on the island, and the encounter time required for $i^\ast + 1$ atoms forming a stable nucleus to meet. Application to the problem of second-layer nucleation on growing first layer islands yields a sequence of scaling regimes with different scaling exponents relating the critical island size, at which nucleation takes place, to the diffusion and deposition rates. Second layer nucleation is fluctuation-dominated, in the sense that the typical number of atoms on the island is small compared to $i^\ast + 1$, when the first layer island density exponent $χ$ satisfies $χ(i^\ast + 1) < 2$. The upper critical nucleus size, above which the conventional mean-field theory of second layer nucleation is valid, increases with decreasing dimensionality. In the related case of nucleation on top of multilayer mounds fluctuation-dominated and mean-field like regimes coexist for arbitrary values of the critical nucleus size $i^\ast$.

cond-mat.mtrl-sci↗
arXiv2000

Nonmonotonic roughness evolution in unstable growth

The roughness of vapor-deposited thin films can display a nonmonotonic dependence on film thickness, if the smoothening of the small-scale features of the substrate dominates over growth-induced roughening in the early stage of evolution. We present a detailed analysis of this phenomenon in the framework of the continuum theory of unstable homoepitaxy. Using the spherical approximation of phase ordering kinetics, the effect of nonlinearities and noise can be treated explicitly. The substrate roughness is characterized by the dimensionless parameter $Q = W_0/(k_0 a^2)$, where $W_0$ denotes the roughness amplitude, $k_0$ is the small scale cutoff wavenumber of the roughness spectrum, and $a$ is the lattice constant. Depending on $Q$, the diffusion length $l_D$ and the Ehrlich-Schwoebel length $l_{ES}$, five regimes are identified in which the position of the roughness minimum is determined by different physical mechanisms. The analytic estimates are compared by numerical simulations of the full nonlinear evolution equation.

cond-mat.stat-mech↗
arXiv2000

Submonolayer epitaxy with impurities

The effect of impurities on epitaxial growth in the submonolayer regime is studied using kinetic Monte Carlo simulations of a two-species solid-on-solid growth model. Both species are mobile, and attractive interactions among adatoms and between adatoms and impurities are incorporated. Impurities can be codeposited with the growing material or predeposited prior to growth. The activated exchange of impurities and adatoms is identified as the key kinetic process in the formation of a growth morphology in which the impurities decorate the island edges. The dependence of the island density on flux and coverage is studied in detail. The impurities strongly increase the island density without appreciably changing its power-law dependence on flux, apart from a saturation of the flux dependence at high fluxes and low coverages. A simple analytic theory taking into account only the dependence of the adatom diffusion constant on impurity coverage is shown to provide semi-quantitative agreement with many features observed in the simulations.

cond-mat.mtrl-sci↗
arXiv1999

Island nucleation in the presence of step edge barriers: Theory and applications

We develop a theory of nucleation on top of two-dimensional islands bordered by steps with an additional energy barrier $ΔE_S$ for descending atoms. The theory is based on the concept of the residence time of an adatom on the island,and yields an expression for the nucleation rate which becomes exact in the limit of strong step edge barriers. This expression differs qualitatively and quantitatively from that obtained using the conventional rate equation approach to nucleation [J. Tersoff et al., Phys. Rev. Lett.72, 266 (1994)]. We argue that rate equation theory fails because nucleation is dominated by the rare instances when two atoms are present on the island simultaneously. The theory is applied to two distinct problems: The onset of second layer nucleation in submonolayer growth, and the distribution of the sizes of top terraces of multilayer mounds under conditions of strong step edge barriers. Application to homoepitaxial growth on Pt(111) yields the estimate $ΔE_S \geq 0.33$ eV for the additional energy barrier at CO-decorated steps.

cond-mat.mtrl-sci↗
arXiv1999

Phase separation in disordered exclusion models

The effect of quenched disorder in the one-dimensional asymmetric exclusion process is reviewed. Both particlewise and sitewise disorder generically induces phase separation in a range of densities. In the particlewise case the existence of stationary product measures in the homogeneous phase implies that the critical density can be computed exactly, while for sitewise disorder only bounds are available. The coarsening of phase-separated domains starting from a homogeneous initial condition is addressed using scaling arguments and extremal statistics considerations. Some of these results have been obtained previously in the context of directed polymers subject to columnar disorder.

cond-mat.stat-mech↗
arXiv1999

Crystal symmetry, step-edge diffusion and unstable growth

We study the effect of crystal symmetry and step-edge diffusion on the surface current governing the evolution of a growing crystal surface. We find there are two possible contributions to anisotropic currents, which both lead to the destabilization of the flat surface: terrace current (j_t), which is parallel to the surface slope, and step current (j_s), which has components parallel (j_pa) and perpendicular (j_pe) to the slope. On a high-symmetry surface, terrace and step currents are generically singular at zero slope, and this does not allow to perform the standard linear stability analysis. As far as a one-dimensional profile is considered, (j_pe) is irrelevant and (j_pa) suggests that mound sides align along [110] and [1-10] axes. On a vicinal surface, (j_s) destabilizes against step bunching; its effect against step meandering depends on the step orientation, in agreement with the recent findings by O.Pierre-Louis et al. [Phys. Rev. Lett. 82, 3661 (1999)].

cond-mat.mtrl-sci↗
arXiv1999

Submonolayer growth with decorated island edges

We study the dynamics of island nucleation in the presence of adsorbates using kinetic Monte Carlo simulations of a two-species growth model. Adatoms (A-atoms) and impurities (B-atoms) are codeposited, diffuse and aggregate subject to attractive AA- and AB-interactions. Activated exchange of adatoms with impurities is identified as the key process to maintain decoration of island edges by impurities during growth. While the presence of impurities strongly increases the island density, a change in the scaling of island density with flux, predicted by a rate equation theory for attachment-limited growth [D. Kandel, Phys. Rev. Lett. 78, 499 (1997)], is not observed. We argue that, within the present model, even completely covered island edges do not provide efficient barriers to attachment.

cond-mat.mtrl-sci↗
arXiv1999

Linear theory of unstable growth on rough surfaces

Unstable homoepitaxy on rough substrates is treated within a linear continuum theory. The time dependence of the surface width $W(t)$ is governed by three length scales: The characteristic scale $l_0$ of the substrate roughness, the terrace size $l_D$ and the Ehrlich-Schwoebel length $l_{ES}$. If $l_{ES} \ll l_D$ (weak step edge barriers) and $l_0 \ll l_m \sim l_D \sqrt{l_D/l_{ES}}$, then $W(t)$ displays a minimum at a coverage $θ_{\rm min} \sim (l_D/l_{ES})^2$, where the initial surface width is reduced by a factor $l_0/l_m$. The rôle of deposition and diffusion noise is analyzed. The results are applied to recent experiments on the growth of InAs buffer layers [M.F. Gyure {\em et al.}, Phys. Rev. Lett. {\bf 81}, 4931 (1998)]. The overall features of the observed roughness evolution are captured by the linear theory, but the detailed time dependence shows distinct deviations which suggest a significant influence of nonlinearities.

cond-mat.stat-mech↗
arXiv1999

Linear theory of unstable growth on rough surfaces

Unstable homoepitaxy on rough substrates is treated within a linear continuum theory. The time dependence of the surface width W(t) is governed by three length scales: The characteristic scale $l_0$ of the substrate roughness, the terrace size $l_D$ and the Ehrlich-Schwoebel length $l_{ES}$. If $l_{ES} \ll l_D$ (weak step edge barriers) and $l_0 \ll l_m \sim l_D \sqrt{l_D/l_{ES}}$, then W(t) displays a minimum at a coverage $θ_{\rm min} \sim (l_D/l_{ES})^2$, where the initial surface width is reduced by a factor $l_0/l_m$. The rôle of deposition and diffusion noise is analyzed. The results are applied to recent experiments on the growth of InAs buffer layers [M.F. Gyure {\em et al.}, Phys. Rev. Lett. {\bf 81}, 4931 (1998)]. The overall features of the observed roughness evolution are captured by the linear theory, but the detailed time dependence shows distinct deviations which suggest a significant influence of nonlinearities.

cond-mat.stat-mech↗
arXiv1998

Fast coarsening in unstable epitaxy with desorption

Homoepitaxial growth is unstable towards the formation of pyramidal mounds when interlayer transport is reduced due to activation barriers to hopping at step edges. Simulations of a lattice model and a continuum equation show that a small amount of desorption dramatically speeds up the coarsening of the mound array, leading to coarsening exponents between 1/3 and 1/2. The underlying mechanism is the faster growth of larger mounds due to their lower evaporation rate.

cond-mat.stat-mech↗
arXiv1998

Persistence of Kardar-Parisi-Zhang Interfaces

The probabilities $P_\pm(t_0,t)$ that a growing Kardar-Parisi-Zhang interface remains above or below the mean height in the time interval $(t_0, t)$ are shown numerically to decay as $P_\pm \sim (t_0/t)^{θ_\pm}$ with $θ_+ = 1.18 \pm 0.08$ and $θ_- = 1.64 \pm 0.08$. Bounds on $θ_\pm$ are derived from the height autocorrelation function under the assumption of Gaussian statistics. The autocorrelation exponent $\bar λ$ for a $d$--dimensional interface with roughness and dynamic exponents $β$ and $z$ is conjectured to be $\bar λ= β+ d/z$. For a recently proposed discretization of the KPZ equation we find oscillatory persistence probabilities, indicating hidden temporal correlations.

cond-mat.stat-mech↗
arXiv1997

Damping of Growth Oscillations in Molecular Beam Epitaxy: A Renormalization Group Approach

The conserved Sine-Gordon Equation with nonconserved shot noise is used to model homoepitaxial crystal growth. With increasing coverage the renormalized pinning potential changes from strong to weak. This is interpreted as a transition from layer-by-layer to rough growth. The associated length and time scales are identified, and found to agree with recent scaling arguments. A heuristically postulated nonlinear term $\nabla^2 (\nabla h)^2$ is created under renormalization.

cond-mat.stat-mech↗
arXiv1996

Coarsening of Surface Structures in Unstable Epitaxial Growth

We study unstable epitaxy on singular surfaces using continuum equations with a prescribed slope-dependent surface current. We derive scaling relations for the late stage of growth, where power law coarsening of the mound morphology is observed. For the lateral size of mounds we obtain $ξ\sim t^{1/z}$ with $z \geq 4$. An analytic treatment within a self-consistent mean-field approximation predicts multiscaling of the height-height correlation function, while the direct numerical solution of the continuum equation shows conventional scaling with z=4, independent of the shape of the surface current.

cond-mat.stat-mech↗
arXiv1996

Impurity-induced diffusion bias in epitaxial growth

We introduce two models for the action of impurities in epitaxial growth. In the first, the interaction between the diffusing adatoms and the impurities is ``barrier''-like and, in the second, it is ``trap''-like. For the barrier model, we find a symmetry breaking effect that leads to an overall down-hill current. As expected, such a current produces Edwards-Wilkinson scaling. For the trap model, no symmetry breaking occurs and the scaling behavior appears to be of the conserved-KPZ type.

cond-mat↗