arXiv subjects

Katsunori Wakabayashi

Publications and source records attributed to Katsunori Wakabayashi.

At least 55 records · Page 3Linked to original sources

arXiv2020

Enhanced solar photothermal effect of PANi fabrics with plasmonic nanostructures

The photothermal energy conversion in hanging and floating polyaniline (PANi)-cotton fabrics is investigated using a model based on the heat diffusion equation. Perfect absorption and anti-reflection of wet hanging PANi-cotton fabrics cause quick transfer of total incident light into water confining nearly 100 $\%$ of the sunlight. As a result, a hanging membrane is found to have more attractive properties than a floating above water fabric. We find, however, that the photothermal properties of a floating PANi-cotton membrane can greatly be enhanced by dispersing TiN nanoparticles in the water below the fabric. The calculated temperature gradients for TiN nanoparticle solutions show that the absorbed energy grows with increasing the nanoparticle density and that the photothermal process occurs mostly near the surface. The collective heating effects depend on the size and density of nanoparticles, which can further be used to modulate the photothermal process.

cond-mat.mes-hall↗

arXiv2020

Theoretical and Experimental Study of Compression Effects on Structural Relaxation of Glass-Forming Liquids

We develop the elastically collective nonlinear Langevin equation theory of bulk relaxation of glass-forming liquids to investigate molecular mobility under compression conditions. The applied pressure restricts more molecular motion and therefore significantly slows-down the molecular dynamics when increasing the pressure. We quantitatively determine the temperature and pressure dependence of the structural relaxation time. To validate our model, dielectric spectroscopy experiments for three rigid and non-polymeric supramolecules are carried out at ambient and elevated pressures. The numerical results quantitatively agree with experimental data.

cond-mat.soft↗

arXiv2020

Structural Relaxation Time and Dynamic Shear Modulus of Glassy Graphene

We theoretically investigate glass transition behaviors of the glassy graphene in a wide range of temperature, where this amorphous graphene is described as a hard-sphere fluid. The dynamic arrest of a particle is assumingly caused by interactions with its nearest neighbors and surrounding fluid particles. The assumption allows us to analyze roles of local and collective particle mobility. We calculate the temperature dependence of structural relaxation time and dynamic shear modulus, the dynamic fragility, and the glass transition temperature. In addition, correlations between these physical quantities are comprehensively discussed. Our theoretical calculations agree quantitatively well with recent simulations and Dyre's shoving model.

cond-mat.soft↗

arXiv2020

Momentum selective optical absorption in triptycene molecular membrane

The optical properties of triptycene molecular membranes (TMMs) under the linearly and circularly polarized light irradiation have been theoretically studied. Since TMMs have the double-layered Kagome lattice structures for their $π$-electrons, i.e., tiling of trigonal and hexagonal-symmetric rings, the electronic band structures of TMMs have non-equivalent Dirac cones and perfect flat bands. By constructing the tight-binding model to describe the pi-electronic states of TMMs, we have evaluated the optical absorption intensities and valley selective excitation of TMMs based on the Kubo formula. It is found that absorption intensities crucially depend on both light polarization angle and the excitation position in momentum space, i.e., the momentum and valley selective optical excitation. The polarization dependence and optical selection rules are also clarified by using group theoretical analyses.

cond-mat.mes-hall↗

arXiv2020

Molecular relaxations in supercooled liquid and glassy states of amorphous gambogic acid: dielectric spectroscopy, calorimetry and theoretical approach

The relaxation dynamics and thermodynamic properties of supercooled and glassy gambogic acid are investigated using both theory and experiment. We measure the temperature dependence of the relaxation times in three polymorphs (alpha-, beta-, and gamma-form). To gain insight into the relaxation processes, we propose a theoretical approach to quantitatively understand nature of these three relaxations. The alpha-relaxation captures cooperative motions of molecules while the beta-process is mainly governed by local dynamics of a single molecule within the cage formed by its nearest neighbors. Based on quantitative agreement between theory and experimental data, our calculations clearly indicate that the beta-process is a precursor of the structural relaxation and intramolecular motions are responsible for the gamma-relaxation. Moreover, the approach is exploited to study effects of the heating process on alpha relaxation. We find that the heating rate varies logarithmically with Tg and 1000/Tg. These variations are qualitatively consistent with many prior studies.

cond-mat.soft↗

arXiv2019

Effects of Mid-infrared Graphene Plasmons on Photothermal Heating

We theoretically investigate the plasmonic heating of graphene-based systems under the mid-infrared laser irradiation, where periodic arrays of graphene plasmonic resonators are placed on dielectric thin films. Optical resonances are sensitive to structural parameters and the number of graphene layers. Under mid-infrared laser irradiation, the steady-state temperature gradients are calculated. We find that graphene plasmons significantly enhance the confinement of electromagnetic fields in the system and lead to a large temperature rise compared to the case without graphene. The correlations between temperature change and the optical power, laser spot, and thermal conductivity of dielectric layer in these systems are discussed. Our numerical results are in accordance with experiments.

physics.app-ph↗

arXiv2019

Effects of Cooling Rate on Structural Relaxation in Amorphous Drugs: Elastically Collective Nonlinear Langevin Equation Theory and Machine Learning Study

Theoretical approaches are formulated to investigate the molecular mobility under various cooling rates of amorphous drugs. We describe the structural relaxation of a tagged molecule as a coupled process of cage-scale dynamics and collective molecular rearrangement beyond the first coordination shell. The coupling between local and non-local dynamics behaves distinctly in different substances. Theoretical calculations for the structural relaxation time, glass transition temperature, and dynamic fragility are carried out over twenty-two amorphous drugs and polymers. Numerical results have a quantitatively good accordance with experimental data and the extracted physical quantities using the Vogel-Fulcher-Tammann fit function and machine learning. The machine learning method reveals the linear relation between the glass transition temperature and the melting point, which is a key factor for pharmaceutical solubility. Our predictive approaches are reliable tools for developing drug formulation.

cond-mat.soft↗

arXiv2019

Confinement effect on solar thermal heating process of TiN solutions

We propose a theoretical approach to describe quantitatively the heating process in aqueous solutions of dispersed TiN nanoparticles under solar illumination. The temperature gradients of solution with different concentrations of TiN nanoparticles are calculated when confinement effects of the container on the solar absorption are taken into account. We find that the average penetration of solar radiation into the solution is significantly reduced with increasing the nanoparticle concentration. At high concentrations, our numerical results show that photons are localized near the surface of the solution. Moreover, the heat energy balance equation at the vapor-liquid interface is used to describe the solar steam generation. The theoretical time dependence of temperature rise and vaporization weight losses is consistent with experiments. Our calculations give strong evidence that the substantially localized heating near the vapor-liquid interface is the main reason for the more efficient steam generation process by floating plasmonic membranes when compared to randomly dispersed nanoparticles. The validated theoretical model suggests that our approach can be applied towards new predictions and other experimental data descriptions.

cond-mat.mtrl-sci↗

arXiv2019

Dimensional Crossover of Topological Edge States in Su-Schrieffer-Heeger Model

Su-Schrieffer-Heeger (SSH) model on two-dimensional square lattice exhibits a topological phase transition, which is related to the Zak phase determined by bulk band topology. The strong modulation of electron hopping causes nontrivial charge polarization even in the presence of inversion symmetry. The energy band structures and topological edge states have been calculated numerically in previous studies. Here, however, full energy spectrum and explicit form of wave functions for two-dimensional bulk and one-dimensional ribbon geometries of SSH model are analytically derived using wave mechanics approach. Explicit analytic representations of wave functions provide the information of parity for each subband, localization length and critical point of topological phase transition in SSH ribbon. It is also shown that the dimensional crossover of topological transition point for SSH model from one to two-dimension.

cond-mat.mes-hall↗

arXiv2019

Theoretical model for the structural relaxation time in co-amorphous drugs

We propose a simple approach to investigate the structural relaxation time and glass transition of amorphous drugs. Amorphous materials are modeled as a set of equal sized hard spheres. The structural relaxation time over many decades in hard sphere fluids is theoretically calculated using the Elastically Collective Nonlinear Langevin Equation theory associated with Kramer's theory. Then, a new thermal mapping from a real material to an effective hard sphere fluid provides temperature-dependent relaxation time, which can compare to experiments. Numerical results quantitatively agree with previous experiments for pharmaceutical binary mixtures having different weight ratios. We carry out experiments to test our calculations for an ezetimibe-simvastatin-Kollidon VA64 mixture. Our approach would provide a simple but comprehensive description of glassy dynamics in amorphous composites.

cond-mat.soft↗

arXiv2019

Topological Edge States Induced by Zak's Phase in A3B Monolayers

In crystalline systems, charge polarization is related to Zak's phase determined by bulk band topology. Nontrivial charge polarization induces robust edge states accompanied with fractional charge. In Su-Schrieffer-Heeger (SSH) model, it is known that the strong modulation of electron hopping causes nontrivial charge polarization even in the presence of inversion symmetry. Here, we consider a bi-atomic honeycomb lattice to introduce such strong modulation, i.e. A$_3$B sheet. By tuning hopping ratio and onsite potential difference between A and B atoms, we show that topological phase transition characterized by Zak's phase occurs. Furthermore, we propose that C$_3$N and BC$_3$ are the possible realistic materials on the basis of first-principles calculations. Both of them display topological edge states induced by Zak's phase without spin-orbital couplings and external fields unlike conventional topological insulators.

cond-mat.mes-hall↗

arXiv2018

Photonic crystal nanocavity based on a topological corner state

Topological phonics has emerged as a novel approach to engineer the flow of light and provides unprecedented means for developing diverse photonic elements, including robust optical waveguides immune to structural imperfections. However, the development of nanoscale standing-wave cavities in topological photonics is rather slow, despite its importance when building densely-integrated photonic integrated circuits. In this Letter, we report a photonic crystal nanocavity based on a topological corner state, supported at a 90-degrees-angled rim of a two dimensional photonic crystal. A combination of the bulk-edge and edge-corner correspondences guarantees the presence of the higher-order topological state in a hierarchical manner. We experimentally observed a corner mode that is tightly localized in space while supporting a high Q factor over 2,000, verifying its promise as a nanocavity. These results cast new light on the way to introduce nanocavities in topological photonics platforms.

cond-mat.mes-hall↗

arXiv2018

Helical Topological Edge States in a Quadrupole Phase

Topological electric quadrupole is a recently proposed concept that extends the theory of electric polarization of crystals to higher orders. Such a quadrupole phase supports topological states localized on both edges and corners. In this work, we show that in a quadrupole phase of honeycomb lattice, topological helical edge states and pseudo-spin-polarized corner states appear by making use of a pseudo-spin degree of freedom related to point group symmetry. Furthermore, we argue that a general condition for emergence of helical edge states in a (pseudo-)spinful quadrupole phase is mirror or time-reversal symmetry. Our results offers a way of generating topological helical edge states without spin-orbital couplings.

cond-mat.mes-hall↗

arXiv2018

Multilayered plasmonic nanostructures for solar energy harvesting

Optical properties of core-shell-shell Au@SiO2@Au nanostructures and their solar energy harvesting applications are theoretically investigated using Mie theory and heat transfer equations. The theoretical analysis associated with size-dependent modification of the bulk gold dielectric function agrees well with previous experimental results. We use the appropriate absorption cross-section to determine the solar energy absorption efficiency of the nano-heterostructures, which is strongly structure-dependent, and to predict the time-dependent temperature increase of the nanoshell solution under simulated solar irradiation. Comparisons to prior temperature measurements and theoretical evaluation of the solar power conversion efficiency are discussed to provide new insights into underlying mechanisms. Our approach would accelerate materials and structure testing in solar energy harvesting.

physics.app-ph↗

arXiv2017

Novel Topological Phase with Zero Berry Curvature

We present a two-dimensional (2D) lattice model that exhibits a nontrivial topological phase in the absence of the Berry curvature. Instead, the Berry connection provides the topological nontrivial phase in the model, whose integration over the momentum space, the so-called 2D Zak phase, yields a fractional wave polarization in each direction. These fractional wave polarizations manifest themselves as degenerated edge states with opposite parities in the model.

cond-mat.mes-hall↗

arXiv2017

Thermal Hall conductivity in the spin-triplet superconductor with broken time-reversal symmetry

Motivated by the spin-triplet superconductor Sr2RuO4, the thermal Hall conductivity is investigated for several pairing symmetries with broken time-reversal symmetry. In the chiral p-wave phase with a fully opened quasiparticle excitation gap, the temperature dependence of the thermal Hall conductivity has a temperature linear term associated with the topological property directly, and an exponential term, which shows a drastic change around the Lifshitz transition. Examining f-wave states as alternative candidates with $\bm d=Δ_0\hat{z}(k_x^2-k_y^2)(k_x\pm ik_y)$ and $\bm d=Δ_0\hat{z}k_xk_y(k_x\pm ik_y)$ with gapless quasiparticle excitations, we study the temperature dependence of the thermal Hall conductivity, where for the former state the thermal Hall conductivity has a quadratic dependence on temperature, originating from the linear dispersions, in addition to linear and exponential behavior. The obtained result may enable us to distinguish between the chiral p-wave and f-wave states in Sr2RuO4.

cond-mat.supr-con↗

arXiv2016

Possible self-amplification channel for surface plasma waves

Surface plasma waves (SPWs) have been extensively studied in the past two decades with a promise for many applications. However, the effort has so far been met with limited success. It is widely believed that a major caveat lies with the energy losses experienced by SPWs during their propagation. To compensate for the losses, amplifiers have been designed, which are all extrinsic and need an external agent to supply the energy. Here we theoretically show that there exists an intrinsic amplification channel for SPWs in the collision-less limit. We pin down the origin of this channel and analytically calculate the amplification rate. Our finding unveils a hitherto unchartered yet fundamental property of SPWs and may bear far-reaching practical consequences.

cond-mat.mes-hall↗

arXiv2016

Optical excitation of surface plasma waves without grating structures

Surface plasma waves (SPWs) are usually discussed in the context of a metal in contact with a dielectric. However, they can also exist between two metals. In this work we study these bimetallic waves. We find that their dispersion curve always cuts the light line, which allows direct optical coupling without surface grating structures. We propose practical schemes to excite them and the excitation efficiency is estimated. We also show that these waves can be much less lossy than conventional SPWs and their losses can be systematically controlled, a highly desirable attribute in applications. Conducting metal oxides are apt for experimental studies.

cond-mat.mes-hall↗