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Kevin Volk

Publications and source records attributed to Kevin Volk.

At least 19 recordsLinked to original sources

Detection of CO$_2$ ice in the planetary nebula NGC 6302

Using JWST/MIRI observations, we report the detection of CO$_2$ ice in the dusty torus of the planetary nebula NGC 6302, an environment generally considered hostile to fragile molecular species and ices due to intense UV irradiation. This detection accompanies cold (20-50 K) gas-phase CO$_2$ along the same sightlines. The ice absorption profile exhibits a double-peak profile, a characteristic of pure, crystalline CO$_2$ ice. The CO$_2$ gas-to-ice ratio is more than an order of magnitude higher than in young stellar objects, pointing to distinct ice formation or processing mechanisms in evolved stellar environments. This discovery demonstrates that the dusty torus provides sufficient shielding to harbour ice chemistry, and that ice-mediated surface reactions must be incorporated into chemical models of planetary nebulae.

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Detection of CH3+ in the O-rich planetary nebula NGC 6302

Planetary nebulae are sites where ejected stellar material evolves into complex molecules, but the precise physical conditions and chemical routes that govern these processes are unclear. The presence of abundant carbon-rich molecules in O-rich environments poses particular challenges. Here we report the first detection of methyl cation (CH3+) in any planetary nebula, observed in the O-rich nebula NGC 6302 using JWST MIRI/MRS observations. CH3+ is a key driver of organic chemistry in UV-irradiated environments. Spatially resolved observations reveal that CH3+ is co-located with 12CO, H2, H II, HCO+, and Polycyclic aromatic hydrocarbons (PAHs). LTE modelling of the CH3+ emission yields excitation temperatures of 500-800K in the inner bubble and torus, rising to 1000-2000K in the outer bubble of NGC 6302, with column densities ranging from ~10^11 to 10^13 cm^-2. This detection demonstrates that hydrocarbon radical chemistry must be incorporated into planetary nebulae chemical models. Further near-IR observations are crucial to map different chemical networks operating in these environments.

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Empirical Modeling of Zodiacal Backgrounds to Improve JWST NIRISS/SOSS Data Reduction

Zodiacal light -- arising from both the thermal emission and scattered sunlight by interplanetary dust -- is the dominant component of the sky background in NIRISS Single Object Slitless Spectroscopy (SOSS) observations. The GR700XD grism disperses the zodiacal background across multiple diffraction orders, producing a characteristic two-dimensional, spectral order-dependent background pattern on the detector that reflects the combined contribution of overlapping orders. Observations reveal significant variability in background intensity driven by JWST's sky pointing and seasonal changes, underscoring the need for precise background subtraction during SOSS data reduction. Current methods rely on a generic background template derived during commissioning, scaled to match individual exposures. However, mis-scaled templates can leave behind structured residuals that may compromise the precision of exoplanet transit depth measurements. To improve background modeling, we conducted two calibration programs (PID 4479 and 6658) using the FULL frame readout mode and a 5-row by 2-column mosaic pattern to sample a range of sky positions. These observations enable empirical reconstruction of the sky background and provide detailed insights into its spatial and spectral characteristics. We present a library of empirically derived background templates and evaluate their performance, alongside the current template, by benchmarking against the PID 2113 dataset, which includes contemporaneous background exposures. This work supports aims to enhance background subtraction for SOSS time-series to achieve higher-precision exoplanet spectroscopy with JWST.

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The JWST/MIRI view of the planetary nebula NGC 6302 I.: a UV irradiated torus and a hot bubble triggering PAH formation

NGC 6302 is a spectacular bipolar planetary nebula (PN) whose spectrum exhibits fast outflows and highly ionized emission lines, indicating the presence of a very hot central star (~220,000 K). Its infrared spectrum reveals a mixed oxygen and carbon dust chemistry, displaying both silicate and polycyclic aromatic hydrocarbon (PAH) features. Using the JWST Mid-Infrared Instrument (MIRI) and Medium Resolution Spectrometer, a mosaic map was obtained over the core of NGC 6302, covering the wavelength range of 5--28 micron and spanning an area of ~18.5 arcsec x15 arcsec. The spatially resolved spectrum reveals ~200 molecular and ionized lines from species requiring ionisation potentials of up to 205 eV. The spatial distributions highlight a complex structure at the nebula's centre. Highly ionized species such as Mg VII and Si VII show compact structures, while lower-ionization species such as H^+ extend much farther outwards, forming filament-defined rims that delineate a bubble. Within the bubble, the H^+ and H_2 emission coincide, while the PAH emission appears farther out, indicating an ionization structure distinct from typical photodissociation regions, such as the Orion Bar. This may be the first identification of a PAH formation site in a PN. This PN appears to be shaped not by a steady, continuous outflow, but by a series of dynamic, impulsive bubble ejections, creating local conditions conducive to PAH formation. A dusty torus surrounds the core, primarily composed of large (micron-sized) silicate grains with crystalline components. The long-lived torus contains a substantial mass of material, which could support an equilibrium chemistry and a slow dust-formation process.

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JWST observations of the Ring Nebula (NGC 6720) -- II. PAH emission

Polycyclic aromatic hydrocarbons (PAHs) and carbonaceous dust have been observed in clumpy circumstellar environments, yet their formation and evolutionary pathways in such environments remain elusive. We aim to characterize the PAH emission in a clumpy planetary nebula to decipher their formation and evolution pathways. We obtained JWST Near-Infrared Spectrograph (NIRSpec) and Mid-Infrared Instrument (MIRI) integral field unit spectroscopic observations of two individual knots in the Ring Nebula (NGC 6720), a clumpy planetary nebula, and determine the PAH spectral characteristics. We detect the 3.3 and 11.2 um PAH emission bands in both knots but do not detect PAH emission in the 6-9 um range. We supplement our data with Spitzer Infrared Spectrograph (IRS) Short-Low 1 (SL1) and SL2 data, containing 11.2, weak 6.2, and weak 7.7 um PAH emission bands. The JWST data confirm the unusual profile of the 11.2 um band, which is very broad and redshifted with respect to typical 11.2 um PAH profiles. We estimate the PAH population to be largely neutral. The relative integrated surface brightness of the 3.3 and 11.2 um bands indicates the presence of small-sized PAHs, consisting of 35 +/- 6 carbon atoms. We find that the PAH emission is concentrated outside of the clumps, in the inter-clump medium, and confirm the existence of enhanced PAH emission in a narrow 'PAH ring' centred on the central star. This morphology suggests that PAHs formed during the Ring Nebula's asymptotic giant branch phase, in the central star's dust-driven wind.

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Effects of Jump Detection and Ramp Fitting Algorithms on NIRISS/SOSS Exoplanet Time-Series Observations

Jump detection and ramp fitting are fundamental steps when elevating JWST data products from up-the-ramp measurements to integration level count rate images. Occurring at an early stage of the overall data reduction and calibration framework, these steps, and any biases introduced by them, have the potential to significantly impact end-stage scientific measurements. Here we explore the differential impacts of jump detection and ramp fitting for the current default JWST pipeline implementation versus a newly developed, likelihood-based method, in the context of NIRISS/SOSS exoplanet time-series observations. Across both on-sky data and a suite of simulated data, we find that the two methods show differences in end product transmission spectra of order 10's to 100's parts-per-million. For the simulated data in particular, we show that the likelihood method offers a 12-18% improvement in the residual scatter and maximum deviations from the simulated ground truth. Finally, by repeating our simulations across various noise prescriptions, we corroborate the need for group-level 1/f noise corrections and re-emphasize the default implementation of such procedures as a key priority for the JWST pipeline with respect to near-infrared time-series observing modes.

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JWST observations of the Ring Nebula (NGC 6720): III. A dusty disk around its Central Star

The planetary nebula NGC 6720, also known as the ``Ring Nebula", is one of the most iconic examples of nearby planetary nebulae whose morphologies present a challenge to our theoretical understanding of the processes that govern the deaths of most stars in the Universe that evolve on a Hubble time. We present new imaging with JWST of the central star of this planetary nebula (CSPN) and its close vicinity, in the near- to mid-IR wavelength range. We find the presence of a dust cloud around the CSPN, both from the spectral energy distribution at wavelengths >~5 micron, as well as radially-extended emission in the 7.7, 10 and 11.3 micron images. From modeling of these data, we infer that the CSPN has a luminosity of 310 Lsun and is surrounded by a dust cloud with a size of ~2600 au, consisting of relatively small amorphous silicate dust grains (radius ~0.01 micron) with a total mass of 1.9 x 10^(-6) M_earth. However, our best-fit model shows a significant lack of extended emission at 7.7 micron -- we show that such emission can arise from a smaller (7.3 x 10^(-7) M_earth) but uncertain mass of (stochastically-heated) ionized PAHs. However, the same energetic radiation also rapidly destroys PAH molecules, suggesting that these are most likely being continuously replenished, via the outgassing of cometary bodies and/or the collisional grinding of planetesimals. We also find significant photometric variability of the central source that could be due to the presence of a close dwarf companion of mass < ~0.1 Msun.

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A First Look with JWST Aperture Masking Interferometry (AMI): Resolving Circumstellar Dust around the Wolf-Rayet Binary WR 137 beyond the Rayleigh Limit

We present infrared aperture masking interferometry (AMI) observations of newly formed dust from the colliding winds of the massive binary system Wolf-Rayet (WR) 137 with JWST using the Near Infrared Imager and Slitless Spectrograph (NIRISS). NIRISS AMI observations of WR 137 and a point-spread-function calibrator star, HD~228337, were taken using the F380M and F480M filters in 2022 July and August as part of the Director's Discretionary Early Release Science (DD-ERS) program 1349. Interferometric observables (squared visibilities and closure phases) from the WR 137 "interferogram" were extracted and calibrated using three independent software tools: ImPlaneIA, AMICAL, and SAMpip. The analysis of the calibrated observables yielded consistent values except for slightly discrepant closure phases measured by ImPlaneIA. Based on all three sets of calibrated observables, images were reconstructed using three independent software tools: BSMEM, IRBis, and SQUEEZE. All reconstructed image combinations generated consistent images in both F380M and F480M filters. The reconstructed images of WR 137 reveal a bright central core with a $\sim300$ mas linear filament extending to the northwest. A geometric colliding-wind model with dust production constrained to the orbital plane of the binary system and enhanced as the system approaches periapsis provided a general agreement with the interferometric observables and reconstructed images. Based on a colliding-wind dust condensation analysis, we suggest that dust formation within the orbital plane of WR 137 is induced by enhanced equatorial mass-loss from the rapidly rotating O9 companion star, whose axis of rotation is aligned with that of the orbit.

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An Algorithm to Mitigate Charge Migration Effects in Data from the Near Infrared Imager and Slitless Spectrograph on the James Webb Space Telescope

We present an algorithm that mitigates the effects of charge migration due to the "brighter-fatter effect'' (BFE) that occurs for highly illuminated stars in the Teledyne HAWAII-2RG detectors used in the NIRCam, NIRISS, and NIRSpec science instruments aboard the James Webb Space Telescope (JWST). The impact of this effect is most significant for photometry and spectrophotometry of bright stars in data for which the point spread function (PSF) is undersampled, which is the case for several observing modes of the NIRISS instrument. The main impact of the BFE to NIRISS data is incorrect count rate determinations for pixels in the central regions of PSFs of bright stars due to jump detections that are caused by charge migration from peak pixels to surrounding pixels. The effect is especially significant for bright compact sources in resampled, distortion-free images produced by the drizzle algorithm: quantitatively, apparent flux losses of $>$ 50% can occur in such images due to the BFE. We describe the algorithm of the "charge_migration'' mitigation step that has been implemented in version 10.0 of the operational JWST calibration pipeline as of Dec 5, 2023. We illustrate the impact of this step in terms of the resulting improvements of the precision of imaging photometry of point sources. The algorithm renders the effects of the BFE on photometry and surface brightness measurements to stay within 1%.

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Characterization of the visit-to-visit Stability of the GR700XD Spectral Traces for NIRISS/SOSS Observations

In this report, we present the results of our analysis of trace position changes during NIRISS/SOSS observations. We examine the visit-to-visit impact of the GR700XD pupil wheel (PW) position alignment on trace positions for spectral orders 1 and 2 using the data obtained to date. Our goal is to improve the wavelength solution by correlating the trace positions on the detector with the PW position angle. We find that there is a one-to-one correspondence between PW position and spectral trace rotation for both orders. This allowed us in turn to find an analytic model that is able to predict a trace position/shape as a function of PW position with sub-pixel accuracy of about ~0.1 pixels. Such a function can be used to predict the trace position in low signal-to-noise ratio cases, and/or as a template to track trace position changes as function of time in Time Series Observations (TSOs).

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Characterization of the visit-to-visit Stability of the GR700XD Wavelength Calibration for NIRISS/SOSS Observations

When utilizing the NIRISS/SOSS mode on JWST, the pupil wheel (tasked with orienting the GR700XD grism into the optical path) does not consistently settle into its commanded position resulting in a minor misalignment with deviations of a few fractions of a degree. These small offsets subsequently introduce noticeable changes in the trace positions of the NIRISS SOSS spectral orders between visits. This inconsistency, in turn, can lead to variations of the wavelength solution. In this report, we present the visit-to-visit characterization of the NIRISS GR700XD Wavelength Calibration for spectral orders 1 and 2. Employing data from Calibration Program 1512 (PI: Espinoza), which intentionally and randomly sampled assorted pupil wheel positions during observations of the A-star BD+60-1753, as well as data from preceding commissioning and calibration activities to model this effect, we demonstrate that the wavelength solution can fluctuate in a predictable fashion between visits by up to a few pixels. We show that via two independent polynomial regression models for spectral orders 1 and 2, respectively, using the measured x-pixel positions of known Hydrogen absorption features in the A-star spectra and pupil wheel positions as regressors, we can accurately predict the wavelength solution for a particular visit with an RMS error within a few tenths of a pixel. We incorporate these models in PASTASOSS, a Python package for predicting the GR700XD spectral traces, which now allows to accurately predict spectral trace positions and their associated wavelengths for any NIRISS/SOSS observation.

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JWST observations of the Ring Nebula (NGC 6720): I. Imaging of the rings, globules, and arcs

We present JWST images of the well-known planetary nebula NGC 6720 (the Ring Nebula), covering wavelengths from 1.6$μ$m to 25 $μ$m. The bright shell is strongly fragmented with some 20 000 dense globules, bright in H$_2$, with a characteristic diameter of 0.2 arcsec and density $n_{\rm H} \sim 10^5$-$10^6$ cm$^{-3}$. The shell contains a thin ring of polycyclic aromatic hydrocarbon (PAH) emission. H$_2$ is found throughout the shell and in the halo. H$_2$ in the halo may be located on the swept-up walls of a biconal polar flow. The central cavity is shown to be filled with high ionization gas and shows two linear structures. The central star is located 2 arcsec from the emission centroid of the cavity and shell. Linear features (`spikes') extend outward from the ring, pointing away from the central star. Hydrodynamical simulations are shown which reproduce the clumping and possibly the spikes. Around ten low-contrast, regularly spaced concentric arc-like features are present; they suggest orbital modulation by a low-mass companion with a period of about 280 yr. A previously known much wider companion is located at a projected separation of about 15 000 au; we show that it is an M2-M4 dwarf. The system is therefore a triple star. These features, including the multiplicity, are similar to those seen in the Southern Ring Nebula (NGC 3132) and may be a common aspect of such nebulae.

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Awesome SOSS: Transmission Spectroscopy of WASP-96b with NIRISS/SOSS

The future is now - after its long-awaited launch in December 2021, JWST began science operations in July 2022 and is already revolutionizing exoplanet astronomy. The Early Release Observations (ERO) program was designed to provide the first images and spectra from JWST, covering a multitude of science cases and using multiple modes of each on-board instrument. Here, we present transmission spectroscopy observations of the hot-Saturn WASP-96b with the Single Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph, observed as part of the ERO program. As the SOSS mode presents some unique data reduction challenges, we provide an in-depth walk-through of the major steps necessary for the reduction of SOSS data: including background subtraction, correction of 1/f noise, and treatment of the trace order overlap. We furthermore offer potential routes to correct for field star contamination, which can occur due to the SOSS mode's slitless nature. By comparing our extracted transmission spectrum with grids of atmosphere models, we find an atmosphere metallicity between 1x and 5x solar, and a solar carbon-to-oxygen ratio. Moreover, our models indicate that no grey cloud deck is required to fit WASP-96b's transmission spectrum, but find evidence for a slope shortward of 0.9$μ$m, which could either be caused by enhanced Rayleigh scattering or the red wing of a pressure-broadened Na feature. Our work demonstrates the unique capabilities of the SOSS mode for exoplanet transmission spectroscopy and presents a step-by-step reduction guide for this new and exciting instrument.

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The Near Infrared Imager and Slitless Spectrograph for the James Webb Space Telescope -- III. Single Object Slitless Spectroscopy

The Near Infrared Imager and Slitless Spectrograph instrument (NIRISS) is the Canadian Space Agency (CSA) contribution to the suite of four science instruments of JWST. As one of the three NIRISS observing modes, the Single Object Slitless Spectroscopy (SOSS) mode is tailor-made to undertake time-series observations of exoplanets to perform transit spectroscopy. The SOSS permits observing point sources between 0.6 and 2.8 um at a resolving power of 650 at 1.25 um using a slit-less cross-dispersing grism while its defocussing cylindrical lens enables observing targets as bright as J=6.7 by spreading light across 23 pixels along the cross-dispersion axis. This paper officially presents the design of the SOSS mode, its operation, characterization, and its performance, from ground-based testing and flight-based Commissioning. On-sky measurements demonstrate a peak photon conversion efficiency of 55% at 1.2 um. The first time-series on the A-type star BD+60o1753 achieves a flux stability close to the photon-noise limit, so far tested to a level of 20 parts per million on 40-minute time-scales after simply subtracting a long-term trend. Uncorrected 1/f noise residuals underneath the spectral traces add an extra source of noise equivalent to doubling the readout noise. Preliminary analysis of a HAT-P-14b transit time-series indicates that it is difficult to remove all the noise in pixels with partially saturated ramps. Overall, the SOSS delivers performance at the level required to tackle key exoplanet science programs such as detecting secondary atmospheres on terrestrial planets and measuring abundances of several chemical species in gas giants.

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The Near Infrared Imager and Slitless Spectrograph for the James Webb Space Telescope -- I. Instrument Overview and in-Flight Performance

The Near-Infrared Imager and Slitless Spectrograph (NIRISS) is the science module of the Canadian-built Fine Guidance Sensor (FGS) onboard the James Webb Space Telescope (JWST). NIRISS has four observing modes: 1) broadband imaging featuring seven of the eight NIRCam broadband filters, 2) wide-field slitless spectroscopy (WFSS) at a resolving power of $\sim$150 between 0.8 and 2.2 $μ$m, 3) single-object cross-dispersed slitless spectroscopy (SOSS) enabling simultaneous wavelength coverage between 0.6 and 2.8 $μ$m at R$\sim$700, a mode optimized for exoplanet spectroscopy of relatively bright ($J<6.3$) stars and 4) aperture masking interferometry (AMI) between 2.8 and 4.8 $μ$m enabling high-contrast ($\sim10^{-3}-10^{-4}$) imaging at angular separations between 70 and 400 milliarcsec for relatively bright ($M<8$) sources. This paper presents an overview of the NIRISS instrument, its design, its scientific capabilities, and a summary of in-flight performance. NIRISS shows significantly better response shortward of $\sim2.5\,μ$m resulting in 10-40% sensitivity improvement for broadband and low-resolution spectroscopy compared to pre-flight predictions. Two time-series observations performed during instrument commissioning in the SOSS mode yield very stable spectro-photometry performance within $\sim$10% of the expected noise. The first space-based companion detection of the tight binary star AB Dor AC through AMI was demonstrated.

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Water and an escaping helium tail detected in the hazy and methane-depleted atmosphere of HAT-P-18b from JWST NIRISS/SOSS

JWST is here. The early release observation program (ERO) provides us with the first look at the scientific data and the spectral capabilities. One of the targets from ERO is HAT-P-18b, an inflated Saturn-mass planet with an equilibrium temperature of $\sim$850K. We present the NIRISS/SOSS transmission spectrum of HAT-P-18b from 0.6 to 2.8$μm$ and reveal the planet in the infrared beyond 1.6$μm$ for the first time. From the spectrum, we see clear water and escaping helium tail features in an otherwise very hazy atmosphere. Our free chemistry retrievals with ATMO show moderate Bayesian evidence (3.79) supporting the presence of methane, but the spectrum does not display any clearly identifiable methane absorption features. The retrieved methane abundance is $\sim$2 orders of magnitude lower than that of solar composition. The methane-depleted atmosphere strongly rejects simple equilibrium chemistry forward models with solar metallicity and C/O ratio and disfavors high metallicity (100 times) and low C/O ratio (0.3). This calls for additional physical processes such as vertical mixing and photochemistry which can remove methane from the atmosphere.

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The Near Infrared Imager and Slitless Spectrograph for the James Webb Space Telescope -- IV. Aperture Masking Interferometry

The James Webb Space Telescope's Near Infrared Imager and Slitless Spectrograph (JWST-NIRISS) flies a 7-hole non-redundant mask (NRM), the first such interferometer in space, operating at 3-5 \micron~wavelengths, and a bright limit of $\simeq 4$ magnitudes in W2. We describe the NIRISS Aperture Masking Interferometry (AMI) mode to help potential observers understand its underlying principles, present some sample science cases, explain its operational observing strategies, indicate how AMI proposals can be developed with data simulations, and how AMI data can be analyzed. We also present key results from commissioning AMI. Since the allied Kernel Phase Imaging (KPI) technique benefits from AMI operational strategies, we also cover NIRISS KPI methods and analysis techniques, including a new user-friendly KPI pipeline. The NIRISS KPI bright limit is $\simeq 8$ W2 magnitudes. AMI (and KPI) achieve an inner working angle of $\sim 70$ mas that is well inside the $\sim 400$ mas NIRCam inner working angle for its circular occulter coronagraphs at comparable wavelengths.

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The Near Infrared Imager and Slitless Spectrograph for JWST -- V. Kernel Phase Imaging and Data Analysis

Kernel phase imaging (KPI) enables the direct detection of substellar companions and circumstellar dust close to and below the classical (Rayleigh) diffraction limit. We present a kernel phase analysis of JWST NIRISS full pupil images taken during the instrument commissioning and compare the performance to closely related NIRISS aperture masking interferometry (AMI) observations. For this purpose, we develop and make publicly available the custom "Kpi3Pipeline" enabling the extraction of kernel phase observables from JWST images. The extracted observables are saved into a new and versatile kernel phase FITS file (KPFITS) data exchange format. Furthermore, we present our new and publicly available "fouriever" toolkit which can be used to search for companions and derive detection limits from KPI, AMI, and long-baseline interferometry observations while accounting for correlated uncertainties in the model fitting process. Among the four KPI targets that were observed during NIRISS instrument commissioning, we discover a low-contrast (~1:5) close-in (~1 $λ/D$) companion candidate around CPD-66~562 and a new high-contrast (~1:170) detection separated by ~1.5 $λ/D$ from 2MASS~J062802.01-663738.0. The 5-$σ$ companion detection limits around the other two targets reach ~6.5 mag at ~200 mas and ~7 mag at ~400 mas. Comparing these limits to those obtained from the NIRISS AMI commissioning observations, we find that KPI and AMI perform similar in the same amount of observing time. Due to its 5.6 times higher throughput if compared to AMI, KPI is beneficial for observing faint targets and superior to AMI at separations >325 mas. At very small separations (<100 mas) and between ~250-325 mas, AMI slightly outperforms KPI which suffers from increased photon noise from the core and the first Airy ring of the point-spread function.

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