arXiv subjects

K. E. Gray

Publications and source records attributed to K. E. Gray.

At least 19 recordsLinked to original sources

arXiv2025

Broad-based experimental evidence for a hidden phase of cuprate coexistence with far-reaching implications

Analyses of experimental data in the literature show thresholds that directly imply a coexistent superconductive (SC) and pseudogap (PG) phase that, to our knowledge, has not been previously identified. The data used emphasize the essences of d-wave cuprate SC, i.e., the superfluid density and the momentum dependence. For severe underdoping, these data imply that SC condenses conventionally onto the unaltered low-energy density-of-states of a high-temperature PG. Beyond a doping threshold, the high-temperature normal state is replaced, below the SC transition temperature, by a single energetically-favorable thermodynamic phase that embodies a more complex interplay of these orders. This previously hidden phase occupies a central portion of the SC dome, enhances the superfluid density by a factor of two or more to benefit applications, can resolve thirteen mysteries in the literature and suggests an alternative approach to cuprate SC.

cond-mat.supr-con↗

arXiv2013

Powerful terahertz emission from Bi2Sr2CaCu2O8+delta mesa arrays

Stacks of intrinsic Josephson junctions (IJJs) in high-temperature superconductors enable the fabrication of compact sources of coherent terahertz radiation. Here we demonstrate that multiple stacks patterned on the same Bi2Sr2CaCu2O8+delta crystal can - under optimized conditions - be synchronized to emit high-power THz-radiation. For three synchronized stacks we achieved 610 microwatts of continuous-wave coherent radiation power at 0.51 THz. We suggest that synchronization is promoted by THz-waves in the base crystal. We note though that synchronization cannot be achieved in all samples. However, even in these cases powers on the 100-microwatt scale can be generated.

cond-mat.supr-con↗

arXiv2013

The chiral phase transition in charge ordered 1T-TiSe2

It was recently discovered that the low temperature, charge ordered phase of 1T-TiSe2 has a chiral character. This unexpected chirality in a system described by a scalar order parameter could be explained in a model where the emergence of relative phase shifts between three charge density wave components breaks the inversion symmetry of the lattice. Here, we present experimental evidence for the sequence of phase transitions predicted by that theory, going from disorder to non-chiral and finally to chiral charge order. Employing X-ray diffraction, specific heat, and electrical transport measurements, we find that a novel phase transition occurs ~7 K below the main charge ordering transition in TiSe2, in agreement with the predicted hierarchy of charge ordered phases.

cond-mat.str-el↗

arXiv2013

Effect of high temperature heat treatments on the quality factor of a large-grain superconducting radio-frequency niobium cavity

Large-grain Nb has become a viable alternative to fine-grain Nb for the fabrication of superconducting radio-frequency cavities. In this contribution we report the results from a heat treatment study of a large-grain 1.5 GHz single-cell cavity made of "medium purity" Nb. The baseline surface preparation prior to heat treatment consisted of standard buffered chemical polishing. The heat treatment in the range 800 - 1400 C was done in a newly designed vacuum induction furnace. Q0 values of the order of 2x1010 at 2.0 K and peak surface magnetic field (Bp) of 90 mT were achieved reproducibly. A Q0-value of (5+-1)1010 at 2.0 K and Bp = 90 mT was obtained after heat treatment at 1400 C. This is the highest value ever reported at this temperature, frequency and field. Samples heat treated with the cavity at 1400 C were analyzed by secondary ion mass spectrometry, secondary electron microscopy, energy dispersive X-ray, point contact tunneling and X-ray diffraction and revealed a complex surface composition which includes titanium oxide, increased carbon and nitrogen content but reduced hydrogen concentration compared to a non heat-treated sample.

cond-mat.supr-con↗

arXiv2013

Antiferromagnetic Domain Structure in Bilayer Manganite

We report a novel soft x-ray nanodiffraction study of antiferromagnetic domains in the strongly correlated bylayer manganite La$_{0.96}$Sr$_{2.04}$Mn$_{2}$O$_{7}$. We find that the antiferromagnetic domains are quenched, forming a unique domain pattern with each domain having an intrinsic memory of its spin direction, and with associated domain walls running along crystallographic directions. This can be explained by the presence of crystallographic or magnetic imperfections locked in during the crystal growth process which pin the antiferromagnetic domains. The antiferromagnetic domain pattern shows two distinct types of domain. We observe, in one type only, a periodic ripple in the manganese spin direction with a period of approximately 4 \micro\meter. We propose that the loss of inversion symmetry within a bilayer is responsible for this ripple structure through a Dzyaloshinskii-Moriya-type interaction.

cond-mat.mtrl-sci↗

arXiv2011

Tunable terahertz emission from Bi2Sr2CaCu2O8+δ mesa devices

We have measured coherent terahertz emission spectra from Bi2Sr2CaCu2O8+δ mesa devices, as a function of temperature and mesa bias voltage. The emission frequency is found to be tunable by up to 12% by varying the temperature and bias voltage. We attribute the appearance of tunability to asymmetric boundaries at the top and bottom, and the non-rectangular cross-section of the mesas. This interpretation is consistent with numerical simulations of the dynamics of intrinsic Josephson junctions in the mesa. Easily tunable emission frequency may have important implications for the design of terahertz devices based on stacked intrinsic Josephson junctions.

cond-mat.supr-con↗

arXiv2010

Rebuttal to "Comment by V.M. Krasnov on 'Counterintuitive consequence of heating in strongly-driven intrinsic junctions of Bi2Sr2CaCu2O8+d Mesas' "

In our article [1], we found that with increasing dissipation there is a clear, systematic shift and sharpening of the conductance peak along with the disappearance of the higher-bias dip/hump features (DHF), for a stack of intrinsic Josephson junctions (IJJs) of intercalated Bi2Sr2CaCu2O8+δ (Bi2212). Our work agrees with Zhu et al [2] on unintercalated, pristine Bi2212, as both studies show the same systematic changes with dissipation. The broader peaks found with reduced dissipation [1,2] are consistent with broad peaks in the density-of-states (DOS) found among scanning tunneling spectroscopy [3] (STS), mechanical contact tunneling [4] (MCT) and inferred from angle (momentum) resolved photoemission spectroscopy [5] (ARPES); results that could not be ignored. Thus, sharp peaks are extrinsic and cannot correspond to the superconducting DOS. We suggested that the commonality of the sharp peaks in our conductance data, which is demonstrably shown to be heating-dominated, and the peaks of previous intrinsic tunneling spectroscopy (ITS) data implies that these ITS reports might need reinterpretation.

cond-mat.supr-con↗

arXiv2009

Counterintuitive Consequence of Heating in Strongly-Driven Intrinsic-Junctions of Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ Mesas

Anomalously high and sharp peaks in the conductance of intrinsic Josephson junctions in Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ (Bi2212) mesas have been universally interpreted as superconducting energy gaps, but here we show they are a result of heating. This interpretation follows from a direct comparison to the equilibrium gap, $\mathit Δ$, measured in break junctions on similar Bi2212 crystals. As the dissipated power increases with a greater number of junctions in the mesa, the conductance peak abruptly sharpens and its voltage decreases to well below 2$\mathit Δ$. This sharpening, found in our experimental data, defies conventional intuition of heating effects on tunneling spectra, but it can be understood as an instability into a nonequilibrium two-phase coexistent state. The measured peak positions occur accurately within the voltage range that an S-shaped backbending is found in the {\it calculated} current-voltage curves for spatially {\it uniform} self-heating and that S-shape implies the potential for the uniform state to be unstable.

cond-mat.supr-con↗

arXiv2009

Emission of Terahertz Waves from Stacks of Intrinsic Josephson Junctions

By patterning mesoscopic crystals of Bi2Sr2CaCu2O8 (BSCCO) into electromagnetic resonators the oscillations of a large number of intrinsic Josephson junctions can be synchronized into a macroscopic coherent state accompanied by the emission of strong continuous wave THz-radiation. The temperature dependence of the emission is governed by the interplay of self-heating in the resonator and by re-trapping of intrinsic Josephson junctions which can yield a strongly nonmonotonic temperature dependence of the emission power. Furthermore, proper shaping of the resonators yields THzsources with voltage-tunable emission frequencies.

cond-mat.supr-con↗

arXiv2009

Thermal Management in Large Bi2212 Mesas used for Terahertz Sources

We present a thermal analysis of a patterned mesa on a Bi2Sr2CaCu2O8 (Bi2212) single crystal that is based on tunneling characteristics of the c-axis stack of ~800 intrinsic Josephson junctions in the mesa. Despite the large mesa volume (e.g., 40x300x1.2 micron3) and power dissipation that result in selfheating and backbending of the current-voltage curve (I-V), there are accessible bias conditions for which significant polarized THz-wave emission can be observed. We estimate the mesa temperature by equating the quasiparticle resistance, Rqp(T), to the ratio V/I over the entire I-V including the backbending region. These temperatures are used to predict the unpolarized black-body radiation reaching our bolometer and there is substantial agreement over the entire I-V. As such, backbending results from the particular Rqp(T) for Bi2212, as first discussed by Fenton, rather than a significant suppression of the energy gap. This model also correctly predicts the observed disappearance of backbending above ~60 K.

cond-mat.supr-con↗

arXiv2008

Improvement and protection of niobium surface superconductivity by Atomic Layer Deposition and heat treatment

A method to treat the surface of Nb is described which potentially can improve the performance of superconducting RF cavities. We present tunneling and x-ray photoemission spectroscopy (XPS) measurements at the surface of cavity-grade niobium samples coated with a 3 nm alumina overlayer deposited by Atomic Layer Deposition (ALD). The coated samples baked in ultra high vacuum (UHV) at low temperature reveal at first degraded superconducting surface. However, at temperatures above 450C, the tunneling conductance curves show significant improvements of the superconducting density of states (DOS) compared with untreated surfaces.

cond-mat.supr-con↗

arXiv2008

Tunneling study of cavity grade Nb: possible magnetic scattering at the surface

Tunneling spectroscopy was performed on Nb pieces prepared by the same processes used to etch and clean superconducting radio frequency (SRF) cavities. Air exposed, electropolished Nb exhibited a surface superconducting gap delta=1.55 meV, characteristic of clean, bulk Nb. However the tunneling density of states (DOS) was broadened significantly. The Nb pieces treated with the same mild baking used to improve the Q-slope in SRF cavities, reveal a sharper DOS. Good fits to the DOS were obtained using Shiba theory, suggesting that magnetic scattering of quasiparticles is the origin of the gapless surface superconductivity and a heretofore unrecognized contributor to the Q-slope problem of Nb SRF cavities.

cond-mat.supr-con↗

arXiv2007

Characteristic Energy of the Coulomb Interactions and the Pileup of States

Tunneling data on $\mathrm{La_{1.28}Sr_{1.72}Mn_2O_7}$ crystals confirm Coulomb interaction effects through the $\sqrt{\mathrm{E}}$ dependence of the density of states. Importantly, the data and analysis at high energy, E, show a pileup of states: most of the states removed from near the Fermi level are found between ~40 and 130 meV, from which we infer the possibility of universal behavior. The agreement of our tunneling data with recent photoemission results further confirms our analysis.

cond-mat.str-el↗

arXiv2007

Evidence of Strong-Coupled Superconductivity in CaC6 from Tunneling Spectroscopy

Point-contact tunneling on CaC$_6$ crystals reproducibly reveals superconducting gaps, $Δ$, of 2.3$\pm$0.2 meV which are $\sim$~40% larger than earlier reports. That puts CaC$_6$ into the class of very strong-coupled superconductors since 2$Δ$/kT$_c\sim$~4.6. Thus soft Ca phonons will be primarily involved in the superconductivity, a conclusion that explains the large Ca isotope effect found recently for CaC$_6$. Consistency among superconductor-insulator-normal metal (SIN), SIS and Andreev reflection (SN) junctions reinforces the intrinsic nature of this result.

cond-mat.supr-con↗

arXiv2007

Reentrant Orbital Order and the True Ground State of LaSr2Mn2O7

Contrary to conventional wisdom, our purified La2-2xSr1+2xMn2O7 crystals exhibit CE-type orbital and charge order as the low-temperature ground state for a hole doping level h = 0.5. For small deviations from h = 0.5, the high temperature CE phase is replaced at low temperatures by an A-type antiferromagnet without coexistence. Larger deviations result in a lack of CE order at any temperature. Thus, small inhomogeneities in cation or oxygen composition could explain why others commonly see this reentrance with coexistence.

cond-mat.str-el↗

arXiv2007

Investigation of the Tunneling Spectra in HgBr2-Intercalated Bi-2212 Single Crystals below and above Tc

Interlayer tunneling spectroscopy measurements were performed on mesa arrays of Bi-2212 single crystals, intercalated with HgBr$_2$. Tunneling conductances were obtained over a wide temperature range to examine the spectral features, especially the behavior of the quasiparticle peaks corresponding to superconducting energy gaps (SGs). Experimental spectra showed that gap-like features are still present even for the temperatures far above the transition temperature, T$_c$. This evidence is consistent with the idea that the SG evolves into a pseudogap above T$_c$ for HgBr$_2$-intercalated Bi-2212 single crystals.

cond-mat.supr-con↗

arXiv2006

Tunneling spectroscopy of Tl2Ba2CaCu2O8 single crystals and thin films

Early electron tunneling experiments with the Tl2Ba2CaCu2O8 measured Δ= 16-28 meV, while bulk optical experiments measured Δ= 43-45 meV. We report new tunneling measurements of Tl2Ba2CaCu2O8 single crystals and c-axis oriented thin films, where the measured Δvalues on both sample types cover the range of 24-50 meV, with more than 70% of the junctions displaying Δ> 30 meV. This work resolves the inconsistency between previously published results of tunneling and optical experiments. New tunneling conductances reveal improved superconducting gap region characteristics consistent with d-wave symmetry. The tunneling spectra also display features similar to the dip feature observed in Bi2Sr2CaCu2O8. We discuss our results in context of experiments reported previously on related materials.

cond-mat.supr-con↗

arXiv2006

Suppressed Magnetization at the Surfaces and Interfaces of Ferromagnetic Metallic Manganites

What happens to ferromagnetism at the surfaces and interfaces of manganites? With the competition between charge, spin, and orbital degrees of freedom, it is not surprising that the surface behavior may be profoundly different than that of the bulk. Using a powerful combination of two surface probes, tunneling and polarized x-ray interactions, this paper reviews our work on the nature of the electronic and magnetic states at manganite surfaces and interfaces. The general observation is that ferromagnetism is not the lowest energy state at the surface or interface, which results in a suppression or even loss of ferromagnetic order at the surface. Two cases will be discussed ranging from the surface of the quasi-2D bilayer manganite (La$_{2-2x}$Sr$_{1+2x}$Mn$_2$O$_7$) to the 3D Perovskite (La$_{2/3}$Sr$_{1/3}$MnO$_3$)/SrTiO$_3$ interface. For the bilayer manganite, that is, ferromagnetic and conducting in the bulk, these probes present clear evidence for an intrinsic insulating non-ferromagnetic surface layer atop adjacent subsurface layers that display the full bulk magnetization. This abrupt intrinsic magnetic interface is attributed to the weak inter-bilayer coupling native to these quasi-two-dimensional materials. This is in marked contrast to the non-layered manganite system (La$_{2/3}$Sr$_{1/3}$MnO$_3$/SrTiO$_3$), whose magnetization near the interface is less than half the bulk value at low temperatures and decreases with increasing temperature at a faster rate than the bulk.

cond-mat.str-el↗