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Lisa Dang

Publications and source records attributed to Lisa Dang.

At least 19 recordsLinked to original sources

Evolutionary pathways toward survival of a thick CO2- or SO2-rich atmosphere on the lava world TOI-561 b

Rocky planets evolve through the exchange of volatiles between their interiors and atmospheres, an interplay still poorly constrained by observations. Remarkably, highly irradiated ultrashort-period (USP) exoplanets may offer a window into this exchange -- some retain low bulk densities compatible with volatile-rich envelopes surrounding rocky interiors, indicating possible secondary atmospheres. TOI-561 b is a prime example, with a bulk density of $4.3\pm0.4$ g cm$^{-3}$ and recent JWST observations favoring a thick volatile atmosphere overlying a dayside magma ocean. Here, we investigate the evolutionary pathways allowing TOI-561 b to retain a substantial atmosphere over gigayears using the PROTEUS coupled interior--atmosphere framework. We explore different core radius fractions, Bond albedos, atmospheric escape efficiencies, mantle redox states, and initial C--H--O--N--S volatile inventories, under in situ evolution and late inward migration. Over half of our simulations leave a bare interior too dense to match observations. Successful cases favor a volatile-rich origin ($\lesssim200$ Earth oceans of hydrogen, S/H $\le10$, and N/H $\le1$), an oxidized mantle ($f$O$_2 \gtrsim \mathrm{IW}+4$), a small iron core ($\le 0.40$ for the core radius fraction), and low escape efficiency ($\epsilon \lesssim 10^{-3}$) in the hydrodynamic escape regime. At present, TOI-561 b is consistent with a global magma ocean beneath a thick (surface pressure $\approx 10^{3}$--$10^{4}$ bar), high mean molecular weight atmosphere ($38$--$60$ g mol$^{-1}$). Two archetypes emerge, differentiated by bulk sulfur content: a CO$_2$-dominated and an SO$_2$-dominated atmosphere. Migration is viable but not required to reproduce the observations. Our study illustrates how interior--atmosphere coupling governs atmospheric retention on irradiated rocky planets.

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A Highly Reflective Atmosphere on the Lava World TOI-561b Revealed by JWST/NIRSpec Phase Curve

Ultra-short period (USP) rocky planets are expected to be depleted of any substantial gaseous envelope due to the intense irradiation they receive from their host star, making the recent detection of an atmosphere around TOI-561~b particularly surprising. That finding was based on the planet's bulk density and dayside emission spectrum, but full-orbit phase curve observations offer a more comprehensive way to constrain the presence and characteristics of a planet's atmosphere. In this paper, we map TOI-561~b's 3-5~$\mu$m emission using JWST/NIRSpec multi-orbit spectroscopic phase curves, explicitly accounting for the curvature of the out-of-eclipse baseline and possible hotspot offsets. From a simple energy balance argument as well as comparing to general circulation models, we find the phase curve observations are best explained with high Bond albedo and moderate global heat transfer. Our 37-hour continuous observation provides a long baseline that allows us to model stellar granulation, the planetary phase curve, and dayside emission simultaneously, effectively disentangling these signals and yielding a dayside emission spectrum that is more robust against stellar variability and consistent with previous eclipse-only fits. Using general circulation model outputs, we constrain where clouds can plausibly form and test candidate compositions, finding that silicate clouds, such as SiO$_2$ and MgSiO$_3$, can form on the dayside near the terminator and explain the observed albedo. Our findings confirm that TOI-561~b appears to have a global reflective atmosphere, suggesting exchange of volatiles with the interior to maintain it.

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Atmospheric Reconnaissance of TRAPPIST-1 f with JWST NIRISS SOSS: No Evidence for the Transit Light Source Effect

In just over three years of operation, JWST has observed all seven planets of the TRAPPIST-1 system. The two innermost planets were found to have little to no atmosphere, barring the presence of high-altitude aerosols. Here we present the first JWST transit spectra of the habitable-zone exoplanet TRAPPIST-1 f, which were obtained with NIRISS SOSS over the course of five transits. At least one stellar flare occurred in each visit, but unlike observations of closer-in TRAPPIST-1 planets, no evidence for contamination of the transit spectra from unocculted stellar surface heterogeneities was found. This non-detection does not guarantee the absence of unocculted heterogeneities in all future transit observations of this planet, and it could be explained by the transit chord of TRAPPIST-1 f having properties similar to the average, out-of-transit, visible stellar hemisphere at the time of observation. The transit spectra exhibit slopes ranging from -365 ppm/um down to 15 ppm/um, which we attribute to stellar variability, that is, flares and/or smaller-scale events. The visits least affected by flares rule out H2/He-dominated atmospheres with surface pressures higher than about 20 mbar at 95% confidence. For high-mean-molecular-mass atmospheres, the exact upper limits on surface pressures depend on the reduction pipeline and on the treatment of the residual slopes in the transit spectra.

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Unraveling the Mystery of the Peculiar and Young Hot Jupiter CoRoT-2b II: Phase Resolved Emission Spectroscopy with VLT/CRIRES+ and Gemini-S/IGRINS

Hot Jupiters are expected to be tidally locked and synchronously rotating due to their short orbital periods. These conditions create large day-night temperature contrasts and are thought to drive eastward super-rotating jets. Indeed, the majority of hot Jupiters are observed to have the hottest region of the planet either at the substellar point or offset in the eastern direction. However, the full phase curve of CoRoT-2b, observed with the Spitzer Space Telescope, exhibits robust evidence of a western hotspot offset. To determine the origin of this peculiar hotspot offset, we present phase-resolved high-resolution observations of CoRoT-2b from the CRIRES+ spectrograph on the Very Large Telescope (VLT) and the IGRINS spectrograph on Gemini South, covering both pre- and post-eclipse phases (0.34--0.63). We detect the signal from the planet (S/N$>$4) in both pre- and post-eclipse phases separately, and therefore perform separate cross-correlation and retrieval analyses at the two epochs. The phase-resolved retrievals show highly consistent abundances and C/Os, but prefer a hotter and more isothermal temperature-pressure profile at post-eclipse phases, consistent with the phase curve observations that indicated a western hotpsot offset. By testing multiple hypotheses invoked to drive a western hotspot offset, we find the most likely explanation to be sub-synchronous planetary rotation. We measure the planet's rotational broadening to be $2.24\substack{+0.81\\-0.77}$ km s$^{-1}$, whereas the expectation from tidally locked rotation is $4.37\pm0.13$ km s$^{-1}$ (2.6-$\sigma$ discrepant). Other observations, such as high precision phase curves or eclipse mapping, would help to further confirm the western hotspot offset and sub-synchronous rotation.

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The breaking of cold traps and onset of titanium in ultra-hot Jupiter atmospheres: WASP-189b in context

Condensates are ubiquitous to all Solar System planets with significant ($>$10mbar) atmospheres. The same is true for most exoplanets with characterised atmospheres, with even ultra-hot exoplanets being able to form clouds on their cooler nightsides. One high-interest condensate is titanium, a highly refractory element that as an oxide (TiO) is a potent optical absorber long believed to be a driver of thermal inversions in highly irradiated exoplanet atmospheres. Observations have shown that some ultra-hot Jupiters have strong thermal inversions despite being significantly Ti-depleted, likely due to cold trapping, raising doubts about whether TiO is the main cause of their inverted temperature structures. Our aim was to retrieve the titanium-to-iron ratio of the dayside atmosphere of the ultra-hot Jupiter WASP-189b to determine whether the full titanium budget is accounted for in the gas phase. We analysed thermal emission observations of WASP-189b taken with the HARPS and NIRPS spectrographs using different atmospheric retrieval prescriptions to infer the planet's atmospheric thermal structure and composition. We observed Fe and Ti signals in cross-correlation and measured a sub-solar Ti/Fe ratio for WASP-189b using both free and chemical equilibrium retrieval approaches. We find the Ti/Fe of the planetary atmosphere to be between 28% and 81% (1-$\sigma$ bounds) that of the stellar value. The slight underabundance of Ti with respect to Fe on the dayside atmosphere of WASP-189b suggests that some titanium is missing from the gas phase, potentially due to a partial nightside cold trap. In the context of the ultra-hot Jupiter population, the onset of titanium in exoplanetary atmospheres appears to occur progressively, coinciding not with when thermal inversions begin but rather when the vapourisation threshold of titanium is reached on the nightside.

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GJ 3929 b as the First Complete Rocky Worlds DDT Data Set

Despite their large abundance, it is still unknown whether and under what conditions rocky planets around M dwarf stars can host atmospheres. This open question motivated the on-going Rocky Worlds DDT survey focused on searching for atmospheres on relatively low-temperature rocky exoplanets by systematically probing for the presence of day-night heat redistribution and CO2 absorption through JWST/MIRI 15 $\mu$m eclipse observations. Here we present the analysis of the first full data set from this survey, consisting of four observations of the warm Earth-size exoplanet GJ 3929 b, with a planetary mass of 1.75+0.44-0.45 M$_\oplus$ and instellation flux of 17.3+/-0.7 S$_\oplus$. In our analysis, we include two previously unpublished eclipse observations and find an overall eclipse depth of 118+/-22 ppm and a dayside surface brightness temperature of 641+59-64 K. This is marginally lower than the eclipse depth of 160+26-27 ppm previously reported based on only the first two observations. While the full data set remains consistent with bare rock scenarios, it also leaves more room for thin atmosphere scenarios. Only thick CO2 atmospheres without thermal inversion remain ruled out at greater than 3$\sigma$. We also continue with lessons-learned in robustly analyzing these kind of high-precision JWST/MIRI 15 $\mu$m eclipse observations. Notably, we find that the Frame Normalized Principal Component Analysis (FN-PCA) method appears more robust against the choice of extraction aperture size, which otherwise can have a significant impact on the inferred eclipse depth and scientific conclusions when using a standard polynomial baseline detrending method.

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Unraveling the Mystery of the Peculiar and Young Hot Jupiter CoRoT-2b. I. H$_2$O and CO Detection from Dayside Observations with Gemini-S/IGRINS

We present ground-based high-resolution spectroscopic pre-eclipse observations of the hot Jupiter CoRoT-2b obtained with the IGRINS spectrograph on Gemini South. Using cross-correlation analysis, we detect the Doppler-shifted signature of the planet's thermal emission with a signal-to-noise ratio of 4.32. Our independent analyses confirm the presence of H$_2$O with a confidence level of 2.6$\sigma$ and an abundance of log$_{10}$$-5.08^{+0.43}_{-0.43}$, as well as CO with 2.3$\sigma$ confidence and an abundance of log$_{10}$$-4.21^{+0.48}_{-0.81}$ in CoRoT-2b's atmosphere, using two fully independent data reduction and retrieval pipelines. No significant detections of CH$_4$, CO$_2$, TiO, or VO are reported. While our cross-correlation analysis tentatively suggests the presence of HCN and OH, retrieval analysis does not confirm these molecules. The detected H$_2$O and CO features indicate that CoRoT-2b's dayside spectrum is not featureless, as previously inferred from lower-resolution observations, but instead reveals a complex atmospheric structure. Interestingly, we find a lack of significant molecular features at wavelengths shorter than 1.7 $\mu m$, potentially due to high-altitude absorbers such as H$^-$, clouds, or observational systematics. From our retrieved abundances of CO and H$_2$O, we constrain a supersolar C/O ratio of $0.91^{+0.08}_{-0.17}$ and a subsolar metallicity. This study provides the first high-resolution constraints on the atmospheric composition of CoRoT-2b and serves as the foundation for future investigations into its peculiar westward hotspot offset. Further phase-resolved observations will be required to explore the underlying atmospheric dynamics in more detail.

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Comparing Results from Two Uniform Phase Curve Surveys

We present a comparison of the two most recent and comprehensive Spitzer phase curve studies - Dang et al. (2025) and Swain et al. (2025) - which report analyses of the Spitzer 4.5 $\mu$m phase curves. The studies employ different approaches for correcting instrument systematics and they also use different approaches for selecting the optimal exoplanet system parameters. To evaluate the level of consistency between the two studies, we compared the constraints on the ratio of planet-to-star radii ($R_P/R_\star$), eclipse depth ($F_P/F_\star$), phase curve amplitude ($A$), and phase curve offset ($\phi$). We find that the two studies produce similar results at the population level although results for individual planets can vary, especially for phase curve offset values. We examined the difference of planet system parameters to see if inconsistencies in individual planet results were due to data reduction methods or system parameter choices. We also examined whether the system parameters used by both studies were consistent with Kepler's third law. During this comparison, we identified one case where stellar mass, planet semi-major axis, and orbital period did not follow Kepler's law even though the values were all compiled from the same publication. To assess whether this kind of discrepancy was recurrent, we recalculated the orbital periods using Kepler's third law and compared them with the values listed in the NASA Exoplanet Archive. Our detailed analysis of archival system parameters strongly suggests that testing reported/selected parameters for consistency with Kepler's third law is worthwhile.

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The NUV transit of XO-3 b

Near-UV (NUV) measurements of exoplanet transits offer a means to probe atmospheric escape, cloud formation, and planetary magnetic fields. We examine a 2024 XMM-Newton Optical Monitor NUV observation of the transit of XO-3~b, a massive hot Jupiter on an eccentric orbit with a previously observed abnormally large NUV-absorbing atmosphere. We analyze this NUV data jointly with a concurrent ground-based optical observation and all TESS transit observations, and find a NUV transit depth of $R_{p,NUV}/R_{\star} = 0.1371^{+0.016}_{-0.019}$, which is 30-70% deeper than the optical transit. Although the optical transits do not show signs of transit timing variations, the transit center in the NUV is $22^{+13}_{-11}$ minutes late compared to the optical ephemeris. We investigate atmospheric escape as a potential explanation of the properties of this NUV transit by examining X-ray data from XMM-Newton, characterizing the X-ray luminosity of XO-3 for the first time and estimating an extremely small mass-loss rate of $\sim10^4$ g/s ($\sim10^{-19}$ M$_{\text{jup}}$/yr). Finally, we investigate the likelihood of an NUV-absorbent bow-shock by estimating the magnetic field of the planet. While such a mechanism is capable of producing NUV transit offsets on the order of tens of minutes, our analytic approximations predict an early rather than late transit, indicating a need for further magnetohydrodynamic simulations.

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The Days Drag On on WASP-121 b: Interpreting its NIRISS Spectroscopic Phase Curve with General Circulation Models

Ultra-hot Jupiters present extreme atmospheric phenomena not found in the Solar System. These planets' daysides experience strong temperature inversions, molecular species (including H2) dissociate, and magnetism disrupts their atmospheric circulation. On their nightsides H2 can recombine and clouds may form. Spectroscopic phase curves let us measure these spatially inhomogeneous conditions, which can then be interpreted with three-dimensional (3-D) models. In this work we compare the JWST/NIRISS spectroscopic phase curve of the ultra-hot Jupiter WASP-121 b to state-of-the-art 3-D models with varying modeling assumptions, including the aforementioned physical phenomena. We demonstrate the importance of accurately accounting for the planet's radius in comparison between data and models, as it changes the implied overall planetary emission. We find that the 3-D models predict planet emission $\sim$12% higher than observed, contributing to a continued tension between measured and predicted hot Jupiter albedos. We identify multiple pieces of evidence that confirm a strong source of drag operating in this planet's atmosphere. In addition, the nightside emission spectrum is devoid of strong absorption features, which may be best explained by nightside clouds. One feature of the dataset that is not matched by the 3-D models is a trend of increasing eastward phase offset with decreasing wavelength, for wavelengths shorter than $\sim$1.4 \textmu m. This result is not consistent with reflection from dayside clouds, nor can it be explained by removing atmospheric opacity sources. Our analysis highlights the complexities in generating 3-D models and interpreting observations of ultra-hot Jupiters in the JWST era.

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Diversity in the haziness and chemistry of temperate sub-Neptunes

Recent transit observations of K2-18b and TOI-270d revealed strong molecular absorption signatures, lending credence to the idea that temperate sub-Neptunes (T$_\mathrm{eq}$=250-400K) have upper atmospheres mostly free of aerosols. These observations also indicated higher-than-expected CO$_2$ abundances on both planets, implying bulk compositions with high water mass fractions. However, it remains unclear whether these findings hold true for all temperate sub-Neptunes. Here, we present the JWST NIRSpec/PRISM 0.7-5.4$\mathbf{\mu}$m transmission spectrum of a third temperate sub-Neptune, the 2.4R$_\oplus$ planet LP 791-18c (T$_\mathrm{eq}$=355K), which is even more favorable for atmospheric characterization thanks to its small M6 host star. Intriguingly, despite LP 791-18c's radius, mass, and equilibrium temperature being in between those of K2-18b and TOI-270d, we find a drastically different transmission spectrum. While we also detect methane on LP 791-18c, its transit spectrum is dominated by strong haze scattering and there is no discernible CO$_2$ absorption. Overall, we infer a deep metal-enriched atmosphere (246-415$\times$solar) for LP 791-18c, with a CO$_2$-to-CH$_4$ ratio smaller than 0.07 (at 2$\sigma$), indicating less H$_2$O in the deep envelope of LP 791-18c and implying a relatively dry formation inside the water ice-line. These results show that sub-Neptunes that are near-analogues in density and temperature can show drastically different aerosols and envelope chemistry, and are intrinsically diverse beyond a simple temperature dependence.

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Reanalysis of the eclipses of LHS 1140 c: No evidence of an atmosphere and implications for the internal structure of the planet

We present the reanalysis of three 15 micron JWST/MIRI secondary eclipses of LHS 1140 c, a warm super-Earth (R$_{\rm{p}}$ = 1.272 R$_{\oplus}$) in a 3.78-day orbit around an M4.5 dwarf. We present a novel method for data reduction that leverages spatial derivatives of the point-spread function and compare it to widely used aperture photometry. Both methods yield eclipse depth consistent within 1 sigma of the values reported in the literature. We measure an eclipse depth of 271$^{+31}_{-30}$ ppm corresponding to a brightness temperature of $T_B=595^{+33}_{-34}$ K, consistent with a bare rock. The secondary eclipse occurs 4.1$\pm$0.8 minutes before the circular-orbit predicted time. We explore the implications of our results on the internal structure of LHS 1140 c, the orbital architecture of the system and the possibility of future observations with JWST. We find a core-mass fraction (CMF) informed by the stellar abundances of refractory elements of 0.34$\pm$0.11, inflated compared to the CMF from radius and mass measurements, suggesting the possible presence of bulk volatiles in the interior.

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A complex structure of escaping helium spanning more than half the orbit of the ultra-hot Jupiter WASP-121\,b

Atmospheric escape of planets on short orbital periods, driven by the host star's irradiation, influences their evolution, composition, and atmospheric dynamics. Our main avenue to probe atmospheric escape is through the near-infrared metastable helium triplet, which has enabled mass loss rate measurements for tens of exoplanets. Among them, only a few studies show evidence for out-of-transit absorption, supporting the presence of a hydrodynamic outflow. However, none of these observations precisely identified the physical extent of the outflow, either due to non-continuous or short-duration observations. This limits our measurements of accurate mass loss rates. Here we present the first continuous, full-orbit helium phase curve monitoring of an exoplanet, the ultra-hot Jupiter WASP-121b, obtained with JWST/NIRISS. It reveals helium absorption for nearly 60% of the orbit at >3sigma significance. Our results show that WASP-121b sustains a strong outflow, separating into two tails trailing and leading the planet. The persistent absorption from these tails, together with their measured radial velocity shifts, suggests that they remain in a collisional fluid regime at large distances from the planet and display very different dynamics. The leading trail has a higher density and moves toward the star, whereas the trailing trail is being pushed away from the star, with the latter being blue-shifted due to stellar irradiation pressure. While qualitatively agreeing with theoretical expectations, the observed structure of helium is not self-consistently reproducible by current models, limiting constraints on the mass loss rate. Furthermore, we show that while ground-based observations of the helium triplet are essential to measure the outflow dynamics precisely, they ideally should be combined with continuous JWST phase curves to constrain the absolute level of helium absorption.

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A Thick Volatile Atmosphere on the Ultrahot Super-Earth TOI-561 b

Ultrashort-period (USP) exoplanets -- with $R_p \leq 2~$R$_{\oplus}$ and periods $\leq$1 day -- are expected to be stripped of volatile atmospheres by intense host star irradiation, which is corroborated by their nominal bulk densities and previous eclipse observations consistent with bare rock surfaces. However, a few USP planets appear anomalously under-dense relative to an Earth-like composition, suggesting an exotic interior structure (e.g., core-less) or a volatile-rich secondary atmosphere increasing their apparent radius. Here we present the first dayside emission spectrum of the low-density (4.3$\pm$0.4 g~cm$^{-3}$) USP planet TOI-561 b, which orbits an iron-poor, alpha-rich, $\sim$10 Gyr old thick disk star. Our 3-5 $\mu$m JWST/NIRSpec observations demonstrate the dayside of TOI-561 b is inconsistent with a bare-rock surface at high statistical significance, suggesting instead a thick volatile envelope that is cooling the dayside to well below the $\sim$3000 K expected in the bare-rock or thin-atmosphere case. These results reject the popular hypothesis of complete atmospheric desiccation for highly irradiated exoplanets and support predictions that planetary-scale magma oceans can retain substantial reservoirs of volatiles, opening the geophysical study of ultrahot super-Earths through the lenses of their atmospheres.

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Precise Constraints on the Energy Budget of WASP-121 b from its JWST NIRISS/SOSS Phase Curve

Ultra-hot Jupiters exhibit day-to-night temperature contrasts upwards of 1000 K due to competing effects of strong winds, short radiative timescales, magnetic drag, and H2 dissociation/recombination. Spectroscopic phase curves provide critical insights into these processes by mapping temperature distributions and constraining the planet's energy budget across different pressure levels. Here, we present the first NIRISS/SOSS phase curve of an ultra-hot Jupiter, WASP-121 b. The instrument's bandpass [0.6 - 2.85 micron] captures an estimated 50-83% of the planet's bolometric flux, depending on orbital phase, allowing for unprecedented constraints on the planet's global energy budget; previous measurements with HST/WFC3 and JWST/NIRSpec/G395H captured roughly 20% of the planetary flux. Accounting for the unobserved regions of the spectrum, we estimate effective day and nightside temperatures of T_day = 2717 +/- 17 K and T_night = 1562 +/- 19 K corresponding to a Bond albedo of A_B = 0.277 +/- 0.016 and a heat recirculation efficiency of epsilon = 0.246 +/- 0.014. Matching the phase-dependent effective temperature with energy balance models yields a similar Bond albedo of 0.3 and a mixed layer pressure of 1 bar consistent with photospheric pressures, but unexpectedly slow winds of 0.2 km/s, indicative of inefficient heat redistribution. The shorter optical wavelengths of the NIRISS/SOSS Order 2 yield a geometric albedo of A_g = 0.093 +/- 0.029 (3 sigma upper limit of 0.175), reinforcing the unexplained trend of hot Jupiters exhibiting larger Bond albedos than geometric albedos. We also detect near-zero phase curve offsets for wavelengths above 1.5 micron, consistent with inefficient heat transport, while shorter wavelengths potentially sensitive to reflected light show eastward offsets.

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On the synergetic use of Ariel and JWST for exoplanet atmospheric science

This paper explores the potential for strategic synergies between the JWST and the Ariel telescopes, two flagship observatories poised to revolutionise the study of exoplanet atmospheres. Both telescopes have the potential to address common fundamental questions about exoplanets-especially concerning their nature and origins-and serve a growing scientific community. With their operations now anticipated to overlap, starting from 2030, there is a unique opportunity to enhance the scientific outputs of both observatories through coordinated efforts. In this report, authored by the Ariel-JWST Synergy Working Group, part of the Ariel Consortium Science Team, we summarise the capabilities of JWST and Ariel; we highlight their key differences, similarities, synergies, and distinctive strengths. Ariel is designed to conduct a broad survey of exoplanet atmospheres but remains highly flexible, allowing the mission to integrate insights from JWST's discoveries. Findings from JWST, including data from initiatives shaped by NASA's decadal survey priorities and community-driven research themes, will inform the development of Ariel's core survey strategy. Conversely, Ariel's ability to perform broad-wavelength coverage observations for bright targets provides complementary avenues for exoplanet researchers, particularly those interested in time-domain observations and large-scale atmospheric studies. This paper identifies key pathways for fostering JWST-Ariel synergies, many of which can be initiated even before Ariel's launch. Leveraging their complementary designs and scopes, JWST and Ariel can jointly address fundamental questions about the nature, formation, and evolution of exoplanets. Such strategic collaboration has the potential to maximise the scientific returns of both observatories and lay the foundation for future facilities in the roadmap to exoplanet exploration.

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Enriched volatiles and refractories but deficient titanium on the dayside atmosphere of WASP-121b revealed by JWST/NIRISS

With dayside temperatures elevated enough for all atmospheric constituents to be present in gas form, ultra-hot Jupiters offer a unique opportunity to probe the composition of giant planets. We aim to infer the composition and thermal structure of the dayside atmosphere of the ultra-hot Jupiter WASP-121b from two NIRISS$/$SOSS secondary eclipses observed as part of a full phase curve. We extract the eclipse spectrum of WASP-121b with two independent data reduction pipelines and analyse it using different atmospheric retrieval prescriptions to explore the effects of thermal dissociation, reflected light, and titanium condensation on the inferred atmospheric properties. We find that the observed dayside spectrum of WASP-121b is best fit by atmosphere models possessing a stratospheric inversion with temperatures reaching over 3000K, with spectral contributions from H2O, CO, VO, H-, and either TiO or reflected light. We measure the atmosphere of WASP-121b to be metal enriched (~10x stellar) but comparatively titanium poor (~1x stellar), potentially due to partial cold-trapping. The inferred C/O depends on model assumptions such as whether reflected light is included, ranging from being consistent with stellar if a geometric albedo of zero is assumed to being super-stellar for a freely fitted Ag = 0.16 +/- 0.02. The volatile-to-refractory ratio is measured to be consistent with the stellar value. We infer that WASP-121b has an atmosphere enriched in both volatile and refractory metals, but not in ultra-refractory titanium, suggesting the presence of a nightside cold-trap. Considering H2O dissociation is critical in free retrieval analyses, leading to order-of-magnitude differences in retrieved abundances for WASP-121b if neglected. Simple chemical equilibrium retrievals assuming that all species are governed by a single metallicity parameter drastically overpredict the TiO abundance.

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Strict limits on potential secondary atmospheres on the temperate rocky exo-Earth TRAPPIST-1 d

The nearby TRAPPIST-1 system, with its seven small rocky planets orbiting a late-type M8 star, offers an unprecedented opportunity to search for secondary atmospheres on temperate terrestrial worlds. In particular, the 0.8 Earth-radii planet TRAPPIST-1 d lies at the edge of the habitable zone (equilibrium temperature ~262 K). Here we present the first 0.6-5.2 micron NIRSpec/PRISM transmission spectrum of TRAPPIST-1 d from two transits with JWST. We find that stellar contamination from unocculted bright heterogeneities introduces 500-1,000 ppm visit-dependent slopes, consistent with constraints from the out-of-transit stellar spectrum. Once corrected, the transmission spectrum is flat within $\pm$100-150 ppm, showing no evidence for a haze-like slope or molecular absorption despite NIRSpec/PRISM's sensitivity to CH4, H2O, CO, SO2, and CO2. Our observations exclude clear, hydrogen-dominated atmospheres with high confidence (greater than 3$\sigma$). We leverage our constraints on even trace amounts of CH4, H2O, and CO2 to further reject high mean molecular weight compositions analogous to Titan, a cloud-free Venus, early Mars, and both Archean Earth and a cloud-free modern Earth scenario (greater than 95% confidence). If TRAPPIST-1 d retains an atmosphere, it is likely extremely thin or contains high-altitude aerosols, with water cloud formation at the terminator predicted by 3D global climate models. Alternatively, if TRAPPIST-1 d is airless, our evolutionary models indicate that TRAPPIST-1 b, c, and d must have formed with less than approximately 4 Earth oceans of water, though this would not preclude atmospheres on the cooler habitable-zone planets TRAPPIST-1 e, f, and g.

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