arXiv subjects

Linda Podio

Publications and source records attributed to Linda Podio.

At least 19 recordsLinked to original sources

arXiv2026

Dust Seeding Molecules in a Massive Protostar -- Detection of TiO in Orion Source I

We report the first detection of TiO in star-forming regions based on Atacama Large Millimeter/submillimeter Array observations of Orion Source I, a well-characterized massive protostar. Multiple rotational transitions are identified, with emission spatially resolved within $\sim 50$ au, showing a compact distribution with a velocity structure consistent with the base of a rotating outflow. The spatial and velocity distributions of TiO are consistent with those of AlO, with both species being key dust seeding refractory molecules. \textbf{The column density of TiO is derived to be $(3.0 \pm 0.4)\times10^{15}\ {\rm cm^{-2}}$, corresponding to $X_{\rm TiO/SiO} \sim 12.8 \pm 1.7 \times10^{-3}$, higher than CI chondrites and indicative of efficient dust-to-gas conversion near the protostar.} We also identify a tentative detection of AlOH, which exhibits a more extended distribution along the disk surface, possibly indicating different conditions from those traced by TiO and AlO. The detection of TiO, a key dust seeding species, offers important constraints on refractory chemistry and the formation environments of primitive minerals, linking astrochemical processes in protostellar systems to the earliest stages of Solar System material formation.

astro-ph.GA↗

arXiv2026

A JWST, ALMA and VLA survey of the Ophiuchus-A star-forming region: Unveiling hidden dust mass and connecting infrared outflows to their radio origins

We present an infrared, millimetre, and radio survey of 20 Class 0-III young stellar objects in the Ophiuchus A L1688 star-forming cluster, combining high-resolution (7-25 au) VLA and JWST observations with archival ALMA data. We implement physically motivated models to derive dust and ionised gas properties, spectral behaviour and their relative contributions through the millimetre-centimetre radio spectral energy distribution. Our models reveal circumstellar dust disks that are, on average, tens to hundreds of times more massive than millimetre-only estimates (subject to uncertainties arising from the choice of dust opacity) and contain millimetre-sized grains even at the Class 0 stage. Owing to the VLA's high resolution we are able to connect outflows to their origins, detecting protostellar jet emission on scales of 10s-1000s au. Our results represent a homogeneous characterisation of the dust and ionised gas properties in Ophiuchus and present a potential solution to the long-standing 'missing disk mass' problem. However, our understanding is still limited by resolution and sensitivity at frequencies <40 GHz. Future facilities like the SKA and ngVLA are needed to provide the necessary capabilities to fully spatially resolve this emission (<0.18") even in one of the closest star-forming regions.

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arXiv2026

Ionized gas emission in protoplanetary disks with the SKAO

Protoplanetary disks represent a crucial stage in the evolution of Young Stellar Objects towards the formation of fully formed planetary systems. While substantial progress has been made in the last decades in the characterization of the dust and molecular gas in these systems, the ionized component remains poorly understood. Ionized gas traces important processes such as photoevaporation, accretion, disk winds, and jets, and therefore is key to studying disk dynamics, evolution, and ultimately planet formation. In this paper, we investigate the capabilities of the forthcoming SKA telescope to probe this component in protoplanetary disks within nearby star forming regions. We present state-of-the-art simulations of photoevaporative, magneto-thermal, and magnetohydrodynamic winds, and generate theoretical predictions and synthetic SKAO observations to assess its potential in detecting and characterizing free-free emission and Hydrogen recombination lines. Finally, we discuss synergies with complementary facilities and how they will provide a comprehensive, multi-scale view of disk winds and offer critical insights on the mechanisms driving disk evolution and the onset of planet formation.

astro-ph.SR↗

arXiv2026

SHARPing accretion and outflows in young stellar objects in star forming regions of the outer Galaxy and beyond

As part of the science book of SHARP, we present here the science case of star-disk interaction of low-mass (\Mstar$\leq$2\Msun) young stellar objects (YSOs), in low-metallicity (Z$<$ 0.2 \Zsun) star forming regions (SFRs) and supermassive star clusters, using the SHARP instrument mounted on the ESO-ELT. Extreme adaptive optics (AOs), with a spatial resolution a factor $\sim$3 better than JWST, as well as sensitive multiplexing capabilities, uniquely offered by SHARP, are essential to efficiently survey the whole area of low-Z SFRs and massive clusters in the outer Milky Way (MW) Galaxy and in the Magellanic Clouds (MCs). Using the SHARP exposure time calculator (ETC) we demonstrate that SHARP can achieve the required signal-to-noise, both for the continuum and emission lines, to investigate accretion and outflows in YSOs in distant (d$>$5\,kpc) SFRs, including those relatively embedded. SHARP will be able to observe very faint YSOs ($H\sim$\,24\,mag), allowing us extending studies to very low-mass YSOs in distant SFRs. The performance of SHARP in terms of sensitivity and spatial resolution in the NIR will provide significant insights into the evolution of protoplanetary disks in low-metallicity and massive environments: studies of accretion, jets/winds and photo-evaporation processes, down to the very low-mass ($\sim$0.2\,\Msun) regime in the MCs, and down to substellar YSOs in SFRs of the outer MW Galaxy (d\,$\lesssim$\,10\,kpc), will be possible. SHARP will also be able to observe jets/outflows in targets that are several magnitudes fainter than those reachable with current instruments, and will facilitate studies in low metallicity environments of wide binaries and multiple systems, with separations of $\sim$1600\,au, at a distance $\sim$50\,kpc scale, and of $\sim$150\,au, in regions of the outer MW Galaxy (d $\sim$10\,kpc).

astro-ph.IM↗

arXiv2026

Demographics of planet-forming disks with the SKAO

Understanding how solid material in planet-forming disks evolves from micron-sized dust to planetary cores is a central challenge in modern astrophysics. This study has advanced dramatically in the past decade, largely driven by ALMA and high-contrast imaging facilities. However, major uncertainties remain regarding the presence, evolution, and role of centimeter-sized grains (the pebbles) in planet formation. The SKAO will fill this gap by enabling the first large-scale, high-resolution survey of disk emission at centimeter wavelengths. This chapter presents the scientific rationale and observational strategies to detect and characterize pebbles in the planet-forming disks of nearby star-forming regions. By resolving their spatial distribution, spectral properties, and evolutionary trends, SKA will offer essential constraints on dust growth and disk dynamics. This work provides observational strategies, target selection, and predictions on the detectability of hundreds of nearby disks. The chapter also explores SKA's potential to uncover the actual dust mass in disks, protoplanets and their circumplanetary disks, and other aspects of the planet formation. Together, these capabilities will establish SKAO as a cornerstone facility for planet formation science in the coming decade.

astro-ph.EP↗

arXiv2026

Chemical Complexity in the Early Stages of Star Formation in the SKAO Era

About 350 molecules have been identified in the interstellar medium (ISM), including complex molecules relevant to prebiotic chemistry. A remarkable level of molecular diversity has been observed from the earliest stages of star formation, providing the initial chemical inventory inherited by planetary systems. Radio observations have played a pivotal role in these discoveries, starting with the identification of the first polyatomic molecule, $\text{NH}_3$ (Cheung et al. 1968). (Sub-)millimeter observations have revealed complex organic molecules of prebiotic relevance, including formamide ($\text{NH}_2\text{CHO}$), glycolaldehyde ($\text{CH}_2\text{OHCHO}$), and even urea ($(\text{NH}_2)_2\text{CO}$), and hydroxylamine ($\text{NH}_2\text{OH}$), which are possible precursors of RNA nucleotides (Ceccarelli et al. 2023; Jim\'enez-Serra et al. 2020). However, in dense protostellar regions, dust opacity hampers the detection of molecular emission. Additionally, large molecules and those containing heavy atoms, which have rotational transitions at lower frequencies, often remain inaccessible to current instruments. The Square Kilometre Array Observatory (SKAO) will provide an unprecedented combination of sensitivity and angular resolution at radio wavelengths. This will allow for the detection of prebiotic species and offer new insights into the chemical pathways that shape emerging planetary systems (Jim\'enez-Serra et al. 2022). This chapter details the scientific questions and advancements that the SKAO, and more specifically, SKA-Mid equipped with the Band 5 receivers, will pursue in the field of astrochemistry, focusing on the chemical complexity in both high-mass and solar-type star-forming regions.

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arXiv2026

Unveiling Complex Chemistry in Planet-forming Disks with the SKAO

The chemical composition of planets is inherited from that of the natal protoplanetary disk at the time of planet formation. In recent years, we have made huge progress in characterizing disk chemistry. (Sub-)millimeter interferometers, such as ALMA, allowed us to detect emission lines from simple to complex organic molecules and to probe their radial and vertical distribution in disks. On the other hand, JWST has started to unveil the composition of disk ices, and line emission from the innermost disk regions. The advent of SKA will open new domains in the field, by observing emission lines from heavier molecules including heavy carbon chains and rings, and prebiotic molecules with peak emission in the cm range. Moreover, SKA will probe molecular emission from regions which are obscured by dust opacity at mm wavelengths, hence from the disk midplane, and often from the inner 30 au region. These observations will constrain the initial conditions for disk evolution and planet formation, allowing us to predict the chemical composition of the forming planets and their atmospheres. Comparison with forthcoming results on exoplanet atmospheres and on the chemistry of pristine bodies in the Solar System will provide new hints on the origin and evolution of planetary systems including our own.

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arXiv2026

Substructures in Planet-Forming Disks with the SKAO

Disks of gas and dust orbiting young stars are the arenas and material reservoirs for planet formation. Over the past decade, multiwavelength observations, from infrared to radio, have resolved the spatial distribution of hundreds of protoplanetary disks in nearby star-forming regions, revealing a diverse zoo of substructures. These substructures are morphological features such as rings, gaps, spirals, vortices, asymmetries, warps, or clumps that trace variations in density, temperature, or composition relative to an otherwise smooth distribution of gas and dust. Many unknowns persist as to the origin of these substructures, their role in planet assembly, and their true properties. SKA-Mid Band 5b continuum observations, offering angular resolutions of $\sim 0.05''$ ($\sim 0.15''$) with AA4 (AA*) at $12.5$ GHz / $2.4$ cm, will enable new progress at this frontier. In this chapter, we outline the open questions in the field of disk substructure that SKA-Mid is uniquely poised to address, with a lens on dust thermal emission.

astro-ph.EP↗

arXiv2026

Jets and Outflows in Young Stellar Objects with the SKAO

Jets and outflows are ubiquitous phenomena associated with the formation of young stellar objects (YSOs). They play a crucial role in removing angular momentum from the accreting system and in regulating star-formation efficiency. Theoretical studies and observations with ALMA and VLA have shown that jets and winds may have a crucial role in promoting dust growth in the envelope-disc system and in shaping the physical and chemical properties of the surrounding environment. Despite these significant advances, many fundamental questions remain unanswered regarding the acceleration, collimation, and chemical impact of jets and outflows from YSOs. The SKA-project will overcome the limitations of current mm/cm-facilities by enabling high-angular resolution and high-sensitivity cm-observations, crucial for probing jets/outflows near YSOs. Radio recombination lines, combined with proper motions, offer a unique opportunity to study the 3D-kinematics of jets. Non-thermal linearly polarised synchrotron emission will allow measuring magnetic field strength and morphology at unprecedented scales of a few au. Observations of dust emission in outflow cavities will allow studying how dust grows and is eventually transported from the disc to the envelope and back. Finally, the SKA-project will allow exploring the dust composition and chemical enrichment in shocks, where sputtering/shattering of grains cause the release of their mantles and refractory cores in the gas-phase. Complementary to ALMA's detection of simple and complex organic molecules, the SKAO will probe, for the first time, long carbon chains/rings, several Cl-, Al-, Mg-, and other metal-bearing species (missed by current sub-mm facilities).

astro-ph.GA↗

arXiv2026

Carbon chain diversity in L1544 and IRAS 16293-2422: an astrochemical pathfinder study for the SKAO

Astrochemical observations have revealed a surprisingly high level of chemical complexity, including long carbon chains, in the earliest stages of Sun-like star formation. The origin of these species and whether they undergo further growth, possibly contributing to the molecular complexity of planetary systems, remain open questions. We present recent observations performed using the 100-m Green Bank Telescope of the prestellar core L1544 and the protostellar system IRAS 16293-2422. In L1544, we detected several complex carbon-bearing species, including $\mathrm{C_2S}$, $\mathrm{C_3S}$, $\mathrm{C_3N}$, $\mathrm{c\text{-}C_3H}$, $\mathrm{C_4H}$, and $\mathrm{C_6H}$, complementing previously reported emission of cyanopolyynes. In IRAS 16293-2422, we detected $\mathrm{c\text{-}C_3H}$ and, for the first time, $\mathrm{HC_7N}$. Thanks to the high spectral resolution, we refine the rest frequencies of several $\mathrm{c\text{-}C_3H}$ and $\mathrm{C_6H}$ transitions. We perform radiative transfer analysis, highlighting a chemical difference between the two sources: IRAS 16293-2422 shows column densities 10-100 times lower than L1544. We perform astrochemical modeling, employing an up-to-date chemical network with revised reaction rates. The models reproduce the general trends, with cyanopolyyne and polyynyl radical abundances decreasing as molecular size increases, but they underestimate the abundances of cyanopolyynes longer than $\mathrm{HC_5N}$ by up to two orders of magnitude. Current models, which include the dominant neutral-neutral formation routes, cannot account for this discrepancy, suggesting that the chemical network is incomplete. We propose that additional ion-molecule reactions are crucial for the formation of these species. Developing a more comprehensive chemical network for long carbon chains is essential for accurately interpreting present and future observations.

astro-ph.GA↗

arXiv2025

FAUST XXX: Dust enhancement in the young binary L1551 IRS 5

Young binary stars with discs provide unique laboratories to study the earliest stages of planet formation in star-forming environments. The detection of substructure in discs around Class I protostars challenges current models of disc evolution, suggesting that planets may form earlier than previously expected ($<1$ Myr). In the context of the ALMA Large Program FAUST, we present observations of the circumbinary disc (CBD) around the young binary system L1551 IRS 5. The CBD exhibits two prominent over-densities in the continuum emission at the edge of the cavity, with the Northern over-density being about 20% brighter than the Southern one. By analysing the disc morphology and kinematics of L1551 IRS 5, we delineate dynamical constraints on the binary's orbital parameters. Additionally, we present 3D hydrodynamical models of the CBD to predict both the dust and the gas surface densities. Then, we compare the resulting synthetic observations with ALMA observations of the continuum emission at 1.3 mm and the C$^{18}$O line emission. Our analysis suggests that the density enhancements observed with ALMA in L1551 IRS 5 can be caused by interactions between the binary stars and the CBD, leading to dust concentration within the disc. We conclude that the observed over-density corresponds to a location where could potentially grow under favourable conditions.

astro-ph.SR↗

arXiv2025

FAUST XXIX. OCS line emission: a new method for measuring the luminosity of embedded protostars in binary systems

The luminosity of embedded protostars is commonly measured via observations of the dust continuum spectral energy distribution from millimetre to infrared wavelengths. However, this method cannot be applied to embedded protostars in binary or multiple systems, where their components are usually unresolved over this extended wavelength range. We propose a new method, based on the idea that a molecule formed (mainly) on the grain surfaces only emits lines in the region where it thermally sublimates from the grain mantles, heated by the photons emitted by the embedded source. In this respect, carbonyl sulfide (OCS) is an optimal molecule, because of its low binding energy and rotational lines in the millimetre. We apply the method to the protobinary system NGC1333 IRAS4A, using ALMA high-spatial resolution ($\sim$50 au) observations of the OCS(19-18) line as part of the ALMA Large Program FAUST. We also present new quantum mechanics calculations of the OCS binding energy distribution, essential for the application of the method. We found that the two binary components, A1 and A2, have a comparable luminosity within the error bars, 7.5$\pm$2.5 and 7$\pm$1 L$_\odot$, respectively. We discuss the reliability of the estimated luminosities and the potential of this new method for measuring the luminosity of embedded protostars in binary and multiple systems.

astro-ph.SR↗

arXiv2025

PROJECT-J: the shocking H2 outflow from HH46

We analyze the H2 emission observed in the HH46 Class I system as part of PROJECT-J (Protostellar Jets Cradle Tested with JWST), to investigate the origin and excitation of the warm molecular outflow. We used NIRSpec and MIRI spectral maps (1.6-27.9 microns) to trace the structure and physical conditions of the outflow. By fitting the H2 rotational diagrams with a multi-temperature gas model, we derived key physical parameters including temperature, extinction, column densities, and the ortho-to-para ratio. This information is combined with a detailed kinematical analysis and comparison with irradiated shock models. We find no evidence of H2 temperature or velocity stratification from the axis to the edge of the outflow, as would be expected in MHD disk-wind models and as observed in other outflows. Instead, the observations suggest that the H2 emission arises from shock interactions between jet bow shocks and/or wide-angle winds with the ambient medium and cavity walls. NIRSpec emission and velocity maps reveal expanding molecular shells, likely driven by the less luminous source in the binary system. We infer an accretion rate of less than 10^-9 solar masses per year for the secondary source, approximately one order of magnitude lower than that of the primary. The H2 emission is consistent with excitation by low-velocity (approximately 10 km/s) J-type shocks, irradiated by an external UV field that may originate from strong dissociative shocks driven by the atomic jet. Future JWST observations will further constrain the evolution of the expanding shell and the mechanisms driving the outflow.

astro-ph.GA↗

arXiv2025

Glycolaldehyde and ethanol toward the L1157 outflow: resolved images and constraints on glycolaldehyde formation

Two main formation routes have been proposed for interstellar complex organic molecules (iCOMs): on dust grain surfaces and in the gas phase. Observing such molecules in protostellar outflow shock regions - provided that their ages are well-constrained - can help distinguish between these pathways by probing chemical evolution over time. This study focuses on the potential daughter-mother relationship of glycolaldehyde (CH$_2$OHCHO) and ethanol (C$_2$H$_5$OH), previously proposed in the literature. We test whether gas-phase reactions converting ethanol into glycolaldehyde derived in these works can explain the observed abundance of the latter in star-forming regions. We target the southern outflow of L1157, which hosts three shock regions, B0, B1 and B2, of increasing ages: about 900, 1500 and 2300 yr. We obtained high-resolution IRAM NOEMA maps of three lines of glycolaldehyde and one line of ethanol. We derived their abundances in the three shocks and used a pseudo time-dependent astrochemical model to simulate gas-phase and grain-surface formation scenarios for glycolaldehyde. Ethanol is assumed to form on grains and be released in the gas by shocks, where it is gradually converted into glycolaldehyde via the ethanol-tree reaction network. We present the first spatially resolved maps of glycolaldehyde and ethanol in the L1157 southern outflow, and more generally toward solar-like star forming regions. The abundance ratio [CH$_2$OHCHO]/[C$_2$H$_5$OH] increases from B1 to B2, consistent with model predictions. However, the model cannot reproduce all three shocked regions simultaneously, suggesting that one of the assumptions of our model, such as the same excitation temperature and grain composition in B0, B1 and B2, or gas temperature evolution, is wrong. Nonetheless, our modeling rules out the possibility that all the observed gaseous glycolaldehyde is a grain-surface product.

astro-ph.SR↗

arXiv2025

FAUST XXVII: The circumbinary disk and the outflow of the L 1551 IRS 5 binary system

Using continuum and $\text{C}^{18}\text{O}\:(2-1)$ line data obtained from the large ALMA program FAUST, we studied the structure of the protostellar binary system L1551 IRS5 at scales between 30 and 3,000 au to constrain its properties, from the circumstellar and circumbinary disks up to the envelope and outflow scales, which exhibits complex and entangled structures at the scales of its inner and outer envelopes, presumably caused by the influence of the central binary. Assuming a dust-to-gas ratio of 100, we calculated the dust+gas mass for the circumbinary disk and each circumstellar disk of the binary, obtaining 0.018 M$_{\odot}$, for the circumbinary disk, 0.004 M$_{\odot}$, and 0.002 M$_{\odot}$, for the northern and southern circumstellar disk respectively. From the line emission, we retrieved the gas masses for each structure component. With the $\text{C}^{18}\text{O}\:(2-1)$ PV diagram along the circumbinary disk, we were able to constrain the centrifugal barrier, $r_{CB}=55$ au, update the specific angular momentum, $j\sim270$~au~km~s$^{-1}$. We built an analytical model that can be used to predict the influence of the morphology of the outflow and a few dynamic features that can reproduce the system emission, allowing us to explain and discern the outflow contribution from the complex emission due to the binary. Additionally, we inferred the density power law index, $\alpha=1.7$, and the envelope rotation velocity, $v_{c}=2$~km~s$^{-1}$. Finally, the observations gave us the physical constraints to obtain a coherent outflow model for L1551 IRS5.

astro-ph.SR↗

arXiv2025

Characterising the multiple protostellar system VLA 1623-2417 with JWST, ALMA and VLA: outflow origins, dust growth and an unsettled disk

Utilising JWST, ALMA and the VLA we present high angular resolution (0.06''- 0.42''), multi-wavelength (4 micron - 3cm) observations of the VLA 1623-2417 protostellar system to characterise the origin, morphology and, properties of the continuum emission. JWST observations at 4.4 micron reveal outflow cavities for VLA 1623 A and, for the first time, VLA 1623 B, as well as scattered light from the upper layers of the VLA 1623 W disk. We model the millimetre-centimetre spectral energy distributions to quantify the relative contributions of dust and ionised gas emission, calculate dust masses, and use spectral index maps to determine where optical depth hinders this analysis. In general, all objects appear to be optically thick down to ~90 GHz, show evidence for significant amounts (10's - 100's M_Earth) of large (>1 mm) dust grains, and are dominated by ionised gas emission for frequencies ~<15 GHz. In addition, we find evidence of unsettled millimetre dust in the inclined disk of VLA 1623 B possibly attributed to instabilities within the circumstellar disk, adding to the growing catalogue of unsettled Class 0/I disks. Our results represent some of the highest resolution observations possible with current instrumentation, particularly in the case of the VLA. However, our interpretation is still limited at low frequencies (~<22 GHz) and thus motivates the need for next-generation interferometers operating at centimetre wavelengths.

astro-ph.SR↗

arXiv2024

Multiple Components of the Outflow in the Protostellar System HH 212: Outer Outflow Shell, Rotating Wind, Shocked Wind, and Jet

We present the Atacama Large Millimeter/submillimeter Array Band 7 observations of the CO (J=3-2) line emission of the protostellar system HH 212 at $\sim$24 au spatial resolution and compare them to those of the SiO (J=8-7) and SO (J=8-7) line emission reported in the literature. We find that the CO line traces four distinct regions: (1) an outer outflow shell, (2) a rotating wind region between the SiO and CO shells, (3) the shocked and wide-angle inner X-wind inside a SiO shell, and (4) the jet. The origin of the CO outer outflow shell could be associated with the entrained material of the envelope, or an extended disk wind. The rotating wind, which is shocked, is launched from a radius of 9-15 au, slightly exterior to that of the previously detected SO shell, which marks the boundary where the wide-angle X-wind is interacting with and shocking the disk wind. Additionally, the SO is found to be mixed with the CO emission within the thick and extended rotating wind region. The large scale CO shocked wind coexists with the SO emission near the upper portion of the inner shocked region converged on top of the inner SiO knots. The CO jet is traced by a chain of knots with roughly equal interval, exhibiting quasi-periodicity, as reported in other jets in the literature.

astro-ph.SR↗

arXiv2024

Full interferometric map of the L1157 southern outflow: Formamide (NH$_2$CHO) can form in the gas, after all

The formation mechanism of interstellar formamide (NH$_2$CHO), a key prebiotic precursor, is currently a matter of hot debate within the astrochemistry community, with both gas-phase and grain-surface chemical pathways having been proposed as its dominant formation route. The aim of the present study is to place firm observational constraints on the formation pathways leading to formamide thanks to new interferometric observations of the molecular outflow driven by the protostellar binary L1157. We employed the IRAM NOEMA interferometer to map the entire southern outflow of L1157, which contains three main shocked regions with increasing post-shock age: B0, B1, and B2. This allowed us to measure how the abundance of formamide, that of acetaldehyde (CH$_3$CHO), and the ratio of the two, vary with time in this region. In order to gain a greater understanding of the most likely formation routes of formamide, we ran a grid of astrochemical models and compared these to our observations. A comparison between observations and astrochemical modelling indicates that there are two possible scenarios: one in which the amount of formamide observed can be explained by gas-phase-only chemistry, and more specifically via the reaction H$_2$CO + NH$_2$ $\rightarrow$ NH$_2$CHO + H$_2$, and another in which part of the observed formamide originates from surface chemistry and part from gas-phase chemistry. Surface chemistry alone cannot account for the abundance of formamide that we measure. While grain-surface chemistry cannot be ruled out, the present study brings definitive proof that gas-phase chemistry does work in L1157-B and acts efficiently in the production of this molecular species.

astro-ph.GA↗