arXiv subjects
Publications and source records attributed to Marc Mezard.
This paper is an introduction to some of the main present issues in the theory of structural glasses. After recalling a few experimental facts, it gives a short account of the analogy between fragile glasses and the mean field discontinuous spin glasses. The many valley picture is presented, and a brief account of recent attempts to obtain quantitative results from first principle computations is summarised.
We study the elastic behaviour of a supercoiled DNA molecule. The simplest model is that of a rod like chain, involving two elastic constants, the bending and the twist rigidities. We show that this model is singular and needs a small distance cut-off, which is a natural length scale giving the limit of validity of the model, of the order of the double helix pitch. The rod like chain in presence of the cutoff is able to reproduce quantitatively the experimentally observed effects of supercoiling on the elongation-force characteristics, in the small supercoiling regime. An exact solution of the model, using both transfer matrix techniques and its mapping to a quantum mechanics problem, allows to extract, from the experimental data,the value of the twist rigidity. We also analyse the variation of the torque and the writhe to twist ratio versus supercoiling, showing analytically the existence of a rather sharp crossover regime which can be related to the excitation of plectonemic-like structures. Finally we study the extension fluctuations of a stretched and supercoiled DNA molecule, both at fixed torque and at fixed supercoiling angle, and we compare the theoretical predictions to some preliminary experimental data.
We introduce a simple model of economy, where the time evolution is described by an equation capturing both exchange between individuals and random speculative trading, in such a way that the fundamental symmetry of the economy under an arbitrary change of monetary units is insured. We investigate a mean-field limit of this equation and show that the distribution of wealth is of the Pareto (power-law) type. The Pareto behaviour of the tails of this distribution appears to be robust for finite range models, as shown using both a mapping to the random `directed polymer' problem, as well as numerical simulations. In this context, a transition between an economy dominated by a few individuals from a situation where the wealth is more evenly spread out, is found. An interesting outcome is that the distribution of wealth tends to be very broadly distributed when exchanges are limited, either in amplitude or topologically. Favoring exchanges (and, less surprisingly, increasing taxes) seems to be an efficient way to reduce inequalities.
This paper gives an introduction and brief overview of some of our recent work on the equilibrium thermodynamics of glasses. We have focused onto first principle computations in simple fragile glasses, starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting molecules, each molecule being built of $m$ atoms, and having a gyration radius (related to the cage size) which vanishes at zero temperature. We use a small cage expansion, valid at low temperatures, which allows to compute the cage size, the specific heat (which follows the Dulong and Petit law), and the configurational entropy. The no-replica interpretation of the computations is also briefly described. The results, particularly those concerning the Kauzmann tempaerature and the configurational entropy, are compared to recent numerical simulations.
We compute the thermodynamic properties of the glass phase in a binary mixture of soft spheres. Our approach is a generalization to mixtures of the replica strategy, recently proposed by Mezard and Parisi, providing a first principle statistical mechanics computation of the thermodynamics of glasses. The method starts from the inter-atomic potentials, and translates the problem into the study of a molecular liquid. We compare uor analytical predictions to numerical simulations, focusing onto the values of the thermodynamic transition and the configurational entropy.
We propose a first principle computation of the equilibrium thermodynamics of simple fragile glasses starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting molecules, each molecule being built of m atoms, and having a gyration radius (related to the cage size) which vanishes at zero temperature. We use a small cage expansion, valid at low temperatures, which allows to compute the cage size, the specific heat (which follows the Dulong and Petit law), and the configurational entropy.
We compute the correlation functions of the eigenvalues in the Gaussian unitary ensemble using the fermionic replica method. We show that non--trivial saddle points, which break replica symmetry, must be included in the calculation in order to reproduce correctly the exact results for the correlation functions at large distance.
We compute energy level correlations in weakly disordered metallic grains using the fermionic replica method. We use the standard sigma-model approach and show that non--trivial saddle points, which break replica symmetry, must be included in the calculation to reproduce the oscillatory behavior of the correlations. We calculate the correlation functions in all three classical ensembles GOE, GUE and GSE including the finite-dimensional gradient corrections. Our results coincides with those obtained by the supersymmetric sigma-model and the semi-classical trace formula.
The recently proposed strategy for studying the equilibrium thermodynamics of the glass phase using a molecular liquid is reviewed and tested in details on the solvable case of the $p$-spin model. We derive the general phase diagram, and confirm the validity of this procedure. We point out the efficacy of a system of two weakly coupled copies in order to identify the glass transition, and the necessity to study a system with $m<1$ copies ('clones') of the original problem in order to derive the thermodynamic properties of the glass phase.
We propose a first principle computation of the thermodynamics of simple fragile glasses starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting molecules, each molecule being built of $m$ atoms, and having a gyration radius (related to the cage size) which vanishes at zero temperature. We use a small cage expansion, valid at low temperatures, which allows to compute the cage size, the specific heat (which follows the Dulong and Petit law), and the configurational entropy.
We review recent theoretical progress on glassy dynamics, with special emphasis on the importance and universality of the ``aging regime'', which is relevant to many experimental situations. The three main subjects which we address are: (i) Phenomenological models of aging (coarsening, trap models), (ii) Analytical results for the low-temperature dynamics of mean-field models (corresponding to the mode-coupling equations); and (iii) Simple non-disordered models with glassy dynamics. We discuss the interrelation between these approaches, and also with previous work in the field. Several open problems are underlined -- in particular the precise relation between mean-field like (or mode-coupling) descriptions and finite dimensional problems.
We present a new method to study disordered systems in the low temperature limit. The method uses the replicated Hamiltonian. It studies the saddle points of this Hamiltonian and shows how the various saddle point contributions can be resummed in order to obtain the scaling behaviour at low temperatures. In a large class of strongly disordered systems, it is necessary to include saddle points of the Hamiltonian which break the replica symmetry in a vector sector, as opposed to the usual matrix sector breaking of spin glass mean field theory.
We propose a method to study quantitatively the glass transition in a system of interacting particles. In spite of the absence of any quenched disorder, we introduce a replicated version of the hypernetted chain equations. The solution of these equations, for hard or soft spheres, signals a transition to the glass phase. However the predicted value of the energy and specific heat in the glass phase are wrong, calling for an improvement of this method.
We discuss the large scale effective potential for elastic objects (manifolds) in the presence of a random pinning potential, from the point of view of the Functional Renormalisation Group (FRG) and of the replica method. Both approaches suggest that the energy landscape at large scales is a succession of parabolic wells of random depth, matching on singular points where the effective force is discontinuous. These parabolas are themselves subdivided into smaller parabolas, corresponding to the motion of smaller length scales, in a hierarchical manner. Consequences for the dynamics of these pinned objects are underlined.
Contents: I. Introduction II. Manifolds in random media III. Thermal fluctuations without disorder IV. Random forces V. Random potential: variational approach VI. Physical interpretation of the solution
We study the Metropolis dynamics of a simple spin system without disorder, which exhibits glassy dynamics at low temperatures. We use an implementation of the algorithm of Bortz, Kalos and Lebowitz \cite{bortz}. This method turns out to be very efficient for the study of glassy systems, which get trapped in local minima on many different time scales. We find strong evidence of aging effects at low temperatures. We relate these effects to the distribution function of the trapping times of single configurations.