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Léonard Desvignes

Publications and source records attributed to Léonard Desvignes.

3 recordsLinked to original sources

Unlocking extreme doping and strain in epitaxial monocrystalline silicon

Hyperdoping, overcoming the solubility limit of dopants in a crystalline semiconductor, is a fertile method for the enhancement of the electrical, structural and optical devices' performances and for the exploration of exotic phases such as superconductivity. We demonstrate an unprecedented control on the dopant concentration and lattice deformation via nanosecond laser doping in epitaxial boron doped silicon, achieving record carrier concentrations (8 at.%) and lattice deformations (3 %). Probing the microscopical hyperdoping limitations, we show that the relevant mechanisms are caught by a simple combinatorial model, which quantitatively explains both the experimental carrier concentration and lattice deformation evolution. First principle calculations complete and support such simple model. Indeed, at the high doping levels now attainable, the maximum carrier concentration is inherently limited by the probability of two or three substitutional dopants occupying neighboring lattice sites, forming partially inactive complexes that we detail. This description is valid in the case of perfect layers with no crystallographic defects and a fully substitutional dopant occupation, highlighting the quality of the epitaxial layers realized.

cond-mat.mtrl-sci↗

Evidence of boron pairs in highly boron laser doped silicon

Secondary Ions Mass Spectroscopy and Hall effect measurements were performed on boron doped silicon with concentration between 0.02 at.% and 12 at.%. Ultra-high boron doping was made by saturating the chemisorption sites of a Si wafer with BCl3, followed by nanosecond laser anneal (Gas Immersion Laser Doping). The boron concentration varies thus nearly linearly with the number of process repetitions. However, it is not the case for the hole concentration which tends to saturate at high boron concentration. The difference between boron and hole concentration increases as the square of boron concentration, pointing towards the formation of boron pairs as the dominant contribution to the increase of inactive boron.

cond-mat.mtrl-sci↗

Tunable high speed atomic rotor in Bi$_{2}$Se$_{3}$ revealed by current noise

The ability to manipulate individual atoms and molecules using a scanning tunnelling microscope (STM) has been crucial for the development of a vast array of atomic scale devices and structures ranging from nanoscale motors and switches to quantum corrals. Molecular motors in particular have attracted considerable attention in view of their potential for assembly into complex nanoscale machines. Whereas the manipulated atoms or molecules are usually on top of a substrate, motors embedded in a lattice can be very beneficial for bottom-up construction, and may additionally be used to probe the in uence of the lattice on the electronic properties of the host material. Here, we present the discovery of controlled manipulation of a rotor in Fe doped Bi$_{2}$Se$_{3}$. We find that the current into the rotor, which can be finely tuned with the voltage, drives omni-directional switching between three equivalent orientations, each of which can be frozen in at small bias voltage. Using current fluctuation measurements at 1MHz and model simulations, we estimate that switching rates of hundreds of kHz for sub-nA currents are achieved.

cond-mat.str-el↗