arXiv subjects

L. Francis

Publications and source records attributed to L. Francis.

At least 19 recordsLinked to original sources

arXiv2026

JOYS+ analyses of OCN$^-$, N$_2$O, NO, and complex cyanides in ices -- Thermal processing results in modest enhancement of OCN$^-$ ice

Nitrogen-bearing molecules are more difficult to observe than oxygen-bearing ones, mainly due to the lower abundance of nitrogen in the interstellar medium. Therefore, the formation pathways of many of these species is still under debate. Studies prior to the launch of the JWST did not have the sensitivity to observe ices toward the youngest and most deeply embedded Class 0 objects. Here we will focus on OCN$^-$, CH$_3$CN, C$_2$H$_5$CN, NO, and N$_2$O in ices to better understand their formation. We use the data from the JOYS+ program to study 8 Class 0 and 11 Class I objects with JWST. We firmly detect OCN$^-$ in ices for all these objects, tentatively detect CH$_3$CN, C$_2$H$_5$CN, and N$_2$O toward three sources, and find upper limits on the NO abundance in ices. The OCN$^-$/CO$_2$ ratios are found to be larger by a factor of ~2-3 for the objects that have a visible CO$_2$ double peak (a sign of ice thermal processing) pointing to the moderate effect of temperature on OCN$^-$ production. Relation of H$_2$O, CO$_2$, and OCN$^-$ with $A_{\rm V}$ indicates that OCN$^-$ may tentatively form at a later stage than H$_2$O and CO$_2$. We find that the ratios of CH$_3$CN, C$_2$H$_5$CN, and N$_2$O with respect to OCN$^-$ are relatively constant within one order of magnitude across our objects, likely suggesting that they have similar ice environments. The upper limit abundances of NO are ~1 order of magnitude lower than what was previously predicted in ices of a mature protoplanetary disk. This indicates that the detected gas-phase NO in that disk may be a product of another molecule (e.g. N$_2$O) in the ices. We conclude that OCN$^-$ can get enhanced at higher temperatures by only a factor of ~2-3 and thus OCN$^-$ detection alone does not imply ice heating. Large-sample studies of OCN$^-$ toward pre-stellar cores will be useful to further confirm the formation timeline of this molecule.

astro-ph.GA↗

arXiv2026

JOYS$+$: A JWST/MIRI survey of the evolution of H$_2$ winds and jets from low-mass protostars

Protostellar outflows display wide-angle winds and collimated jets, the magnetocentrifugal launching of which enables accretion onto the protostar. The majority of the outflow mass is likely ejected or entrained molecular H$_2$, which can now be studied in unprecedented detail with JWST. Using JWST MIRI/MRS observations towards 13 single and 20 multiple Class 0 and I protostars, we investigate the nature and evolution of the H$_2$ wind and jet morphology, mass outflow rate, and velocity and temperature structure. We construct line flux and velocity maps of the H$_2$ S(1) and S(7) lines as well as the sub-mm CO traced by ALMA. Low-$J$ ($J\le4$) H$_2$ transitions trace extended wide-angle, low-velocity (0-20 km s$^{-1}$) winds within the contours of the low-velocity ($< 30$ km s$^{-1}$) sub-mm CO emission, while high-$J$ ($J >5$) transitions are associated with shocks and knots. In Class 0 sources with a known high-velocity ($> 30$ km s$^{-1}$) molecular CO or SiO jet, higher H$_2$ velocities are found along the jet axis. The opening angle of the wind traced by the H$_2$ S(1) line broadens from $\sim20^\circ$ to $\sim90^\circ$ through the Class 0 to Class I stage. Near the base of each blue-shifted outflow lobe, we extract representative spectra, where rotation diagram fitting of the H$_2$ lines is combined with the outflow width and H$_2$ line velocity to measure the mass-loss rates. The rotation diagrams show a warm $\sim 600$ K, component with two orders of magnitude more mass than the hot, 1500-3000 K component. The H$_2$ outflow mass-loss rates decline by two orders of magnitude from the Class 0 to Class II stage and are correlated with bolometric luminosity. The declining warm H$_2$ mass loss rates and increasing opening angles from the Class 0 to I stages, and the absence of H$_2$ jets in the Class I sources, are consistent with the predictions of MHD disk wind models.

astro-ph.SR↗

arXiv2026

Unlocking accretion rate diagnostics for high-mass protostars using JWST/MIRI HI lines

While many aspects of high-mass star formation have been investigated, the accretion onto the central protostars is one of the most fundamental but less explored physical properties. JWST/MIRI offers a unique opportunity to explore tracers of accretion at less-extincted wavelengths (5 to 27 um) than those studied so far. We probe the MIRI (MRS/IFU) capability to detect and resolve atomic Hydrogen (HI) emission lines in such embedded objects, to subsequently estimate accretion luminosities (Lacc) and accretion rates (Macc) for the first time in a sample of high-mass star forming regions at different evolutionary stages. We use dereddened HI line luminosities as tracers of accretion by applying existing line-to-accretion-luminosity relations (Lacc-calibrations). As they were originally established for low-mass Class II objects, we assess their applicability on our sample prior to estimating Macc. The infrared continuum reveals, at much higher spatial resolution than before, the location of new protostars, toward which we detect a handful of HI lines. While a few lines are secure detections, many are tentative. The most commonly detected line is HI 7-6, followed by HI 8-6 and HI 6-5. Assuming that their line fluxes are dominated by accretion, we find that two of the three existing Lacc-calibrations predict excessively high Lacc that largely exceed the corresponding L_bol, and that the third Lacc-calibration still overpredicts Lacc for some sources. Considering the given uncertainties, estimated accretion rates are only tentative. This work demonstrates the great potential of JWST/MIRI to probe HI line emission originated in the innermost regions of high-mass protostars, setting the ground floor for further investigations into accretion. While this project had the ambitious goal of robustly quantifying Macc, we have shed light on what outstanding methodological challenges remain.

astro-ph.SR↗

arXiv2026

JOYS: Linking the molecular ice and gas-phase composition towards the high-mass hot core IRAS 18089-1732

Context. The formation and destruction of molecules in the interstellar medium is a complex interplay between gas-phase reactions as well as processes on grain surfaces and within icy mantles. For many decades, the gas-phase composition of the cold material towards star-forming regions could be well characterized using (sub)mm facilities. Prior to the launch of the James Webb Space Telescope (JWST), ice species other than the main constituents (H2O, CO, CO2, NH3, CH4, CH3OH) were challenging to detect due to insufficient sensitivity as well as angular and/or spectral resolution. Aims. We determine molecular ice and gas-phase column densities towards the young and embedded high-mass hot core IRAS 18089-1732 within a region of 5000 au. Methods. We use spectroscopic data from 5-28 micron obtained with JWST to derive ice column densities of H2O, SO2, OCN-, CH4, HCOO-, HCOOH, CH3CHO, CH3COOH, C2H5OH, CH3OCH3, and CH3COCH3. Gas-phase column densities of a total of 38 molecules, including, O-, N-, S-, and Si-bearing species as well as less abundant isotopologues, are inferred from sensitive molecular line observations taken with the Atacama Large Millimeter/submillimeter Array (ALMA) at 3 mm wavelengths. Results. We find comparable abundances (relative to C2H5OH or CH3OH) in both phases for C2H5OH, CH3OH, and CH3OCH3. The abundances of SO2 and CH3COCH3 are higher in the gas-phase suggesting additional gas-phase formation routes. The abundance of CH3CHO is one order of magnitude higher in the ices compared to the gas-phase. The ice abundances (relative to H2O ice) towards the IRAS 18089 hot core are similar to previously studied Galactic low- and high-mass protostars. There are hints of a decreasing abundance with Galactocentric distance for OCN-, CH3OH, and CH3CHO ice. (abridged)

astro-ph.GA↗

arXiv2026

JOYS: JWST MIRI/MRS spectra of the inner 500 au region of the L1527 IRS bipolar outflow

This study characterized the physical and kinematic properties within the innermost 500 au region of the L1527 bipolar outflow, a class 0/I low-mass protostar using JWST MIRI/MRS spectroscopy across 5-28 micron at 0.2-1.0 arcsec resolution. We identified emission lines from molecular and ionized species and analyzed their spatial morphology using line-integrated intensity maps. We derived gas temperatures and column densities through excitation diagram analysis of H2 rotational lines and compared results with shock models. The observations reveal extended molecular hydrogen emission tracing the bipolar outflow, with the H2 gas temperatures distributed into warm (~550 K) and hot (~2500 K) components, likely originating from moderate-velocity J-type shocks and some UV irradiation. We detect forbidden atomic and ionized emission lines of [Ni ii], [Ar ii], [Ne ii], [Ne iii], [S i], and [Fe ii] showing spatially extended morphology. Double-peaked emission profiles were seen in [Ar ii], [Ne iii], and [Fe ii], in the eastern region, suggesting that the high velocity component traces a fast, highly ionized jet. A radial velocity map derived from [Ne ii] emission shows the eastern region to be redshifted and the western region blueshifted, contrary to earlier interpretations. The analysis of the MIRI/MRS observations reveals molecular, atomic, and ionized emission lines in this low-mass protostar connected with active outflow signatures. The most striking feature discovered is the presence of a poorly collimated high-velocity ionized jet, embedded within a broader wide-angle molecular outflow likely driven by a disk wind. The coexistence of these components supports a stratified outflow structure and suggests that L1527 exhibits unique jet-launching characteristics atypical of its early evolutionary stage.

astro-ph.SR↗

arXiv2025

UV-irradiated outflows from low-mass protostars in Ophiuchus with JWST/MIRI

The main accretion phase of protostars is characterized by the ejection of material in the form of jets/outflows. External UV irradiation can potentially have a significant impact on the excitation conditions within these outflows. High-resolution observations in the mid-infrared allow us to investigate the details of those energetic processes through the emission of shock-excited H$_2$ . Our aim is to spatially resolve H$_2$ and ionic/atomic emission within the outflows of low-mass protostars, and investigate its origin in connection to shocks influenced by external ultraviolet irradiation. We analyze spectral maps of 5 Class I protostars in the Ophiuchus molecular cloud from the James Webb Space Telescope (JWST) Medium Resolution Spectrometer (MIRI/MRS). Four out of five protostars show strong H$_2$, [\ion{Ne}{II}], and [\ion{Fe}{II}] emission associated with outflows/jets. Pure rotational H$_2$ transitions from S(1) to S(8) are found and show two distinct temperature components on Boltzmann diagrams with rotational temperatures of $\sim$500-600 K and $\sim$1000-3000 K respectively. Both $C$-type shocks propagating at high pre-shock densities (n$_\text{H} \ge$10$^4$ cm$^{-3}$) and $J$-type shocks at low pre-shock densities (n$_\text{H} \le$10$^3$ cm$^{-3}$) reproduce the observed line ratios. However, only $C$-type shocks produce sufficiently high column densities of H$_2$, whereas predictions from a single $J$-type shock reproduce the observed rotational temperatures of the gas better. A combination of various types of shocks could play a role in protostellar outflows as long as UV irradiation is included in the models. The origin of this radiation is likely internal, since no significant differences in the excitation conditions of outflows are seen at various locations in the cloud.

astro-ph.GA↗

arXiv2025

JWST Observations of Young protoStars (JOYS): overview of program and early results

The embedded phase is a crucial period in the development of a young star. Mid-IR observations, now possible with JWST with unprecedented sensitivity, spectral resolution and sharpness are key for probing many physical and chemical processes on sub-arcsecond scales. JOYS addresses a wide variety of questions, from protostellar accretion and the nature of primeval jets, winds and outflows, to the chemistry of gas and ice, and the characteristics of embedded disks. We introduce the program and show representative results. MIRI-MRS data of 17 low-mass and 6 high-mass protostars show a wide variety of features. Atomic line maps differ among refractory (e.g., Fe), semi-refractory (e.g., S) and volatile elements (e.g., Ne), linked to their different levels of depletion and local (shock) conditions. Nested, stratified jet structures consisting of an inner ionized core seen in [Fe II] with an outer H2 layer are commonly seen. Wide-angle winds are found in low-J H2 lines. [S I] follows the jet in the youngest protostars, but is concentrated on source when more evolved. [Ne II] reveals a mix of jet shock and photoionized emission. H I lines measure accretion, but are also associated with jets. Molecular emission (CO2, C2H2, HCN, H2O, ..) is cool compared with disks, and likely associated with hot cores. Deep ice absorption features reveal not just the major ice components but also ions (as part of salts) and complex organic molecules, with comparable abundances from low- to high-mass sources. A second detection of HDO ice in a solar-mass source is presented with HDO/H2O ~ 0.4%, providing a link with disks and comets. A deep search for solid O2 suggests it is not a significant oxygen reservoir. Only few embedded Class I disks show the same forest of water lines as Class II disks do, perhaps due to significant dust extinction of the upper layers [abridged].

astro-ph.GA↗

arXiv2025

Mid-infrared extinction curve for protostellar envelopes from JWST-detected embedded jet emission: the case of TMC1A

Context: Dust grains are key components of the interstellar medium and play a central role in star formation, acting as catalysts for chemical reactions and as building blocks of planets. Extinction curves are essential for characterizing dust properties, but mid-infrared (MIR) extinction remains less constrained in protostellar environments. Gas-phase line ratios from embedded protostellar jets provide a spatially resolved method for probing extinction through protostellar envelopes, complementing background starlight approaches. Aims: We aim to derive MIR extinction curves along sightlines toward a protostellar jet embedded in an envelope and assess whether they differ from those in dense molecular clouds. Methods: We analyze JWST NIRSpec IFU and MIRI MRS observations of four positions along the blue-shifted TMC1A jet. We extract observed [Fe II] line intensities and model intrinsic ratios using the Cloudy spectral synthesis code across a range of electron densities and temperatures. By comparing observed near-IR (NIR) and MIR line ratios to Cloudy predictions, we infer the relative extinction between NIR and MIR wavelengths. Results: Electron densities (ne) derived from NIR [Fe II] lines range from ~5 x 10^4 to ~5 x 10^3 cm^-3 at scales <~350 AU. MIR extinction values show stronger reddening than the empirical dark cloud curve from McClure (2009) at similar ne and temperatures (~10^3 to 10^4 K). If MIR emission arises from cooler, lower-density gas, extinction curves remain consistent with background starlight measurements. Conclusions: This method enables spatially resolved MIR extinction curves in embedded protostellar systems. Results suggest either a change in dust size distribution (e.g., from grain growth) or that MIR emission originates from cooler, less dense regions than NIR emission. (Abstract shortened for arXiv. See PDF for full version.)

astro-ph.SR↗

arXiv2025

JOYS: The [D/H] abundance derived from protostellar outflows across the Galactic disk measured with JWST

The total deuterium abundance [D/H] in the universe is set by just two processes: the creation of deuterium in Big Bang Nucleosynthesis at an abundance of [D/H]$=2.58\pm0.13\times10^{-5}$, and its destruction within stellar interiors. Measurements of the total [D/H] abundance can potentially provide a probe of Galactic chemical evolution, however, most measurements of [D/H] are only sensitive to the gas-phase deuterium, and the amount of deuterium sequestered in carbonaceous dust grains is debated. With the launch of JWST, it is now possible to measure the gas-phase [D/H] at unprecedented sensitivity and distances through observation of mid-IR lines of H$_2$ and HD. We employ data from the JWST Observations of Young protoStars (JOYS) program to measure the gas-phase [D/H] abundance with a rotation diagram analysis towards 5 nearby low-mass and 5 distant high-mass protostellar outflows. The gas-phase [D/H] varies between low-mass sources by up to a factor of $\sim4$, despite these sources likely having formed in a region of the Galactic disk that would be expected to have nearly constant total [D/H]. Most measurements of gas-phase [D/H] from our work or previous studies produce [D/H] $\lesssim 1.0\times10^{-5}$, a factor of $2-4$ lower than found from local UV absorption lines and as expected from Galactic chemical evolution models. The variations in [D/H] between our low-mass sources and the low [D/H] with respect to Galactic chemical evolution models suggest that our observations are not sensitive to the total [D/H]. Significant depletion of deuterium onto carbonaceous dust grains is a possible explanation, and tentative evidence of enhanced [D/H] towards shock positions with higher gas-phase Fe abundance is seen in the HH 211 outflow. Deeper observations of HD and H$_2$ in shocked environments and modelling of dust-grain destruction are warranted to test for the effects of depletion.

astro-ph.GA↗

arXiv2024

JWST Observations of Young protoStars (JOYS). Overview of gaseous molecular emission and absorption in low-mass protostars

The MIRI-MRS instrument onboard JWST allows for probing the molecular gas composition at mid-IR wavelengths at unprecedented resolution and sensitivity. It is important to study these features in low-mass embedded protostellar systems since the formation of planets is thought to start in this phase. We present JWST/MIRI-MRS data of 18 low-mass protostellar systems in the JOYS program, focusing on gas-phase molecular lines in spectra extracted from the central protostellar positions. Besides H2, the most commonly detected molecules are H2O, CO2, CO, and OH. Other molecules such as 13CO2, C2H2, 13CCH, HCN, C4H2, CH4, and SO2 are detected only toward at most three of the sources. The JOYS data also yield the surprising detection of SiO gas toward two sources (BHR71-IRS1, L1448-mm) and for the first time CS and NH3 at mid-IR wavelengths toward a low-mass protostar (B1-c). The temperatures derived for the majority of the molecules are 100-300 K, much lower than what is typically derived toward more evolved Class II sources (>500 K). Toward three sources (e.g., TMC1-W), hot (~1000 K) H2O is detected, indicative of the presence of hot molecular gas in the embedded disks, but such warm emission from other molecules is absent. The agreement in abundance ratios with respect to H2O between ice and gas point toward ice sublimation in a hot core for a few sources (e.g., B1-c) whereas their disagreement and velocity offsets hint at high-temperature (shocked) conditions toward other sources (e.g., L1448-mm, BHR71-IRS1). The typical temperatures of the gas-phase molecules of 100-300 K are consistent with both ice sublimation in hot cores as well as high-temperature gas phase chemistry. Molecular features originating from the inner embedded disks are not commonly detected, likely because they are too extincted even at mid-IR wavelengths by small not-settled dust grains in upper layers of the disk.

astro-ph.SR↗

arXiv2024

JOYS+ study of solid state $^{12}$C/$^{13}$C isotope ratios in protostellar envelopes: Observations of CO and CO$_2$ ice with JWST

The carbon isotope ratio is a powerful tool for studying the evolution of stellar systems. Recent detections of CO isotopologues in disks and exoplanet atmospheres pointed towards significant fractionation in these systems. In order to understand the evolution of this quantity, it is crucial to trace the isotope abundance from stellar nurseries to planetary systems. During the protostellar stage the multiple vibrational modes of CO$_2$ and CO ice provide a unique opportunity to examine the carbon isotope ratio in the solid state. Now with the sensitivity of the \textit{James Webb Space Telescope}, these absorption features have become accessible at high S/N in Solar-mass systems. We quantify the $^{12}$CO$_2$/$^{13}$CO$_2$ and the $^{12}$CO/$^{13}$CO isotope ratios in 17 class 0/I low mass protostars from the $^{12}$CO$_2$ combination modes (2.70 ${\mu}$m and 2.77 ${\mu}$m), the $^{12}$CO$_2$ stretching mode (4.27 ${\mu}$m), the $^{13}$CO$_2$ stretching mode (4.39 ${\mu}$m), the $^{12}$CO$_2$ bending mode (15.2 ${\mu}$m), the $^{12}$CO stretching mode (4.67 ${\mu}$m) and the $^{13}$CO stretching mode (4.78 ${\mu}$m) using JWST observations. We also report a detection of the $^{12}$CO overtone mode at 2.35 ${\mu}$m. The $^{12}$CO$_2$/$^{13}$CO$_2$ ratios are in agreement and we find mean ratios of 85 $\pm$ 23, 76 $\pm$ 12 and 97 $\pm$ 17 for the 2.70 ${\mu}$m, 4.27 ${\mu}$m and the 15.2 ${\mu}$m bands, respectively. The main source of uncertainty stem from the error on the band strengths. The $^{12}$CO/$^{13}$CO ratios derived from the 4.67 ${\mu}$m bands are consistent, albeit elevated with respect to the $^{12}$CO$_2$/$^{13}$CO$_2$ ratios and we find a mean ratio of 165 $\pm$ 52. These findings indicate that ices leave the pre-stellar stage with elevated carbon isotope ratios relative to the interstellar medium and that fractionation becomes significant during the later stages.

astro-ph.SR↗

arXiv2024

JWST Observations of Young protoStars (JOYS). HH 211: the textbook case of a protostellar jet and outflow

We use the James Webb Space Telescope (JWST) and its Mid-Infrared Instrument (MIRI) (5-28 um), to study the embedded HH 211 flow. We map a 0.95'x0.22' region, covering the full extent of the blue-shifted lobe, the central protostellar region, and a small portion of the red-shifted lobe. The jet driving source is not detected even at the longest mid-IR wavelengths. The overall morphology of the flow consists of a highly collimated jet, mostly molecular (H2, HD) with an inner atomic ([FeI], [FeII], [SI], [NiII]) structure. The jet shocks the ambient medium, producing several large bow-shocks, rich in forbidden atomic and molecular lines, and is driving an H2 molecular outflow, mostly traced by low-J, v=0 transitions. Moreover, 0-0 S(1) uncollimated emission is also detected down to 2"-3" (~650-1000 au) from the source, tracing a cold (T=200-400 K), less dense and poorly collimated molecular wind. The atomic jet ([FeII] at 26 um) is detected down to ~130 au from source, whereas the lack of H2 emission close to the source is likely due to the large visual extinction. Dust continuum-emission is detected at the terminal bow-shocks, and in the blue- and red-shifted jet, being likely dust lifted from the disk. The jet shows an onion-like structure, with layers of different size, velocity, temperature, and chemical composition. Moreover, moving from the inner jet to the outer bow-shocks, different physical, kinematic and excitation conditions for both molecular and atomic gas are observed. The jet mass-flux rate, momentum, and momentum flux of the warm H2 component are up to one order of magnitude higher than those inferred from the atomic jet component. Our findings indicate that the warm H2 component is the primary mover of the outflow, namely it is the most significant dynamical component of the jet, in contrast to jets from more evolved YSOs, where the atomic component is dominant.

astro-ph.SR↗

arXiv2024

JOYS+: link between ice and gas of complex organic molecules. Comparing JWST and ALMA data of two low-mass protostars

A rich inventory of complex organic molecules (COMs) has been observed in high abundances in the gas phase toward Class 0 protostars. These molecules are suggested to be formed in ices and sublimate in the warm inner envelope close to the protostar. However, only the most abundant COM, methanol (CH3OH), has been firmly detected in ices before the era of James Webb Space Telescope (JWST). Now it is possible to detect the interstellar ices of other COMs and constrain their ice column densities quantitatively. We aim to determine the column densities of several oxygen-bearing COMs (O-COMs) in both gas and ice for two low-mass protostellar sources, NGC 1333 IRAS 2A and B1-c, as case studies in our JWST Observations of Young protoStars (JOYS+) program. By comparing the column density ratios w.r.t. CH3OH between both phases measured in the same sources, we can probe into the evolution of COMs from ice to gas in the early stages of star formation. We are able to fit the fingerprints range of COM ices between 6.8 and 8.8 um in the JWST/MIRI-MRS spectra of B1-c using similar components as recently used for IRAS 2A. We claim detection of CH4, OCN-, HCOO-, HCOOH, CH3CHO, C2H5OH, CH3OCH3, CH3OCHO, and CH3COCH3 in B1-c, and upper limits are estimated for SO2, CH3COOH, and CH3CN. The comparison of O-COM ratios w.r.t CH3OH between ice and gas shows two different cases. 1) the column density ratios of CH3OCHO and CH3OCH3 match well between the two phases, which may be attributed to a direct inheritance from ice to gas or strong chemical links with CH3OH. 2) the ice ratios of CH3CHO and C2H5OH w.r.t. CH3OH are higher than the gas ratios by 1-2 orders of magnitudes. This difference can be explained by the gas-phase reprocessing following sublimation, or different spatial distributions of COMs in the envelope.

astro-ph.GA↗

arXiv2024

JOYS: MIRI/MRS spectroscopy of gas-phase molecules from the high-mass star-forming region IRAS 23385+6053

Space-based mid-IR spectroscopy provides tracers of warm gas in star-forming regions that are inaccessible from the ground. Past mid-IR spectra of bright high-mass protostars in the hot-core phase typically showed strong absorption features from molecules such as CO$_2$, C$_2$H$_2$, and HCN. However, little is known about their fainter counterparts at earlier stages. We thus aim to characterize the gas-phase molecular features in JWST MIRI/MRS observations of the young high-mass star-forming region IRAS 23385+6053. Spectra were extracted from two mid-IR sources and three H$_2$ bright outflow knots in the MIRI/MRS field of view. Rich molecular spectra with emission from CO, H$_2$, HD, H$_2$O, C$_2$H$_2$, HCN, CO$_2$, and OH are detected towards the two mid-IR sources. However, only CO and OH are seen towards the brightest H$_2$ knots, suggesting that the majority of the observed species are associated with disks or hot core regions rather than outflows. Simple Local thermodynamic equilibrium (LTE) slab models were used to fit the observed molecular features. The LTE model fits to $^{12}$CO$_{2}$, C$_{2}$H$_{2}$, and HCN emission suggest warm $120-200$ K emission arising from a disk surface around one or both protostars. Weak $\sim500$ K H$_2$O emission at $\sim$ 6-7 $\mu$m is detected towards one mid-IR source, whereas $250-1050$ K H$_2$O absorption is found in the other. The H$_2$O absorption may occur in the disk atmosphere due to strong accretion-heating of the midplane, or in a disk wind viewed at an ideal angle for absorption. CO emission may originate in the hot inner disk or outflow shocks. OH emission is likely excited in a non-LTE manner through water photodissociation or chemical formation. The observations are consistent with disks having already formed in the young IRAS 23385+6053 system, but further observations are needed to disentangle the effects of geometry and evolution.

astro-ph.GA↗

arXiv2023

JWST Observations of Young protoStars (JOYS+): Detection of icy complex organic molecules and ions. I. CH$_4$, SO$_2$, HCOO$^-$, OCN$^-$, H$_2$CO, HCOOH, CH$_3$CH$_2$OH, CH$_3$CHO, CH$_3$OCHO, CH$_3$COOH

Complex organic molecules (COMs) detected in the gas phase are thought to be mostly formed on icy grains, but no unambiguous detection of icy COMs larger than CH3OH has been reported so far. Exploring this matter in more detail has become possible with the JWST the critical 5-10 $\mu$m range. In the JOYS+ program, more than 30 protostars are being observed with the MIRI/MRS. This study explores the COMs ice signatures in the low and high-mass protostar, IRAS 2A and IRAS 23385, respectively. We fit continuum and silicate subtracted observational data with IR laboratory ice spectra. We use the ENIIGMA fitting tool to find the best fit between the lab data and the observations and to performs statistical analysis of the solutions. We report the best fits for the spectral ranges between 6.8 and 8.6 $\mu$m in IRAS 2A and IRAS 23385, originating from simple molecules, COMs, and negative ions. The strongest feature in this range (7.7 $\mu$m) is dominated by CH4 and has contributions of SO2 and OCN-. Our results indicate that the 7.2 and 7.4 $\mu$m bands are mostly dominated by HCOO-. We find statistically robust detections of COMs based on multiple bands, most notably CH3CHO, CH3CH2OH, and CH3OCHO. The likely detection of CH3COOH is also reported. The ice column density ratios between CH3CH2OH and CH3CHO of IRAS 2A and IRAS 23385, suggests that these COMs are formed on icy grains. Finally, the derived ice abundances for IRAS 2A correlate well with those in comet 67P/GC within a factor of 5. Based on the MIRI/MRS data, we conclude that COMs are present in interstellar ices, thus providing additional proof for a solid-state origin of these species in star-forming regions. The good correlation between the ice abundances in comet 67P and IRAS 2A is in line with the idea that cometary COMs can be inherited from the early protostellar phases.

astro-ph.SR↗

arXiv2023

JOYS+: mid-infrared detection of gas-phase SO$_2$ emission in a low-mass protostar. The case of NGC 1333 IRAS2A: hot core or accretion shock?

JWST/MIRI has sharpened our infrared eyes toward the star formation process. This paper presents the first mid-infrared detection of gaseous SO$_2$ emission in an embedded low-mass protostellar system. MIRI-MRS observations of the low-mass protostellar binary NGC 1333 IRAS2A are presented from the JWST Observations of Young protoStars (JOYS+) program, revealing emission from the SO$_2~ν_3$ asymmetric stretching mode at 7.35 micron. The results are compared to those derived from high-angular resolution SO$_2$ data obtained with ALMA. The SO$_2$ emission from the $ν_3$ band is predominantly located on $\sim50-100$ au scales around the main component of the binary, IRAS2A1. A rotational temperature of $92\pm8$ K is derived from the $ν_3$ lines. This is in good agreement with the rotational temperature derived from pure rotational lines in the vibrational ground state (i.e., $ν=0$) with ALMA ($104\pm5$ K). However, the emission of the $ν_3$ lines is not in LTE given that the total number of molecules predicted by a LTE model is found to be a factor $2\times10^4$ higher than what is derived for the $ν=0$ state. This difference can be explained by a vibrational temperature that is $\sim100$ K higher than the derived rotational temperature of the $ν=0$ state. The brightness temperature derived from the continuum around the $ν_3$ band of SO$_2$ is $\sim180$ K, which confirms that the $ν_3=1$ level is not collisionally populated but rather infrared pumped by scattered radiation. This is also consistent with the non-detection of the $ν_2$ bending mode at 18-20 micron. Given the rotational temperature, the extent of the emission ($\sim100$ au in radius), and the narrow line widths in the ALMA data (3.5 km/s), the SO$_2$ in IRAS2A likely originates from ice sublimation in the central hot core around the protostar rather than from an accretion shock at the disk-envelope boundary.

astro-ph.SR↗

arXiv2023

JOYS: Disentangling the warm and cold material in the high-mass IRAS 23385+6053 cluster

(abridged) We study and compare the warm (>100 K) and cold (<100 K) material toward the high-mass star-forming region IRAS 23385+6053 (IRAS 23385 hereafter) combining high angular resolution observations in the mid-infrared (MIR) with the JWST Observations of Young protoStars (JOYS) project and with the NOEMA at mm wavelengths at angular resolutions of 0.2"-1". The spatial morphology of atomic and molecular species is investigated by line integrated intensity maps. The temperature and column density of different gas components is estimated using H2 transitions (warm and hot component) and a series of CH3CN transitions as well as 3 mm continuum emission (cold component). Toward the central dense core in IRAS 23385 the material consists of relatively cold gas and dust (~50 K), while multiple outflows create heated and/or shocked H2 and show enhanced temperatures (~400 K) along the outflow structures. An energetic outflow with enhanced emission knots of [Fe II] and [Ni II] hints at J-type shocks, while two other outflows have enhanced emission of only H2 and [S I] caused by C-type shocks. The latter two outflows are also more prominent in molecular line emission at mm wavelengths (e.g., SiO, SO, H2CO, and CH3OH). Even higher angular resolution data are needed to unambiguously identify the outflow driving sources given the clustered nature of IRAS 23385. While most of the forbidden fine structure transitions are blueshifted, [Ne II] and [Ne III] peak at the source velocity toward the MIR source A/mmA2 suggesting that the emission is originating from closer to the protostar.

astro-ph.SR↗

arXiv2023

The diverse chemistry of protoplanetary disks as revealed by JWST

Early results from the JWST-MIRI guaranteed time programs on protostars (JOYS) and disks (MINDS) are presented. Thanks to the increased sensitivity, spectral and spatial resolution of the MIRI spectrometer, the chemical inventory of the planet-forming zones in disks can be investigated with unprecedented detail across stellar mass range and age. Here data are presented for five disks, four around low-mass stars and one around a very young high-mass star. The mid-infrared spectra show some similarities but also significant diversity: some sources are rich in CO2, others in H2O or C2H2. In one disk around a very low-mass star, booming C2H2 emission provides evidence for a ``soot'' line at which carbon grains are eroded and sublimated, leading to a rich hydrocarbon chemistry in which even di-acetylene (C4H2) and benzene (C6H6) are detected (Tabone et al. 2023). Together, the data point to an active inner disk gas-phase chemistry that is closely linked to the physical structure (temperature, snowlines, presence of cavities and dust traps) of the entire disk and which may result in varying CO2/H2O abundances and high C/O ratios >1 in some cases. Ultimately, this diversity in disk chemistry will also be reflected in the diversity of the chemical composition of exoplanets.

astro-ph.GA↗