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Lee C. Bassett

Publications and source records attributed to Lee C. Bassett.

34 records · Page 2Linked to original sources

Network structure and dynamics of effective models of non-equilibrium quantum transport

Across all scales of the physical world, dynamical systems can often be usefully represented as abstract networks that encode the system's units and inter-unit interactions. Understanding how physical rules shape the topological structure of those networks can clarify a system's function and enhance our ability to design, guide, or control its behavior. In the emerging area of quantum network science, a key challenge lies in distinguishing between the topological properties that reflect a system's underlying physics and those that reflect the assumptions of the employed conceptual model. To elucidate and address this challenge, we study networks that represent non-equilibrium quantum-electronic transport through quantum antidot devices -- an example of an open, mesoscopic quantum system. The network representations correspond to two different models of internal antidot states: a single-particle, non-interacting model and an effective model for collective excitations including Coulomb interactions. In these networks, nodes represent accessible energy states and edges represent allowed transitions. We find that both models reflect spin conservation rules in the network topology through bipartiteness and the presence of only even-length cycles. The models diverge, however, in the minimum length of cycle basis elements, in a manner that depends on whether electrons are considered to be distinguishable. Furthermore, the two models reflect spin-conserving relaxation effects differently, as evident in both the degree distribution and the cycle-basis length distribution. Collectively, these observations serve to elucidate the relationship between network structure and physical constraints in quantum-mechanical models. More generally, our approach underscores the utility of network science in understanding the dynamics and control of quantum systems.

cond-mat.mes-hall↗

Probing Electron-Electron Interactions with a Quantum Antidot

In the integer quantum Hall (IQH) regime, an antidot provides a finite, controllable `edge' of quantum Hall fluid that is an ideal laboratory for investigating the collective dynamics of large numbers of interacting electrons. Transport measurements of single antidots probe the excitation spectra of the antidot edge, and gate-defined antidot devices offer the flexibility to vary both the antidot's dimensions and its couplings to extended IQH edge modes which serve as leads. We also use the spin-selectivity of the IQH edge modes to perform spin-resolved transport measurements, from which we can infer the antidot spin-structure. This thesis describes a combination of such transport experiments and related computational models designed to investigate the effects of electron-electron interactions in quantum antidots, with general implications for the physics of spin and charge in IQH systems.

cond-mat.mes-hall↗

Efficient Optical Quantification of Heterogeneous Emitter Ensembles

Defect-based quantum emitters in solid state materials offer a promising platform for quantum communication and sensing. Confocal fluorescence microscopy techniques have revealed quantum emitters in a multitude of host materials. In some materials, however, optical properties vary widely between emitters, even within the same sample. In these cases, traditional ensemble fluorescence measurements are confounded by heterogeneity, whereas individual defect-by-defect studies are impractical. Here, we develop a method to quantitatively and systematically analyze the properties of heterogeneous emitter ensembles using large-area photoluminescence maps. We apply this method to study the effects of sample treatments on emitters in hexagonal boron nitride, and we find that low-energy (3 keV) electron irradiation creates emitters, whereas high-temperature (850 $^\circ$C) annealing in an inert gas environment brightens emitters.

cond-mat.mtrl-sci↗

Quantum optics with single spins

Defects in solids are in many ways analogous to trapped atoms or molecules. They can serve as long-lived quantum memories and efficient light-matter interfaces. As such, they are leading building blocks for long-distance quantum networks and distributed quantum computers. This chapter describes the quantum-mechanical coupling between atom-like spin states and light, using the diamond nitrogen-vacancy (NV) center as a paradigm. We present an overview of the NV center's electronic structure, derive a general picture of coherent light-matter interactions, and describe several methods that can be used to achieve all-optical initialization, quantum-coherent control, and readout of solid-state spins. These techniques can be readily generalized to other defect systems, and they serve as the basis for advanced protocols at the heart of many emerging quantum technologies.

quant-ph↗

Real-Time Charge Initialization of Diamond Nitrogen-Vacancy Centers for Enhanced Spin Readout

A common impediment to qubit performance is imperfect state initialization. In the case of the diamond nitrogen-vacancy (NV) center, the initialization fidelity is limited by fluctuations in the defect's charge state during optical pumping. Here, we use real-time control to deterministically initialize the NV center's charge state at room temperature. We demonstrate a maximum charge initialization fidelity of 99.4$\pm$0.1% and present a quantitative model of the initialization process that allows for systems-level optimization of the spin-readout signal-to-noise ratio. Even accounting for the overhead associated with the initialization sequence, increasing the charge initialization fidelity from the steady-state value of 75% near to unity allows for a factor-of-two speedup in experiments while maintaining the same signal-to-noise-ratio. In combination with high-fidelity readout based on spin-to-charge conversion, real-time initialization enables a factor-of-20 speedup over traditional methods, resulting in an ac magnetic sensitivity of 1.3 nT/Hz$^{1/2}$ for our single NV-center spin. The real-time control method is immediately beneficial for quantum sensing applications with NV centers as well as probing charge-dependent physics, and it will facilitate protocols for quantum feedback control over multi-qubit systems.

quant-ph↗

Network architecture of energy landscapes in mesoscopic quantum systems

Mesoscopic quantum systems exhibit complex many-body quantum phenomena, where interactions between spins and charges give rise to collective modes and topological states. Even simple, non-interacting theories display a rich landscape of energy states --- distinct many-particle configurations connected by spin- and energy-dependent transition rates. The collective energy landscape is difficult to characterize or predict, especially in regimes of frustration where many-body effects create a multiply degenerate landscape. Here we use network science to characterize the complex interconnection patterns of these energy-state transitions. Using an experimentally verified computational model of electronic transport through quantum antidots, we construct networks where nodes represent accessible energy states and edges represent allowed transitions. We then explore how physical changes in currents and voltages are reflected in the network topology. We find that the networks exhibit Rentian scaling, which is characteristic of efficient transportation systems in computer circuitry, neural circuitry, and human mobility, and can be used to measure the interconnection complexity of a network. Remarkably, networks corresponding to points of frustration in quantum transport (due, for example, to spin-blockade effects) exhibit an enhanced topological complexity relative to networks not experiencing frustration. Our results demonstrate that network characterizations of the abstract topological structure of energy landscapes can capture salient properties of quantum transport. More broadly, our approach motivates future efforts to use network science in understanding the dynamics and control of complex quantum systems.

cond-mat.mes-hall↗

Spin Readout Techniques of the Nitrogen-Vacancy Center in Diamond

The diamond nitrogen-vacancy (NV) center is a leading platform for quantum information science due to its optical addressability and room-temperature spin coherence. However, measurements of the NV center's spin state typically require averaging over many cycles to overcome noise. Here, we review several approaches to improve the readout performance and highlight future avenues of research that could enable single-shot electron-spin readout at room temperature.

quant-ph↗

Spin-Dependent Quantum Emission in Hexagonal Boron Nitride at Room Temperature

Optically addressable spins associated with defects in wide-bandgap semiconductors are versatile platforms for quantum information processing and nanoscale sensing, where spin-dependent inter-system crossing (ISC) transitions facilitate optical spin initialization and readout. Recently, the van der Waals material hexagonal boron nitride (h-BN) has emerged as a robust host for quantum emitters (QEs), but spin-related effects have yet to be observed. Here, we report room-temperature observations of strongly anisotropic photoluminescence (PL) patterns as a function of applied magnetic field for select QEs in h-BN. Field-dependent variations in the steady-state PL and photon emission statistics are consistent with an electronic model featuring a spin-dependent ISC between triplet and singlet manifolds, indicating that optically-addressable spin defects are present in h-BN $-$ a versatile two-dimensional material promising efficient photon extraction, atom-scale engineering, and the realization of spin-based quantum technologies using van der Waals heterostructures.

quant-ph↗

Fabrication of (111)-Faced Single-Crystal Diamond Plates by Laser Nucleated Cleaving

Single-crystal diamond plates with surfaces oriented in a (111) crystal plane are required for high-performance solid-state device platforms ranging from power electronics to quantum information processing architectures. However, producing plates with this orientation has proven challenging. In this paper, we demonstrate a method for reliably and precisely fabricating (111)-faced plates from commercially available, chemical-vapor-deposition-grown, type-IIa single-crystal diamond substrates with (100) faces. Our method uses a nanosecond-pulsed visible laser to nucleate and propagate a mechanical cleave in a chosen (111) crystal plane, resulting in faces as large as 3.0 mm$\times$0.3 mm with atomically flat surfaces, negligible miscut angles, and near zero kerf loss. We discuss the underlying physical mechanisms of the process along with potential improvements that will enable the production of millimeter-scale (111)-faced single-crystal diamond plates for a variety of emerging devices and applications.

cond-mat.mtrl-sci↗

Imaging a Nitrogen-Vacancy Center with a Diamond Immersion Metalens

Solid-state quantum emitters have emerged as robust single-photon sources and addressable spins: key components in rapidly developing quantum technologies for broadband magnetometry, biological sensing, and quantum information science. Performance in these applications, be it magnetometer sensitivity or quantum key generation rate, is limited by the number of photons detected. However, efficient collection of a quantum emitter's photoluminescence (PL) is challenging as its atomic scale necessitates diffraction-limited imaging with nanometer-precision alignment, oftentimes at cryogenic temperatures. In this letter, we image an individual quantum emitter, an isolated nitrogen-vacancy (NV) center in diamond, using a dielectric metalens composed of subwavelength pillars etched into the diamond's surface. The metalens eliminates the need for an objective by operating as a high-transmission-efficiency immersion lens with a numerical aperture (NA) greater than 1.0. This design provides a scalable approach for fiber coupling solid-state quantum emitters that will enable the development of deployable quantum devices.

physics.optics↗

Amplified Sensitivity of Nitrogen-Vacancy Spins in Nanodiamonds using All-Optical Charge Readout

Nanodiamonds containing nitrogen-vacancy (NV) centers offer a versatile platform for sensing applications spanning from nanomagnetism to in-vivo monitoring of cellular processes. In many cases, however, weak optical signals and poor contrast demand long acquisition times that prevent the measurement of environmental dynamics. Here, we demonstrate the ability to perform fast, high-contrast optical measurements of charge distributions in ensembles of NV centers in nanodiamonds and use the technique to improve the spin readout signal-to-noise ratio through spin-to-charge conversion. A study of 38 nanodiamonds, each hosting 10-15 NV centers with an average diameter of 40 nm, uncovers complex, multiple-timescale dynamics due to radiative and non-radiative ionization and recombination processes. Nonetheless, the nanodiamonds universally exhibit charge-dependent photoluminescence contrasts and the potential for enhanced spin readout using spin-to-charge conversion. We use the technique to speed up a $T_1$ relaxometry measurement by a factor of five.

quant-ph↗

Optical Signatures of Quantum Emitters in Suspended Hexagonal Boron Nitride

Hexagonal boron nitride (h-BN) is a tantalizing material for solid-state quantum engineering. Analogously to three-dimensional wide-bandgap semiconductors like diamond, h-BN hosts isolated defects exhibiting visible fluorescence, and the ability to position such quantum emitters within a two-dimensional material promises breakthrough advances in quantum sensing, photonics, and other quantum technologies. Critical to such applications, however, is an understanding of the physics underlying h-BN's quantum emission. We report the creation and characterization of visible single-photon sources in suspended, single-crystal, h-BN films. The emitters are bright and stable over timescales of several months in ambient conditions. With substrate interactions eliminated, we study the spectral, temporal, and spatial characteristics of the defects' optical emission, which offer several clues about their electronic and chemical structure. Analysis of the defects' spectra reveals similarities in vibronic coupling despite widely-varying fluorescence wavelengths, and a statistical analysis of their polarized emission patterns indicates a correlation between the optical dipole orientations of some defects and the primitive crystallographic axes of the single-crystal h-BN film. These measurements constrain possible defect models, and, moreover, suggest that several classes of emitters can exist simultaneously in free-standing h-BN, whether they be different defects, different charge states of the same defect, or the result of strong local perturbations.

cond-mat.mes-hall↗

Near-Infrared-Assisted Charge Control and Spin Readout of the Nitrogen-Vacancy Center in Diamond

We utilize nonlinear absorption to design all-optical protocols that improve both charge state initialization and spin readout for the nitrogen-vacancy (NV) center in diamond. Non-monotonic variations in the equilibrium charge state as a function of visible and near-infrared (NIR) optical power are attributed to competing multiphoton absorption processes. In certain regimes, multicolor illumination enhances the steady-state population of the NV's negative charge state above 90%. At higher NIR intensities, selective ionization of the singlet manifold facilitates a protocol for spin-to-charge conversion that dramatically enhances the spin readout fidelity. We demonstrate a 6-fold increase in the signal-to-noise ratio for single-shot spin measurements and predict an orders-of-magnitude experimental speedup over traditional methods for emerging applications in magnetometry and quantum information science using NV spins.

quant-ph↗

Single-Mode Optical Waveguides on Native High-Refractive-Index Substrates

High-refractive-index semiconductor optical waveguides form the basis for modern photonic integrated circuits (PICs) , but the conventional methods of achieving optical confinement require a thick lower-refractive-index support layer that impedes large-scale co-integration with electronics. To address this challenge, we present a general architecture for single-mode waveguides that confine light in a high-refractive-index material on a native substrate. Our waveguide consists of a high-aspect-ratio fin of the guiding material surrounded by lower-refractive-index dielectrics and is compatible with standard top-down fabrication techniques. The proposed waveguide geometry removes the need for a buried-oxide-layer in silicon photonics, as well as the InGaAsP layer in InP-based PICs and will allow for photonic integration on emerging material platforms such as diamond and SiC.

physics.optics↗

All-optical control of a solid-state spin using coherent dark states

The study of individual quantum systems in solids, for use as quantum bits (qubits) and probes of decoherence, requires protocols for their initialization, unitary manipulation, and readout. In many solid-state quantum systems, these operations rely on disparate techniques that can vary widely depending on the particular qubit structure. One such qubit, the nitrogen-vacancy (NV) center spin in diamond, can be initialized and read out through its special spin selective intersystem crossing, while microwave electron spin resonance (ESR) techniques provide unitary spin rotations. Instead, we demonstrate an alternative, fully optical approach to these control protocols in an NV center that does not rely on its intersystem crossing. By tuning an NV center to an excited-state spin anticrossing at cryogenic temperatures, we use coherent population trapping and stimulated Raman techniques to realize initialization, readout, and unitary manipulation of a single spin. Each of these techniques can be directly performed along any arbitrarily-chosen quantum basis, removing the need for extra control steps to map the spin to and from a preferred basis. Combining these protocols, we perform measurements of the NV center's spin coherence, a demonstration of this full optical control. Consisting solely of optical pulses, these techniques enable control within a smaller footprint and within photonic networks. Likewise, this approach obviates the need for both ESR manipulation and spin addressability through the intersystem crossing. This method could therefore be applied to a wide range of potential solid-state qubits, including those which currently lack a means to be addressed.

quant-ph↗

Engineering shallow spins in diamond with nitrogen delta-doping

We demonstrate nanometer-precision depth control of nitrogen-vacancy (NV) center creation near the surface of synthetic diamond using an in situ nitrogen delta-doping technique during plasma-enhanced chemical vapor deposition. Despite their proximity to the surface, doped NV centers with depths (d) ranging from 5 - 100 nm display long spin coherence times, T2 > 100 \mus at d = 5 nm and T2 > 600 \mus at d \geq 50 nm. The consistently long spin coherence observed in such shallow NV centers enables applications such as atomic-scale external spin sensing and hybrid quantum architectures.

cond-mat.mtrl-sci↗