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M. Gerin

Publications and source records attributed to M. Gerin.

At least 37 records · Page 2Linked to original sources

Chlorine-bearing molecules in molecular absorbers at intermediate redshifts

We use observations of chlorine-bearing species in molecular absorbers at intermediate redshifts to investigate chemical properties and $^{35}$Cl/$^{37}$Cl isotopic ratios in the absorbing sightlines. Chloronium (H$_2$Cl$^+$) is detected along three independent lines of sight in the z=0.89 and z=0.68 molecular absorbers located in front of the lensed quasars PKS 1830-211 and B 0218+357, respectively. Hydrogen chloride (HCl) was observed only toward PKS 1830-211, and is found to behave differently from H$_2$Cl$^+$. It is detected in one line of sight with an abundance ratio [H$_2$Cl$^+$]/[HCl] $\sim 1$, but remains undetected in the other, more diffuse, line of sight, with a ratio [H$_2$Cl$^+$]/[HCl]~$>17$. The absorption profiles of these two chlorine-bearing species are compared to other species and discussed in terms of the physical properties of the absorbing gas. Our findings are consistent with the picture emerging from chemical models where different species trace gas with different molecular hydrogen fraction. The $^{35}$Cl/$^{37}$Cl isotopic ratios are measured in the different lines of sight and are discussed in terms of stellar nucleosynthesis.

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Abundances of sulphur molecules in the Horsehead nebula. First NS+ detection in a photodissociation region

Aims. Our goal is to complete the inventory of S-bearing molecules and their abundances in the prototypical photodissociation region (PDR) the Horsehead nebula to gain insight into sulphur chemistry in UV irradiated regions. Based on the WHISPER millimeter (mm) line survey, our goal is to provide an improved and more accurate description of sulphur species and their abundances towards the core and PDR positions in the Horsehead. Methods. The Monte Carlo Markov chain (MCMC) methodology and the molecular excitation and radiative transfer code RADEX were used to explore the parameter space and determine physical conditions and beam-averaged molecular abundances. Results. A total of 13 S-bearing species (CS, SO, SO2, OCS, H2CS - both ortho and para - HDCS, C2S, HCS+, SO+, H2S, S2H, NS and NS+) have been detected in the two targeted positions. This is the first detection of SO+ in the Horsehead and the first detection of NS+ in any PDR. We find a differentiated chemical behaviour between C-S and O-S bearing species within the nebula. The C-S bearing species C2S and o-H2CS present fractional abundances a factor grater than two higher in the core than in the PDR. In contrast, the O-S bearing molecules SO, SO2, and OCS present similar abundances towards both positions. A few molecules, SO+, NS, and NS+, are more abundant towards the PDR than towards the core, and could be considered as PDR tracers. Conclusions. This is the first complete study of S-bearing species towards a PDR. Our study shows that CS, SO, and H2S are the most abundant S-bearing molecules in the PDR with abundances of a few 1E-9. We recall that SH, SH+, S, and S+ are not observable at the wavelengths covered by the WHISPER survey. At the spatial scale of our observations, the total abundance of S atoms locked in the detected species is < 1E-8, only ~0.1% of the cosmic sulphur abundance.

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Standing in the shadow of dark gas: ALMA observations of absorption from dark CO in the molecular DNM of Chamaeleon

% context We had detected J=1-0 HCO+ absorption in 12 directions lacking detected CO emission in the outskirts of the Chamaeleon complex and on 1 sightline with integrated CO emission 2.4 K-\kms. 8 sightlines had a much larger mean column density of dark neutral medium (DNM)-gas not represented in H I or CO emission-and were found to have much higher mean molecular column density. The 5 other sightlines had little or no DNM and were found to have much smaller but still detectable N(HCO+). % aims To determine N(CO) along previously-observed Chamaeleon sightlines and to determine why CO emission was not detected in directions where molecular gas is present. % methods We took \cotw\ J=1-0 absorption profiles on 5 sightlines having higher DNM and HCO+ column densities and 1 sightline with smaller N(DNM) and N(HCO+). We converted the integrated HCO+ optical depths to N(H2) in the weak-excitation limit using N(HCO+)/N(H2)$=3\times10^{-9}$ and converted the integrated CO optical depths \ICO\ to CO column density N(CO) $= 1.861\times 10^{15}\pcc \ICO^{1.131}$ as found along comparable lines of sight previously studied in J=1-0 and J=2-1 CO absorption&emission. %results CO absorption was detected along the 5 sightlines in the higher-DNM group, with CO column densities $4\times 10^{13} \pcc<$ N(CO) $<10^{15}\pcc$ that are generally below the detectability limit of CO emission surveys. %conclusions In the outskirts of the Chamaeleon complex, the presence of molecular DNM resulted primarily from small CO column densities at the onset of CO formation around the HI/\HH\ transition in diffuse molecular gas. CO relative abundances N(CO)/N(H2) $< 2\times 10^{-6}$ in the outskirts of Chamaeleon are comparable to those seen in UV absorption toward early-type stars, including in Chamaeleon.

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Gas phase Elemental abundances in Molecular cloudS (GEMS) I. The prototypical dark cloud TMC 1

GEMS is an IRAM 30m Large Program whose aim is determining the elemental depletions and the ionization fraction in a set of prototypical star-forming regions. This paper presents the first results from the prototypical dark cloud TMC 1. Extensive millimeter observations have been carried out with the IRAM 30m telescope (3mm and 2mm) and the 40m Yebes telescope (1.3cm and 7mm) to determine the fractional abundances of CO, HCO+, HCN, CS, SO, HCS+, and N2H+ in three cuts which intersect the dense filament at the well-known positions TMC 1-CP, TMC 1-NH3, and TMC 1-C, covering a visual extinction range from Av~3 to ~20mag. Two phases with differentiated chemistry can be distinguished: i) the translucent envelope with molecular hydrogen densities of (1-5)x10$^3$ cm$^{-3}$; and ii) the dense phase, located at Av>10mag, with molecular hydrogen densities >10$^4$ cm$^{-3}$. Observations and modeling show that the gas phase abundances of C and O progressively decrease along the C+/C/CO transition zone where C/H~8x10$^{-5}$ and C/O~0.8-1, until the beginning of the dense phase at Av~10 mag. This is consistent with the grain temperatures being below the CO evaporation temperature in this region. In the case of sulfur, a strong depletion should occur before the translucent phase where we estimate a S/H~(0.4 - 2.2) x10$^{-6}$, an abundance ~7-40 times lower than the solar value. A second strong depletion must be present during the formation of the thick icy mantles to achieve the values of S/H measured in the dense cold cores (S/H~8x10$^{-8}$). Based on our chemical modeling, we constrain the value of $ζ_{\rm H_2}$ to ~(0.5 - 1.8) x10$^{-16}$ s$^{-1}$ in the translucent cloud.

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Molecular ion abundances in the diffuse ISM : CF+, HCO+, HOC+, and C3H+

The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Because of the relatively simple networks controlling their abundances, molecular ions are usually good probes of the underlying physical conditions including for instance the fraction of gas in molecular form or the fractional ionization. In this paper we focus on three possible probes of the molecular hydrogen column density, HCO+, HOC+, and CF+. We presented high sensitivity ALMA absorption data toward a sample of compact HII regions and bright QSOs with prominent foreground absorption, in the ground state transitions of the molecular ions HCO+, HOC+, and CF+ and the neutral species HCN and HNC, and from the excited state transitions of C3H+(4-3) and 13CS(2-1). These data are compared with Herschel absorption spectra of the ground state transition of HF and p-H2O. We show that the HCO+, HOC+, and CF+ column densities are well correlated with each other. HCO+ and HOC+ are tightly correlated with p-H2O, while they exhibit a different correlation pattern with HF depending on whether the absorbing matter is located in the Galactic disk or in the central molecular zone. We report new detections of C3H+ confirming that this ion is ubiquitous in the diffuse matter, with an abundance relative to H2 of ~7E-11. We confirm that the CF+ abundance is lower than predicted by simple chemical models and propose that the rate of the main formation reaction is lower by a factor of about 3 than usually assumed. In the absence of CH or HF data, we recommend to use the ground state transitions of HCO+, CCH, and HOC+ to trace diffuse molecular hydrogen, with mean abundances relative to H2 of 3E-9, 4E-8 and 4E-11.

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ALMA observations of the young protostellar system Barnard 1b: signatures of an incipient hot corino in B1b-S

The Barnard 1b core shows signatures of being at the earliest stages of low-mass star formation, with two extremely young and deeply embedded protostellar objects. Hence, this core is an ideal target to study the structure and chemistry of the first objects formed in the collapse of prestellar cores. We present ALMA Band 6 spectral line observations at ~0.6'' of angular resolution towards Barnard 1b. We have extracted the spectra towards both protostars, and used a Local Thermodynamic Equilibrium (LTE) model to reproduce the observed line profiles. B1b-S shows rich and complex spectra, with emission from high energy transitions of complex molecules, such as CH3OCOH and CH3CHO, including vibrational level transitions. We have tentatively detected for the first time in this source emission from NH2CN, NH2CHO, CH3CH2OH, CH2OHCHO, CH3CH2OCOH and both aGg' and gGg' conformers of (CH2OH)2. This is the first detection of ethyl formate (CH3CH2OCOH) towards a low-mass star forming region. On the other hand, the spectra of the FHSC candidate B1b-N are free of COMs emission. In order to fit the observed line profiles in B1b-S, we used a source model with two components: an inner hot and compact component (200 K, 0.35'') and an outer and colder one (60 K, 0.6''). The resulting COM abundances in B1b-S range from 1e-13 for NH2CN and NH2CHO, up to 1e-9 for CH3OCOH. Our ALMA Band 6 observations reveal the presence of a compact and hot component in B1b-S, with moderate abundances of complex organics. These results indicate that a hot corino is being formed in this very young Class 0 source.

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High-speed molecular cloudlets around the Galactic Center supermassive black hole

We present 1"-resolution ALMA observations of the circumnuclear disk (CND) and the environment around SgrA*. The images unveil the presence of small spatial scale CO (J=3-2) molecular "cloudlets" within the central pc of the Milky Way, moving at high speeds, up to 300 km/s along the line-of-sight. The CO-emitting structures show intricate morphologies: extended and filamentary at high negative-velocities (v_LSR < -150 km/s), more localized and clumpy at extreme positive-velocities (v_LSR > +200 km/s). Based on the pencil-beam CO absorption spectrum toward SgrA* synchrotron emission, we also present evidence for a diffuse gas component producing absorption features at more extreme negative-velocities (v_LSR < -200 km/s). The CND shows a clumpy spatial distribution. Its motion requires a bundle of non-uniformly rotating streams of slightly different inclinations. The inferred gas density peaks are lower than the local Roche limit. This supports that CND molecular cores are transient. We apply the two standard orbit models, spirals vs. ellipses, invoked to explain the kinematics of the ionized gas streamers around SgrA*. The location and velocities of the CO cloudlets are inconsistent with the spiral model, and only two of them are consistent with the Keplerian ellipse model. Most cloudlets, however, show similar velocities that are incompatible with the motions of the ionized streamers or with gas bounded to the central gravity. We speculate that they are leftovers of more massive, tidally disrupted, clouds that fall into the cavity, or that they originate from instabilities in the inner rim of the CND and infall from there. Molecular cloudlets, all together with a mass of several 10 M_Sun, exist around SgrA*. Most of them must be short-lived: photoevaporated by the intense stellar radiation field, blown away by winds from massive stars, or disrupted by strong gravitational shears.

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High-velocity hot CO emission close to Sgr A*: Herschel/HIFI submillimeter spectral survey toward Sgr A*

The properties of molecular gas, the fuel that forms stars, inside the cavity of the circumnuclear disk (CND) are not well constrained. We present results of a velocity-resolved submillimeter scan (~480 to 1250 GHz}) and [CII]158um line observations carried out with Herschel/HIFI toward Sgr A*; these results are complemented by a ~2'x2' CO (J=3-2) map taken with the IRAM 30 m telescope at ~7'' resolution. We report the presence of high positive-velocity emission (up to about +300 km/s) detected in the wings of CO J=5-4 to 10-9 lines. This wing component is also seen in H2O (1_{1,0}-1_{0,1}) a tracer of hot molecular gas; in [CII]158um, an unambiguous tracer of UV radiation; but not in [CI]492,806 GHz. This first measurement of the high-velocity CO rotational ladder toward Sgr A* adds more evidence that hot molecular gas exists inside the cavity of the CND, relatively close to the supermassive black hole (< 1 pc). Observed by ALMA, this velocity range appears as a collection of CO (J=3-2) cloudlets lying in a very harsh environment that is pervaded by intense UV radiation fields, shocks, and affected by strong gravitational shears. We constrain the physical conditions of the high positive-velocity CO gas component by comparing with non-LTE excitation and radiative transfer models. We infer T_k~400 K to 2000 K for n_H~(0.2-1.0)x10^5 cm^-3. These results point toward the important role of stellar UV radiation, but we show that radiative heating alone cannot explain the excitation of this ~10-60 M_Sun component of hot molecular gas inside the central cavity. Instead, strongly irradiated shocks are promising candidates.

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Molecular Gas and Dark Neutral Medium in the Outskirts of Chamaeleon

%context More gas is inferred to be present in molecular cloud complexes than can be accounted for by HI and CO emission, a phenomenon known as dark neutral medium (DNM) or CO-dark gas for the molecules. %aims To see if molecular gas can be detected in Chamaeleon when gas column densities in the DNM were inferred and CO emission was not detected. % methods We took 3mm absorption profiles of HCO+ and other molecules toward quasars across Chamaeleon, 1 of which had detectable CO emission. We derived N(H2) assuming N(HC+)/N(H2) = 3x10^{-9}. %results With the possible exception of 1 weak continuum target HCO+ absorption was detected in all directions, \cch\ in 8 and HCN in 4 directions. The sightlines divide in 2 groups according to their DNM content with 1 group of 8 directions having N(DNM) \ga 2x10^{20} \pcc and another group of 5 directions having N(DNM) < .5x10^{20}\pcc. The groups have comparable in Chamaeleon 6-7 x 10^{20}\pcc and 0.33 vs 0.18 mag, 3.3 vs .14 x 10^{20}\pcc and <2N(H2)> = 5.6 vs 0.8 x 10^{20} \pcc. Gas at more positive velocities is enriched in molecules and DNM. %conclusion Overall the quantity of H2 inferred from HCO+ fully accounts for the previously-inferred DNM along the studied sightlines. H2 is concentrated in the high-DNM group, where the molecular fraction is 46% vs. 13% otherwise and 38% overall. Thus, neutral gas in the outskirts of the complex is mostly atomic but the DNM is mostly molecular. Saturation of the HI emission may occur along 3 of the 4 sightlines having the largest DNM column densities but there is no substantial reservoir of 'dark' atomic or molecular gas that remains undetected as part of the inventory of dark neutral medium.

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Structure of photodissociation fronts in star-forming regions revealed by observations of high-J CO emission lines with Herschel

In bright photodissociation regions (PDRs) associated to massive star formation, the presence of dense "clumps" that are immersed in a less dense interclump medium is often proposed to explain the difficulty of models to account for the observed gas emission in high-excitation lines. We aim at presenting a comprehensive view of the modeling of the CO rotational ladder in PDRs, including the high-J lines that trace warm molecular gas at PDR interfaces. We observed the 12CO and 13CO ladders in two prototypical PDRs, the Orion Bar and NGC 7023 NW using the instruments onboard Herschel. We also considered line emission from key species in the gas cooling of PDRs (C+, O, H2) and other tracers of PDR edges such as OH and CH+. All the intensities are collected from Herschel observations, the literature and the Spitzer archive and are analyzed using the Meudon PDR code. A grid of models was run to explore the parameter space of only two parameters: thermal gas pressure and a global scaling factor that corrects for approximations in the assumed geometry. We conclude that the emission in the high-J CO lines, which were observed up to Jup=23 in the Orion Bar (Jup=19 in NGC7023), can only originate from small structures of typical thickness of a few 1e-3 pc and at high thermal pressures (Pth~1e8 K cm-3). Compiling data from the literature, we found that the gas thermal pressure increases with the intensity of the UV radiation field given by G0, following a trend in line with recent simulations of the photoevaporation of illuminated edges of molecular clouds. This relation can help rationalising the analysis of high-J CO emission in massive star formation and provides an observational constraint for models that study stellar feedback on molecular clouds.

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ALMA observations of molecular absorption in four directions toward the Galactic bulge

Alma Cycle 3 observations showed strong absorption from diffuse molecular gas in the bulge at -200 \kms\ $< {\rm v} < -140$ \kms\ toward J1744-3116 (l,b)= (-2.13d,-1d) We aimed to test if bulge molecular gas could also be seen toward the three other sufficiently strong mm-wave sources seen toward the bulgeat $|b| < 3$°We took absorption profiles of \hcop (1-0) and other species in ALMA Cy 4 toward J1713-3418, J1717-3341, J1733-3722 and J1744-3116. Strong molecular absorption from disk gas at $|\rmv| \la 30$ \kms\ was detected in all directions, and absorption from the 3 kpc arm was newly detected toward J1717 and J1744. However, only the sightline toward J1744 is dominated by molecular gas overall and no other sightlines showed molecular absorption from gas deep inside the bulge. No molecular absorption was detected toward J1717 where H I emission from the bulge was previously known. As observed in \hcop, HCN, \cch\ and CS, the bulge gas toward J1744 at $v < -135$ \kms\ has chemistry and kinematics like that seen near the Sun and in the Milky Way disk generally. We measured isotopologic ratios N(\hcop)/N(H$^{13}$CO\p) $> 51~(3σ)$ for the bulge gas toward J1744 and $58\pm9$ and $64\pm4$ for the disk gas toward J1717 and J1744, respectively, all well above the value of 20-25 typical of the central molecular zone.} %conclusions heading (optional), leave it empty if necessary {The kinematics and chemistry of the bulge gas observed toward J1744 more nearly resemble that of gas in the Milky Way disk than in the central molecular zone.}

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Evidence for disks at an early stage in class 0 protostars?

The formation epoch of protostellar disks is debated because of the competing roles of rotation, turbulence, and magnetic fields in the early stages of low-mass star formation. Magnetohydrodynamics simulations of collapsing cores predict that rotationally supported disks may form in strongly magnetized cores through ambipolar diffusion or misalignment between the rotation axis and the magnetic field orientation. Detailed studies of individual sources are needed to cross check the theoretical predictions. We present 0.06-0.1" resolution images at 350 GHz toward B1b-N and B1b-S, which are young class 0 protostars, possibly first hydrostatic cores. The images have been obtained with ALMA, and we compare these data with magnetohydrodynamics simulations of a collapsing turbulent and magnetized core. The submillimeter continuum emission is spatially resolved by ALMA. Compact structures with optically thick 350 GHz emission are detected toward both B1b-N and B1b-S, with 0.2 and 0.35" radii (46 and 80 au at the Perseus distance of 230 pc), within a more extended envelope. The flux ratio between the compact structure and the envelope is lower in B1b-N than in B1b-S, in agreement with its earlier evolutionary status. The size and orientation of the compact structure are consistent with 0.2" resolution 32 GHz observations obtained with the Very Large Array as a part of the VANDAM survey, suggesting that grains have grown through coagulation. The morphology, temperature, and densities of the compact structures are consistent with those of disks formed in numerical simulations of collapsing cores. Moreover, the properties of B1b-N are consistent with those of a very young protostar, possibly a first hydrostatic core. These observations provide support for the early formation of disks around low-mass protostars.

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The ALMA view of UV irradiated cloud edges: unexpected structures and processes

Far-UV photons (E<13.6 eV) from hot massive stars regulate, or at least influence, the heating, ionization, and chemistry of most of the neutral interstellar medium. Investigating the interaction between FUV radiation and interstellar matter thus plays an important role in astrochemistry. We have used ALMA to mosaic a small field of the Orion Bar where the critical transition from atomic to molecular gas takes place. These observations provide an unprecedented sharp view of this transition layer (~1" resolution or ~414 AU). The resulting images (so far in the rotational emission of CO, HCO+, H13CO+, SO+, SO, and reactive ions SH+ and HOC+) show the small-scale structure in gas density and temperature, and the steep abundance gradients. The images reveal a pattern of high-density substructures, photo-ablative gas flows and instabilities at the edge of the molecular cloud. We have also used the IRAM 30m telescope to carry out a line-survey of the illuminated edge of the Bar in the mm domain. Our observations reveal the presence of complex organic molecules that were not expected in such a harsh environment. In particular, we have reported the first detection of the unstable cis conformer of formic acid (HCOOH) in the ISM. The energy barrier to internal rotation (the conversion from trans to cis) is approximately 4827 cm-1. Hence, this detection is surprising. The low inferred trans-to-cis abundance ratio of 2.8+/-1.0 supports a photoswitching mechanism: a given conformer absorbs a FUV stellar photon that radiatively excites the molecule to electronic states above the interconversion barrier. Subsequent fluorescent decay leaves the molecule in a different conformer form. This mechanism, which we have specifically studied with ab initio quantum calculations, was not considered so far in astrochemistry although it can affect the structure of a variety of molecules in PDRs. (abridged)

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Spatially resolved images of reactive ions in the Orion Bar

We report high angular resolution (4.9" x 3.0") images of reactive ions SH+, HOC+, and SO+ toward the Orion Bar photodissociation region (PDR). We used ALMA-ACA to map several rotational lines at 0.8 mm, complemented with multi-line observations obtained with the IRAM 30m telescope. The SH+ and HOC+ emission is restricted to a narrow layer of 2"- to 10"-width (~800 to 4000 AU depending on the assumed PDR geometry) that follows the vibrationally excited H2^* emission. Both ions efficiently form very close to the H/H2 transition zone, at a depth of A_V < 1 mag into the neutral cloud, where abundant C+, S+, and H2^* coexist. SO+ peaks slightly deeper into the cloud. The observed ions have low rotational temperatures (T_rot~10-30 K << T_k) and narrow line-widths (~2-3 km/s), a factor of ~2 narrower that those of the lighter reactive ion CH+. This is consistent with the higher reactivity and faster radiative pumping rates of CH+ compared to the heavier ions, which are driven relatively faster toward smaller velocity dispersion by elastic collisions and toward lower T_rot by inelastic collisions. We estimate column densities and average physical conditions from a non-LTE excitation model (n(H2)~10^5-10^6 cm^-3, n(e^-)~10 cm^-3, and T_k~200 K). Regardless of the excitation details, SH+ and HOC+ clearly trace the most exposed layers of the UV-irradiated molecular cloud surface, whereas SO+ arises from slightly more shielded layers.

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Hydrogen in diffuse molecular clouds in the Milky Way: Atomic column densities and molecular fraction along prominent lines of sight

Recent submillimeter and far-infrared wavelength observations of absorption in the rotational ground-state lines of various simple molecules against distant Galactic continuum sources have opened the possibility of studying the chemistry of diffuse molecular clouds throughout the Milky Way. In order to calculate abundances, the column densities of molecular and atomic hydrogen, HI, must be known. We aim at determining the atomic hydrogen column densities for diffuse clouds located on the sight lines toward a sample of prominent high-mass star-forming regions that were intensely studied with the HIFI instrument onboard Herschel. Based on Jansky Very Large Array data, we employ the 21 cm HI absorption-line technique to construct profiles of the HI opacity versus radial velocity toward our target sources. These profiles are combined with lower resolution archival data of extended HI emission to calculate the HI column densities of the individual clouds along the sight lines. We employ Bayesian inference to estimate the uncertainties of the derived quantities. Our study delivers reliable estimates of the atomic hydrogen column density for a large number of diffuse molecular clouds at various Galactocentric distances. Together with column densities of molecular hydrogen derived from its surrogates observed with HIFI, the measurements can be used to characterize the clouds and investigate the dependence of their chemistry on the molecular fraction, for example.

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ALMA hints at the existence of an unseen reservoir of diffuse molecular gas in the Galactic bulge

Aims. We aim to understand the unexpected presence of mm-wave molecular absorption at -200 \kms $< {\rm v} < -140$ \kms\ in a direction that is well away from regions of the Galactic bulge where CO emission at such velocities is prominent. Methods. We compared 89 GHz Cycle 2 ALMA absorption spectra of \hcop, HCN, and HNC toward the extragalactic continuum source B1741-312 at l=-2.14\degr, b=-1.00\degr\ with existing CO, H I, and dust emission and absorption measurements. We placed the atomic and molecular gas in the bulge and disk using circular and non-circular galactic kinematics, deriving N(H I) from a combination of 21cm emission and absorption and we derive N(\HH) from scaling of the \hcop\ absorption. We then inverted the variation of near-IR reddening E(J-K) with distance modulus and scale E(J-K) to a total gas column density N(H) that may be compared to N(H I) and N(\HH). Results. At galactocentric radii \Rgal\ $>$ 1.5 kpc, conventional measures such as the standard CO-\HH\ conversion factor and locally observed N(\hcop)/N(\HH) ratio separately imply that H I and \HH\ contribute about equally to N(H), and the gas-derived N(H) values are in broad agreement with those derived from E(J-K). Within the Galactic bulge at \Rgal $<$ 1.5 kpc, H I contributes less than 10\% of the material inferred from E(J-K), so that the molecular absorption detected here is needed to understand the extinction.

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CO Spectral Line Energy Distributions in Galactic Sources: Empirical Interpretation of Extragalactic Observations

The relative populations in rotational transitions of CO can be useful for inferring gas conditions and excitation mechanisms at work in the interstellar medium. We present CO emission lines from rotational transitions observed with Herschel/HIFI in the star-forming cores Orion S, Orion KL, Sgr B2(M), and W49N. Integrated line fluxes from these observations are combined with those from Herschel/PACS observations of the same sources to construct CO spectral line energy distributions (SLEDs) from $5\leq J_u\leq48$. These CO SLEDs are compared to those reported in other galaxies, with the intention of empirically determining which mechanisms dominate excitation in such systems. We find that CO SLEDs in Galactic star-forming cores cannot be used to reproduce those observed in other galaxies, although the discrepancies arise primarily as a result of beam filling factors. The much larger regions sampled by the Herschel beams at distances of several Mpc contain significant amounts of cooler gas which dominate the extragalactic CO SLEDs, in contrast to observations of Galactic star-forming regions which are focused specifically on cores containing primarily hot molecular gas.

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Herschel / HIFI spectral line survey of the Orion Bar - Temperature and density differentiation near the PDR surface

Photon Dominated Regions (PDRs) are interfaces between the mainly ionized and mainly molecular material around young massive stars. Analysis of the physical and chemical structure of such regions traces the impact of far-ultraviolet radiation of young massive stars on their environment. We present results on the physical and chemical structure of the prototypical high UV-illumination edge-on Orion Bar PDR from an unbiased spectral line survey with a wide spectral coverage. A spectral scan from 480-1250 GHz and 1410-1910 GHz at 1.1 MHz resolution was obtained by the HIFI instrument onboard the Herschel Space Observatory. For molecules with multiple transitions we used rotational diagrams to obtain excitation temperatures and column densities. For species with a single detected transition we used an optically thin LTE approximation. In case of species with available collisional rates, we also performed a non-LTE analysis to obtain kinetic temperatures, H2 volume densities, and column densities. About 120 lines corresponding to 29 molecules (including isotopologues) have been detected in the Herschel/HIFI line survey, including 11 transitions of CO, 7 transitions of 13CO, 6 transitions of C18O, 10 transitions of H2CO, and 6 transitions of H2O. Most species trace kinetic temperatures in the range between 100 and 150 K and H2 volume densities in the range between 10^5 and 10^6 cm^-3. The species with temperatures and / or densities outside of this range include the H2CO transitions tracing a very high temperature (315 K) and density (1.4x10^6 cm^-3) component and SO corresponding to the lowest temperature (56 K) measured as a part of this line survey. The observed lines/species reveal a range of physical conditions (gas density /temperature) involving structures at high density / high pressure, obsoleting the traditional 'clump / interclump' picture of the Orion Bar.

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