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Manuel Güdel

Publications and source records attributed to Manuel Güdel.

At least 19 recordsLinked to original sources

Self-consistent 1D modelling of Jupiter's upper atmosphere as an exoplanet analogue

Jupiter's upper atmosphere provides a real-world laboratory for validating first-principles models of giant gaseous exoplanets and for constraining the key physical processes that govern them. We extended the 1D first-principles thermo-chemical planetary upper atmosphere model Kompot to simulate hydrogen-rich atmospheres of giant exoplanets and benchmarked it against the archetype giant planet Jupiter. We modelled a longitudinal and latitudinal average thermal and chemical profile of Jupiter's upper atmosphere by solving the equations of energy balance, photochemical kinetics, hydrodynamics, and vertical transport in a 1D radial atmospheric grid. The thermal properties of the upper atmosphere were determined by a balance between heating from solar X-ray and ultraviolet (XUV), and infrared (IR) radiation, thermal conduction, Joule heating, and radiative cooling due to H3+ and CH4. The model results were compared with Jupiter observations from Galileo, JUNO, and other instruments. The simulation results were also used as input in the radiative transfer module of the TauREx code to simulate Jupiter's infrared transmission spectrum. Our model reproduces Jupiter's observed upper-atmospheric thermal structure and observed CH4 volume mixing ratios. The chemical abundances of other gases also exhibit strong agreement with observations and existing photochemical models. Heating and cooling results show that Joule heating is the dominant heating source throughout most of the upper atmosphere. The transmission spectrum indicates the rich presence of CH4 in the near- and mid-IR wavelength ranges. Our physically consistent model framework for Jupiter's upper atmosphere provides a validated baseline for future self-consistent simulations of the thermal and chemical structure of a diverse population of hydrogen-rich exoplanet atmospheres.

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Stellar impact on exoplanetary atmospheric evolution and habitability

This chapter will review the deep connection of planetary habitability and stellar irradiation. We present the long-term stellar evolution as one of the drivers of atmospheric escape and climate changes on exoplanets, as well as the chemistry driven by stellar UV and stellar energetic particles. Habitability is presented in the context of short and long-term stellar variability and evolution to layout what we understand and what we need to know about stellar irradiation to constrain our planetary atmospheric models and choose the best targets for future missions that may characterize those exoplanets.

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JWST/MIRI Detection of Molecular H$_2$ Winds from an Edge-on Class II Source HV Tau C

The evolution of protoplanetary disks is regulated by accretion onto the central star and mass loss through jets and winds. While atomic and ionized outflows are commonly observed, molecular winds in evolved Class II disks remain rarely detected. We characterize the spatial, thermal, kinematic, and dynamical properties of molecular hydrogen (H$_2$) emission from the nearly edge-on Class II disk HV Tau C and assess the impact of its molecular wind. We also constrain accretion using H I recombination lines detected in the same mid-infrared spectrum. Using JWST/MIRI-MRS data from the MINDS Cycle 1 GTO program, we analyze spatially resolved pure-rotational H$_2$ emission. Rotational and position-velocity diagrams constrain excitation and kinematics, from which we estimate wind properties. We detect extended H$_2$ emission tracing a wide-angled, biconical molecular wind extending beyond the near-infrared scattered-light disk, ALMA 887 $μ$m dust continuum, and compact $^{12}$CO ($J=3$-$2$) gas disk. The H$_2$ rotational diagram requires warm ($\sim$600K) and hot ($\sim$2000K) components, similar to those in younger protostars. The gas shows outward motions of a few tens of km s$^{-1}$ and dynamical timescales of tens to hundreds of years. The inferred mass-loss rate is $\sim10^{-8}$ M$_\odot$ yr$^{-1}$, while accretion rates derived from H I lines are $10^{-10}$-$10^{-8}$ M$_\odot$ yr$^{-1}$. The accretion rate may be underestimated because of the edge-on geometry. Our results show that wide-angled molecular H$_2$ winds can persist into the Class II phase, with outflow rates comparable to some protostellar systems, suggesting that such winds may remain important for angular momentum removal, disk evolution, and dispersal. (Abstract modified; see the paper for the full version.)

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Star Planet Interactions

Star-planet interactions (SPIs) describe the continuous exchange of energy, momentum, and mass between exoplanets and their host stars through radiative, tidal, magnetic, and particle-driven processes. Together, these interactions shape the structure, evolution, and observable properties of exoplanetary systems. In this review, we bring together current theoretical and observational understanding of SPIs, highlighting how stellar radiation, winds, and magnetic activity influence planetary atmospheres, interiors, and orbital evolution, while using the Solar System as a valuable reference for interpreting these processes. High-energy stellar radiation, particularly in the far- and extreme-ultraviolet and X-ray bands, drives atmospheric heating, photochemistry, ionisation, and escape. These effects are further influenced by stellar winds and magnetic interactions, which can either protect planetary atmospheres or accelerate their loss over time. Tidal interactions redistribute energy and angular momentum, producing internal heating and driving orbital migration and circularisation. Magnetic star-planet coupling provides additional pathways for energy transfer through reconnection and current systems, potentially enhancing atmospheric escape, heating planetary ionospheres and interiors, and generating observable signatures such as radio emission and enhanced stellar activity. We discuss how these processes work together, emphasising that their long-term impact depends on stellar evolution, planetary properties, atmospheric structure, and magnetic field strength. By presenting radiative, tidal, and magnetic interactions within a unified framework, this review highlights the physical mechanisms that shape planetary environments and identifies the key observational signatures that will complement future studies of exoplanet evolution and habitability.

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Stellar Forcing of (exo)Planetary Environments

The environments of exoplanets are fundamentally shaped by the magnetic activity of their host stars through radiative, plasma, and particle-driven processes. This article presents a comprehensive overview of the four principal forms of stellar forcing that regulate atmospheric structure, chemistry, escape, and long-term planetary evolution: high-energy radiation, magnetized stellar winds, coronal mass ejections, and energetic particles. Using the Sun as a physically resolved benchmark, the discussion extends to increasingly active cool stars to establish a broader picture of star--planet interactions across the main sequence. The article first examines stellar X-ray and extreme ultraviolet emission from chromospheres and coronae, together with variability introduced by flares and magnetic reconnection. Particular attention is given to spectroscopic diagnostics, activity scalings with stellar rotation and age, flare energetics, and the observational links between impulsive and gradual phases of magnetic energy release. The treatment then shifts to magnetized stellar winds, describing the mechanisms that drive them and the role of multidimensional magnetohydrodynamic modeling in determining wind structure, angular momentum loss, and planetary interaction regimes. Solar and stellar coronal mass ejections are explored through their diagnostics, flare associations, propagation, and possible suppression by strong stellar magnetic fields. Finally, galactic and stellar energetic particles are discussed together with methods for estimating particle environments and their consequences for atmospheric chemistry and climate. The article concludes by outlining future observational and numerical developments needed to connect these coupled stellar forcing processes within a unified exoplanetary framework.

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MINDS: Complementary inclinations in the binary system HK Tau reveal gas- and ice-phase chemistry

[Abridged] HK Tau is a roughly equal mass pre-main sequence binary system consisting of a low-inclination primary (57 deg) and an edge-on (83 deg) secondary. We present JWST/MIRI observations targeting both sources, taken as part of the JWST GTO program MINDS. The spectra reveal a line-rich, CO2-dominated primary and a line-poor secondary; this evidence, albeit in line with the evolutionary-motivated trend uncovered by recent observations of binaries at MIRI wavelengths, is likely due to the different configuration of the two sources. Indeed, thermochemical disc models coupled with radiative transfer show that, at inclinations comparable to that of HK Tau B, only ionised atomic lines are expected to remain visible in the spectra. While blocking molecular emission lines, however, the edge-on configuration allows ice absorption bands to be visible against the continuum; in this framework, the HK Tau system provides an unprecedented opportunity to have a simultaneous view of the solid and gaseous component of a pair of coeval protoplanetary discs, thanks to the complementary inclination of the two sources. We detect water ice at 6.2 and 13.6um, CO2 ice at 15.2um, and NH4+ ice at 6.85um in the spectrum of HK Tau B; an additional absorption band between 8.3 and 9um is compatible with both silicate stretching and C-H bending. Neither of the two sources show signs of PAHs. Extended H2 emission is present around both discs, although much more elongated in HK Tau B. The distinctive 'X' shape centred in B, combined with the intensity, morphology, and spectral characteristics of the ionised atomic lines [Ar II], [Ne II], and [Ne III] suggests a low-velocity wind origin with a wide (~ 70 deg) semi-opening angle. The lower forbidden line fluxes and smaller extent of the H2 emission around A imply that, if a wind is launched from the primary as well, it is too cold or dense to be ionised.

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An Ultra-Short Period Super-Earth and a Sub-Neptune Orbiting the K dwarf TOI-4311

We report the discovery and characterisation of the multi-planetary system around TOI-4311, a K dwarf kinematically between the Galactic thick disk and Hercules stream. TOI-4311 hosts an ultra-short-period super-Earth (P$\sim$0.99 d, $1.376\substack{+0.077\\-0.080}$ R$_\oplus$) and a longer period sub-Neptune (P$\sim$15 d, $2.47\substack{+0.12\\-0.11}$ R$_\oplus$) that was first detected in the TESS photometry. Using follow-up observations with CHEOPS and HARPS, we refine the planetary radius of both planets, derive the mass of planet b ($4.5\substack{+1.5\\-1.4}$ M$_\oplus$) and confirm the planetary nature of planet c. Intriguingly, a third periodic signal is clearly detected in our HARPS RVs that we cannot link to stellar activity. This signal could be attributed to a third planet (P$\sim$38 d, Msin(i)=$26.4\substack{+6.3\\-6.8}$ M$_\oplus$) in the system, however with the current photometric dataset we do not find a transit. Our dynamical analysis highlights that this potential outer planet would remain stable. Using the precise radius and mass for TOI-4311 b we model its interior structure and find that it is very dense given the host star's galactic kinematics and chemistry. Hence this system could challenge current formation theories and provide insights into planet formation across the galaxy.

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Spatially resolved metallicity and ionization in the merging system Gz9p3 at z=9.3

Studying the interstellar medium (ISM) in merging high-redshift galaxies is crucial for understanding early galaxy assembly, star formation, and black hole growth, predicted by hierarchical $Λ$CDM models. Deep imaging and spatially resolved spectroscopy with JWST enable unprecedented insight into these processes, even for galaxies in the Epoch of Reionization. We present NIRSpec and MIRI integral field spectroscopy and MIRI imaging of the merging galaxy Gz9p3 at z=9.3 of the UV and optical rest-frame showing a clumpy morphology in the continuum as well as line emission covering the entire galaxy over a range of 5 kpc from the central clump to the tail region. We analyze the integrated spectrum as well as different apertures in the galaxy allowing a spatially resolved characterization of the ionized ISM of this galaxy. We compare our measurements with archival NIRCam imaging and ALMA data. We measure a total star formation rate of 13.4 $\pm$ 1.8 Msun yr$^{-1}$, a metallicity of 12+log(O/H) = 7.84 $\pm$ 0.05 and $ξ_{ion}$= 25.4 $\pm$ 0.1 erg$^{-1}$ Hz and a burstiness parameter of 0.9 $\pm$ 0.1 for the integrated spectrum. We find large spatial differences in these parameters between the central clump and the tail region. The optical [OIII] emission peaks in the main galaxy, the far-infrared [OIII] emission peaks towards the tail, indicating different physical conditions in the ISM of the tail and main galaxy. This study presents the spatially resolved ISM analyses of a galaxy at z>9, revealing nebular line emission and strong spatial variations in star formation, metallicity, physical conditions, and ionizing efficiency. The results indicate a recent, metal-poor starburst in a tail alongside a more evolved, enriched central clump with evidence for extreme excitation. This demonstrates the power of spatially resolved JWST spectroscopy of galaxies in the Epoch of Reionization.

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MINDS: Intertwined evolution of dust and gas in large planet-forming disks. A diversity driven by halted pebble drift?

(Abridged) We aim to investigate the inner regions of large and massive disks orbiting T Tauri stars, thought to be progenitors of systems with wide-orbit planets and possible cases of halted pebble drift. We analyze the MIRI spectra of three disks from the MINDS program: V1094 Sco, DL Tau, and IM Lup. The spectra reveal a striking diversity. V1094 Sco and DL Tau exhibit the highest C$_2$H$_2$/H$_2$O flux ratio in the MINDS sample of T Tauri disks. In V1094 Sco, even cold C$_4$H$_2$ is seen. In contrast, the IM Lup spectrum is dominated by O-bearing species. No one-to-one correspondence is found between the gas in the outer disk, as traced by the C$_2$H/C$^{18}$O flux ratio, and that of the inner disk as traced by the C$_2$H$_2$/H$_2$O flux ratio. To explain these results, we propose a scenario based on a toy model of halted pebble drift. We show that a volatile C/O ratio close to unity and low C and O abundances in inner disks arise only if: (1) ~95$\%$ of the icy grains are blocked in the outer disk, (2) the outer disk is chemically evolved, and (3) the gas in the outer disk has had time to reach the inner disk. DL Tau and perhaps V1094 Sco would be the rare examples for which all these conditions are met. Therefore, a high C$_2$H$_2$/H$_2$O flux ratio in pebble-rich disks would have a different origin than proposed for very-low mass stars, for which fast drift of O-rich pebbles would eventually leave a C-rich inner disk. We also show for the first time that the disks with high C$_2$H$_2$/H$_2$O flux ratio exhibit a prominent silica dust component, a result found in four disks published so far (V1094 Sco, DL Tau, CY Tau, DoAr 33). We propose that the reformation of dust at the sublimation front of silicates in a gas with super-solar (but below unity) C/O ratio leads to a silica stoichiometry (SiO$_2$). In turn, silica is a promising diagnostic of the C/O ratio in the inner disks.

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MINDS. Anatomy of a water-rich, inclined, brown dwarf disk: lack of abundant hydrocarbons

2MASS J04381486+2611399 (or J0438) is one of the few young brown dwarfs (BD) with a highly inclined ($i\!\sim\!70^\circ$) disk. Here we report results from JWST-MIRI MRS, HST-ACS and ALMA Band 7 observations. Despite its late spectral type (M7.25), the spectrum of J0438 resembles those of inner disks around earlier-type stars (K1-M5, T Tauri stars), with a volatile reservoir lacking hydrocarbons (except for acetylene, C$_2$H$_2$) and dominated by water. Other identified species are H$_2$, CO$_2$, HCN, [Ar$^{+}$], and [Ne$^{+}$]. The dominance of water over hydrocarbons is driven by multiple factors such as disk dynamics, young disk age, low accretion rate and possible inner disk clearing. J0438 appears highly dynamic, showing a seesaw-like variability and extended emission in H$_2 \,\,\, S$(1), $S$(3), $S$(5), [Ne$^{+}$] and CO ($J=3-2$). Interestingly, the CO emission reaches up to 400 au from the brown dwarf, suggesting ongoing infalling/outflowing activity impacting the disk chemistry. These observations underscore the combined power of MIRI, HST and ALMA in characterizing the chemical diversity and dynamics of brown dwarf disks.

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MINDS: The molecule-rich disc of the Herbig star HD 35929 revealed with JWST/MIRI

Our knowledge of the chemical composition of the gas in the inner disc of intermediate-mass young stars is limited, due to the lack of suitable instrumentation. The launch of JWST has provided a significant improvement in our ability to probe gas in these inner discs. We analyse the gas composition and emitting conditions of the disc around HD 35929, a young intermediate-mass Herbig star, using MIRI/MRS data. Our goal is to constrain the chemistry and kinematics of the gas phase molecules detected in the inner disc. We use iSLAT to examine the observed molecular lines and DuCKLiNG to detect, fit, and analyse the molecular emission. We find gas phase H2O, CO, CO2, and OH in the disc, as well as HI recombination lines. Surprisingly, we also detect gas phase SiO in the fundamental v=1-0 vibrational band. We derive column densities and temperature ranges of the detected species, arising from the inner ~0.2 au, hinting towards a compact and very warm disc. The molecular column densities are much higher than found in lower mass T Tauri discs. In general, the molecular composition is consistent with an O-rich gas from which silicate-rich solids condense and the strong gas phase molecular line emission suggests a low dust opacity. The unexpected detection of gas phase SiO at the source velocity points to an incomplete condensation of rock forming elements in the disc, suggesting chemical disequilibrium and/or an underestimate of the gas kinetic temperature.

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Knobs and dials of retrieving JWST transmission spectra. II. Impacts of pipeline-level differences on retrieval posteriors

Since the launch of JWST, observations of exoplanetary atmospheres have seen a revolution in data quality. Given that atmospheric parameter inferences depend heavily on the underlying data, a re-evaluation of current methodologies is warranted to assess the reliability of these results. We investigate the impact of variations in input spectra on atmospheric retrievals for the hot Jupiter WASP-39 b using JWST transit data. Specifically, we analyse the reliability of parameter estimations from random perturbations of the underlying spectrum and their sensitivity to three transmission spectra derived from the same observational data. Using the NIRSpec PRISM observation from a single transit of WASP-39 b, we perform retrievals with the TauREx framework. As a baseline, we use a spectrum derived with the Eureka! data reduction pipeline. To evaluate retrieval reliability, we analyse posterior distributions under deviations from this spectrum. We simulate random noise by performing retrievals on scattered instances of this spectrum and compare them with retrievals based on existing spectra reduced from the same raw observation. Our analysis identifies three types of posterior distributions: (1) Stable, Gaussian distributions for species constrained across the entire spectrum (e.g., H2O, CO2); (2) Uniform posteriors with upper bounds for weakly constrained species (e.g., CO, CH4); and (3) Unstable, heavy-tailed posteriors for species constrained by minor spectrum features (e.g., SO2, C2H2). We find that other parameters, such as the planetary radius and p-T profile, are stable under spectral perturbations. Posterior distributions differ for retrievals on independently reduced transmission spectra from the same raw data, complicating interpretation, particularly for skewed distributions. Based on this, we advocate for careful assessment and selection of credible interval sizes to reflect this.

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An Ultra-Short Period Super-Earth and Sub-Neptune Spanning the Radius Valley Orbiting the Kinematic Thick Disk Star TOI-2345

A crucial chemical link between stars and their orbiting exoplanets is thought to exist. If universal, this connection could affect the formation and evolution of all planets. Therefore, this potential vital link needs testing by characterising exoplanets around chemically-diverse stars. We present the discovery of two planets orbiting the metal-poor, kinematic thick-disk K-dwarf TOI-2345. TOI-2345 b is a super-Earth with a period of 1.05 days and TOI-2345 c is a sub-Neptune with a period of 21 days. In addition to the target being observed in 4 TESS sectors, we obtained 5 CHEOPS visits and 26 radial velocities from HARPS. By conducting a joint analysis of all the data, we find TOI-2345 b to have a radius of $1.504\substack{+0.047\\-0.044}$ R$_\oplus$ and a mass of $3.49\pm0.85$ M$_\oplus$; and TOI-2345 c to have a radius of $2.451\substack{+0.045\\-0.046}$ R$_\oplus$ and a mass of $7.27\substack{+2.27\\-2.45}$ M$_\oplus$. To explore chemical links between these planets and their host star, we model their interior structures newly accounting for devolatised stellar abundances. TOI-2345 adds to the limited sample of well characterised planetary systems around thick disk stars. This system challenges theories of formation and populations of planets around thick disk stars with its Ultra-Short Period super-Earth and the wide period distribution of these two planets spanning the radius valley.

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MINDS: The very low-mass star and brown dwarf sample II. Probing disk settling, dust properties, and dust-gas interplay with JWST/MIRI

Disks around very low-mass stars (VLMS) provide environments for the formation of Earth-like planets. Mid-infrared observations have revealed that these disks exhibit weak silicate features and strong hydrocarbon emissions. This study characterizes the dust properties and geometrical structures of VLMS and brown dwarf (BD) disks, observed by the James Webb Space Telescope (JWST)/Mid-Infrared Instrument (MIRI), and connects these to gas column density and potential evolutionary stages. We analyze mid-infrared spectra of ten VLMS and BD disks as a part of the MIRI mid-Infrared Disk Survey (MINDS) program. Spectral slopes and silicate band strengths are compared with hydrocarbon emission line ratios, which probe the gas column density. Moreover, the Dust Continuum Kit with Line emission from Gas is used to quantify grain sizes, dust compositions, and crystallinity in the disk surface. The disks are classified into less, more, and fully settled geometries based on their mid-infrared spectral slopes and silicate band strengths. Less-settled disks show a relatively strong silicate band, high spectral slopes, and low crystallinity, and are dominated by 5 $μ$m-sized grains. More-settled disks have weaker silicate band, low spectral slope, enhanced crystallinity, and higher mass fractions of smaller grains. Fully-settled disks exhibit little or no silicate emission and negative spectral slopes. An overall trend of increasing gas column density with decreasing spectral slope suggests that more molecular gas is exposed when the dust opacity decreases due to dust settling. Our findings may reflect possible evolutionary pathways with dust settling and thermal processing or may point to inner-disk clearing or a collisional cascade. These results highlight the need for broader samples to understand the link between dust and gas appearance in regions where Earth-like planets form.

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SO2, silicate clouds, but no CH4 detected in a warm Neptune

WASP-107b is a warm (~740 K) transiting planet with a Neptune-like mass of ~30.5 Earth masses and Jupiter-like radius of ~0.94 Jupiter radius, whose extended atmosphere is eroding. Previous observations showed evidence for water vapour and a thick high-altitude condensate layer in WASP-107b's atmosphere. Recently, photochemically produced sulphur dioxide (SO2) was detected in the atmosphere of a hot (~1200 K) Saturn-mass planet from transmission spectroscopy near 4.05 microns, but for temperatures below 1000 K sulphur is predicted to preferably form sulphur allotropes instead of SO2. Here we report the 9-sigma detection of two fundamental vibration bands of SO2, at 7.35 microns and 8.69 microns, in the transmission spectrum of WASP-107b using the Mid-Infrared Instrument (MIRI) of the JWST. This discovery establishes WASP-107b as the second irradiated exoplanet with confirmed photochemistry, extending the temperature range of exoplanets exhibiting detected photochemistry from ~1200 K down to ~740 K. Additionally, our spectral analysis reveals the presence of silicate clouds, which are strongly favoured (~7-sigma) over simpler cloud setups. Furthermore, water is detected (~12-sigma), but methane is not. These findings provide evidence of disequilibrium chemistry and indicate a dynamically active atmosphere with a super-solar metallicity.

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MINDS. Strong oxygen depletion in the inner regions of a very low-mass star disk?

JWST is discovering a plethora of species in planet-forming disks around very low-mass stars such as C2H2, C6H6, C4H2, CH3 etc. The column densities of these species retrieved from 0D slab models are very large, e.g. of the order of $10^{20}$\,cm$^{-2}$. This is indicating a carbon-dominated chemistry in a gas with a high C/O ratio. The disk around 2MASS-J1605321-1993159 (M4.5) is one such source showing a molecular pseudo-continuum of C2H2. Still two oxygen-bearing molecules, CO and CO2 are also detected in this source. We aim to take the next step beyond 0D slab models to interpret the spectrum. We examine whether 2D thermo-chemical disk models can produce the large inferred column densities of \ce{C2H2} in the inner regions of the disk and produce a pseudo-continuum in the mid-IR spectrum. We also want to constrain whether depletion of oxygen or enrichment of carbon is causing the high C/O ratio triggering a carbon-dominated chemistry. We utilize the radiative thermo-chemical disk model P{\tiny RO}D{\tiny I}M{\tiny O} to identify a disk structure which is capable of producing the observed molecular emission of species such as CO, CO2, C2H2, and H2O simultaneously. The spectrum is generated using the fast line tracer FLiTs. We derive the gas temperature $\langle T \rangle$, column density $\langle$ log$_{\rm {10}} N\rangle$ and the emitting area $\langle r_{\rm{1}} - r_{\rm{2}} \rangle$ for these molecules from the 2D disk model and compare them to the parameters retrieved originally from 0D slab models. We use the different effect that changing the O or C abundance has on CO and C2H2 respectively to discriminate between O depletion and C enhancement. We find that a disk structure characterised by the presence of a gap can best explain the observations. The inner disk is strongly depleted in dust, especially small grains ($<5\,μ$m), and ..

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MINDS. Cha Hα 1, a brown dwarf with a hydrocarbon-rich disk

Context. Recent JWST observations have shown that brown dwarfs (BD) are chemically rich, offering valuable insights into giant planet formation. Aims. As part of the MIRI mid-INfrared Disk Survey (MINDS) JWST guaranteed time program, we aim to characterize the gas and dust composition of the disk around the brown dwarf [NC98] Cha HA 1, hereafter Cha H$α$ 1, in the mid-infrared. Methods. We obtain data from the MIRI Medium Resolution Spectrometer (MRS) from 4.9 to 28$μ$m. We use the dust fitting tool DuCK to investigate the dust composition and grain sizes while we identify and fit molecular emission using slab models. Results. Compared with disks around very low mass stars, clear silicate emission features are seen in this BD disk. In addition, JWST reveals a plethora of hydrocarbons, including C$_2$H$_2$, $^{13}$CCH$_2$, CH$_3$, CH$_4$, C$_2$H$_4$, C$_4$H$_2$, C$_3$H$_4$, C$_2$H$_6$, and C$_6$H$_6$ which suggest a disk with a gas C/O > 1. Additionally, we detect CO$_2$, $^{13}$CO$_2$, HCN, H$_2$, and H$_2$O. CO and OH are absent from the spectrum. The dust is dominated by large $\sim$4 $μ$m size amorphous silicates (MgSiO$_3$). We infer a small dust mass fraction ($>$10$\%$) of 5 $μ$m size crystalline forsterite. We do not detect polycyclic aromatic hydrocarbons. Conclusions. Cha H$α$ 1 shows the most diverse chemistry seen to date in a BD protoplanetary disk, consisting of a strong dust feature, 12 carbon-bearing molecules plus H$_2$, and water. The diverse molecular environment offers a unique opportunity to test our understanding of BD disks chemistry and how it affects the possible planets forming in them.

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A transition from H$_2$O to C$_2$H$_2$ dominated spectra with decreasing stellar luminosity

The chemical composition of the inner regions of disks around young stars will determine the properties of planets forming there. Many disk physical processes drive the chemical evolution, some of which depend on/correlate with the stellar properties. We aim to explore the connection between stellar properties and inner disk chemistry, using mid-infrared spectroscopy. We use JWST-MIRI observations of a large, diverse sample of sources to explore trends between C$_2$H$_2$ and H$_2$O. Additionally, we calculate the average spectrum for the T Tauri ($M_{*}$$>$0.2 $M_{\odot}$) and very low-mass star (VLMS, $M_{*}$$\leq$0.2 $M_{\odot}$) samples and use slab models to determine the properties. We find a significant anti-correlation between the flux ratio of C$_2$H$_2$/H$_2$O and the stellar luminosity. Disks around VLMS have significantly higher $F_{\rm{C_2H_2}}$/$F_{\rm{H_2O}}$ flux ratios than their higher-mass counterparts. We also explore trends with the strength of the 10 $μ$m silicate feature, stellar accretion rate, and disk dust mass, all of which show correlations with the flux ratio, which may be related to processes driving the carbon-enrichment in disks around VLMS, but also have degeneracies with system properties. Slab model fits to the average spectra show that the VLMS H$_2$O emission is quite similar in temperature and column density to a warm ($\sim$600 K) H$_2$O component in the T Tauri spectrum, indicating that the high C/O gas phase ratio in these disks is not due to oxygen depletion alone. Instead, the presence of many hydrocarbons, including some with high column densities, points to carbon enhancement in the disks around VLMS. The observed differences in the inner disk chemistry as a function of host properties are likely to be accounted for by differences in the disk temperatures, stellar radiation field, and the evolution of dust grains.

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