arXiv subjects

M. Gerin

Publications and source records attributed to M. Gerin.

At least 19 recordsLinked to original sources

arXiv2026

HyGAL: Characterizing the Galactic ISM with observations of hydrides and other small molecules. III. The absorption lines of [O I], CH, and OH

The HyGAL Stratospheric Observatory for Infrared Astronomy (SOFIA) legacy program aims at characterizing the interstellar medium in the Milky Way using hydrides, [C II], and [O I] absorption lines with the 2.7 m SOFIA telescope toward twenty-five submillimeter-bright Galactic star-forming regions. As part of HyGAL, we investigated correlations among the known H$_2$ tracers -- CH and OH from SOFIA observations, and HCO$^+$ and CCH from ancillary absorption line data from ground-based telescopes. We also examined the abundance variation of neutral atomic oxygen, [O I], observed in absorption. CH, OH, HCO$^+$, and CCH all exhibit strong mutual correlations. OH in particular shows tight correlations with HCO$^+$ and CCH, reflecting their linked chemical and physical pathways. Column density ratios among these H$_2$ tracers are consistent with previous measurements in local diffuse clouds and remain uniform across Galactic environments and velocity intervals. The gas phase oxygen abundance relative to total hydrogen, $\langle X$(O)$\rangle=N$(O)/$N$(H$_{\rm total}$), is $(3.09\pm0.64)\times10^{-4}$, slightly below the elemental solar value but consistent with the previous observations measuring gas-phase abundances. We also find that $N$(HI) decreases toward the regions where the molecular fraction exceeds $f_{H_2}^N \sim 0.5$, marking the onset of the molecular phase. While the atomic oxygen abundance remains roughly constant, the abundances of OH, HCO$^+$, and CCH increase with the molecular fraction. Gas traced by the HCO$^+$ absorption corresponds to higher molecular fractions than that traced by HI and hydride ions, highlighting density variations in the diffuse-to-translucent ISM along different lines of sight.

astro-ph.GA↗

arXiv2025

A sub-ppm upper limit on the cosmological variations of the fine structure constant alpha

Absorption spectroscopy toward high-redshift quasars provides strong constraints on the putative variation of fundamental constants of physics on cosmological time scales. The submillimeter ground-state transitions of methylidyne (CH) and water (H2O), both molecules widespread and coeval in the interstellar medium, provide a sensitive test for variations of alpha, the fine structure constant, and mu, the proton-to-electron mass ratio, taking advantage of the unmatched spectral resolution and frequency reliability of radio techniques. We used ALMA simultaneous observations of the two species to constrain any velocity offset between their absorption profiles toward the radio-bright lensed quasars PKS1830-211 (z_abs=0.88582) and B0218+357 (z_abs=0.68466). Our observational setup minimizes instrumental errors and known sources of systematics, such as time variability of the absorption profile and frequency-dependent morphology of the background quasar. The excellent correlation between CH and H2O opacities, the large number of individual narrow velocity components, and the number of independent spectra obtained due to the intrinsic time variability of the absorption profiles ensure that even the chemical segregation bias is minimized. We obtained bulk velocity shifts delta_v = -0.048 pm 0.028 km/s and -0.13 pm 0.14 km/s (1 sigma confidence level) between CH and H2O in the direction of PKS1830-211(NE) and B0218+357(SW), respectively. These values convert into the 3sigma upper limits |Delta_alpha/alpha| < 0.55 ppm and 1.5 ppm, respectively, taking into account the independent upper limits on |Delta_mu/mu| previously obtained for these systems. These constraints on |Delta_alpha/alpha|, at look-back times of about half the present age of the Universe, are two to four times deeper than previous constraints on any other single high-z system.

astro-ph.CO↗

arXiv2025

PDRs4All. XII. FUV-driven formation of hydrocarbon radicals and their relation with PAHs

We present subarcsecond-resolution ALMA mosaics of the Orion Bar PDR in [CI] 609um, C2H (4-3), and C18O (3-2) emission lines complemented by JWST images of H2 and aromatic infrared band (AIB) emission. The rim of the Bar shows very corrugated structures made of small-scale H2 dissociation fronts (DFs). The [CI] 609 um emission peaks very close (~0.002 pc) to the main H2-emitting DFs, suggesting the presence of gas density gradients. These DFs are also bright and remarkably similar in C2H emission, which traces "hydrocarbon radical peaks" characterized by very high C2H abundances, reaching up to several x10^-7. The high abundance of C2H and of related hydrocarbon radicals, such as CH3, CH2, and CH, can be attributed to gas-phase reactions driven by elevated temperatures, the presence of C+ and C, and the reactivity of FUV-pumped H2. The hydrocarbon radical peaks roughly coincide with maxima of the 3.4/3.3 um AIB intensity ratio, a proxy for the aliphatic-to-aromatic content of PAHs. This implies that the conditions triggering the formation of simple hydrocarbons also favor the formation (and survival) of PAHs with aliphatic side groups, potentially via the contribution of bottom-up processes in which abundant hydrocarbon radicals react in situ with PAHs. Ahead of the DFs, in the atomic PDR zone (where [H]>>[H2]), the AIB emission is the brightest, but small PAHs and carbonaceous grains undergo photo-processing due to the stronger FUV field. Our detection of trace amounts of C2H in this zone may result from the photoerosion of these species. This study provides a spatially resolved view of the chemical stratification of key carbon carriers in a PDR. Overall, both bottom-up and top-down processes appear to link simple hydrocarbon molecules with PAHs in molecular clouds; however, the exact chemical pathways and their relative contributions remain to be quantified.

astro-ph.GA↗

arXiv2024

PDRs4All. X. ALMA and JWST detection of neutral carbon in the externally irradiated disk d203-506: Undepleted gas-phase carbon

The gas-phase abundance of carbon, x_C = C/H, and its depletion factors are essential parameters for understanding the gas and solid compositions that are ultimately incorporated into planets. The majority of protoplanetary disks are born in clusters and, as a result, are exposed to external FUV radiation. These FUV photons potentially affect the disk's evolution, chemical composition, and line excitation. We present the first detection of the [CI]609um fine-structure line of neutral carbon (CI), achieved with ALMA, toward one of these disks, d203-506, in the Orion Nebula Cluster. We also report the detection of CI forbidden and permitted lines (from electronically excited states up to 10 eV) observed with JWST in the IR. These lines trace the irradiated outer disk and photo-evaporative wind. Contrary to the common belief that these IR lines are C+ recombination lines, we find that they are dominated by FUV-pumping of CI followed by fluorescence cascades. They trace the transition from atomic to molecular gas, and their intensities scale with G0. The lack of outstanding IR OI fluorescent emission, however, implies a sharper attenuation of external FUV radiation with E > 12 eV (~Lyman-beta). This is related to a lower effective FUV dust absorption cross section compared to that of interstellar grains, implying a more prominent role for FUV shielding by the CI photoionization continuum. The [CI]609um intensity is proportional to N(CI) and can be used to infer x_C. We derive x_C ~ 1.4E-4. This implies that there is no major depletion of volatile carbon compared to x_C measured in the natal cloud, hinting at a young disk. We also show that external FUV radiation impacts the outer disk and wind by vertically shifting the water freeze-out depth, which results in less efficient grain growth and settling. This shift leads to nearly solar gas-phase C/O abundance ratios in these irradiated layers.

astro-ph.GA↗

arXiv2024

Grain growth and its chemical impact in the first hydrostatic core phase

The first hydrostatic core (FHSC) phase is a brief stage in the protostellar evolution that is difficult to detect. Our goal is to characterize the chemical evolution of gas and dust during the formation of the FHSC. Moreover, we are interested in analyzing, for the first time with 3D magnetohydrodynamic (MHD) simulations, the role of grain growth in its chemistry. We postprocessed $2\times10^{5}$ tracer particles from a $\texttt{RAMSES}$ non-ideal MHD simulation using the codes $\texttt{NAUTILUS}$ and $\texttt{SHARK}$ to follow the chemistry and grain growth throughout the simulation. A great chemical inheritance is seen, as gas-phase abundances of most of the C, O, N, and S reservoirs in the hot corino at the end of the simulation match the ice-phase abundances from the prestellar phase. Additionally, interstellar complex organic molecules (iCOMs) such as methyl formate, acetaldehyde, and formamide are formed during the warm-up process. The typical grain size in the hot corino $(n_{\rm H}>10^{11}\ {\rm cm^{-3}})$ increases forty-fold during the last 30 kyr, with negligible effects on its chemical composition. At moderate densities $(10^{10}<n_{\rm H}<10^{11}\ {\rm cm^{-3}})$ and cool temperatures $15<T<50$ K, increasing grain sizes delay molecular depletion. Finally, at low densities $(n_{\rm H}\sim10^{7}\ {\rm cm^{-3}})$, grains do not grow significantly. We also compared our results with a two-step model that reproduces well the abundances of C and O reservoirs, but not the N and S reservoirs. We conclude that the chemical composition of the FHSC is heavily determined by that of the parent prestellar core, chemo-MHD computations are needed for an accurate prediction of the abundances of the main N and S elemental reservoirs, and that the impact of grain growth in moderately dense areas delaying depletion permits the use of abundance ratios as grain growth proxies.

astro-ph.GA↗

arXiv2024

Protonated acetylene in the z=0.89 molecular absorber toward PKS1830-211

We report the first interstellar identification of protonated acetylene, C2H3+, a fundamental hydrocarbon, in the z=0.89 molecular absorber toward the gravitationally lensed quasar PKS1830-211. The molecular species is identified from clear absorption features corresponding to the 2_12-1_01 (rest frequency 494.034 GHz) and 1_11-0_00 (431.316 GHz) ground-state transitions of ortho and para forms of C2H3+, respectively, in ALMA spectra toward the southwestern image of PKS1830-211, where numerous molecules, including other hydrocarbons, have already been detected. From the simple assumption of local thermodynamic equilibrium (LTE) with cosmic microwave background photons and an ortho-to-para ratio of three, we estimate a total C2H3+ column density of 2 x 10^12 cm^-2 and an abundance of 10^-10 compared to H_2. However, formation pumping could affect the population of metastable states, yielding a C2H3+ column density higher than the LTE value by a factor of a few. We explore possible routes to the formation of C2H3+, mainly connected to acetylene and methane, and find that the methane route is more likely in PDR environment. As one of the initial hydrocarbon building blocks, C2H3+ is thought to play an important role in astrochemistry, in particular in the formation of more complex organic molecules.

astro-ph.GA↗

arXiv2023

HCN emission from translucent gas and UV-illuminated cloud edges revealed by wide-field IRAM 30m maps of Orion B GMC: Revisiting its role as tracer of the dense gas reservoir for star formation

We present 5 deg^2 (~250 pc^2) HCN, HNC, HCO+, and CO J=1-0 maps of the Orion B GMC, complemented with existing wide-field [CI] 492 GHz maps, as well as new pointed observations of rotationally excited HCN, HNC, H13CN, and HN13C lines. We detect anomalous HCN J=1-0 hyperfine structure line emission almost everywhere in the cloud. About 70% of the total HCN J=1-0 luminosity arises from gas at A_V < 8 mag. The HCN/CO J=1-0 line intensity ratio shows a bimodal behavior with an inflection point at A_V < 3 mag typical of translucent gas and UV-illuminated cloud edges. We find that most of the HCN J=1-0 emission arises from extended gas with n(H2) ~< 10^4 cm^-3, even lower density gas if the ionization fraction is > 10^-5 and electron excitation dominates. This result explains the low-A_V branch of the HCN/CO J=1-0 intensity ratio distribution. Indeed, the highest HCN/CO ratios (~0.1) at A_V < 3 mag correspond to regions of high [CI] 492 GHz/CO J=1-0 intensity ratios (>1) characteristic of low-density PDRs. Enhanced FUV radiation favors the formation and excitation of HCN on large scales, not only in dense star-forming clumps. The low surface brightness HCN and HCO+ J=1-0 emission scale with I_FIR (a proxy of the stellar FUV radiation field) in a similar way. Together with CO J=1-0, these lines respond to increasing I_FIR up to G0~20. On the other hand, the bright HCN J=1-0 emission from dense gas in star-forming clumps weakly responds to I_FIR once the FUV radiation field becomes too intense (G0>1500). The different power law scalings (produced by different chemistries, densities, and line excitation regimes) in a single but spatially resolved GMC resemble the variety of Kennicutt-Schmidt law indexes found in galaxy averages. As a corollary for extragalactic studies, we conclude that high HCN/CO J=1-0 line intensity ratios do not always imply the presence of dense gas.

astro-ph.GA↗

arXiv2023

The extremely sharp transition between molecular and ionized gas in the Horsehead nebula

(Abridged) Massive stars can determine the evolution of molecular clouds with their strong ultraviolet (UV) radiation fields. Moreover, UV radiation is relevant in setting the thermal gas pressure in star-forming clouds, whose influence can extend from the rims of molecular clouds to entire star-forming galaxies. Probing the fundamental structure of nearby molecular clouds is therefore crucial to understand how massive stars shape their surrounding medium and how fast molecular clouds are destroyed, specifically at their UV-illuminated edges, where models predict an intermediate zone of neutral atomic gas between the molecular cloud and the surrounding ionized gas whose size is directly related to the exposed physical conditions. We present the highest angular resolution (~$0.5$", corresponding to $207$ au) and velocity-resolved images of the molecular gas emission in the Horsehead nebula, using CO J=3-2 and HCO$^+$ J=4-3 observations with ALMA. We find that CO and HCO$^+$ are present at the edge of the cloud, very close to the ionization (H$^+$/H) and dissociation fronts (H/H$_2$), suggesting a very thin layer of neutral atomic gas (<$650$ au) and a small amount of CO-dark gas ($A_V=0.006-0.26$ mag) for stellar UV illumination conditions typical of molecular clouds in the Milky Way. The new ALMA observations reveal a web of molecular gas filaments with an estimated thermal gas pressure of $P_{\mathrm{th}} = (2.3 - 4.0) \times 10^6$ K cm$^{-3}$, and the presence of a steep density gradient at the cloud edge that can be well explained by stationary isobaric PDR models with pressures consistent with our estimations. However, in the HII region and PDR interface, we find $P_{\mathrm{th,PDR}} > P_{\mathrm{th,HII}}$, suggesting the gas is slightly compressed. Therefore, dynamical effects cannot be completely ruled out and even higher angular observations will be needed to unveil their role.

astro-ph.GA↗

arXiv2023

Cosmo-tomography toward PKS1830-211: Variability of the quasar and of its foreground molecular absorption monitored with ALMA

Time variability of astronomical sources provides crude information on their typical size and on the implied physical mechanisms. PKS1830-211 is a remarkable radio-bright lensed quasar with a foreground molecular absorber at z=0.89. Small-scale morphological changes in the core-jet structure of the quasar -- which is magnified by the lensing -- result in a varying illumination of the absorber screen, which in turn causes variations in the absorption profile. We aim to study the time variations of the system [...] in order to obtain constraints on both the quasar activity and small-scale structures in the ISM of the absorber. We used ALMA to monitor the submm continuum emission, together with the absorption spectra of the H2O and CH molecules, with 17 visits spread over six months in 2016. [...] From the continuum data, we followed the evolution of the flux density, flux-density ratio, spectral index, and differential polarization between the two lensed images of the quasar; all quantities show significant variations related to the intrinsic activity of the quasar. We propose a simple parametric model of a core plus a ballistic plasmon to account for the continuum evolution, from which we constrain a time delay of 25+/-3~days between lensed images. The spectral lines reveal significant variations in the foreground absorption. A PCA highlights apparent wavy time variations, possibly linked to the helical jet precession period of the quasar. From the deep averaged spectra towards the SW image, we detect the absorption of 13CH and estimate an abundance ratio of 12CH/13CH~150. We also measure the oxygen isotopic ratios, 16O/18O=65.3+/-0.7 and 18O/17O=11.5+/-0.5. Finally, we find a remarkable continuous shallow trough in the water absorption spanning a velocity interval of nearly 500 km/s. This broad absorption could be the signature of an extra-planar molecular component. [Abridged]

astro-ph.GA↗

arXiv2022

Gas phase Elemental abundances in Molecular cloudS (GEMS) VII. Sulfur elemental abundance

Gas phase Elemental abundances in molecular CloudS (GEMS) is an IRAM 30m large program aimed at determining the elemental abundances of carbon (C), oxygen (O), nitrogen (N), and sulfur (S) in a selected set of prototypical star-forming filaments. In particular, the elemental abundance of S remains uncertain by several orders of magnitude and its determination is one of the most challenging goals of this program. We have carried out an extensive chemical modeling of the fractional abundances of CO, HCO$^+$, HCN, HNC, CS, SO, H$_2$S, OCS, and HCS$^+$ to determine the sulfur depletion toward the 244 positions in the GEMS database. These positions sample visual extinctions from A$_V$ $\sim$ 3 mag to $>$50 mag, molecular hydrogen densities ranging from a few 10$^3$~cm$^{-3}$ to 3$\times$10$^6$~cm$^{-3}$, and T$_k$ $\sim$ 10$-$35 K. Most of the positions in Taurus and Perseus are best fitted assuming early-time chemistry, t=0.1 Myr, $\zeta_{H_2}$$\sim$ (0.5$-$1)$\times$10$^{-16}$ s$^{-1}$, and [S/H]$\sim$1.5$\times$10$^{-6}$. On the contrary, most of the positions in Orion are fitted with t=1~Myr and $\zeta_{H_2}$$\sim$ 10$^{-17}$ s$^{-1}$. Moreover, $\sim$40% of the positions in Orion are best fitted assuming the undepleted sulfur abundance, [S/H]$\sim$1.5$\times$10$^{-5}$. Our results suggest that sulfur depletion depends on the environment. While the abundances of sulfur-bearing species are consistent with undepleted sulfur in Orion, a depletion factor of $\sim$20 is required to explain those observed in Taurus and Perseus. We propose that differences in the grain charge distribution in the envelopes of the studied clouds might explain these variations. The shocks associated with past and ongoing star formation could also contribute to enhance [S/H] in Orion.

astro-ph.GA↗

arXiv2022

HyGAL: Characterizing the Galactic ISM with observations of hydrides and other small molecules -- I. Survey description and a first look toward W3(OH), W3 IRS5 and NGC 7538 IRS1

The HyGAL SOFIA legacy program surveys six hydride molecules -- ArH+, OH+, H2O+, SH, OH, and CH -- and two atomic constituents -- C+ and O -- within the diffuse interstellar medium (ISM) by means of absorption-line spectroscopy toward 25 bright Galactic background continuum sources. This detailed spectroscopic study is designed to exploit the unique value of specific hydrides as tracers and probes of different phases of the ISM, as demonstrated by recent studies with the Herschel Space Observatory. The observations performed under the HyGAL program will allow us to address several questions related to the lifecycle of molecular material in the ISM and the physical processes that impact its phase transition, such as: (1) What is the distribution function of the H2 fraction in the ISM? (2) How does the ionization rate due to low-energy cosmic-rays vary within the Galaxy? (3) What is the nature of interstellar turbulence, and what mechanisms lead to its dissipation? This overview discusses the observing strategy, synergies with ancillary and archival observations, the data reduction and analysis schemes adopted; and presents the first results obtained toward three of the survey targets, W3(OH), W3IRS5 and NGC7538IRS1. Robust measurements of the column densities of these hydrides -- obtained through widespread observations of absorption lines-- help address the questions raised, and there is a timely synergy between these observations and the development of theoretical models, particularly pertaining to the formation of H2 within the turbulent ISM. The provision of enhanced HyGAL data products will therefore serve as a legacy for future ISM studies.

astro-ph.GA↗

arXiv2021

Gas phase Elemental abundances in Molecular cloudS (GEMS). IV. Observational results and statistical trends

Gas phase Elemental abundances in Molecular CloudS (GEMS) is an IRAM 30m Large Program designed to estimate the S, C, N, and O depletions and gas ionization degree, X(e-), in a set of star-forming filaments of Taurus, Perseus and Orion. Our immediate goal is to build up a complete database of molecular abundances that can serve as an observational basis for estimating X(e-) and the C, O, N, and S depletions through chemical modeling. We observed and derived the abundances of 14 species (13CO, C18O, HCO+, H13CO+, HC18O+, HCN, H13CN, HNC, HCS+, CS, SO, 34SO, H2S, and OCS) in 244 positions, covering the AV 3 to 100 mag, n(H2) a few 10$^{3}$ to 10$^6$ cm$^{-3}$, and Tk 10 to 30 K ranges in these clouds, avoiding protostars, HII regions, and outflows. A statistical analysis is carried out to identify general trends between different species and with physical parameters. Relations between molecules reveal strong linear correlations which define three different families: (1) 13CO and C18O; (2) H13CO+, HC18O+, H13CN, and HNC; and (3) the S-bearing molecules. The abundances of the CO isotopologs increase with the gas kinetic temperature until TK 15 K. For higher temperatures, the abundance remains constant with a scatter of a factor of 3. The abundances of H13CO+, HC18O+, H13CN, and HNC are well correlated with each other, and all of them decrease with molecular hydrogen density, following the law n(H2)$^{-0.8\pm0.2}$. The abundances of S-bearing species also decrease with n(H2) at a rate of (S-bearing/H)gas n(H2)$^{-0.6\pm0.1}$. The abundances of molecules belonging to groups 2 and 3 do not present any clear trend with gas temperature. At scales of molecular clouds, the C18O abundance is the quantity that better correlates with the cloud mass. We discuss the utility of the 13CO/C18O, HCO+/H13CO+, and H13CO+/H13CN abundance ratios as chemical diagnostics of star formation in external galaxies.

astro-ph.GA↗

arXiv2020

Origins Space Telescope: From First Light to Life -- ESA Voyage 2050 White Paper

The Origins Space Telescope (Origins) is one of four science and technology definition studies selected by National Aeronautics and Space Administration (NASA) in preparation of the 2020 Astronomy and Astrophysics Decadal survey in the US. Origins will trace the history of our origins from the time dust and heavy elements permanently altered the cosmic landscape to present-day life. It is designed to answer three major science questions: How do galaxies form stars, make metals, and grow their central supermassive black holes from reionization? How do the conditions for habitability develop during the process of planet formation? Do planets orbiting M-dwarf stars support life? Origins operates at mid- to far-infrared wavelengths from ~2.8 to 588 {\mu}m, is more than 1000 times more sensitive than prior far-IR missions due to its cold (~4.5 K) aperture and state-of-the-art instruments.

astro-ph.IM↗

arXiv2020

Interstellar anatomy of the TeV gamma-ray peak in the IC443 supernova remnant

Supernovae remnants (SNRs) represent a major feedback source from stars on the interstellar medium of galaxies. During the latest stage of supernovae explosions, shock waves produced by the initial blast modify the chemistry of gas and dust, inject kinetic energy in the surroundings, and may alter star formation characteristics. Simultaneously, gamma-ray emission is generated by the interaction between the ambiant medium and the cosmic rays. We study the stellar and interstellar contents of IC443, an evolved shell type SNR at a distance of 1.9 kpc, with an estimated age of 30 kyr. We aim to measure the mass of the gas within the extended G region, which corresponds to the peak of gamma-ray emission detected by VERITAS and Fermi. We performed 10'x10' mapped observations of 12CO and 13CO J=1-0, J=2-1 and J=3-2 pure rotational lines, as well as C18O J=1-0 and J=2-1 obtained with the IRAM-30m and APEX telescopes. We first compared our data with local thermodynamic equilbrium (LTE) models. We estimated the optical depth of each line from the emission of the isotopologues 13CO and C18O. We used the population diagram and large velocity gradient (LVG) assumption to measure the column density, mass, and kinetic temperature of the gas using 12CO and 13CO lines. We used complementary data (stars, gas, and dust at multiple wavelengths) and infrared point source catalogues to search for protostar candidates. Our results emphasize how the mass associated with the ring-like structure and the cloudlet cannot be overlooked when quantifying the interaction of cosmic rays with the dense local medium. Additionally, the presence of numerous possible protostars in the region might represent a fresh source of CR, which must also be taken into account in the interpretation of gamma-ray observations in this region.

astro-ph.HE↗

arXiv2020

Gas phase Elemental abundances in Molecular cloudS (GEMS). II. On the quest for the sulphur reservoir in molecular clouds: the $H_{2}S$ case

Sulphur is one of the most abundant elements in the Universe. Surprisingly, sulphuretted molecules are not as abundant as expected in the interstellar medium, and the identity of the main sulphur reservoir is still an open question. Our goal is to investigate the H$_{2}$S chemistry in dark clouds, as this stable molecule is a potential sulphur reservoir. Using millimeter observations of CS, SO, H$_{2}$S, and their isotopologues, we determine the physical conditions and H$_{2}$S abundances along the cores TMC 1-C, TMC 1-CP, and Barnard 1b. The gas-grain model Nautilus is then used to model the sulphur chemistry and explore the impact of photo-desorption and chemical desorption on the H$_2$S abundance. Our model shows that chemical desorption is the main source of gas-phase H$_2$S in dark cores. The measured H$_{2}$S abundance can only be fitted if we assume that the chemical desorption rate decreases by more than a factor of 10 when $n_{\rm H}>2\times10^{4}$. This change in the desorption rate is consistent with the formation of thick H$_2$O and CO ice mantles on grain surfaces. The observed SO and H$_2$S abundances are in good agreement with our predictions adopting an undepleted value of the sulphur abundance. However, the CS abundance is overestimated by a factor of $5-10$. Along the three cores, atomic S is predicted to be the main sulphur reservoir. We conclude that the gaseous H$_2$S abundance is well reproduced, assuming undepleted sulphur abundance and chemical desorption as the main source of H$_2$S. The behavior of the observed H$_{2}$S abundance suggests a changing desorption efficiency, which would probe the snowline in these cores. Our model, however, overestimates the observed gas-phase CS abundance. Given the uncertainty in the sulphur chemistry, our data are consistent with a cosmic elemental S abundance with an uncertainty of a factor of 10.

astro-ph.GA↗

arXiv2020

Detection of deuterated molecules, but not of lithium hydride, in the z=0.89 absorber toward PKS1830-211

Deuterium and lithium are light elements of high cosmological and astrophysical importance. In this work we report the first detection of deuterated molecules and a search for lithium hydride, 7LiH, at redshift z=0.89 in the spiral galaxy intercepting the line of sight to the quasar PKS1830-211. We used ALMA to observe several submillimeter lines of ND, NH2D, and HDO, and their related isotopomers NH2, NH3, and H2^18O, in absorption against the southwest image of the quasar, allowing us to derive XD/XH abundance ratios. The absorption spectra mainly consist of two distinct narrow velocity components for which we find remarkable differences. One velocity component shows XD/XH abundances that is about 10 times larger than the primordial elemental D/H ratio, and no variability of the absorption profile during the time span of our observations. [...] The second component has XD/XH abundances that are 100 times larger than the primordial D/H ratio, a deepening of the absorption by a factor of two within a few months, and a rich chemical composition, with relative enhancements of N2H+, CH3OH, SO2, and complex organic molecules. We therefore speculate that this component is associated with the analog of a Galactic dark cloud, while the first component is likely more diffuse. Our search for the 7LiH (1--0) line was unsuccessful and we derive an upper limit 7LiH/H2 = 4 x 10^-13 (3sigma) in the z=0.89 absorber toward PKS1830-211. Besides, with ALMA archival data, we could not confirm the previous tentative detections of this line in the z=0.68 absorber toward B0218+357; we derive an upper limit 7LiH/H2 = 5 x 10^-11 (3sigma), although this is less constraining than our limit toward PKS1830-211. We conclude that, as in the Milky Way, only a tiny fraction of lithium nuclei are possibly bound in LiH in these absorbers at intermediate redshift.

astro-ph.GA↗

arXiv2019

Origins Space Telescope Mission Concept Study Report

The Origins Space Telescope (Origins) traces our cosmic history, from the formation of the first galaxies and the rise of metals to the development of habitable worlds and present-day life. Origins does this through exquisite sensitivity to infrared radiation from ions, atoms, molecules, dust, water vapor and ice, and observations of extra-solar planetary atmospheres, protoplanetary disks, and large-area extragalactic fields. Origins operates in the wavelength range 2.8 to 588 microns and is 1000 times more sensitive than its predecessors due to its large, cold (4.5 K) telescope and advanced instruments. Origins was one of four large missions studied by the community with support from NASA and industry in preparation for the 2020 Decadal Survey in Astrophysics. This is the final study report.

astro-ph.IM↗

arXiv2019

Chlorine-bearing molecules in molecular absorbers at intermediate redshifts

We use observations of chlorine-bearing species in molecular absorbers at intermediate redshifts to investigate chemical properties and $^{35}$Cl/$^{37}$Cl isotopic ratios in the absorbing sightlines. Chloronium (H$_2$Cl$^+$) is detected along three independent lines of sight in the z=0.89 and z=0.68 molecular absorbers located in front of the lensed quasars PKS 1830-211 and B 0218+357, respectively. Hydrogen chloride (HCl) was observed only toward PKS 1830-211, and is found to behave differently from H$_2$Cl$^+$. It is detected in one line of sight with an abundance ratio [H$_2$Cl$^+$]/[HCl] $\sim 1$, but remains undetected in the other, more diffuse, line of sight, with a ratio [H$_2$Cl$^+$]/[HCl]~$>17$. The absorption profiles of these two chlorine-bearing species are compared to other species and discussed in terms of the physical properties of the absorbing gas. Our findings are consistent with the picture emerging from chemical models where different species trace gas with different molecular hydrogen fraction. The $^{35}$Cl/$^{37}$Cl isotopic ratios are measured in the different lines of sight and are discussed in terms of stellar nucleosynthesis.

astro-ph.GA↗