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Jorma Harju

Publications and source records attributed to Jorma Harju.

26 records · Page 2Linked to original sources

Deuteration of ammonia in the starless core Ophiuchus/H-MM1

Ammonia and its deuterated isotopologues probe physical conditions in dense molecular cloud cores. With the aim of testing the current understanding of the spin-state chemistry of these molecules, we observed spectral lines of NH3, NH2D, NHD2, ND3, and N2D+ towards a dense, starless core in Ophiuchus with the APEX, GBT, and IRAM 30-m telescopes. The observations were interpreted using a gas-grain chemistry model combined with radiative transfer calculations. The chemistry model distinguishes between the different nuclear spin states of light hydrogen molecules, ammonia, and their deuterated forms. High deuterium fractionation ratios with NH2D/NH3=0.4, NHD2/NH2D=0.2, and ND3/NHD2=0.06 were found in the core. The observed ortho/para ratios of NH2D and NHD2 are close to the corresponding nuclear spin statistical weights. The chemistry model can approximately reproduce the observed abundances, but predicts uniformly too low ortho/para-NH2D, and too large ortho/para-NHD2 ratios. The longevity of N2H+ and NH3 in dense gas, which is prerequisite to their strong deuteration, can be attributed to the chemical inertia of N2 on grain surfaces. The discrepancies between the chemistry model and the observations are likely to be caused by the fact that the model assumes complete scrambling in principal gas-phase deuteration reactions of ammonia, which means that all the nuclei are mixed in reactive collisions. If, instead, these reactions occur through proton hop/hydrogen abstraction processes, statistical spin ratios are to be expected. The present results suggest that while the deuteration of ammonia changes with physical conditions and time, the nuclear spin ratios of ammonia isotopologues do not probe the evolutionary stage of a cloud.

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Chemical differentiation in a prestellar core traces non-uniform illumination

Dense cloud cores present chemical differentiation due to the different distribution of C-bearing and N-bearing molecules, the latter being less affected by freeze-out onto dust grains. In this letter we show that two C-bearing molecules, CH$_3$OH and $c$-C$_3$H$_2$, present a strikingly different (complementary) morphology while showing the same kinematics toward the prestellar core L1544. After comparing their distribution with large scale H$_2$ column density N(H$_2$) map from the Herschel satellite, we find that these two molecules trace different environmental conditions in the surrounding of L1544: the $c$-C$_3$H$_2$ distribution peaks close to the southern part of the core, where the surrounding molecular cloud has a N(H$_2$) sharp edge, while CH$_3$OH mainly traces the northern part of the core, where N(H$_2$) presents a shallower tail. We conclude that this is evidence of chemical differentiation driven by different amount of illumination from the interstellar radiation field: in the South, photochemistry maintains more C atoms in the gas phase allowing carbon chain (such as $c$-C$_3$H$_2$) production; in the North, C is mainly locked in CO and methanol traces the zone where CO starts to freeze out significantly. During the process of cloud contraction, different gas and ice compositions are thus expected to mix toward the central regions of the core, where a potential Solar-type system will form. An alternative view on carbon-chain chemistry in star-forming regions is also provided.

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Determination of the far-infrared dust opacity in a prestellar core

(abridged) We correlated near-infrared stellar H-Ks colour excesses of background stars from NTT/SOFI with the far-IR optical depth map, tauFIR, derived from Herschel 160, 250, 350, and 500 um data. The Herschel maps were also used to construct a model for the cloud to examine the effect of temperature gradients on the estimated optical depths and dust absorption cross-sections. A linear correlation is seen between the colour H-Ks and tauFIR up to high extinctions (AV ~ 25). The correlation translates to the average extinction ratio A250um/AJ = 0.0014 +/- 0.0002, assuming a standard near-infrared extinction law and a dust emissivity index beta=2. Using an empirical NH/AJ ratio we obtain an average absorption cross-section per H nucleus of sigmaH(250um) = (1.8 +/- 0.3) * 10^(-25) cm^2 / H-atom, corresponding to a cross-section per unit mass of gas kappaG(250 um) = 0.08 +/- 0.01 cm^2 / g. The cloud model however suggests that owing to the bias caused by temperature changes along the line-of-sight these values underestimate the true cross-sections by up to 40% near the centre of the core. Assuming that the model describes the effect of the temperature variation on tauFIR correctly, we find that the relationship between H-Ks and tauFIR agrees with the recently determined relationship between sigmaH and NH in Orion A. The derived far-IR cross-section agrees with previous determinations in molecular clouds with moderate column densities, and is not particularly large compared with some other cold cores. We suggest that this is connected to the core not beng very dense (the central density is likely to be ~10^5 cm^-3) and judging from previous molecular line data, it appears to be at an early stage of chemical evolution.

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A (sub)millimetre study of dense cores in Orion B9

We aim to further constrain the properties and evolutionary stages of dense cores in Orion B9. The central part of Orion B9 was mapped at 350 micron with APEX/SABOCA. A sample of nine cores in the region were observed in C17O(2-1), H13CO+(4-3) (towards 3 sources), DCO+(4-3), N2H+(3-2), and N2D+(3-2) with APEX/SHFI. These data are used in conjunction with our previous APEX/LABOCA 870-micron dust continuum data. Many of the LABOCA cores show evidence of substructure in the higher-resolution SABOCA image. In particular, we report on the discovery of multiple very low-mass condensations in the prestellar core SMM 6. Based on the 350-to-870 micron flux density ratios, we determine dust temperatures of ~7.9-10.8 K, and dust emissivity indices of ~0.5-1.8. The CO depletion factors are in the range ~1.6-10.8. The degree of deuteration in N2H+ is ~0.04-0.99, where the highest value (seen towards the prestellar core SMM 1) is, to our knowledge, the most extreme level of N2H+ deuteration reported so far. The level of HCO+ deuteration is about 1-2%. We also detected D2CO towards two sources. The detection of subcondensations within SMM 6 shows that core fragmentation can already take place during the prestellar phase. The origin of this substructure is likely caused by thermal Jeans fragmentation of the elongated parent core. A low depletion factor and the presence of gas-phase D2CO in SMM 1 suggest that the core chemistry is affected by the nearby outflow. The very high N2H+ deuteration in SMM 1 is likely to be remnant of the earlier CO-depleted phase.

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Mapping the prestellar core Ophiuchus D (L1696A) in ammonia

The gas kinetic temperature in the centres of starless, high-density cores is predicted to fall as low as 5-6 K. The aim of this study was to determine the kinetic temperature distribution in the low-mass prestellar core Oph D where previous observations suggest a very low central temperature. The densest part of the Oph D core was mapped in the NH3(1,1) and (2,2) inversion lines using the Very Large Array (VLA). The physical quantities were derived from the observed spectra by fitting the hyperfine structure of the lines, and subsequently the temperature distribution of Oph D was calculated using the standard rotational temperature techniques. A physical model of the cores was constructed, and the simulated spectra after radiative transfer calculations with a 3D Monte Carlo code were compared with the observed spectra. Temperature, density, and ammonia abundance of the core model were tuned until a satisfactory match with the observation was obtained. The high resolution of the interferometric data reveals that the southern part of Oph D comprises of two small cores. The gas kinetic temperatures, as derived from ammonia towards the centres of the southern and northern core are 7.4 and 8.9 K, respectively. The observed masses of the cores are only 0.2 M_Sun. Their potential collapse could lead to formation of brown dwarfs or low-mass stars.

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CH abundance gradient in TMC-1

We observed the 9-cm Lambda-doubling lines of CH along the dense filament of TMC-1. The CH column densities were compared with the total H2 column densities derived using the 2MASS NIR data and previously published SCUBA maps and with OH column densities derived using previous observations with Effelsberg. We also modelled the chemical evolution of TMC-1 adopting physical conditions typical of dark clouds using the UMIST Database for Astrochemistry gas-phase reaction network to aid the interpretation of the observed OH/CH abundance ratios. The CH column density has a clear peak in the vicinity of the cyanopolyyne maximum of TMC-1. The fractional CH abundance relative to H2 increases steadily from the northwestern end of the filament where it lies around 1.0e-8, to the southeast where it reaches a value of 2.0e-8. The OH and CH column densities are well correlated, and we obtained OH/CH abundance ratios of ~ 16 - 20. These values are clearly larger than what has been measured recently in diffuse interstellar gas and is likely to be related to C to CO conversion at higher densities. The good correlation between CH and OH can be explained by similar production and destruction pathways. We suggest that the observed CH and OH abundance gradients are mainly due to enhanced abundances in a low-density envelope which becomes more prominent in the southeastern part and seems to continue beyond the dense filament. An extensive envelope probably signifies an early stage of dynamical evolution, and conforms with the detection of a large CH abundance in the southeastern part of the cloud. The implied presence of other simple forms of carbon in the gas phase provides a natural explanation for the observation of "early-type" molecules in this region.

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Physical properties of dense cores in Orion B9

We aim to determine the physical and chemical properties of dense cores in Orion B9. We observed the NH3(1,1) and (2,2), and the N2H+(3-2) lines towards the submm peak positions. These data are used in conjunction with our LABOCA 870 micron dust continuum data. The gas kinetic temperature in the cores is between ~9.4-13.9 K. The non-thermal velocity dispersion is subsonic in most of the cores. The non-thermal linewidth in protostellar cores appears to increase with increasing bolometric luminosity. The core masses are very likely drawn from the same parent distribution as the core masses in Orion B North. Starless cores in the region are likely to be gravitationally bound, and thus prestellar. Some of the cores have a lower radial velocity than the systemic velocity of the region, suggesting that they are members of the "low-velocity part" of Orion B. The observed core-separation distances deviate from the corresponding random-like model distributions. The distances between the nearest-neighbours are comparable to the thermal Jeans length. The fractional abundances of NH3 and N2H+ in the cores are ~1.5-9.8x10^{-8} and ~0.2-5.9x10^{-10}, respectively. The NH3 abundance appears to decrease with increasing H2 column and number densities. The NH3/N2H+ column density ratio is larger in starless cores than in cores with embedded protostars. The core population in Orion B9 is comparable in physical properties to those in nearby low-mass star-forming regions. It is unclear if the origin of cores could be explained by turbulent fragmentation. On the other hand, many of the core properties conform with the picture of dynamic core evolution. The Orion B9 region has probably been influenced by the feedback from the nearby Ori OB 1b group, and the fragmentation of the parental cloud into cores could be caused by gravitational instability.

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LABOCA mapping of the infrared dark cloud MSXDC G304.74+01.32

Infrared dark clouds (IRDCs) likely represent very early stages of high-mass star/star cluster formation. In this study, we aim to determine the physical properties and spatial distribution of dense clumps in the IRDC MSXDC G304.74+01.32 (G304.74), and bring these characteristics into relation to theories concerning the origin of IRDCs and their fragmentation into clumps and star-forming cores. G304.74 was mapped in the 870 $μ$m dust continuum with the LABOCA bolometer on APEX. Archival MSX and IRAS infrared data were used to study the nature and properties of the submillimetre clumps within the cloud. There are 8 clumps within G304.74 which are not associated with mid-infrared (MIR) emission. Some of them are candidates for being/harbouring high-mass starless cores (HMSCs). We compared the clump masses and their spatial distribution in G304.74 with those in several other recently studied IRDCs. There is a high likelihood that the clump mass distributions in G304.74 and in several other IRDCs represent the samples of the same parent distribution. In most cases the spatial distributions of clumps in IRDCs do not deviate significantly from random distributions. This is consistent with the idea that the origin of IRDCs, and their further sub-fragmentation down to scales of clumps is caused by supersonic turbulence in accordance with results from giant molecular clouds.

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