arXiv subjects

M. G. Kozlov

Publications and source records attributed to M. G. Kozlov.

At least 55 records · Page 3Linked to original sources

arXiv2016

Prediction of quantum many-body chaos in protactinium atom

Energy level spectrum of protactinium atom (Pa, Z=91) is simulated with a CI calculation. Levels belonging to the separate manifolds of a given total angular momentum and parity $J^π$ exhibit distinct properties of many-body quantum chaos. Moreover, an extremely strong enhancement of small perturbations takes place. As an example, effective three-electron interaction is investigated and found to play a significant role in the system. Chaotic properties of the eigenstates allow one to develop a statistical theory and predict probabilities of different processes in chaotic systems.

physics.atom-ph↗

arXiv2016

Effective three particle forces in polyvalent atoms

We study effective three-particle interactions between valence electrons, which are induced by the core polarization. Such interactions are enhanced when valence orbitals have strong overlap with the outermost core shell, in particular for the systems with partially filled f-shell. We find that in certain cases the three-particle contributions are large, affecting the order of energy levels, and need to be included in high-precision calculations.

physics.atom-ph↗

arXiv2016

QED shifts in multivalent heavy ions

The quantum electrodynamics (QED) corrections are directly incorporated into the most accurate treatment of the correlation corrections for ions with complex electronic structure of interest to metrology and tests of fundamental physics. We compared the performance of four different QED potentials for various systems to access the accuracy of QED calculations and to make prediction of highly charged ion properties urgently needed for planning future experiments. We find that all four potentials give consistent and reliable results for ions of interest. For the strongly bound electrons the nonlocal potentials are more accurate than the local potential.

physics.atom-ph↗

arXiv2015

A development of the CI + all-order method and application to the parity-nonconserving amplitude and other properties of Pb

We have further developed and extended a method for calculation of atomic properties based on a combination of the configuration interaction and coupled-cluster approach. We have applied this approach to the calculation of different properties of atomic lead, including the energy levels, hyperfine structure constants, electric-dipole transition amplitudes, and E1 parity nonconserving (PNC) amplitude for the (6p^2) ^3P_0 - (6p^2) ^3P_1 transition. The uncertainty of the E1 PNC amplitude was reduced by a factor of two in comparison with the previous most accurate calculation [V.~A.~Dzuba et.al., Europhys. Lett. 7, 413 (1988)]. Our value for the weak charge Q_W=-117(5) is in agreement with the standard model prediction.

physics.atom-ph↗

arXiv2015

Observation of an unexpected negative isotope shift in 229Th+ and its theoretical explanation

We have measured the hyperfine structure and isotope shifts of the 402.0 nm and 399.6 nm resonance lines in 229Th+. These transitions could provide pathways towards the 229Th isomeric nuclear state excitation. An unexpected negative isotope shift relative to 232Th+ is observed for the 399.6 nm line, indicating a strong Coulomb coupling of the excited state to the nucleus. We have developed a new all-order approach to the isotope shift calculations that is generally applicable to heavy atoms and ions with several valence electrons. The theoretical calculations provide an explanation for the negative isotope shift of the 399.6 nm transition and yield a corrected classification of the excited state. The calculated isotope shifts are in good agreement with experimental values.

physics.atom-ph↗

arXiv2015

Correlation, Breit, and QED effects in spectra of Mg-like ions

We calculated spectra of the first six members of the Mg-like isoelectronic sequence using different approximations. The most accurate results were obtained with the configuration interaction + all order method (CI+AO), which provided relative accuracy for transition energies on the level of 0.1\%, or better. On this level of accuracy the Breit and QED corrections become important for the systems with nuclear charge $Z\gtrsim 20$. The retardation part of the Breit interaction and QED corrections for the partial waves with $l\ne 0$ are still too small to be important.

physics.atom-ph↗

arXiv2015

Gluon Reggeization in Yang-Mills Theories

The proof of the multi-Regge form of multiple production amplitudes in the next-to-leading logarithmic approximation is presented for Yang-Mills theories with fermions and scalars in any representations of the colour group and with any Yukawa-type interaction. Explicit expressions for the Reggeized gauge boson trajectory, the Reggeon vertices and the impact factors are given. Fulfilment of the bootstrap conditions is proved.

hep-th↗

arXiv2015

Coherent and stochastic contributions of compound resonances in atomic processes: Electron recombination, photoionization and scattering

In open-shell atoms and ions, processes such as photoionization, combination (Raman) scattering, electron scattering and recombination, are often mediated by many-electron compound resonances. We show that their interference (neglected in the independent-resonance approximation) leads to a coherent contribution, which determines the energy-averaged total cross sections of electron- and photon-induced reactions obtained using the optical theorem. In contrast, the partial cross sections (e.g., electron recombination, or photon Raman scattering) are dominated by the stochastic contributions. Thus, the optical theorem provides a link between the stochastic and coherent contributions of the compound resonances. Similar conclusions are valid for reactions via compound states in molecules and nuclei.

physics.atom-ph↗

arXiv2015

Effective vertex of quark production in collision of Reggeized quark and gluon

We calculated the effective vertex of the quark production in the collision of Reggeized quark and Reggeized gluon in the next-to-leading order (NLO). The vertex in question is the missing component of the multi-Regge NLO amplitudes with the quark and gluon exchanges in $t_i$ channels. The calculation allows us to develop the bootstrap approach to the quark Reggeization proof within next-to-leading logarithmic approximation.

hep-ph↗

arXiv2014

Atomic properties of Cd-like and Sn-like ions for the development of frequency standards and search for the variation of the fine-structure constant

A high-precision relativistic calculations of Cd-like Nd$^{12+}$, Sm$^{14+}$ and Sn-like Pr$^{9+}$, Nd$^{10+}$ atomic properties is carried out using an approach that combines configuration interaction and a linearized coupled-cluster method. These ions have long-lived metastable states with transitions accessible by laser excitations, relatively simple electronic structure, high sensitivity to $α$ variation, and stable isotopes. Breit and QED corrections were included into the calculations. Energies, transition wavelengths, electric- and magnetic-multipole reduced matrix elements, lifetimes, and sensitivity coefficients $q$ and $K$ to the variation of the fine-structure constant $α$ were obtained. A detailed study of uncertainties was performed. Energies for similar Cd-like Ba$^{8+}$, La$^{9+}$, Ce$^{10+}$, Pr$^{11+}$ and Sn-like Ba$^{6+}$ ions were calculated and compared with experiment for further tests of the accuracy.

physics.atom-ph↗

arXiv2014

Sensitivity coefficients to $α$-variation for astrophysically relevant transitions in Ni II

We calculated the dependence of the transition frequencies on the fine-structure constant $α$ ($q$-factors) for Ni~II. Nickel is one of the few elements with high sensitivity to $α$-variation, whose lines are observed at high redshifts. This makes it a sensitive probe for $α$-variation on the cosmological timescale. The electronic structure of Ni II ion was treated within the configuration interaction (CI) method using Dirac-Coulomb Hamiltonian.

physics.atom-ph↗

arXiv2014

Time-reversal symmetry violation in molecules induced by nuclear magnetic quadrupole moments

Recent measurements in paramagnetic molecules improved the limit on the electron electric dipole moment (EDM) by an order of magnitude. Time-reversal (T) and parity (P) symmetry violation in molecules may also come from their nuclei. We point out that nuclear T,P-odd effects are amplified in paramagnetic molecules containing deformed nuclei, where the primary effects arise from the T,P-odd nuclear magnetic quadrupole moment (MQM). We perform calculations of T,P-odd effects in the molecules TaN, ThO, ThF$^+$, HfF$^+$, YbF, HgF, and BaF induced by MQMs. We compare our results with those for the diamagnetic TlF molecule, where the T,P-odd effects are produced by the nuclear Schiff moment. We argue that measurements in molecules with MQMs may provide improved limits on the strength of T,P-odd nuclear forces, on the proton, neutron and quark EDMs, on quark chromo-EDMs, and on the QCD $θ$-term and CP-violating quark interactions.

physics.atom-ph↗

arXiv2014

Study of highly-charged Ag-like and In-like ions for the development of atomic clocks and search for $α$-variation

We carried out detailed high-precision study of Ag-like Nd$^{13+}$, Sm$^{15+}$ and In-like Ce$^{9+}$, Pr$^{10+}$, Nd$^{11+}$, Sm$^{13+}$, Eu$^{14+}$ highly-charged ions. These ions were identified to be of particular interest to the development of ultra-accurate atomic clocks, search for variation of the fine-structure constant $α$, and quantum information [Safronova et. al. Phys. Rev. Lett. 113, 030801 (2014)]. Relativistic linearized coupled-cluster method was used for Ag-like ion calculations, and a hybrid approach that combines configuration interaction and a variant of the coupled-cluster method was used for the In-like ion calculations. Breit and QED corrections were included. Energies, transition wavelengths, electric-dipole, electric-quadrupole, electric-octupole, magnetic-dipole, magnetic-quadrupole, magnetic-octupole reduced matrix elements, lifetimes, and sensitivity coefficients to $α$-variation were calculated. Detailed study of various contributions was carried out to evaluate uncertainties of the final results. Energies for several similar "reference" ions, where the experimental values are available were calculated and compared with experiment for further tests of the accuracy.

physics.atom-ph↗

arXiv2014

Highly-charged ions for atomic clocks, quantum information, and search for $α$-variation

We propose 10 highly-charged ions as candidates for the development of next generation atomic clocks, quantum information, and search for $α$-variation. They have long-lived metastable states with transition frequencies to the ground state between 170-3000 nm, relatively simple electronic structure, stable isotopes and high sensitivity to $α$-variation (e.g., Sm$^{14+}$, Pr$^{10+}$, Sm$^{13+}$, Nd$^{10+}$). We predict their properties crucial for the experimental exploration and highlight particularly attractive systems for these applications.

physics.atom-ph↗

arXiv2014

Stark shift and parity non-conservation for near-degenerate states of xenon

We identify a pair of near-degenerate states of opposite parity in atomic Xe, the $5p^5 10s \,\, ^2[3/2]_2^o$ at $\rm{E}=94759.927$ cm$^{-1}$ and $5p^5 6f \,\, ^2[5/2]_2$ at $\rm{E}= 94759.935$ cm$^{-1}$, for which parity- and time-odd effects are expected to be enhanced by the small energy separation. We present theoretical calculations which indicate narrow widths for both states and we report a calculated value for the weak matrix element, arising from configuration mixing, of $|W|=2.1$ Hz for $^{132}$Xe. In addition, we measured the Stark effect of the $5p^5\,6f$ $^2[5/2]_{2}$ and $5p^5 \,6f \ ^2[3/2]_2$ ($\rm{E} =94737.121\,\rm{cm}^{-1}$) states. The Stark-shift of the $6f$ states is observed to be negative, revealing the presence of nearby $6g$ states at higher energies, which have not been observed before. The Stark-shift measurements imply an upper limit on the weak matrix element of $|W|\!<\!5$ Hz for the near-degenerate states ($10s \,\, ^2[3/2]_2^o$ and $6f \,\, ^2[5/2]_2$), which is in agreement with the presented calculations.

physics.atom-ph↗

arXiv2014

Sensitivity of Tunneling-Rotational Transitions in Ethylene Glycol to Variation of Electron-to-Proton Mass Ratio

Ethylene glycol in its ground conformation has tunneling transition with the frequency about 7 GHz. This leads to a rather complicated tunneling-rotational spectrum. Because tunneling and rotational energies have different dependence on the electron-to-proton mass ratio $μ$, this spectrum is highly sensitive to the possible $μ$ variation. We used simple 14 parameter effective Hamiltonian to calculate dimensionless sensitivity coefficients $Q_μ$ of the tunneling-rotational transitions and found that they lie in the range from $-17$ to $+18$. Ethylene glycol has been detected in the interstellar medium. All this makes it one of the most sensitive probes of $μ$ variation at the large space and time scales.

physics.atom-ph↗

arXiv2014

Zeeman-tuned rotational level-crossing spectroscopy in a diatomic free radical

Rotational levels of molecular free radicals can be tuned to degeneracy using laboratory-scale magnetic fields. Because of their intrinsically narrow width, these level crossings of opposite-parity states have been proposed for use in the study of parity-violating interactions and other applications. We experimentally study a typical manifestation of this system using $^{138}$BaF. Using a Stark-mixing method for detection, we demonstrate level-crossing signals with spectral width as small as 6 kHz. We use our data to verify the predicted lineshapes, transition dipole moments, and Stark shifts, and to precisely determine molecular magnetic g-factors. Our results constitute an initial proof-of-concept for use of this system to study nuclear spin-dependent parity violating effects.

physics.atom-ph↗

arXiv2013

Electron recombination, photoionization and scattering via many-electron compound resonances

Highly excited eigenstates of atoms and ions with open f shell are chaotic superpositions of thousands, or even millions of Hartree-Fock determinant states. The interaction between dielectronic and multielectronic configurations leads to the broadening of dielectronic recombination resonances and relative enhancement of photon emission due to opening of thousands of radiative decay channels. The radiative yield is close to 100% for electron energy . 1 eV and rapidly decreases for higher energies due to opening of many autoionization channels. The same mechanism predicts suppression of photoionization and relative enhancement of the Raman scattering. Results of our calculations of the recombination rate are in agreement with the experimental data for W20+ and Au25+.

physics.atom-ph↗