arXiv subjects

M. Kriener

Publications and source records attributed to M. Kriener.

At least 37 records · Page 2Linked to original sources

arXiv2012

Anomalous suppression of the superfluid density in the CuxBi2Se3 superconductor upon progressive Cu intercalation

CuxBi2Se3 was recently found to be likely the first example of a time-reversal-invariant topological superconductor accompanied by helical Majorana fermions on the surface. Here we present that progressive Cu intercalation into this system introduces significant disorder and leads to an anomalous suppression of the superfluid density which was obtained from the measurements of the lower critical field. At the same time, the transition temperature T_c is only moderately suppressed, which agrees with a recent prediction for the impurity effect in this class of topological superconductors bearing strong spin-orbit coupling. Those unusual disorder effects give support to the possible odd-parity pairing state in CuxBi2Se3.

cond-mat.supr-con↗

arXiv2011

Topological Superconductivity in CuxBi2Se3

A topological superconductor (TSC) is characterized by the topologically-protected gapless surface state that is essentially an Andreev bound state consisting of Majorana fermions. While a TSC has not yet been discovered, the doped topological insulator CuxBi2Se3, which superconducts below ~3 K, has been predicted to possess a topological superconducting state. We report that the point-contact spectra on the cleaved surface of superconducting CuxBi2Se3 present a zero-bias conductance peak (ZBCP) which signifies unconventional superconductivity. Theoretical considerations of all possible superconducting states help us conclude that this ZBCP is due to Majorana Fermions and gives evidence for a topological superconductivity in CuxBi2Se3. In addition, we found an unusual pseudogap that develops below ~20 K and coexists with the topological superconducting state.

cond-mat.supr-con↗

arXiv2011

Electrochemical synthesis and superconducting phase diagram of Cu_xBi2Se3

The superconducting Cu_xBi_2Se_3 is an electron-doped topological insulator and is a prime candidate of the topological superconductor which still awaits discovery. The electrochemical intercalation technique for synthesizing Cu_xBi2Se3 offers good control of restricting Cu into the van-der-Waals gap and yields samples with shielding fractions of up to ~50%. We report essential details of this synthesis technique and present the established superconducting phase diagram of T_c vs x, along with a diagram of the shielding fraction vs x. Intriguingly, those diagrams suggest that there is a tendency to spontaneously form small islands of optimum superconductor in this material.

cond-mat.supr-con↗

arXiv2011

Magnetic Phase Diagram of Li_2(Pd_{1-x}Pt_x)_3B by AC Susceptometry

The H-T phase diagram and several superconducting parameters for Li_2(Pd_{1-x}Pt_x)_3B have been determined as a function of cation substitution x. Notably, the coherence length may be linear in platinum concentration. Despite the superconducting pairing state and band structure apparently changing fundamentally, the H-T phase diagram is essentially unchanged. Unusual aspects of the shape of the H-T phase diagram are discussed. The upper critical field H_c2(0) is not anomalously high for any Pt content, likely due to an absence of high carrier masses - in such a case, the value of H_c2(0) would not serve as a probe for novel physics.

cond-mat.supr-con↗

arXiv2011

Direct Measurement of the Out-of-Plane Spin Texture in the Dirac Cone Surface State of a Topological Insulator

We have performed spin- and angle-resolved photoemission spectroscopy of Bi2Te3 and present the first direct evidence for the existence of the out-of-plane spin component on the surface state of a topological insulator. We found that the magnitude of the out-of-plane spin polarization on a hexagonally deformed Fermi surface (FS) of Bi2Te3 reaches maximally 25% of the in-plane counterpart while such a sizable out-of-plane spin component does not exist in the more circular FS of TlBiSe2, indicating that the hexagonal deformation of the FS is responsible for the deviation from the ideal helical spin texture. The observed out-of-plane polarization is much smaller than that expected from existing theory, suggesting that an additional ingredient is necessary for correctly understanding the surface spin polarization in Bi2Te3.

cond-mat.mes-hall↗

arXiv2011

Bulk superconducting phase with a full energy gap in the doped topological insulator Cu_xBi_2Se_3

The superconductivity recently found in the doped topological insulator Cu_xBi_2Se_3 offers a great opportunity to search for a topological superconductor. We have successfully prepared a single-crystal sample with a large shielding fraction and measured the specific-heat anomaly associated with the superconductivity. The temperature dependence of the specific heat suggests a fully-gapped, strong-coupling superconducting state, but the BCS theory is not in full agreement with the data, which hints at a possible unconventional pairing in Cu_xBi_2Se_3. Also, the evaluated effective mass of 2.6m_e (m_e is the free electron mass) points to a large mass enhancement in this material.

cond-mat.supr-con↗

arXiv2011

Crystallographic and superconducting properties of the fully-gapped noncentrosymmetric 5d-electron superconductors CaMSi3 (M=Ir, Pt)

We report crystallographic, specific heat, transport, and magnetic properties of the recently discovered noncentrosymmetric 5d-electron superconductors CaIrSi3 (Tc = 3.6 K) and CaPtSi3 (Tc = 2.3 K). The specific heat suggests that these superconductors are fully gapped. The upper critical fields are less than 1 T, consistent with limitation by conventional orbital depairing. High, non-Pauli-limited μ0 Hc2 values, often taken as a key signature of novel noncentrosymmetric physics, are not observed in these materials because the high carrier masses required to suppress orbital depairing and reveal the violated Pauli limit are not present.

cond-mat.supr-con↗

arXiv2009

AC susceptibility study of superconducting aluminium-doped silicon carbide

In 2007, type-I superconductivity in heavily boron-doped silicon carbide was discovered. The question arose, if it is possible to achieve a superconducting phase by introducing dopants different from boron. Recently, aluminum-doped silicon carbide was successfully found to superconduct by means of resistivity and DC magnetization measurements. In contrast to boron-doped silicon carbide, the aluminum doped system is treated as a type-II superconductor because of the absence of an hysteresis in data measured upon decreasing and increasing temperature in finite magnetic fields. In this paper, results of a recent AC susceptibility study on aluminum-doped silicon carbide are presented. In higher applied DC magnetic fields and at low temperatures, a weak indication of supercooling with a width of a few mK is found. This supports the conclusion that aluminum-doped silicon carbide is located near to the border between type-I and type-II superconductivity, as pointed out in a recent theoretical work, too.

cond-mat.supr-con↗

arXiv2009

Magnetic and structural transitions in La$_{1-x}A_{1-x}$CoO$_{3}$ ($A$ = Ca, Sr, and Ba)

We report thermal-expansion, lattice-constant, and specific-heat data of the series La_1-xA_xCoO_3 for 0<= x <= 0.30 with A = Ca, Sr, and Ba. For the undoped compound LaCoO_3 the thermal-expansion coefficient alpha(T) exhibits a pronounced maximum around T=50K caused by a temperature-driven spin-state transition from a low-spin state of the Co^{3+$ ions at low towards a higher spin state at higher temperatures. The partial substitution of the La^{3+} ions by divalent Ca^{2+}, Sr^{2+}, or Ba^{2+} ions causes drastic changes in the macroscopic properties of LaCoO3. The large maximum in alpha(T) is suppressed and completely vanishes for x> 0.12. For A = Ca three different anomalies develop in alpha(T) with further increasing x, which are visible in specific-heat data as well. Together with temperature-dependent x-ray data we identify several phase transitions as a function of the doping concentration x and temperature. From these data we propose an extended phase diagram for La_1-xCa_xCoO_3.

cond-mat.str-el↗

arXiv2009

Specific heat of aluminium-doped superconducting silicon carbide

The discoveries of superconductivity in heavily boron-doped diamond, silicon and silicon carbide renewed the interest in the ground states of charge-carrier doped wide-gap semiconductors. Recently, aluminium doping in silicon carbide successfully yielded a metallic phase from which at high aluminium concentrations superconductivity emerges. Here, we present a specific-heat study on superconducting aluminium-doped silicon carbide. We observe a clear jump anomaly at the superconducting transition temperature 1.5 K indicating that aluminium-doped silicon carbide is a bulk superconductor. An analysis of the jump anomaly suggests BCS-like phonon-mediated superconductivity in this system.

cond-mat.supr-con↗

arXiv2008

Superconductivity in heavily boron-doped silicon carbide

The discoveries of superconductivity in heavily boron-doped diamond (C:B) in 2004 and silicon (Si:B) in 2006 renew the interest in the superconducting state of semiconductors. Charge-carrier doping of wide-gap semiconductors leads to a metallic phase from which upon further doping superconductivity can emerge. Recently, we discovered superconductivity in a closely related system: heavily-boron doped silicon carbide (SiC:B). The sample used for that study consists of cubic and hexagonal SiC phase fractions and hence this lead to the question which of them participates in the superconductivity. Here we focus on a sample which mainly consists of hexagonal SiC without any indication for the cubic modification by means of x-ray diffraction, resistivity, and ac susceptibility.

cond-mat.supr-con↗

arXiv2008

Superconductivity of hexagonal heavily-boron doped silicon carbide

In 2004 the discovery of superconductivity in heavily boron-doped diamond (C:B) led to an increasing interest in the superconducting phases of wide-gap semiconductors. Subsequently superconductivity was found in heavily boron-doped cubic silicon (Si:B) and recently in the stochiometric ''mixture'' of heavily boron-doped silicon carbide (SiC:B). The latter system surprisingly exhibits type-I superconductivity in contrast to the type-II superconductors C:B and Si:B. Here we will focus on the specific heat of two different superconducting samples of boron-doped SiC. One of them contains cubic and hexagonal SiC whereas the other consists mainly of hexagonal SiC without any detectable cubic phase fraction. The electronic specific heat in the superconducting state of both samples SiC:B can be described by either assuming a BCS-type exponentional temperature dependence or a power-law behavior.

cond-mat.supr-con↗

arXiv2008

Anomalous expansion and phonon damping due to the Co spin-state transition in RCoO_3 with R = La, Pr, Nd and Eu

We present a combined study of the thermal expansion and the thermal conductivity of the perovskite series RCoO_3 with R = La, Nd, Pr and Eu. The well-known spin-state transition in LaCoO_3 is strongly affected by the exchange of the R ions due to their different ionic radii, i.e. chemical pressure. This can be monitored in detail by measurements of the thermal expansion, which is a highly sensitive probe for detecting spin-state transitions. The Co ions in the higher spin state act as additional scattering centers for phonons, therefore suppressing the phonon thermal conductivity. Based on the analysis of the interplay between spin-state transition and heat transport, we present a quantitative model of the thermal conductivity for the entire series. In PrCoO_3, an additional scattering effect is active at low temperatures. This effect arises from the crystal field splitting of the 4f multiplet, which allows for resonant scattering of phonons between the various 4f levels.

cond-mat.str-el↗

arXiv2008

Specific heat and electronic states of superconducting boron-doped silicon carbide

The discoveries of superconductivity in the heavily-boron doped semiconductors diamond (C:B) in 2004 and silicon (Si:B) in 2006 have renewed the interest in the physics of the superconducting state of doped semiconductors. Recently, we discovered superconductivity in the closely related ''mixed'' system heavily boron-doped silcon carbide (SiC:B). Interestingly, the latter compound is a type-I superconductor whereas the two aforementioned materials are type-II. In this paper we present an extensive analysis of our recent specific-heat study, as well as the band structure and expected Fermi surfaces. We observe an apparent quadratic temperature dependence of the electronic specific heat in the superconducting state. Possible reasons are a nodal gap structure or a residual density of states due to non-superconducting parts of the sample. The basic superconducting parameters are estimated in a Ginzburg-Landau framework. We compare and discuss our results with those reported for C:B and Si:B. Finally, we comment on possible origins of the difference in the superconductivity of SiC:B compared to the two ''parent'' materials C:B and Si:B.

cond-mat.supr-con↗

arXiv2008

Melting of magnetic correlations in charge-orbital ordered La(0.5)Sr(1.5)MnO(4) : competition of ferro and antiferromagnetic states

The magnetic correlations in the charge- and orbital-ordered manganite La(0.5)Sr(1.5)MnO(4) have been studied by elastic and inelastic neutron scattering techniques. Out of the well-defined CE-type magnetic structure with the corresponding magnons a competition between CE-type and ferromagnetic fluctuations develops. Whereas ferromagnetic correlations are fully suppressed by the static CE-type order at low temperature, elastic and inelastic CE-type correlations disappear with the melting of the charge-orbital order at high temperature. In its charge-orbital disordered phase, La(0.5)Sr(1.5)MnO(4) exhibits a dispersion of ferromagnetic correlations which remarkably resembles the magnon dispersion in ferromagnetically ordered metallic perovskite manganites.

cond-mat.str-el↗

arXiv2007

Magnetoelastic coupling in RETiO3 (RE = La, Nd, Sm, Gd, Y)

A detailed analysis of the crystal structure in RETiO3 with RE = La, Nd, Sm, Gd, and Y reveals an intrinsic coupling between orbital degrees of freedom and the lattice which cannot be fully attributed to the structural deformation arising from bond-length mismatch. The TiO6 octahedra in this series are all irregular with the shape of the distortion depending on the RE ionic radius. These octahedron distortions vary more strongly with temperature than the tilt and rotation angles. Around the Ti magnetic ordering all compounds exhibit strong anomalies in the thermal-expansion coefficients, these anomalies exhibit opposite signs for the antiferromagnetic and ferromagnetic compounds. Furthermore the strongest effects are observed in the materials close to the magnetic cross-over from antiferromagnetic to ferromagnetic order.

cond-mat.str-el↗

arXiv2006

Magnetoelastic coupling across the metamagnetic transition in Ca$_{2-x}$Sr$_x$RuO$_4$ (0.2 < x < 0.5)

The magnetoelastic coupling in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$ and in Ca$_{1.5}$Sr$_{0.5}$RuO$_4$ has been studied combining high-resolution dilatometer and diffraction techniques. Both compounds exhibit strong anomalies in the thermal-expansion coefficient at zero and at high magnetic field as well as an exceptionally large magnetostriction. All these structural effects, which are strongest in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$, point to a redistribution of electrons between the different $t_{2g}$ orbitals tuned by temperature and magnetic field. The temperature and the field dependence of the thermal-expansion anomalies in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$ yield evidence for a critical end-point lying close to the low-temperature metamagnetic transition; however, the expected scaling relations are not well fulfilled.

cond-mat.str-el↗

arXiv2006

Evidence for Multiple Phase Transitions in La_1-xCa_xCoO_3

We report thermal-expansion and specific-heat data of the series La_1-xCa_xCoO_3 for 0 <= x <= 0.3. For x = 0 the thermal-expansion coefficient alpha(T) features a pronounced maximum around T = 50 K caused by a temperature-dependent spin-state transition from a low-spin state (S=0) at low temperatures towards a higher spin state of the Co^3+ ions. The partial substitution of the La^3+ ions by divalent Ca^2+ ions causes drastic changes in the macroscopic properties of LaCoO_3. Around x ~ 0.125 the large maximum in alpha(T) has completely vanished. With further increasing x three different anomalies develop.

cond-mat.str-el↗