arXiv subjects

M. Tafalla

Publications and source records attributed to M. Tafalla.

At least 19 recordsLinked to original sources

arXiv2026

PRODIGE - envelope to disk with NOEMA: VII. (Complex) organic molecules in the NGC1333 IRAS4B1 outflow: A new laboratory for shock chemistry

Shock chemistry is an excellent tool to shed light on the formation and destruction mechanisms of complex organic molecules (COMs). The L1157-mm outflow is the only low-mass protostellar outflow that has extensively been studied in this regard. Using the data taken as part of the PRODIGE (PROtostars & DIsks: Global Evolution) large program, we aim to map COM emission and derive the molecular composition of the protostellar outflow driven by the Class 0 protostar NGC1333 IRAS4B1 to introduce it as a new laboratory to study the impact of shocks on COM chemistry. In addition to typical outflow tracers such as SiO and CO, outflow emission is seen from H2CO, HNCO, and HC3N, as well as from the COMs CH3OH, CH3CN, and CH3CHO, and even from deuterated species such as DCN, D2CO, and CH2DOH. Maps of integrated intensity ratios between CH3OH and DCN, D2CO, and CH3CHO reveal gradients with distance from the protostar. Intensity ratio maps of HC3N and CH3CN with respect to CH3OH peak in the southern lobe where temperatures are highest. Rotational temperatures derived towards two positions, one in each lobe, are found in the range ~50-100 K. Abundances with respect to CH3OH are higher by factors of a few than for the L1157-B1. In conclusion, for the first time, we securely detected the COMs CH3CN, CH3CHO, and CH2DOH in the IRAS 4B1 outflow, serendipitously with limited sensitivity and bandwidth. Targeted observations will enable the discovery of new COMs and a more detailed analysis of their emission. Morphological differences between molecules in the IRAS 4B1 outflow lobes and their relative abundances provide first proof that this outflow is a promising new laboratory for shock chemistry, which will offer crucial information on COM formation and destruction as well as outflow structure and kinematics.

astro-ph.GA↗

arXiv2026

Interaction of the central jet with the surrounding gas in the protostellar outflow from IRAS 04166+2706

$Context.$ The outflow from the Class 0 protostar IRAS 04166+2706 (hereafter IRAS 04166) contains a remarkably symmetric jet-like component of extremely high-velocity (EHV) gas. $Aims.$ We studied the IRAS 04166 outflow and investigated the relation between its EHV component and the slower outflow gas. $Methods.$ We mosaicked the CO(2--1) emission from the IRAS 04166 outflow using the 12m and the Compact Arrays of ALMA. We also developed a ballistic toy model of the gas ejected laterally from a jet to interpret the data. $Results.$ In agreement with previous observations, the ALMA data show that the slow outflow component is distributed in two opposed conical lobes and has a shear-flow pattern with velocity increasing toward the axis. The EHV gas consists of a series of arc-like condensations that span the full width of the conical lobes and merge with their walls, suggesting that the fast and slow outflow components are physically connected. In addition, position--velocity diagrams along the outflow axis show finger-like extensions that connect the EHV emission with the origin of the diagram, as if part of the EHV gas had been decelerated by its interaction with the low-velocity outflow. A ballistic model can reproduce these finger-like extensions assuming that the EHV gas consists of jet material that has been ejected laterally over a short period of time and has transferred part of its momentum to the surrounding shear flow. $Conclusions.$ The EHV gas in the IRAS 04166 outflow seems to play a role in the acceleration of the slower gas component. The presence of similar finger-like extensions in the position-velocity diagrams of other outflows suggests that this process may be occurring in other systems, even if the EHV component is not seen because it has an atomic composition.

astro-ph.GA↗

arXiv2025

ANTIHEROES-PRODIGE: Quantifying the connection from envelope to disk with the IRAM 30m telescope and NOEMA I. Attack of the streamers: L1448N's fight for order in the chaos

Star formation is a hierarchical process ranging from molecular clouds down to individual protostars. In particular how infalling asymmetric structures, called streamers, delivering new material onto protostellar systems, are connected to the surrounding envelope is not understood. We investigate the connection between the cloud material at 10000 au scales down to 300 au scales towards L1448N in the Perseus star-forming region hosting three young Class 0/I protostellar systems. Sensitive molecular line observations taken with the IRAM 30m telescope and NOEMA at 1.4 mm are used to study the kinematic properties in the region traced by the molecular lines. Several infalling streamers are associated with the protostellar systems, some of them traced by C18O and DCN, while one of them is bright in SO and SO2. The kinematic properties of the former streamers are consistent with the velocities observed at large envelope scales of 10000 au, while the latter case show different kinematics. The masses and infall rates of the streamers are 0.01 Msun and 0.01-0.1 Msun and 10^-6 Msun/yr and 5-18x10^-6 Msun/yr for IRS3A and IRS3C, respectively. The envelope mass in the L1448N region is ~16Msun, thus the mass of a single streamer is low compared to the envelope mass (<1%). However, compared to the estimated mass of the protostellar systems a single streamer could deliver up to 1% and 8-17% of mass towards IRS3A (M*~1.2 Msun) and IRS3C (M*~1 Msun), respectively. The rotational signatures of structures in L1448N are all connected - from the large-scale envelope, infalling streamers, down to the rotation of all three disks. Two of the three Class 0/I protostellar systems are still fed by this surrounding material, which can be associated to the remnant envelope. However, we also find a streamer that is bright in SO and SO2 towards IRS3C that could be connected to a nearby sulfur reservoir.

astro-ph.SR↗

arXiv2025

PRODIGE - envelope to disk with NOEMA: V. Low 12C/13C ratios for CH3OH and CH3CN in hot corinos

The 12C/13C isotope ratio has been derived towards numerous cold clouds (20-50 K) and a couple protoplanetary disks and exoplanet atmospheres. However, direct measurements of this ratio in the warm gas (>100 K) around young low-mass protostars remain scarce, but are required to study its evolution during star and planet formation. We derived 12C/13C ratios from the isotopologues of the complex organic molecules (COMs) CH3OH and CH3CN in the warm gas towards seven Class 0/I protostellar systems to improve our understanding of the evolution of the 12C/13C ratios during star and planet formation. We used the data that were taken as part of the PRODIGE large program with the NOEMA at 1mm. The emission of CH3OH and CH3CN is spatially unresolved in the PRODIGE data (300au scale). Derived rotational temperatures exceed 100K, telling us that they trace the gas of the hot corino, where CH3CN probes hotter regions than CH3OH on average (290 K versus 180 K). The column density ratios between the 12C and 13C isotopologues, derived from LTE analysis, range from 4 to 30, thus, are significantly lower than the expected local ISM isotope ratio of about 68. Assuming that CH3CN and CH3OH may inherit the 12C/13C ratio from their precursor species, astrochemical models were conducted for the latter and compared with our observational results. We conclude that an enrichment in 13C in COMs at the earliest protostellar stages is likely inherited from the COMs' precursor species, whose 12C/13C ratios are set during the prestellar stage via isotopic exchange reactions. This also implies that low 12C/13C ratios observed at later evolutionary stages could at least partially be inherited. A final conclusion on 12C/13C ratios in protostellar environments requires improved observations to tackle current observational limitations and additional modelling efforts.

astro-ph.GA↗

arXiv2025

Star formation from low to high mass: A comparative view

Star formation has often been studied by separating the low- and high-mass regimes with an approximate boundary at 8M_sun. While some of the outcomes of the star-formation process are different between the two regimes, it is less clear whether the physical processes leading to these outcomes are that different at all. Here, we systematically compare low- and high-mass star formation by reviewing the most important processes and quantities from an observational and theoretical point of view. We identify three regimes where processes are either similar, quantitatively or qualitatively different between low- and high-mass star formation. Similar characteristics can be identified for the turbulent gas properties and density structures of the star-forming regions. Many of the observational characteristics also do not depend that strongly on the environment. Quantitative differences can be found for outflow, infall and accretion rates as well as mean column and volume densities. Also the multiplicity significantly rises from low- to high-mass stars. The importance of the magnetic field for the formation processes appears still less well constrained. Qualitative differences between low- and high-mass star formation relate mainly to the radiative and ionizing feedback that occurs almost exclusively in regions forming high-mass stars. Nevertheless, accretion apparently can continue via disk structures in ionized accretion flows. Finally, we discuss to what extent a unified picture of star formation over all masses is possible and which issues need to be addressed in the future.

astro-ph.GA↗

arXiv2024

Emergence of high-mass stars in complex fiber networks (EMERGE) III. Fiber networks in Orion

The Herschel observations unveiled the complex organisation of the interstellar medium in networks of parsec-scale filaments over the past decade. At the same time, networks of fibers have been recognised describing the gas structures in star-forming regions at sub-parsec scales. We aim to investigate the dense gas organisation prior to the formation of stars in sample of 7 star-forming regions within Orion. This EMERGE Early ALMA Survey includes OMC-1/-2/-3/-4 South, LDN 1641N, NGC 2023, and the Flame Nebula, all surveyed at high spatial resolution (4.5'' or $\sim2000$ au) in N$_2$H$^+$ (1$-$0) using ALMA+IRAM-30m observations. We systematically investigated the star-forming gas spatial distribution, its column density variations, its thermal structure, and its internal motions in a wide range of environments. From the analysis of the gas kinematics, we identified and characterised a total of 152 velocity-coherent fibers in our survey, which appear to be the preferred organisational unit for the dense gas in low-, intermediate- and high-mass star-forming regions alike. Despite the uneven density of fibers within these sub-parsec networks, the masses and lengths of these objects show similar distributions and consistent median values, as well as (trans-)sonic motions, in all of our targets. The comparison between the fiber line masses and virial line masses suggests the majority of these objects to be sub-virial. Those fibers closer to the virial condition, however, also have the most protostars associated to them, proving to be intimately connected to star formation. Finally, the surface density of fibers is linearly correlated with the total dense gas mass throughout roughly one order of magnitude in both parameters. These findings demonstrate how the formation and evolution of fibers networks can explain the current star formation properties of their host region.

astro-ph.GA↗

arXiv2024

Emergence of high-mass stars in complex fiber networks (EMERGE) IV. Environmental dependence of the fiber widths

Despite their variety of scales throughout the interstellar medium, filaments in nearby low-mass clouds show a characteristic width of $\sim$ 0.1 pc from the analysis of {\it Herschel} observations. The origin of this characteristic width, however, has been a matter of intense discussions during the last decade. We explored a possible variation in this typical width with the EMERGE Early ALMA Survey, which includes seven star-forming regions in Orion (OMC-1/-2/-3/-4 South, LDN 1641N, NGC 2023, Flame Nebula). These targets, which exhibit different physical conditions, star formation histories, mass, and density regimes, were homogeneously surveyed at a resolution of $\sim$ 2000 au in N$_2$H$^+$ (1$-$0) with ALMA+IRAM-30m observations. We characterised the column density and temperature radial profiles of the 152 fibers identified in the survey using the automatic fitting routine FilChap. These Orion fibers show a departure from the isothermal condition with significant outward temperature gradients with $\nabla T_\mathrm{K} > 30$ K pc$^{-1}$. They also show a median full width at half maximum ($FWHM$) of $\sim 0.05$ pc, with a corresponding median aspect ratio of $\sim2$. More relevantly, we observe a systematic variation in these fiber $FWHM$ between different regions in our sample, and a direct inverse dependence of these $FWHM$ on their central column density, $N_0$, above $\gtrsim 10^{22}$ cm$^{-2}$. This dependency agrees with the expected $N_0-FWHM$ anti-correlation predicted in previous theoretical studies. Our homogeneous analysis returns the first observational evidence of an intrinsic and systematic variation in the fiber widths across different star-forming regions. While sharing comparable mass, length, and kinematic properties in all of our targets, fibers appear to adjust their $FWHM$ to their density and to the pressure in their host environment.

astro-ph.GA↗

arXiv2024

Emergence of high-mass stars in complex fiber networks (EMERGE). I. Early ALMA Survey: observations and massive data reduction

(Abridged) Recent molecular surveys have revealed a rich gas organization of sonic-like fibers in all kind of environments prior to the formation of low- and high-mass stars. This paper introduces the EMERGE project aiming to investigate whether complex fiber arrangements could explain the origin of high-mass stars and clusters. We analyzed the EMERGE Early ALMA Survey including 7 star-forming regions in Orion (OMC-1/2/3/4 South, L1641N, NGC2023, and Flame Nebula) homogeneously surveyed in both molecular lines (N$_2$H$^+$ J=1-0, HNC J=1-0, plus HC3N J=10-9) and 3mm-continuum using a combination of interferometric ALMA mosaics and IRAM-30m single-dish (SD) maps. Based on our low-resolution (SD) observations, we describe the global properties of our sample covering a wide range of physical conditions including low-, intermediate, and high-mass star-forming regions in different evolutionary stages. Their comparison with ancillary YSO catalogs denotes N$_2$H$^+$ as the best proxy for the dense, star-forming gas in our targets showing a constant star formation efficiency and a fast time evolution of <1 Myr. While apparently clumpy and filamentary in our SD data, all targets show a much more complex fibrous substructure at the enhanced resolution of our ALMA+IRAM-30m maps. A large number of filamentary features at sub-parsec scales are clearly recognized in the high-density gas traced by N$_2$H$^+$ directly connected to the formation of individual protostars. This complex gas organization appears to extend further into the more diffuse gas traced by HNC. This paper presents the EMERGE Early ALMA survey including a first data release of continuum maps and spectral products for this project to be analysed in future papers of this series. A first look at these results illustrates the need of advanced data combination techniques to investigate the intrinsic multi-scale, gas structure of the ISM.

astro-ph.GA↗

arXiv2024

PRODIGE -- Planet-forming disks in Taurus with NOEMA. I. Overview and first results for 12CO, 13CO, and C18O

We are performing a line survey of 8 planet-forming Class II disks in Taurus with the IRAM NOrthern Extended Millimeter Array (NOEMA), as a part of the MPG-IRAM Observatory Program PRODIGE (PROtostars and DIsks: Global Evolution; PIs: P. Caselli and Th. Henning). Compact and extended disks around T Tauri stars CI, CY, DG, DL, DM, DN, IQ Tau, and UZ Tau E are observed in ~80 lines from >20 C-, O,- N-, and S-bearing species. The observations in four spectral settings at 210-280 GHz with $1\sigma$ rms sensitivity of ~ 8-12 mJy/beam at 0.9" and 0.3 km/s resolution will be completed in 2024. The uv-visibilities are fitted with the DiskFit model to obtain key stellar and disk properties. In this paper, the combined $^{12}$CO, $^{13}$CO and C$^{18}$O $J = 2-1$ data are presented. We find that the CO fluxes and disk masses inferred from dust continuum tentatively correlate with the CO emission sizes. We constrain dynamical stellar masses, geometries, temperatures, the CO column densities and gas masses for each disk. The best-fit temperatures at 100 au are ~ 17-37 K, and decrease radially with the power-law exponent q ~ 0.05-0.76. The inferred CO column densities decrease radially with the power-law exponent p ~ 0.2-3.1. The gas masses estimated from $^{13}$CO (2-1) are ~ $0.001-0.2 M_\textrm{Sun}$. The best-fit CO column densities point to severe CO freeze-out in the disks. The DL Tau disk is an outlier, and has either stronger CO depletion or lower gas mass than the rest of the sample. The CO isotopologue ratios are roughly consistent with the observed values in disks and the low-mass star-forming regions.

astro-ph.GA↗

arXiv2023

Characterizing the line emission from molecular clouds. II. A comparative study of California, Perseus, and Orion A

$Aims.$ We characterize the molecular-line emission of three clouds whose star-formation rates span one order of magnitude: California, Perseus, and Orion A. $Methods.$ We use stratified random sampling to select positions representing the different column density regimes of each cloud and observe them with the IRAM-30m telescope. We cover the 3 mm wavelength band and focus our analysis on CO, HCN, CS, HCO+, HNC, and N2H+. $Results.$ We find that the line intensities depend most strongly on the H2 column density. A secondary effect, especially visible in Orion A, is a dependence of the line intensities on the gas temperature. We explored a method that corrects for temperature variations and show that, when it is applied, the emission from the three clouds behaves very similarly. CO intensities vary weakly with column density, while the intensity of traditional dense-gas tracers such as HCN, CS, and HCO+ varies almost linearly with column density. N2H+ differs from all other species in that it traces only cold dense gas. The intensity of the rare HCN and CS isotopologs reveals additional temperature-dependent abundance variations. Overall, the clouds have similar chemical compositions that, as the depth increases, are sequentially dominated by photodissociation, gas-phase reactions, molecular freeze-out, and stellar feedback in the densest parts of Orion A. Our observations also allowed us to calculate line luminosities for each cloud, and a comparison with literature values shows good agreement. We used our HCN data to explore the behavior of the HCN conversion factor, finding that it is dominated by the emission from the outermost cloud layers. It also depends strongly on the gas kinetic temperature. Finally, we show that the HCN/CO ratio provides a gas volume density estimate, and that its correlation with the column density resembles that found in extragalactic observations.

astro-ph.GA↗

arXiv2023

A constant N$_2$H$^+$(1-0)-to-HCN(1-0) ratio on kiloparsec scales

Nitrogen hydrides such as NH$_3$ and N$_2$H$^+$ are widely used by Galactic observers to trace the cold dense regions of the interstellar medium. In external galaxies, because of limited sensitivity, HCN has become the most common tracer of dense gas over large parts of galaxies. We provide the first systematic measurements of N$_2$H$^+$(1-0) across different environments of an external spiral galaxy, NGC6946. We find a strong correlation ($r>0.98,p<0.01$) between the HCN(1-0) and N$_2$H$^+$(1-0) intensities across the inner $\sim8\mathrm{kpc}$ of the galaxy, at kiloparsec scales. This correlation is equally strong between the ratios N$_2$H$^+$(1-0)/CO(1-0) and HCN(1-0)/CO(1-0), tracers of dense gas fractions ($f_\mathrm{dense}$). We measure an average intensity ratio of N$_2$H$^+$(1-0)/HCN(1-0)$=0.15\pm0.02$ over our set of five IRAM-30m pointings. These trends are further supported by existing measurements for Galactic and extragalactic sources. This narrow distribution in the average ratio suggests that the observed systematic trends found in kiloparsec-scale extragalactic studies of $f_\mathrm{dense}$ and the efficiency of dense gas (SFE$_\mathrm{dense}$) would not change if we employed N$_2$H$^+$(1-0) as a more direct tracer of dense gas. At kiloparsec scales our results indicate that the HCN(1-0) emission can be used to predict the expected N$_2$H$^+$(1-0) over those regions. Our results suggest that, even if HCN(1-0) and N$_2$H$^+$(1-0) trace different density regimes within molecular clouds, subcloud differences average out at kiloparsec scales, yielding the two tracers proportional to each other.

astro-ph.GA↗

arXiv2022

PRODIGE -- Envelope to Disk with NOEMA II. Small-scale temperature structure and a streamer feeding the SVS13A protobinary using CH3CN and DCN

Aims. We present high sensitivity and high-spectral resolution NOEMA observations of the Class 0/I binary system SVS13A, composed of the low-mass protostars VLA4A and VLA4B with a separation of ~90 au. VLA4A is undergoing an accretion burst that enriches the chemistry of the surrounding gas. This gives us an excellent opportunity to probe the chemical and physical conditions as well as the accretion process. Methods. We observe the (12K-11K) lines of CH3CN and CH313CN, the DCN (3-2) line, and the C18O (2-1) line toward SVS13A using NOEMA. Results. We find complex line profiles at disk scales which cannot be explained by a single component or pure Keplerian motion. By adopting two velocity components to model the complex line profiles, we find that the temperatures and densities are significantly different between these two components. This suggests that the physical conditions of the emitting gas traced via CH3CN can change dramatically within the circumbinary disk. In addition, combining our observations of DCN (3-2) with previous ALMA high-angular-resolution observations, we find that the binary system (or VLA4A) might be fed by an infalling streamer from envelope scales (~700 au). If this is the case, this streamer contributes to the accretion of material onto the system with a rate of at least 1.4x10-6 Msun yr-1. Conclusions. We conclude that the CH3CN emission in SVS13A traces hot gas from a complex structure. This complexity might be affected by a streamer that is possibly infalling and funneling material into the central region.

astro-ph.GA↗

arXiv2022

A large (~1 pc) contracting envelope around the prestellar core L1544

Prestellar cores, the birthplace of Sun-like stars, form from the fragmentation of the filamentary structure that composes molecular clouds, from which they must inherit at least partially the kinematics. Furthermore, when they are on the verge of gravitational collapse, they show signs of subsonic infall motions. How extended these motions are, which depends on how the collapse occurs, remains largely unknown. We want to investigate the kinematics of the envelope that surrounds the prototypical prestellar core L1544, studying the cloud-core connection. To our aims, we observed the $\rm HCO^+$(1-0) transition in a large map. \hcop is expected to be abundant in the envelope, making it an ideal probe of the large-scale kinematics in the source. We modelled the spectrum at the dust peak by means of a non local-thermodynamical-equilibrium radiative transfer. In order to reproduce the spectrum at the dust peak, a large ($\sim 1\, \rm pc$) envelope is needed, with low density (tens of $\rm cm^{-3}$ at most) and contraction motions, with an inward velocity of $\approx 0.05\,\rm km \, s^{-1}$. We fitted the data cube using the Hill5 model, which implements a simple model {for the optical depth and excitation temperature profiles along the line-of-sight,} in order to obtain a map of the infall velocity. This shows that the infall motions are extended, with typical values in the range $0.1-0.2\,\rm km \, s^{-1}$. Our results suggest that the contraction motions extend in the diffuse envelope surrounding the core, which is consistent with recent magnetic field measurements in the source, which showed that the envelope is magnetically supercritical.

astro-ph.GA↗

arXiv2022

PRODIGE -- Envelope to disk with NOEMA I. A 3000 au streamer feeding a Class I protostar

Context. In the past few years, there has been a rise in the detection of streamers, asymmetric flows of material directed toward the protostellar disk with material from outside the star's natal core. It is unclear how they affect the process of mass accretion, in particular beyond the Class 0 phase. Aims. We investigate the gas kinematics around Per-emb-50, a Class I source in the crowded star-forming region NGC 1333. Our goal is to study how the mass infall proceeds from envelope to disk scales in this source. Results. We discover a streamer delivering material toward Per-emb-50 in H$_2$CO and C$^{18}$O emission. The streamer's emission can be well described by the analytic solutions for an infalling parcel of gas along a streamline with conserved angular momentum, both in the image plane and along the line of sight velocities. The streamer has a mean infall rate of $1.3 \times 10^{ -6}$ M$_{ \odot}$ yr$^{ -1}$, $5 -10$ times higher than the current accretion rate of the protostar. SO and SO$_2$ emission reveal asymmetric infall motions in the inner envelope, additional to the streamer around Per-emb-50. Furthermore, the presence of SO$_2$ could mark the impact zone of the infalling material. Conclusions. The streamer delivers sufficient mass to sustain the protostellar accretion rate and might produce an accretion burst, which would explain the protostar's high luminosity with respect to other Class I sources. Our results highlight the importance of late infall for protostellar evolution: streamers might provide a significant amount of mass for stellar accretion after the Class 0 phase.

astro-ph.GA↗

arXiv2021

Evolutionary view through the starless cores in Taurus: deuteration in TMC 1-C and TMC 1-CP

The chemical and physical evolution of starless and pre-stellar cores are of paramount importance to understanding the process of star formation. The Taurus Molecular Cloud cores TMC 1-C and TMC 1-CP share similar initial conditions and provide an excellent opportunity to understand the evolution of the pre-stellar core phase. We investigated the evolutionary stage of starless cores based on observations towards the prototypical dark cores TMC 1-C and TMC 1-CP, mapping them in the CS $3\rightarrow 2$, C$^{34}$S $3\rightarrow 2$, $^{13}$CS $2\rightarrow 1$, DCN $1\rightarrow 0$, DCN $2\rightarrow 1$, DNC $1\rightarrow 0$, DNC $2\rightarrow 1$, DN$^{13}$C $1\rightarrow 0$, DN$^{13}$C $2\rightarrow 1$, N$_2$H$^+$ $1\rightarrow 0$, and N$_2$D$^+$ $1\rightarrow 0$ transitions. We performed a multi-transitional study of CS and its isotopologs, DCN, and DNC lines to characterize the physical and chemical properties of these cores. We studied their chemistry using the state-of-the-art gas-grain chemical code Nautilus and pseudo time-dependent models to determine their evolutionary stage. Observational diagnostics seem to indicate that TMC 1-C is in a later evolutionary stage than TMC 1-CP, with a chemical age $\sim$1 Myr. TMC 1-C shows signs of being an evolved core at the onset of star formation, while TMC 1-CP appears to be in an earlier evolutionary stage due to a more recent formation or, alternatively, a collapse slowed down by a magnetic support.

astro-ph.GA↗

arXiv2021

Gas phase Elemental abundances in Molecular cloudS (GEMS). IV. Observational results and statistical trends

Gas phase Elemental abundances in Molecular CloudS (GEMS) is an IRAM 30m Large Program designed to estimate the S, C, N, and O depletions and gas ionization degree, X(e-), in a set of star-forming filaments of Taurus, Perseus and Orion. Our immediate goal is to build up a complete database of molecular abundances that can serve as an observational basis for estimating X(e-) and the C, O, N, and S depletions through chemical modeling. We observed and derived the abundances of 14 species (13CO, C18O, HCO+, H13CO+, HC18O+, HCN, H13CN, HNC, HCS+, CS, SO, 34SO, H2S, and OCS) in 244 positions, covering the AV 3 to 100 mag, n(H2) a few 10$^{3}$ to 10$^6$ cm$^{-3}$, and Tk 10 to 30 K ranges in these clouds, avoiding protostars, HII regions, and outflows. A statistical analysis is carried out to identify general trends between different species and with physical parameters. Relations between molecules reveal strong linear correlations which define three different families: (1) 13CO and C18O; (2) H13CO+, HC18O+, H13CN, and HNC; and (3) the S-bearing molecules. The abundances of the CO isotopologs increase with the gas kinetic temperature until TK 15 K. For higher temperatures, the abundance remains constant with a scatter of a factor of 3. The abundances of H13CO+, HC18O+, H13CN, and HNC are well correlated with each other, and all of them decrease with molecular hydrogen density, following the law n(H2)$^{-0.8\pm0.2}$. The abundances of S-bearing species also decrease with n(H2) at a rate of (S-bearing/H)gas n(H2)$^{-0.6\pm0.1}$. The abundances of molecules belonging to groups 2 and 3 do not present any clear trend with gas temperature. At scales of molecular clouds, the C18O abundance is the quantity that better correlates with the cloud mass. We discuss the utility of the 13CO/C18O, HCO+/H13CO+, and H13CO+/H13CN abundance ratios as chemical diagnostics of star formation in external galaxies.

astro-ph.GA↗

arXiv2021

Characterizing the line emission from molecular clouds. Stratified random sampling of the Perseus cloud

$Context.$ The traditional approach to characterize the structure of molecular clouds is to map their line emission. $Aims.$ We aim to test and apply a stratified random sampling technique that can characterize the line emission from molecular clouds more efficiently than mapping. $Methods.$ We sampled the molecular emission from the Perseus cloud using the H2 column density as a proxy. We divided the cloud into ten logarithmically spaced column density bins, and we randomly selected ten positions from each bin. The resulting 100 cloud positions were observed with the IRAM 30m telescope, covering the 3mm-wavelength band and parts of the 2 and 1mm bands. $Results.$ We focus our analysis on 11 molecular species detected toward most column density bins. In all cases, the line intensity is tightly correlated with the H2 column density. For the CO isotopologs, the trend is relatively flat, while for high-dipole moment species such as HCN, CS, and HCO+ the trend is approximately linear. We reproduce this behavior with a cloud model in which the gas density increases with column density, and where most species have abundance profiles characterized by an outer photodissociation edge and an inner freeze-out drop. The intensity behavior of the high-dipole moment species arises from a combination of excitation effects and molecular freeze out, with some modulation from optical depth. This quasi-linear dependence with the H2 column density makes the gas at low column densities dominate the cloud-integrated emission. It also makes the emission from most high-dipole moment species proportional to the cloud mass inside the photodissociation edge. $Conclusions.$ Stratified random sampling is an efficient technique for characterizing the emission from whole molecular clouds. It shows that despite the complex appearance of Perseus, its molecular emission follows a relatively simple pattern.

astro-ph.GA↗

arXiv2020

Gas-phase Elemental abundances in Molecular cloudS (GEMS) III. Unlocking the CS chemistry: the CS+O reaction

CS is among the most abundant gas-phase S-bearing molecules in cold dark molecular clouds. It is easily observable with several transitions in the millimeter wavelength range, and has been widely used as a tracer of the gas density in the interstellar medium in our Galaxy and external galaxies. Chemical models fail to account for the observed CS abundances when assuming the cosmic value for the elemental abundance of sulfur. The CS+O -> CO + S reaction has been proposed as a relevant CS destruction mechanism at low temperatures, and could explain the discrepancy between models and observations. Its reaction rate has been experimentally measured at temperatures of 150-400 K, but the extrapolation to lower temperatures is doubtful. Here we calculate the CS+O reaction rate at temperatures <150 K which are prevailing in the interstellar medium. We performed ab initio calculations to obtain the three lowest PES of the CS+O system. These PESs are used to study the reaction dynamics, using several methods to eventually calculate the CS+O thermal reaction rates. We compare the results of our theoretical calculations for 150-400 K with those obtained in the laboratory. Our detailed theoretical study on the CS+O reaction, which is in agreement with the experimental data obtained at 150-400 K, demonstrates the reliability of our approach. After a careful analysis at lower temperatures, we find that the rate constant at 10 K is negligible, which is consistent with the extrapolation of experimental data using the Arrhenius expression. We use the updated chemical network to model the sulfur chemistry in TMC1 based on molecular abundances determined from GEMS project observations. In our model, we take into account the expected decrease of the cosmic ray ionization rate along the cloud. The abundance of CS is still overestimated when assuming the cosmic value for the sulfur abundance.

astro-ph.GA↗