arXiv subjects

Jorma Harju

Publications and source records attributed to Jorma Harju.

At least 19 recordsLinked to original sources

arXiv2026

Unveiling the Trans-Neptunian Region with the SKA

We explore the potential of the SKA staged delivery AA4 (SKA-AA4) to detect and characterise the thermal emission of trans-Neptunian objects (TNOs) and Centaurs at centimetre wavelengths. These distant icy bodies preserve important information on the formation and evolution of the outer Solar System and provide a valuable link to planetary systems observed around other stars. The unprecedented sensitivity of SKA-AA4 will enable thermal detections of several of the brightest TNOs and Centaurs, extending radiometric studies beyond the capabilities of current radio facilities. Combined with shorter-wavelength observations and occultation measurements, these data will provide new constraints on spectral emissivity behaviour, thermophysical properties, and subsurface structure. At its highest angular resolutions, SKA-AA4 may partially resolve the largest systems, enabling investigations of surface heterogeneity, extended structures such as rings, and the partial resolution of some wide binary systems. We also assess the feasibility of radio occultation observations, which can provide independent constraints on object sizes, shapes, atmospheres, rings, or satellites. Together with observations from ALMA, JWST, and occultation campaigns, SKA-AA4 will establish centimetre-wavelength studies as a powerful new tool for investigating the thermal and structural properties of outer Solar System bodies.

astro-ph.EP↗

arXiv2026

Oxygen in the protostellar clump OMC-2 FIR4

Atomic oxygen (OI), OH, H2O, and CO are the main carriers of oxygen in dense interstellar gas and important coolants of shocks associated with protostellar outflows. We determine the relative abundances of these species in the warm inner parts of the protostellar clump OMC-2 FIR4 in Orion A. The clump contains several young stellar objects. The upGREAT receiver including the High Frequency Array (HFA, operating at 4.74 THz, 63 micron) onboard the Stratospheric Observatory for Far-Infrared Astronomy (SOFIA) was used to observe OMC-2 FIR4 in the lines of OI, OH, OD, HDO, and CO. Additional HDO lines were observed with the Atacama Pathfinder Experiment (APEX). Archival H2O and CO spectra observed by the Herschel satellite were included in the analysis. The observed lines were reasonably well reproduced by an expanding spherical shell model. The OI spectrum at 63 micron towards OMC-2 FIR4 is dominated by a broad line component, on top of which medium-wide and narrow line components can be discerned. The same components are present in the OH, H2O, and high-J CO spectra towards this source. We find that OI is more abundant than H2O in the shocked gas. In the broad line component, the following abundance ratios are derived: OI/H2O ~ 700, OI/OH ~ 300, OI/CO ~ 4. The high relative abundance of atomic oxygen there suggests an origin in dissociative J-shocks that are associated with strong ultraviolet radiation. The OI/CO ratio decreases below unity in the components with a smaller velocity dispersion, and these components also have higher abundances of H2O than the broad line component, although remaining below that of CO. The HDO/H2O ratio in the low-velocity components corresponds to the average ratio in the icy mantles of dust grains, and the presence of water there could also be understood in terms of sublimation without invoking high-temperature chemistry.

astro-ph.GA↗

arXiv2025

Statistical nuclear spin ratios of deuterated ammonia in the pre-stellar core L1544

We determined the ortho/para (o/p) ratios of NH2D and NHD2 in the archetypical pre-stellar core L1544. The core was observed in the two lowest rotational lines of ortho- and para-NH2D using the APEX and the IRAM 30 m telescopes. The ground-state lines of ortho- and para-NHD2 were observed with APEX. The distributions of chemical abundances in the core were predicted using a gas-grain chemistry model with two different scenarios concerning proton transfer reactions in the gas. One of the scenarios, the so-called full scrambling (FS), allows protons and deuterons to be completely mixed in the intermediate reaction complex before dissociation, whereas the other describes these reactions as proton or deuteron hops (PH). We also tested assumed abundance profiles independent of the chemistry models. Radiative transfer calculations were used to simulate the observed NH2D and NHD2 lines from the predicted and assumed abundance profiles. Our modelling efforts suggest that the ground-state lines of NH2D and NHD2 at the wavelength 0.9 mm that are observable with the same beam and in the same spectrometer band are the most reliable probes of the o/p ratios. Simulations using the PH reaction scheme show systematically better agreement with the observations than simulations with the FS model. Simulations using a broken power law abundance profile as a function of the gas density give spin ratios that are close to the predictions of the PH scenario: o/p-NH2D=2.85+-0.05, o/p-NHD2=2.10+-0.06 (1 sigma). The o/p ratios predicted by the PH scenario in the gas phase correspond to the nuclear spin statistical weights, that is, o/p-NH2D=3, o/p-NHD2=2. In view of the fact that H and D atom addition reactions on grain surfaces also result in these ratios, it is reasonable to assume that the spin ratios of interstellar ammonia and its deuterated forms are in general equal to their statistical values.

astro-ph.GA↗

arXiv2024

A low cosmic-ray ionisation rate in the prestellar core Ophiuchus/H-MM1. Mapping of the molecular ions ortho-H2D+, N2H+, and DCO+

(abridged) We have mapped the prestellar core H-MM1 in Ophiuchus in rotational lines of ortho-H2D+ (oH2D+), N2H+, and DCO+ at the wavelength 0.8 mm with the Large APEX sub-Millimeter Array (LAsMA) multibeam receiver of the Atacama Pathfinder EXperiment (APEX) telescope. We also ran a series of chemistry models to predict the abundance distributions of the observed molecules, and to estimate the effect of the cosmic-ray ionisation rate on their abundances. The three line maps show different distributions. The oH2D+ map is extended and outlines the general structure of the core, while N2H+ mainly shows the density maxima, and the DCO+ emission peaks are shifted towards one edge of the core where a region of enhanced desorption has been found previously. According to the chemical simulation, the fractional oH2D+ abundance remains relatively high in the centre of the core, and its column density correlates strongly with the cosmic-ray ionisation rate. Simulated line maps constrain the cosmic-ray ionisation rate per hydrogen molecule to be low, between 5e-18/s and 1e-17/s in the H-MM1 core. This estimate agrees with the gas temperature measured in the core. Modelling line emission of oH2D+ provides a straightforward method of determining the cosmic-ray ionisation rate in dense clouds, where the primary ion, H3+, is not observable.

astro-ph.GA↗

arXiv2023

Nuclear spin ratios of deuterated ammonia in prestellar cores. LAsMA observations of H-MM1 and Oph D

We determine the ortho/para ratios of NH2D and NHD2 in two dense, starless cores, where their formation is supposed to be dominated by gas-phase reactions, which, in turn, is predicted to result in deviations from the statistical spin ratios. The Large APEX sub-Millimeter Array (LAsMA) multibeam receiver of the Atacama Pathfinder EXperiment (APEX) telescope was used to observe the prestellar cores H-MM1 and Oph D in Ophiuchus in the ground-state lines of ortho and para NH2D and NHD2. The fractional abundances of these molecules were derived employing 3D radiative transfer modelling, using different assumptions about the abundance profiles as functions of density. We also ran gas-grain chemistry models with different scenarios concerning proton or deuteron exchanges and chemical desorption from grains to find out if one of these models can reproduce the observed spin ratios. The observationally deduced ortho/para ratios of NH2D and NHD2 are in both cores within 10% of their statistical values 3 and 2, respectively, and taking 3-sigma limits, deviations from these of about 20% are allowed. Of the chemistry models tested here, the model that assumes proton hop (as opposed to full scrambling) in reactions contributing to ammonia formation, and a constant efficiency of chemical desorption, comes nearest to the observed abundances and spin ratios. The nuclear spin ratios derived here are in contrast with spin-state chemistry models that assume full scrambling in proton donation and hydrogen abstraction reactions leading to deuterated ammonia. The efficiency of chemical desorption influences strongly the predicted abundances of NH3, NH2D, and NHD2, but has a lesser effect on their ortho/para ratios. For these the proton exchange scenario in the gas is decisive. We suggest that this is because of rapid re-processing of ammonia and related cations by gas-phase ion-molecule reactions.

astro-ph.GA↗

arXiv2023

Initial conditions of star formation at $\lesssim$2000 au: physical structure and NH$_{3}$ depletion of three early-stage cores

Pre-stellar cores represent a critical evolutionary phase in low-mass star formation. We aim to unveil the detailed thermal structure and density distribution of three early-stage cores, starless core L1517B, and prestellar core L694-2 and L429, with the high angular resolution observations of the NH$_{3}$ (1,1) and (2,2) inversion transitions obtained with VLA and GBT. In addition, we explore where/if NH$_{3}$ depletes in the central regions. Applying the mid-infrared extinction method to the $\textit{Spitzer}$ 8$~μ$m map we obtain a high angular resolution hydrogen column density map, and derive the gas density profile to assess the variation of NH$_{3}$ abundance as a function of gas volume density. The measured temperature profiles of L429 and L1517B show a minor decrease towards the core center, dropping from $\sim$9K to below 8K, and $\sim$11 K to 10 K, while L694-2 has a rather uniform temperature distribution around $\sim$9 K. Among the three cores, L429 has the highest central gas density, close to sonic velocity line-width, and largest localised velocity gradient, all indicative of an advanced evolutionary stage. We resolve that the abundance of NH$_{3}$ becomes two times lower in the central region of L429, occurring around a gas density of 4.4$\times$10$^{4}$$~cm^{-3}$. Compared to Ophiuchus/H-MM1 which shows an even stronger drop of the NH$_{3}$ abundance at 2$\times$10$^{5}$$~cm^{-3}$, the abundance variations of the three cores plus Ophiuchus/H-MM1 suggest a progressive NH$_{3}$ depletion with increasing central density of the core.

astro-ph.GA↗

arXiv2022

An Interferometric View of H-MM1. I. Direct Observation of NH3 Depletion

Spectral lines of ammonia, NH$_3$, are useful probes of the physical conditions in dense molecular cloud cores. In addition to advantages in spectroscopy, ammonia has also been suggested to be resistant to freezing onto grain surfaces, which should make it a superior tool for studying the interior parts of cold, dense cores. Here we present high-resolution NH$_3$ observations with the Very Large Array (VLA) and Green Bank Telescope (GBT) towards a prestellar core. These observations show an outer region with a fractional NH$_3$ abundance of X(NH$_3$) = (1.975$\pm$0.005)$\times 10^{-8}$ ($\pm 10\%$ systematic), but it also reveals that after all, the X(NH$_3$) starts to decrease above a H$_2$ column density of $\approx 2.6 \times 10^{22}$ cm$^{-2}$. We derive a density model for the core and find that the break-point in the fractional abundance occurs at the density n(H$_2$) $\sim 2\times10^5$ cm$^{-3}$, and beyond this point the fractional abundance decreases with increasing density, following the power law $n^{-1.1}$. This power-law behavior is well reproduced by chemical models where adsorption onto grains dominates the removal of ammonia and related species from the gas at high densities. We suggest that the break-point density changes from core to core depending on the temperature and the grain properties, but that the depletion power law is anyway likely to be close to $n^{-1}$ owing to the dominance of accretion in the central parts of starless cores.

astro-ph.GA↗

arXiv2022

The Central 1000 au of a Pre-stellar Core Revealed with ALMA. II. Almost Complete Freeze-out

Pre-stellar cores represent the initial conditions in the process of star and planet formation. Their low temperatures ($<$10 K) allow the formation of thick icy dust mantles, which will be partially preserved in the future protoplanetary disks, ultimately affecting the chemical composition of planetary systems. Previous observations have shown that carbon- and oxygen-bearing species, in particular CO, are heavily depleted in pre-stellar cores due to the efficient molecular freeze-out onto the surface of cold dust grains. However, N-bearing species such as NH$_3$ and, in particular, its deuterated isotopologues, appear to maintain high abundances where CO molecules are mainly in solid phase. Thanks to ALMA, we present here the first clear observational evidence of NH$_2$D freeze-out toward the L1544 pre-stellar core, suggestive of the presence of a"complete-depletion zone" within a $\simeq$1800 au radius, in agreement with astrochemical pre-stellar core model predictions. Our state-of-the-art chemical model coupled with a non-LTE radiative transfer code demonstrates that NH$_2$D becomes mainly incorporated in icy mantles in the central 2000 au and starts freezing-out already at $\simeq$7000 au. Radiative transfer effects within the pre-stellar core cause the NH$_2$D(1$_{11}$-1$_{01}$) emission to appear centrally concentrated, with a flattened distribution within the central $\simeq$3000 au, unlike the 1.3 mm dust continuum emission which shows a clear peak within the central $\simeq$1800 au. This prevented NH$_2$D freeze-out to be detected in previous observations, where the central 1000 au cannot be spatially resolved.

astro-ph.SR↗

arXiv2022

Chemical exploration of Galactic cold cores

A solar-type system starts from an initial molecular core that acquires organic complexity as it evolves. The so-called prestellar cores that can be studied are rare, which has hampered our understanding of how organic chemistry sets in and grows. Aims. We selected the best prestellar core targets from the cold core catalogue that represent a diversity in terms of their environment to explore their chemical complexity: 1390 (in the compressed shell of Lambda Ori), 869 (in the MBM12 cloud), and 4149 (in the California nebula). We obtained a spectral survey with the IRAM 30 m telescope in order to explore the molecular complexity of the cores. We carried out a radiative transfer analysis of the detected transitions in order to place some constraints on the physical conditions of the cores and on the molecular column densities. We also used the molecular ions in the survey to estimate the cosmic-ray ionisation rate and the S/H initial elemental abundance using a gas-phase chemical model to reproduce their abundances. We found large differences in the molecular complexity (deuteration, complex organic molecules, sulphur, carbon chains, and ions) and compared their chemical properties with a cold core and two prestellar cores. The chemical diversity we found in the three cores seems to be correlated with their chemical evolution: two of them are prestellar (1390 and 4149), and one is in an earlier stage (869). The influence of the environment is likely limited because cold cores are strongly shielded from their surroundings. The high extinction prevents interstellar UV radiation from penetrating deeply into the cores. Higher spatial resolution observations of the cores are therefore needed to constrain the physical structure of the cores, as well as a larger-scale distribution of molecular ions to understand the influence of the environment on their molecular complexity.

astro-ph.GA↗

arXiv2021

Methanol Mapping in Cold Cores: Testing Model Predictions

Chemical models predict that in cold cores gas-phase methanol is expected to be abundant at the outer edge of the CO depletion zone, where CO is actively adsorbed. CO adsorption correlates with volume density in cold cores, and, in nearby molecular clouds, the catastrophic CO freeze-out happens at volume densities above 10$^4$ cm$^{-3}$. The methanol production rate is maximized there and its freeze-out rate does not overcome its production rate, while the molecules are shielded from UV destruction by gas and dust. Thus, in cold cores, methanol abundance should generally correlate with visual extinction that depends both on volume and column density. In this work, we test the most basic model prediction that maximum methanol abundance is associated with a local $A_V\simeq$4 mag in dense cores and constrain the model parameters with the observational data. With the IRAM 30 m antenna, we mapped the CH$_3$OH (2-1) and (3-2) transitions toward seven dense cores in the L1495 filament in Taurus to measure the methanol abundance. We use the Herschel/SPIRE maps to estimate visual extinction, and the C$^{18}$O(2-1) maps from Tafalla & Hacar (2015) to estimate CO depletion. We explored the observed and modeled correlations between the methanol abundances, CO depletion, and visual extinction varying the key model parameters. The modeling results show that hydrogen surface diffusion via tunneling is crucial to reproduce the observed methanol abundances, and the needed reactive desorption efficiency matches the one deduced from laboratory experiments.

astro-ph.GA↗

arXiv2020

Efficient methanol production on the dark side of a prestellar core

We present ALMA maps of the starless molecular cloud core Ophiuchus/H-MM1 in the lines of deuterated ammonia (ortho-NH2D), methanol (CH3OH), and sulphur monoxide (SO). The dense core is seen in NH2D emission, whereas the CH3OH and SO distributions form a halo surrounding the core. Because methanol is formed on grain surfaces, its emission highlights regions where desorption from grains is particularly efficient. Methanol and sulphur monoxide are most abundant in a narrow zone that follows the eastern side of the core. This side is sheltered from the stronger external radiation field coming from the west. We show that photodissociation on the illuminated side can give rise to an asymmetric methanol distribution, but that the stark contrast observed in H-MM1 is hard to explain without assuming enhanced desorption on the shaded side. The region of the brightest emission has a wavy structure that rolls up at one end. This is the signature of Kelvin-Helmholtz instability occurring in sheared flows. We suggest that in this zone, methanol and sulphur are released as a result of grain-grain collisions induced by shear vorticity.

astro-ph.GA↗

arXiv2019

Search for H$_3^+$ isotopologues toward CRL 2136 IRS 1

Deuterated interstellar molecules frequently have abundances relative to their main isotopologues much higher than the overall elemental D-to-H ratio in the cold dense interstellar medium. The H$_3^+$ and its isotopologues play a key role in the deuterium fractionation; however, the abundances of these isotopologues have not been measured empirically with respect to H$_3^+$ to date. Our aim was to constrain the relative abundances of H$_2$D$^+$ and D$_3^+$ in the cold outer envelope of the hot core CRL 2136 IRS 1. We carried out three observations targeting H$_3^+$ and its isotopologues using the spectrographs CRIRES at the VLT, iSHELL at IRTF, and EXES on board SOFIA. In addition, the CO overtone band at 2.3 $μ$m was observed by iSHELL to characterize the gas on the line of sight. The H$_3^+$ ion was detected toward CRL 2136 IRS 1 as in previous observations. Spectroscopy of lines of H$_2$D$^+$ and D$_3^+$ resulted in non-detections. The 3$σ$ upper limits of $N({\rm H_2D^+})/N({\rm H_3^+})$ and $N({\rm D_3^+})/N({\rm H_3^+})$ are 0.24 and 0.13, respectively. The population diagram for CO is reproduced by two components of warm gas with the temperatures 58 K and 530 K, assuming a local thermodynamic equilibrium (LTE) distribution of the rotational levels. Cold gas ($<$20 K) makes only a minor contribution to the CO molecular column toward CRL 2136 IRS 1. The critical conditions for deuterium fractionation in a dense cloud are low temperature and CO depletion. Given the revised cloud properties, it is no surprise that H$_3^+$ isotopologues are not detected toward CRL 2136 IRS 1. The result is consistent with our current understanding of how deuterium fractionation proceeds.

astro-ph.SR↗

arXiv2019

Cloud G074.11+00.11: a stellar cluster in formation

We present molecular line and dust continuum observations of a Planck-detected cold cloud, G074.11+00.11. The cloud consists of a system of curved filaments and a central star-forming clump. The clump is associated with several infrared sources and H2O maser emission. We aim to determine the mass distribution and gas dynamics within the clump, to investigate if the filamentary structure seen around the clump repeats itself on a smaller scale, and to estimate the fractions of mass contained in dense cores and filaments. The velocity distribution of pristine dense gas can be used to investigate the global dynamical state of the clump, the role of filamentary inflows, filament fragmentation and core accretion. We use molecular line and continuum observations from single dish observatories and interferometric facilities to study the kinematics of the region. The molecular line observations show that the central clump may have formed as a result of a large-scale filament collision. The central clump contains three compact cores. Assuming a distance of 2.3 kpc, based on Gaia observations and a three-dimensional extinction method of background stars, the mass of the central clump exceeds 700 solar masses, which is roughly 25% of the total mass of the cloud. Our virial analysis suggests that the central clump and all identified substructures are collapsing. We find no evidence for small-scale filaments associated with the cores. Our observations indicate that the clump is fragmented into three cores with masses in the range [10,50] solar masses and that all three are collapsing. The presence of an H2O maser emission suggests active star formation. However, the CO lines show only weak signs of outflows. We suggest that the region is young and any processes leading to star formation have just recently begun.

astro-ph.GA↗

arXiv2019

Deuterated forms of H${_3^+}$ and their importance in astrochemistry

At the low temperatures ($\sim$10 K) and high densities ($\sim$100,000 H$_2$ molecules per cc) of molecular cloud cores and protostellar envelopes, a large amount of molecular species (in particular those containing C and O) freeze-out onto dust grain surfaces. It is in these regions that the deuteration of H$_3^+$ becomes very efficient, with a sharp abundance increase of H$_2$D$^+$ and D$_2$H$^+$. The multi-deuterated forms of H$_3^+$ participate in an active chemistry: (i) their collision with neutral species produces deuterated molecules such as the commonly observed N$_2$D$^+$, DCO$^+$ and multi-deuterated NH$_3$; (ii) their dissociative electronic recombination increases the D/H atomic ratio by several orders of magnitude above the D cosmic abundance, thus allowing deuteration of molecules (e.g. CH$_3$OH and H$_2$O) on the surface of dust grains. Deuterated molecules are the main diagnostic tools of dense and cold interstellar clouds, where the first steps toward star and protoplanetary disk formation take place. Recent observations of deuterated molecules are reviewed and discussed in view of astrochemical models inclusive of spin-state chemistry. We present a new comparison between models based on complete scrambling (to calculate branching ratio tables for reactions between chemical species that include protons and/or deuterons) and models based on non-scrambling (proton hop) methods, showing that the latter best agree with observations of NH$_3$ deuterated isotopologues and their different nuclear spin symmetry states.

astro-ph.GA↗

arXiv2019

Magnetic Field Structure of Dense Cores using Spectroscopic Methods

We develop a new ''core field structure'' (CFS) model to predict the magnetic field strength and magnetic field fluctuation profile of dense cores using gas kinematics. We use spatially resolved observations of the nonthermal velocity dispersion from the Green Bank Ammonia survey along with column density maps from SCUBA-2 to estimate the magnetic field strength across seven dense cores located in the L1688 region of Ophiuchus. The CFS model predicts the profile of the relative field fluctuation, which is related to the observable dispersion in direction of the polarization vectors. Within the context of our model we find that all the cores have a transcritical mass-to-flux ratio.

astro-ph.GA↗

arXiv2018

Radio interferometric observation of an asteroid occultation

The occultation of the radio galaxy 0141+268 by the asteroid (372) Palma on 2017 May 15 was observed using six antennas of the Very Long Baseline Array (VLBA). The shadow of Palma crossed the VLBA station at Brewster, Washington. Owing to the wavelength used, and the size and the distance of the asteroid, a diffraction pattern in the Fraunhofer regime was observed. The measurement retrieves both the amplitude and the phase of the diffracted electromagnetic wave. This is the first astronomical measurement of the phase shift caused by diffraction. The maximum phase shift is sensitive to the effective diameter of the asteroid. The bright spot at the shadow's center, the so called Arago--Poisson spot, is clearly detected in the amplitude time-series, and its strength is a good indicator of the closest angular distance between the center of the asteroid and the radio source. A sample of random shapes constructed using a Markov chain Monte Carlo algorithm suggests that the silhouette of Palma deviates from a perfect circle by 26+-13%. The best-fitting random shapes resemble each other, and we suggest their average approximates the shape of the silhouette at the time of the occultation. The effective diameter obtained for Palma, 192.1+-4.8 km, is in excellent agreement with recent estimates from thermal modeling of mid-infrared photometry. Finally, our computations show that because of the high positional accuracy, a single radio interferometric occultation measurement can reduce the long-term ephemeris uncertainty by an order of magnitude.

astro-ph.EP↗

arXiv2018

$^{14}$N/$^{15}$N ratio measurements in prestellar cores with N$_2$H$^+$: new evidence of $^{15}$N-antifractionation

Context: The $^{15}$N fractionation has been observed to show large variations among astrophysical sources, depending both on the type of target and on the molecular tracer used. These variations cannot be reproduced by the current chemical models. Aims: Until now, the $^{14}$N/$^{15}$N ratio in N$_2$H$^+$ has been accurately measured in only one prestellar source, L1544, where strong levels of fractionation, with depletion in $^{15}$N, are found ($^{14}$N/$^{15}$N$\: \approx 1000$). In this paper we extend the sample to three more bona fide prestellar cores, in order to understand if the antifractionation in N$_2$H$^+$ is a common feature of this kind of sources. Methods: We observed N$_2$H$^+$,N$^{15}$NH$^+$ and $^{15}$NNH$^+$ in L183, L429 and L694-2 with the IRAM 30m telescope. We modeled the emission with a non-local radiative transfer code in order to obtain accurate estimates of the molecular column densities, including the one for the optically thick N$_2$H$^+$. We used the most recent collisional rate coefficients available, and with these we also re-analysed the L1544 spectra previously published. Results: The obtained isotopic ratios are in the range $630-770$ and significantly differ with the value, predicted by the most recent chemical models, of $\approx 440$, close to the protosolar value. Our prestellar core sample shows high level of depletion of $^{15}$N in diazenylium, as previously found in L1544. A revision of the N chemical networks is needed in order to explain these results.

astro-ph.GA↗

arXiv2017

Detection of interstellar ortho-D2H+ with SOFIA

We report on the detection of the ground-state rotational line of ortho-D2H+ at 1.477 THz (203 micron) using the German REceiver for Astronomy at Terahertz frequencies (GREAT) onboard the Stratospheric Observatory For Infrared Astronomy (SOFIA). The line is seen in absorption against far-infrared continuum from the protostellar binary IRAS 16293-2422 in Ophiuchus. The para-D2H+ line at 691.7 GHz was not detected with the APEX telescope toward this position. These D2H+ observations complement our previous detections of para-H2D+ and ortho-H2D+ using SOFIA and APEX. By modeling chemistry and radiative transfer in the dense core surrounding the protostars, we find that the ortho-D2H+ and para-H2D+ absorption features mainly originate in the cool (T<18 K) outer envelope of the core. In contrast, the ortho-H2D+ emission from the core is significantly absorbed by the ambient molecular cloud. Analyses of the combined D2H+ and H2D+ data result in an age estimate of ~500 000 yr for the core, with an uncertainty of ~200 000 yr. The core material has probably been pre-processed for another 500 000 years in conditions corresponding to those in the ambient molecular cloud. The inferred time scale is more than ten times the age of the embedded protobinary. The D2H+ and H2D+ ions have large and nearly equal total (ortho+para) fractional abundances of ~$10^{-9}$ in the outer envelope. This confirms the central role of H3+ in the deuterium chemistry in cool, dense gas, and adds support to the prediction of chemistry models that also D3+ should be abundant in these conditions.

astro-ph.GA↗