arXiv subjects

M. G. Kozlov

Publications and source records attributed to M. G. Kozlov.

At least 37 records · Page 2Linked to original sources

arXiv2020

Predicting quasibound states of negative ions

We demonstrated the accurate prediction of a quasibound spectrum of a negative ion using a novel high-precision theoretical approach. We used La$^-$ as a test case due to a recent experiment that measured energies of 11 resonances in its photodetachment spectrum attributed to transitions to quasibound states [C. W. Walter et al., PRA, in press (2020); arXiv:2010.01122]. We identified all of the observed resonances, and predicted one more peak just outside the range of the prior experiment. Following the theoretical prediction, the peak was observed at the predicted wavelength, validating the identification. The same approach is applicable to a wide range of negative ions. Moreover, theory advances reported in this work can be used for massive generation of atomic transition properties for neutrals and positive ions needed for a variety of applications.

physics.atom-ph↗

arXiv2020

Constraints on the electron-to-proton mass ratio variation at the epoch of reionization

Far infrared fine-structure transitions of CI and CII and rotational transitions of CO are used to probe hypothetical variations of the electron-to-proton mass ratio mu = m_e/m_p at the epoch of reionization (z > 6). A constraint on Delta mu/mu = (mu_obs - mu_lab)/mu_lab = (0.7 +/- 1.2)x10^-5 (1sigma) obtained at = 6.31 is the most stringent up-to-date limit on the variation of mu at such high redshift. For all available estimates of Delta mu/mu ranging between z = 0 and z = 1100, - the epoch of recombination, - a regression curve Delta mu/mu = k_mu (1+z)^p, with k_mu = (1.6 +/- 0.3) x10^-8 and p = 2.00 +/- 0.03, is deduced. If confirmed, this would imply a dynamical nature of dark matter/dark energy.

astro-ph.CO↗

arXiv2020

Calculation of hyperfine magnetic anomaly in many-electron atoms

The precision measurements of the ratio of hyperfine structure constants for $s_{1/2}$ and $p_{1/2}$ states allow us to estimate the difference between hyperfine magnetic anomalies for these levels. We calculate the atomic factor in order to recover the absolute values of the hyperfine magnetic anomalies from their difference. Taking into account the hyperfine anomaly correction allows one to increase the accuracy of determining the g-factors of short-lived isotopes by more than an order of magnitude.

physics.atom-ph↗

arXiv2020

Optical clocks based on the Cf$^{15+}$ and Cf$^{17+}$ ions

Recent experimental progress in cooling, trapping, and quantum logic spectroscopy of highly-charged ions (HCIs) made HCIs accessible for high resolution spectroscopy and precision fundamental studies. Based on these achievements, we explore a possibility to develop optical clocks using transitions between the ground and a low-lying excited state in the Cf$^{15+}$ and Cf$^{17+}$ ions. Using a high-accuracy relativistic method of calculation we predicted the wavelengths of clock transitions, calculated relevant atomic properties, and analyzed a number of systematic effects (such as the electric quadrupole-, micromotion-, and quadratic Zeeman shifts of the clock transitions) that affect the accuracy and stability of the optical clocks. We also calculated magnetic dipole hyperfine-structure constants of the clock states and the blackbody radiation shifts of the clock transitions.

physics.atom-ph↗

arXiv2019

Accurate prediction of clock transitions in a highly charged ion with complex electronic structure

We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel atomic clocks with high sensitivity to the variation of the fine-structure constant and dark matter searches. The clock transitions are weak and very difficult to identity without accurate theoretical predictions. In the case of Ir$^{17+}$, even stronger electric-dipole (E1) transitions eluded observation despite years of effort raising the possibility that theory predictions are grossly wrong. In this work, we provide accurate predictions of transition wavelengths and E1 transition rates in Ir$^{17+}$. Our results explain the lack of observation of the E1 transitions and provide a pathway towards detection of clock transitions. Computational advances demonstrated in this work are widely applicable to most elements in the periodic table and will allow to solve numerous problems in atomic physics, astrophysics, and plasma physics.

physics.atom-ph↗

arXiv2019

Dependence of atomic parity-violation effects on neutron skins and new physics

We estimate the relative contribution of nuclear structure and new physics couplings to the parity non-conserving spin-independent effects in atomic systems, for both single isotopes and isotopic ratios. General expressions are presented to assess the sensitivity of isotopic ratios to neutron skins and to couplings beyond standard model at tree level. The specific coefficients for these contributions are calculated assuming Fermi distribution for proton and neutron nuclear densities for isotopes of Cs, Ba, Sm, Dy, Yb, Pb, Fr, and Ra. The present work aims to provide a guide to the choice of the best isotopes and pairs of isotopes for conducting atomic PNC measurements.

physics.atom-ph↗

arXiv2018

Fast configuration-interaction calculations for nobelium and ytterbium

We calculate excitation energies for low states of nobelium, including states with open $5f$ subshell. An efficient version of the many-electron configuration-interaction method for treating the atom as a sixteen external electrons system has been developed and used. The method is tested on calculations for ytterbium which has external electron structure similar to nobelium. The results for nobelium are important for prediction of its spectrum and for interpretation of recent measurements. Ytterbium is mostly used to study the features of the method.

physics.atom-ph↗

arXiv2018

Hyperfine induced transitions 1S0 - 3D1 in Yb

Parity violation experiment in Yb is made on the strongly forbidden M1 transition 6s^2 1S0 \to 5d6s 3D1. The hyperfine mixing of the 5d6s 3D1 and 5d6s 3D2 levels opens E2 channel, whose amplitude differs for F-sublevels of the 3D1 level. This effect may be important for the experimental search for the nuclear-spin-dependent parity violation effects predominantly caused by the nuclear anapole moment.

physics.atom-ph↗

arXiv2018

Sensitivity coefficients to variation of fundamental constants

Atoms and molecules can serve as sensitive probes of a possible variation of the fine structure constant $α$ and electron-to-proton mass ratio $μ$. Two types of sensitivity coefficients are often used to quantify and compare the sensitivity of different species to the variation of fundamental constants. The dimensionless coefficients $K$ are related to the fractional sensitivity, while dimensional factors $q$ are related to the absolute sensitivity. Here we discuss several common errors and misconceptions regarding these coefficients that frequently appear in the literature.

physics.atom-ph↗

arXiv2018

Nuclear charge radii of $^{229}$Th from isotope and isomer shifts

The isotope $^{229}$Th is unique in that it possesses an isomeric state of only a few eV above the ground state, suitable for nuclear laser excitation. An optical clock based on this transition is expected to be a very sensitive probe for variations of fundamental constants, but the nuclear properties of both states have to be determined precisely to derive the actual sensitivity. We carry out isotope shift calculations in Th$^+$ and Th$^{2+}$ including the specific mass shift, using a combination of configuration interaction and all-order linearized coupled-cluster methods and estimate the uncertainty of this approach. We perform experimental measurements of the hyperfine structure of Th$^{2+}$ and isotopic shift between $^{229}$Th$^{2+}$ and $^{232}$Th$^{2+}$ to extract the difference in root-mean-square radii as $δ\langle r^{2} \rangle^{232,229}=0.299(15)$ fm$^2$. Using the recently measured values of the isomer shift of lines of $^{229\textrm{m}}$Th, we derive the value for the mean-square radius change between $^{229}$Th and its low lying isomer $^{229\textrm{m}}$Th to be $δ\langle r^2 \rangle^{229\textrm{m},229} = 0.0105(13)\,{\rm fm}^2$.

physics.atom-ph↗

arXiv2018

Calculation of francium hyperfine anomaly

The Dirac-Hartree-Fock plus many-body perturbation theory (DHF+MBPT) method has been used to calculate hyperfine structure constants for Fr. Calculated hyperfine structure anomaly for hydrogen-like ion has been shown to be in good agreement with analytical expressions. It has been shown that the ratio of the anomalies for $s$ and $p_{1/2}$ states is weakly dependent on the principal quantum number. Finally, we estimate Bohr--Weisskopf corrections for several Fr isotopes. Our results may be used to improve experimental accuracy for the nuclear $g$ factors of short-lived isotopes.

physics.atom-ph↗

arXiv2018

Highly charged ions: optical clocks and applications in fundamental physics

Recent developments in frequency metrology and optical clocks have been based on electronic transitions in atoms and singly charged ions as references. These systems have enabled relative frequency uncertainties at a level of a few parts in $10^{-18}$. This accomplishment not only allows for extremely accurate time and frequency measurements, but also to probe our understanding of fundamental physics, such as variation of fundamental constants, violation of the local Lorentz invariance, and forces beyond the Standard Model of Physics. In addition, novel clocks are driving the development of sophisticated technical applications. Crucial for applications of clocks in fundamental physics are a high sensitivity to effects beyond the Standard Model and Einstein's Theory of Relativity and a small frequency uncertainty of the clock. Highly charged ions offer both. They have been proposed as highly accurate clocks, since they possess optical transitions which can be extremely narrow and less sensitive to external perturbations compared to current atomic clock species. The selection of highly charged ions in different charge states offers narrow transitions that are among the most sensitive ones for a change in the fine-structure constant and the electron-to-proton mass ratio, as well as other new physics effects. Recent advances in trapping and sympathetic cooling of highly charged ions will in the future enable high accuracy optical spectroscopy. Progress in calculating the properties of selected highly charged ions has allowed the evaluation of systematic shifts and the prediction of the sensitivity to the "new physics" effects. This article reviews the current status of theory and experiment in the field.

physics.atom-ph↗

arXiv2017

Atomic properties of actinide ions with particle-hole configurations

We study the effects of higher-order electronic correlations in the systems with particle-hole excited states using a relativistic hybrid method that combines configuration interaction and linearized coupled-cluster approaches. We find the configuration interaction part of the calculation sufficiently complete for eight electrons while maintaining good quality of the effective coupled-cluster potential for the core. Excellent agreement with experiment was demonstrated for a test case of La$^{3+}$. We apply our method for homologue actinide ions Th$^{4+}$ and U$^{6+}$ which are of experimental interest due to a puzzle associated with the resonant excitation Stark ionization spectroscopy (RESIS) method. These ions are also of interest to actinide chemistry and this is the first precision calculation of their atomic properties.

physics.atom-ph↗

arXiv2017

Multipolar polarizabilities and hyperpolarizabilities in the Sr optical lattice clock

We address the problem of the lattice Stark shifts in the Sr clock caused by the multipolar $M1$ and $E2$ atom-field interactions and by the term nonlinear in lattice intensity and determined by the hyperpolarizability. We have developed an approach to calculate hyperpolarizabilities for atoms and ions based on a solution of the inhomogeneous equation which allows to effectively and accurately carry out complete summations over intermediate states. We applied our method to the calculation of the hyperpolarizabilities for the clock states in Sr. We also carried out an accurate calculation of the multipolar polarizabilities for these states at the magic frequency. Understanding these Stark shifts in optical lattice clocks is crucial for further improvement of the clock accuracy.

physics.atom-ph↗

arXiv2017

Relativistic all-order many-body calculation of energies, wavelengths, and $M1$ and $E2$ transition rates for the $3d^n$ configurations in tungsten ions

Energy levels, wavelengths, magnetic-dipole and electric-quadrupole transition rates between the low-lying states are evaluated for W$^{51+}$ to W$^{54+}$ ions with $3d^n$ (n = 2 to 5) electronic configurations using an approach combining configuration interaction with linearized coupled-cluster single-double method. The QED corrections are directly incorporated into the calculations and their effect is studied in detail. Uncertainties of the calculations are discussed. This first study of such highly charged ions with the present method opens the way for future applications allowing an accurate prediction of properties for a very wide range of highly charged ions aimed at providing precision benchmarks for various applications.

physics.atom-ph↗

arXiv2017

Calculation of thallium hyperfine anomaly

We suggest a method to calculate hyperfine anomaly for many-electron atoms and ions. At first, we tested this method by calculating hyperfine anomaly for hydrogen-like thallium ion and obtained fairly good agreement with analytical expressions. Then we did calculations for the neutral thallium and tested an assumption, that the the ratio between the anomalies for $s$ and $p_{1/2}$ states is the same for these two systems. Finally, we come up with recommendations about preferable atomic states for the precision measurements of the nuclear $g$ factors.

physics.atom-ph↗

arXiv2017

Fine-structure transitions as a tool for studying variation of alpha at high redshifts

Star-forming galaxies at high redshifts are the ideal targets to probe the hypothetical variation of the fine-structure constant alpha over cosmological time scales. We propose a modification of the alkali doublets method which allows us to search for variation in alpha combining far infrared and submillimeter spectroscopic observations. This variation manifests as velocity offsets between the observed positions of the fine-structure and gross-structure transitions when compared to laboratory wavelengths. Here we describe our method whose sensitivity limit to the fractional changes in alpha is about 5*10^-7. We also demonstrate that current spectral observations of hydrogen and [C II] 158 micron lines provide an upper limit on |Delta alpha/alpha| < 6*10^-5 at redshifts z = 3.1 and z = 4.7.

astro-ph.CO↗

arXiv2016

Precision calculation of energy levels for four-valent Si I

We report results of the calculation of the low-lying levels of neutral Si using a combination of the configuration interaction and many-body perturbation theory (CI+MBPT method). We treat Si I as an atom with four valence electrons and use two different starting approximations, namely $V^{N-2}$ and $V^{N-4}$. We conclude that both approximations provide comparable accuracy, on the level of 1%.

physics.atom-ph↗