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Luis Welbanks

Publications and source records attributed to Luis Welbanks.

At least 55 records · Page 3Linked to original sources

Prospects for Detecting Signs of Life on Exoplanets in the JWST Era

The search for signs of life in the Universe has entered a new phase with the advent of the James Webb Space Telescope (JWST). Detecting biosignature gases via exoplanet atmosphere transmission spectroscopy is in principle within JWST's reach. We reflect on JWST's early results in the context of the potential search for biological activity on exoplanets. The results confront us with a complex reality. Established inverse methods to interpret observed spectra-already known to be highly averaged representations of intricate 3D atmospheric processes-can lead to disparate interpretations even with JWST's quality of data. Characterizing rocky or sub-Neptune-size exoplanets with JWST is an intricate task, and moves us away from the notion of finding a definitive "silver bullet" biosignature gas. Indeed, JWST results necessitate us to allow "parallel interpretations" that will perhaps not be resolved until the next generation of observatories. Nonetheless, with a handful of habitable-zone planet atmospheres accessible given the anticipated noise floor, JWST may continue to contribute to this journey by designating a planet as biosignature gas candidate. To do this we will need to sufficiently refine our inverse methods and physical models for confidently quantifying specific gas abundances and constraining the atmosphere context. Looking ahead, future telescopes and innovative observational strategies will be essential for the reliable detection of biosignature gases.

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A JWST Panchromatic Thermal Emission Spectrum of the Warm Neptune Archetype GJ 436b

GJ 436b is the archetype warm Neptune exoplanet. The planet's thermal emission spectrum was previously observed via intensive secondary eclipse campaigns with Spitzer. The atmosphere has long been interpreted to be extremely metal-rich, out of chemical equilibrium, and potentially tidally heated. We present the first panchromatic emission spectrum of GJ 436b observed with JWST's NIRCAM (F322W2 and F444W) and MIRI (LRS) instruments between 2.4 and 11.9 $μ$m. Surprisingly, the JWST spectrum appears significantly fainter around 3.6 $μ$m than that implied by Spitzer photometry. The molecular absorption features in the spectrum are relatively weak, and we only find tentative evidence of CO$_2$ absorption at 2$σ$ significance. Under the assumption of a day-side blackbody, we find $T_{\rm day}$=662.8$\pm$5.0 K, which is similar to the zero Bond albedo equilibrium temperature. We use it to obtain a 3$σ$ upper limit on the Bond albedo of $A_B{\le}$0.66. To understand the spectrum we employ 1D radiative-convective models but find that atmospheric constraints depend strongly on model assumptions. If thermochemical equilibrium is assumed, we find a cloudy metal-enriched atmosphere (metallicity $\ge$ 300$\times$solar). We employ 1D photochemical modeling to show that the observed spectrum is also consistent with a cloud-free, relatively lower-metallicity atmosphere (metallicity $\ge$ 80$\times$solar) with a cold internal temperature ($T_{\rm int}$$\sim$60 K). These are much lower metallicities and internal temperatures than inferences from Spitzer photometry. The low $T_{\rm day}$ and non-detection of transmission features at high spectral resolution does suggest a role for cloud opacity, but this is not definitive.

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Evidence for a volcanic atmosphere on the sub-Earth L98-59b

Assessing the prevalence of atmospheres on rocky planets around M-dwarf stars is a top priority of exoplanet science. High-energy activity from M-dwarfs can destroy the atmospheres of these planets, which could explain the lack of atmosphere detections to date. Volcanic outgassing has been proposed as a mechanism to replenish the atmospheres of tidally-heated rocky planets. L 98-59 b, a sub-Earth transiting a nearby M dwarf, was recently identified as the most promising exoplanet to detect a volcanic atmosphere. We present the transmission spectrum of L 98-59 b from four transits observed with JWST NIRSpec G395H. Although the airless model provides an adequate fit to the data based on its $χ^2$, an SO$_2$ atmosphere is preferred by 3.6$σ$ over a flat line in terms of the Bayesian evidence. Such an atmosphere would likely be in a steady state where volcanism balances escape. If so, L 98-59 b must experience at least eight times as much volcanism and tidal heating per unit mass as Io. If volcanism is driven by runaway melting of the mantle, we predict the existence of a subsurface magma ocean in L 98-59 b extending up to $R_p\sim 60-90\%$. An SO$_2$-rich volcanic atmosphere on L 98-59 b would be indicative of an oxidized mantle with an oxygen fugacity of $f\rm{O}_2>IW+2.7$, and it would imply that L 98-59 b must have retained some of its volatile endowment despite its proximity to its star. Our findings suggest that volcanism may revive secondary atmospheres on tidally heated rocky planets around M-dwarfs.

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A Possible Metal-Dominated Atmosphere Below the Thick Aerosols of GJ 1214 b Suggested by its JWST Panchromatic Transmission Spectrum

GJ1214b is the archetype sub-Neptune for which thick aerosols have prevented us from constraining its atmospheric properties for over a decade. In this study, we leverage the panchromatic transmission spectrum of GJ1214b established by HST and JWST to investigate its atmospheric properties using a suite of atmospheric radiative transfer, photochemistry, and aerosol microphysical models. We find that the combined HST, JWST/NIRSpec and JWST/MIRI spectrum can be well-explained by atmospheric models with an extremely high metallicity of [M/H]$\sim$3.5 and an extremely high haze production rate of $F_{\rm haze}{\sim}10^{-8}$--$10^{-7}$ g cm$^{-2}$ s$^{-1}$. Such high atmospheric metallicity is suggested by the relatively strong CO2 feature compared to the haze absorption feature or the CH4 feature in the NIRSpec-G395H bandpass of 2.5--5 $μ$m. The flat 5--12 $μ$m MIRI spectrum also suggests a small scale height with a high atmospheric metallicity that is needed to suppress a prominent 6 $μ$m haze feature. We tested the sensitivity of our interpretation to various assumptions for uncertain haze properties, such as optical constants and production rate, and all models tested here consistently suggest extremely high metallicity. Thus, we conclude that GJ1214b likely has a metal-dominated atmosphere where hydrogen is no longer the main atmospheric constituent. We also find that different assumptions for the haze production rate lead to distinct inferences for the atmospheric C/O ratio. We stress the importance of high precision follow-up observations to confirm the metal-dominated atmosphere and to constrain the C/O ratio, which provides further insights on the planet formation process. The confirmation of the metal-dominated atmosphere is particularly crucial, as it challenges the conventional understanding of interior structure and evolution of sub-Neptunes.

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Statistical trends in JWST transiting exoplanet atmospheres

Our brains are hardwired for pattern recognition as correlations are useful for predicting and understanding nature. As more exoplanet atmospheres are being characterized with JWST, we are starting to unveil their properties on a population level. Here we present a framework for comparing exoplanet transmission spectroscopy from 3 to 5$μ$m with four bands: L (2.9 - 3.7$μ$m), SO$_2$ (3.95 - 4.1$μ$m), CO$_2$ (4.25 - 4.4$μ$m) and CO (4.5 - 4.9$μ$m). Together, the four bands cover the major carbon, oxygen, nitrogen, and sulfur-bearing molecules including H$_2$O, CH$_4$, NH$_3$, H$_2$S, SO$_2$, CO$_2$, and CO. Among the eight high-precision gas giant exoplanet planet spectra we collected, we found strong correlations between the SO$_2$-L index and planet mass (r=-0.41$\pm$0.09) and temperature (r=-0.64$\pm$0.08), indicating SO$_2$ preferably exists (SO$_2$-L$>$-0.5) among low mass ($\sim<$0.3M$_J$) and cooler ($\sim<$1200K) targets. We also observe strong temperature dependency for both CO$_2$-L and CO-L indices. Under equilibrium chemistry and isothermal thermal structure assumptions, we find that the planet sample favors super-solar metallicity and low C/O ratio ($<$0.7). In addition, the presence of a mass-metallicity correlation is favored over uniform metallicity with the eight planets. We further introduce the SO$_2$-L versus CO$_2$-L diagram alike the color-magnitude diagram for stars and brown dwarfs. All reported trends here will be testable and be further quantified with existing and future JWST observations within the next few years.

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Evidence for Morning-to-Evening Limb Asymmetry on the Cool Low-Density Exoplanet WASP-107b

The atmospheric properties of hot exoplanets are expected to be different between the morning and the evening limb due to global atmospheric circulation. Ground-based observations at high spectral resolution have detected this limb asymmetry in several ultra-hot (>2000 K) exoplanets, but the prevalence of the phenomenon in the broader exoplanetary population remains unexplored. Here we use JWST/NIRCam transmission spectra between 2.5 and 4.0 $μ$m to find evidence of limb asymmetry on exoplanet WASP-107 b. With its equilibrium temperature of 770 K and low density of 0.126 gm c$^{-3}$, WASP-107 b probes a very different regime compared to ultra-hot giant planets and was not expected to exhibit substantial spatial heterogeneity according to atmospheric models. We infer instead a morning-evening temperature difference on the order of 100 K with a hotter evening limb. Further observations on other cooler exoplanets are needed to determine whether WASP-107 b is an outlier or the models underestimate the presence of limb asymmetry in exoplanets.

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A Measurement of the Water Abundance in the Atmosphere of the Hot Jupiter WASP-43b with High-resolution Cross-correlation Spectroscopy

Measuring the abundances of carbon- and oxygen-bearing molecules has been a primary focus in studying the atmospheres of hot Jupiters, as doing so can help constrain the carbon-to-oxygen (C/O) ratio. The C/O ratio can help reveal the evolution and formation pathways of hot Jupiters and provide a strong understanding of the atmospheric composition. In the last decade, high-resolution spectral analyses have become increasingly useful in measuring precise abundances of several carbon- and oxygen-bearing molecules. This allows for a more precise constraint of the C/O ratio. We present four transits of the hot Jupiter WASP-43b observed between 1.45 $-$ 2.45 $μ$m with the high-resolution Immersion GRating InfraRed Spectrometer (IGRINS) on the Gemini-S telescope. We detected H$_2$O at a signal-to-noise ratio (SNR) of 3.51. We tested for the presence of CH$_4$, CO, and CO$_2$, but we did not detect these carbon-bearing species. We ran a retrieval for all four molecules and obtained a water abundance of $\log_{10}(\text{H}_2\text{O}) = -2.24^{+0.57}_{-0.48}$. We obtained an upper limit on the C/O ratio of C/O $<$ 0.95. These findings are consistent with previous observations from the Hubble Space Telescope and the James Webb Space Telescope.

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The Roasting Marshmallows Program with IGRINS on Gemini South II -- WASP-121 b has super-stellar C/O and refractory-to-volatile ratios

A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet's initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultra hot Jupiter WASP-121 b using the high resolution (R=45,000) IGRINS instrument on Gemini South. Probing the planet's direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly super-stellar C/O ratio of 0.70$^{+0.07}_{-0.10}$ and a moderately super-stellar refractory-to-volatile ratio at 3.83$^{+3.62}_{-1.67} \times$ stellar. This combination is most consistent with formation between the soot line and H$_2$O snow line, but we cannot rule out formation between the H$_2$O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H$_2$O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet day side. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high resolution spectroscopy in the near-infrared H and K bands.

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Possible Carbon Dioxide Above the Thick Aerosols of GJ 1214 b

Sub-Neptune planets with radii smaller than Neptune (3.9 Re) are the most common type of planet known to exist in The Milky Way, even though they are absent in the Solar System. These planets can potentially have a large diversity of compositions as a result of different mixtures of rocky material, icy material and gas accreted from a protoplanetary disk. However, the bulk density of a sub-Neptune, informed by its mass and radius alone, cannot uniquely constrain its composition; atmospheric spectroscopy is necessary. GJ 1214 b, which hosts an atmosphere that is potentially the most favorable for spectroscopic detection of any sub-Neptune, is instead enshrouded in aerosols (thus showing no spectroscopic features), hiding its composition from view at previously observed wavelengths in its terminator. Here, we present a JWST NIRSpec transmission spectrum from 2.8 to 5.1 um that shows signatures of carbon dioxide and methane, expected at high metallicity. A model containing both these molecules is preferred by 3.3 and 3.6 sigma as compared to a featureless spectrum for two different data analysis pipelines, respectively. Given the low signal-to-noise of the features compared to the continuum, however, more observations are needed to confirm the carbon dioxide and methane signatures and better constrain other diagnostic features in the near-infrared. Further modeling of the planet's atmosphere, interior structure and origins will provide valuable insights about how sub-Neptunes like GJ 1214 b form and evolve.

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A Fourth Planet in the Kepler-51 System Revealed by Transit Timing Variations

Kepler-51 is a $\lesssim 1\,\mathrm{Gyr}$-old Sun-like star hosting three transiting planets with radii $\approx 6$-$9\,R_\oplus$ and orbital periods $\approx 45$-$130\,\mathrm{days}$. Transit timing variations (TTVs) measured with past Kepler and Hubble Space Telescope (HST) observations have been successfully modeled by considering gravitational interactions between the three transiting planets, yielding low masses and low mean densities ($\lesssim 0.1\,\mathrm{g/cm^3}$) for all three planets. However, the transit time of the outermost transiting planet Kepler-51d recently measured by the James Webb Space Telescope (JWST) 10 years after the Kepler observations is significantly discrepant from the prediction made by the three-planet TTV model, which we confirmed with ground-based and follow-up HST observations. We show that the departure from the three-planet model is explained by including a fourth outer planet, Kepler-51e, in the TTV model. A wide range of masses ($\lesssim M_\mathrm{Jup}$) and orbital periods ($\lesssim 10\,\mathrm{yr}$) are possible for Kepler-51e. Nevertheless, all the coplanar solutions found from our brute-force search imply masses $\lesssim 10\,M_\oplus$ for the inner transiting planets. Thus their densities remain low, though with larger uncertainties than previously estimated. Unlike other possible solutions, the one in which Kepler-51e is around the $2:1$ mean motion resonance with Kepler-51d implies low orbital eccentricities ($\lesssim 0.05$) and comparable masses ($\sim 5\,M_\oplus$) for all four planets, as is seen in other compact multi-planet systems. This work demonstrates the importance of long-term follow-up of TTV systems for probing longer period planets in a system.

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JWST/NIRISS reveals the water-rich "steam world" atmosphere of GJ 9827 d

With sizable volatile envelopes but smaller radii than the solar system ice giants, sub-Neptunes have been revealed as one of the most common types of planet in the galaxy. While the spectroscopic characterization of larger sub-Neptunes (2.5-4R$_\oplus$) has revealed hydrogen-dominated atmospheres, smaller sub-Neptunes (1.6--2.5R$_\oplus$) could either host thin, rapidly evaporating hydrogen-rich atmospheres or be stable metal-rich "water worlds" with high mean molecular weight atmospheres and a fundamentally different formation and evolutionary history. Here, we present the 0.6--2.8$μ$m JWST NIRISS/SOSS transmission spectrum of GJ 9827 d, the smallest (1.98 R$_\oplus$) warm (T$_\mathrm{eq, A_B=0.3} \sim 620$K) sub-Neptune where atmospheric absorbers have been detected to date. Our two transit observations with NIRISS/SOSS, combined with the existing HST/WFC3 spectrum, enable us to break the clouds-metallicity degeneracy. We detect water in a highly metal-enriched "steam world" atmosphere (O/H of $\sim 4$ by mass and H$_2$O found to be the background gas with a volume mixing ratio of >31%). We further show that these results are robust to stellar contamination through the transit light source effect. We do not detect escaping metastable He, which, combined with previous nondetections of escaping He and H, supports the steam atmosphere scenario. In water-rich atmospheres, hydrogen loss driven by water photolysis happens predominantly in the ionized form which eludes observational constraints. We also detect several flares in the NIRISS/SOSS light-curves with far-UV energies of the order of 10$^{30}$ erg, highlighting the active nature of the star. Further atmospheric characterization of GJ 9827 d probing carbon or sulfur species could reveal the origin of its high metal enrichment.

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The Featherweight Giant: Unraveling the Atmosphere of a 17 Myr Planet with JWST

The characterization of young planets (< 300 Myr) is pivotal for understanding planet formation and evolution. We present the 3-5$μ$m transmission spectrum of the 17 Myr, Jupiter-size ($R$ $\sim$10$R_{\oplus}$) planet, HIP 67522 b, observed with JWST/NIRSpec/G395H. To check for spot contamination, we obtain a simultaneous $g$-band transit with SOAR. The spectrum exhibits absorption features 30-50% deeper than the overall depth, far larger than expected from an equivalent mature planet, and suggests that HIP 67522 b's mass is $<$20 $M_{\oplus}$ irrespective of cloud cover and stellar contamination. A Bayesian retrieval analysis returns a mass constraint of $13.8\pm1.0M_{\oplus}$. This challenges the previous classification of HIP 67522 b as a hot Jupiter and instead, positions it as a precursor to the more common sub-Neptunes. With a density of $<$0.10g/cm$^{3}$, HIP 67522 b is one of the lowest density planets known. We find strong absorption from H$_{2}$O and CO$_{2}$ ($\ge7σ$), a modest detection of CO (3.5$σ$), and weak detections of H$_2$S and SO$_2$ ($\simeq2σ$). Comparisons with radiative-convective equilibrium models suggest supersolar atmospheric metallicities and solar-to-subsolar C/O ratios, with photochemistry further constraining the inferred atmospheric metallicity to 3$\times$10 Solar due to the amplitude of the SO$_2$ feature. These results point to the formation of HIP 67522 b beyond the water snowline, where its envelope was polluted by icy pebbles and planetesimals. The planet is likely experiencing substantial mass loss (0.01-0.03 M$_{\oplus}$ Myr$^{-1}$), sufficient for envelope destruction within a Gyr. This highlights the dramatic evolution occurring within the first 100 Myr of its existence.

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Lessons from Hubble and Spitzer: 1D Self-Consistent Model Grids for 19 Hot Jupiter Emission Spectra

We present a population-level analysis of the dayside thermal emission spectra of 19 planets observed with Hubble WFC3 and Spitzer IRAC 3.6 and 4.5 microns, spanning equilibrium temperatures 1200-2700 K and 0.7-10.5 Jupiter masses. We use grids of planet-specific 1D, cloud-free, radiative-convective-thermochemical equilibrium models (1D-RCTE) combined with a Bayesian inference framework to estimate atmospheric metallicity, the carbon-to-oxygen ratio, and day-to-night heat redistribution. In general, we find that the secondary eclipse data cannot reject the physics encapsulated within the 1D-RCTE assumption parameterized with these three variables. We find a large degree of scatter in atmospheric metallicities, with no apparent trend, and carbon-to-oxygen ratios that are mainly consistent with solar or subsolar values but do not exhibit population agreement. Together, these indicate either (1) formation pathways vary over the hot and ultra-hot Jupiter population and/or (2) more accurate composition measurements are needed to identify trends. We also find a broad scatter in derived dayside temperatures that do not demonstrate a trend with equilibrium temperature. Like with composition estimates, this suggests either significant variability in climate drivers over the population and/or more precise dayside temperature measurements are needed to identify a trend. We anticipate that 1D-RCTE models will continue to provide valuable insights into the nature of exoplanet atmospheres in the era of JWST.

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On the Application of Bayesian Leave-One-Out Cross-Validation to Exoplanet Atmospheric Analysis

Over the last decade, exoplanetary transmission spectra have yielded an unprecedented understanding about the physical and chemical nature of planets outside our solar system. Physical and chemical knowledge is mainly extracted via fitting competing models to spectroscopic data, based on some goodness-of-fit metric. However, current employed metrics shed little light on how exactly a given model is failing at the individual data point level and where it could be improved. As the quality of our data and complexity of our models increases, there is an urgent need to better understand which observations are driving our model interpretations. Here we present the application of Bayesian leave-one-out cross-validation to assess the performance of exoplanet atmospheric models and compute the expected log pointwise predictive density (elpd$_\text{LOO}$). elpd$_\text{LOO}$ estimates the out-of-sample predictive accuracy of an atmospheric model at data point resolution providing interpretable model criticism. We introduce and demonstrate this method on synthetic HST transmission spectra of a hot Jupiter. We apply elpd$_\text{LOO}$ to interpret current observations of HAT-P-41b and assess the reliability of recent inferences of H$^-$ in its atmosphere. We find that previous detections of H$^{-}$ are dependent solely on a single data point. This new metric for exoplanetary retrievals complements and expands our repertoire of tools to better understand the limits of our models and data. elpd$_\text{LOO}$ provides the means to interrogate models at the single data point level, a prerequisite for robustly interpreting the imminent wealth of spectroscopic information coming from JWST.

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Inhomogeneous terminators on the exoplanet WASP-39 b

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ μ$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator.

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Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $μ$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $μ$m in the 5-12 $μ$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$σ$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $μ$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

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Hydrogen sulfide and metal-enriched atmosphere for a Jupiter-mass exoplanet

As the closest transiting hot Jupiter to Earth, HD 189733b has been the benchmark planet for atmospheric characterization. It has also been the anchor point for much of our theoretical understanding of exoplanet atmospheres from composition, chemistry, aerosols to atmospheric dynamics, escape, and modeling techniques. Prior studies of HD 189733b have detected carbon and oxygen-bearing molecules H2O and CO in the atmosphere. The presence of CO2 and CH4 has been claimed but later disputed. The inferred metallicity based on these measurements, a key parameter in tracing planet formation locations, varies from depletion to enhancement, hindered by limited wavelength coverage and precision of the observations. Here we report detections of H2O (13.4 sigma), CO2 (11.2 sigma), CO (5 sigma), and H2S (4.5 sigma) in the transmission spectrum (2.4-5 micron) of HD 189733b. With an equilibrium temperature of ~1200K, H2O, CO, and H2S are the main reservoirs for oxygen, carbon, and sulfur. Based on the measured abundances of these three major volatile elements, we infer an atmospheric metallicity of 3-5 times stellar. The upper limit on the methane abundance at 5 sigma is 0.1 ppm which indicates a low carbon-to-oxygen ratio (<0.2), suggesting formation through the accretion of water-rich icy planetesimals. The low oxygen-to-sulfur and carbon-to-sulfur ratios also support the planetesimal accretion formation pathway.

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Multiple Clues for Dayside Aerosols and Temperature Gradients in WASP-69 b from a Panchromatic JWST Emission Spectrum

WASP-69 b is a hot, inflated, Saturn-mass planet 0.26 Mjup with a zero-albedo equilibrium temperature of 963 K. Here, we report the JWST 2 to 12 um emission spectrum of the planet consisting of two eclipses observed with NIRCam grism time series and one eclipse observed with MIRI LRS. The emission spectrum shows absorption features of water vapor, carbon dioxide and carbon monoxide, but no strong evidence for methane. WASP-69 b's emission spectrum is poorly fit by cloud-free homogeneous models. We find three possible model scenarios for the planet: 1) a Scattering Model that raises the brightness at short wavelengths with a free Geometric Albedo parameter 2) a Cloud Layer model that includes high altitude silicate aerosols to moderate long wavelength emission and 3) a Two-Region model that includes significant dayside inhomogeneity and cloud opacity with two different temperature-pressure profiles. In all cases, aerosols are needed to fit the spectrum of the planet. The Scattering model requires an unexpectedly high Geometric Albedo of 0.64. Our atmospheric retrievals indicate inefficient redistribution of heat and an inhomogeneous dayside distribution, which is tentatively supported by MIRI LRS broadband eclipse maps that show a central concentration of brightness. Our more plausible models (2 and 3) retrieve chemical abundances enriched in heavy elements relative to solar composition by 6x to 14x solar and a C/O ratio of 0.65 to 0.94, whereas the less plausible highly reflective scenario (1) retrieves a slightly lower metallicity and lower C/O ratio.

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