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Marco Bianchi

Publications and source records attributed to Marco Bianchi.

At least 73 records · Page 4Linked to original sources

Synthesis of Epitaxial Single-Layer MoS$_2$ on Au(111)

We present a method for synthesizing large area epitaxial single-layer MoS$_2$ on the Au(111) surface in ultrahigh vacuum. Using scanning tunneling microscopy and low energy electron diffraction, the evolution of the growth is followed from nanoscale single-layer MoS$_2$ islands to a continuous MoS$_2$ layer. An exceptionally good control over the MoS$_2$ coverage is maintained using an approach based on cycles of Mo evaporation and sulfurization to first nucleate the MoS$_2$ nano-islands and then gradually increase their size. During this growth process the native herringbone reconstruction of Au(111) is lifted as shown by low energy electron diffraction measurements. Within these MoS$_2$ islands, we identify domains rotated by 60$^{\circ}$ that lead to atomically sharp line defects at domain boundaries. As the MoS$_2$ coverage approaches the limit of a complete single-layer, the formation of bilayer MoS$_2$ islands is initiated. Angle-resolved photoemission spectroscopy measurements of both single and bilayer MoS$_2$ samples show a dramatic change in their band structure around the center of the Brillouin zone. Brief exposure to air after removing the MoS$_2$ layer from vacuum is not found to affect its quality.

cond-mat.mtrl-sci↗

Growth and electronic structure of epitaxial single-layer WS$_2$ on Au(111)

Large-area single-layer WS$_2$ is grown epitaxially on Au(111) using evaporation of W atoms in a low pressure H$_2$S atmosphere. It is characterized by means of scanning tunneling microscopy, low-energy electron diffraction and core-level spectroscopy. Its electronic band structure is determined by angle-resolved photoemission spectroscopy. The valence band maximum at $\bar{K}$ is found to be significantly higher than at $\barΓ$. The observed dispersion around $\bar{K}$ is in good agreement with density functional theory calculations for a free-standing monolayer, whereas the bands at $\barΓ$ are found to be hybridized with states originating from the Au substrate. Strong spin-orbit coupling leads to a large spin-splitting of the bands in the neighborhood of the $\bar{K}$ points, with a maximum splitting of 419(11)~meV. The valence band dispersion around $\bar{K}$ is found to be highly anisotropic with spin-branch dependent effective hole masses of $0.40(02)m_e$ and $0.57(09)m_e$ for the upper and lower split valence band, respectively. The large size of the spin-splitting and the low effective mass of the valence band maximum make single-layer WS$_2$ a promising alternative to the widely studied MoS$_2$ for applications in electronics, spintronics and valleytronics.

cond-mat.str-el↗

Strongly anisotropic spin-orbit splitting in a two-dimensional electron gas

Near-surface two-dimensional electron gases on the topological insulator Bi$_2$Te$_2$Se are induced by electron doping and studied by angle-resolved photoemission spectroscopy. A pronounced spin-orbit splitting is observed for these states. The $k$-dependent splitting is strongly anisotropic to a degree where a large splitting ($\approx 0.06$ Å$^{-1}$) can be found in the $\barΓ\bar{M}$ direction while the states are hardly split along $\barΓ\bar{K}$. The direction of the anisotropy is found to be qualitatively inconsistent with results expected for a third-order anisotropic Rashba Hamiltonian. However, a $\mathbf{k} \cdot \mathbf{p}$ model that includes the possibility of band structure anisotropy as well as both isotropic and anisotropic third order Rashba splitting can explain the results. The isotropic third order contribution to the Rashba Hamiltonian is found to be negative, reducing the energy splitting at high $k$. The interplay of band structure, higher order Rashba effect and tuneable doping offers the opportunity to engineer not only the size of the spin-orbit splitting but also its direction.

cond-mat.str-el↗

Secrecy Transmission on Block Fading Channels: Theoretical Limits and Performance of Practical Codes

We consider a system where an agent (Alice) aims at transmitting a message to a second agent (Bob) over a set of parallel channels, while keeping it secret from a third agent (Eve) by using physical layer security techniques. We assume that Alice perfectly knows the set of channels with respect to Bob, but she has only a statistical knowledge of the channels with respect to Eve. We derive bounds on the achievable outage secrecy rates, by considering coding either within each channel or across all parallel channels. Transmit power is adapted to the channel conditions, with a constraint on the average power over the whole transmission. We also focus on the maximum cumulative outage secrecy rate that can be achieved. Moreover, in order to assess the performance in a real life scenario, we consider the use of practical error correcting codes. We extend the definitions of security gap and equivocation rate, previously applied to the single additive white Gaussian noise channel, to Rayleigh distributed parallel channels, on the basis of the error rate targets and the outage probability. Bounds on these metrics are also derived, taking into account the statistics of the parallel channels. Numerical results are provided, that confirm the feasibility of the considered physical layer security techniques.

cs.IT↗

Electronic Structure of Epitaxial Single-Layer MoS$_2$

The electronic structure of epitaxial single-layer MoS$_2$ on Au(111) is investigated by angle-resolved photoemission spectroscopy. Pristine and potassium-doped layers are studied in order to gain access to the conduction band. The potassium-doped layer is found to have a (1.39$\pm$0.05)~eV direct band gap at $\bar{K}$ with the valence band top at $\barΓ$ having a significantly higher binding energy than at $\bar{K}$. The moiré superstructure of the epitaxial system does not lead to the presence of observable replica bands or minigaps. The degeneracy of the upper valence band at $\bar{K}$ is found to be lifted by the spin-orbit interaction, leading to a splitting of (145$\pm$4)~meV. This splitting is anisotropic and in excellent agreement with recent calculations. Finally, it is shown that the strength of the potassium doping is $k$-dependent, leading to the possibility of band structure engineering in single-layers of transition metal dichalcogenides.

cond-mat.mtrl-sci↗

Enhanced public key security for the McEliece cryptosystem

This paper studies a variant of the McEliece cryptosystem able to ensure that the code used as the public key is no longer permutation-equivalent to the secret code. This increases the security level of the public key, thus opening the way for reconsidering the adoption of classical families of codes, like Reed-Solomon codes, that have been longly excluded from the McEliece cryptosystem for security reasons. It is well known that codes of these classes are able to yield a reduction in the key size or, equivalently, an increased level of security against information set decoding; so, these are the main advantages of the proposed solution. We also describe possible vulnerabilities and attacks related to the considered system, and show what design choices are best suited to avoid them.

cs.IT↗

High Crystallinity and Decoupling of Graphene on a Metal: Reduced Coulomb Screening and Tunable pn-Junctions

High quality epitaxial graphene films can be applied as templates for tailoring graphene-substrate interfaces that allow for precise control of the charge carrier behavior in graphene through doping and many-body effects. By combining scanning tunneling microscopy, angle-resolved photoemission spectroscopy and density functional theory we demonstrate that oxygen intercalated epitaxial graphene on Ir(111) has high structural quality, is quasi free-standing, and shows signatures of many-body interactions. Using this system as a template, we show that tunable pn-junctions can be patterned by adsorption and intercalation of rubidium, and that the n-doped graphene regions exhibit a reduced Coulomb screening via enhanced electron-plasmon coupling. These findings are central for understanding and tailoring the properties of graphene-metal contacts e.g. for realizing quantum tunneling devices.

cond-mat.mtrl-sci↗

Bulk Band Structure of Bi$_2$Te$_3$

The bulk band structure of Bi$_2$Te$_3$ has been determined by angle-resolved photoemission spectroscopy and compared to first-principles calculations. We have performed calculations using the local density approximation (LDA) of density functional theory and the one-shot $GW$ approximation within the all-electron full-potential linearized augmented-plane-wave (FLAPW) formalism, fully taking into account spin-orbit coupling. Quasiparticle effects produce significant changes in the band structure of \bite~when compared to LDA. Experimental and calculated results are compared in the spectral regions where distinct differences between the LDA and $GW$ results are present. Overall a superior agreement with $GW$ is found, highlighting the importance of many-body effects in the band structure of this family of topological insulators.

cond-mat.mtrl-sci↗

Advanced coding schemes against jamming in telecommand links

The aim of this paper is to study the performance of some coding schemes recently proposed for updating the TC channel coding standard for space applications, in the presence of jamming. Besides low-density parity-check codes, that appear as the most eligible candidates, we also consider other solutions based on parallel turbo codes and extended BCH codes. We show that all these schemes offer very good performance, which approaches the theoretical limits achievable.

cs.IT↗

Advanced channel coding for space mission telecommand links

We investigate and compare different options for updating the error correcting code currently used in space mission telecommand links. Taking as a reference the solutions recently emerged as the most promising ones, based on Low-Density Parity-Check codes, we explore the behavior of alternative schemes, based on parallel concatenated turbo codes and soft-decision decoded BCH codes. Our analysis shows that these further options can offer similar or even better performance.

cs.IT↗

Direct Measurement of Surface Transport on a Bulk Topological Insulator

Topological insulators are guaranteed to support metallic surface states on an insulating bulk, and one should thus expect that the electronic transport in these materials is dominated by the surfaces states. Alas, due to the high remaining bulk conductivity, surface contributions to transport have so-far only been singled out indirectly via quantum oscillations, or for devices based on gated and doped topological insulator thin films, a situation in which the surface carrier mobility could be limited by defect and interface scattering. Here we present the first direct measurement of surface-dominated conduction on an atomically clean surface of bulk-insulating Bi$_2$Te$_2$Se. Using nano-scale four point setups with variable contact distance, we show that the transport at 30 K is two-dimensional rather than three-dimensional and by combining these measurements with angle-resolved photoemission results from the same crystals, we find a surface state mobility of 390(30) cm$^{2}$V$^{-1}$s$^{-1}$ at 30 K at a carrier concentration of 8.71(7)$\times 10^{12}$ cm$^{-2}$.

cond-mat.mtrl-sci↗

Coding with Scrambling, Concatenation, and HARQ for the AWGN Wire-Tap Channel: A Security Gap Analysis

This study examines the use of nonsystematic channel codes to obtain secure transmissions over the additive white Gaussian noise (AWGN) wire-tap channel. Unlike the previous approaches, we propose to implement nonsystematic coded transmission by scrambling the information bits, and characterize the bit error rate of scrambled transmissions through theoretical arguments and numerical simulations. We have focused on some examples of Bose-Chaudhuri-Hocquenghem (BCH) and low-density parity-check (LDPC) codes to estimate the security gap, which we have used as a measure of physical layer security, in addition to the bit error rate. Based on a number of numerical examples, we found that such a transmission technique can outperform alternative solutions. In fact, when an eavesdropper (Eve) has a worse channel than the authorized user (Bob), the security gap required to reach a given level of security is very small. The amount of degradation of Eve's channel with respect to Bob's that is needed to achieve sufficient security can be further reduced by implementing scrambling and descrambling operations on blocks of frames, rather than on single frames. While Eve's channel has a quality equal to or better than that of Bob's channel, we have shown that the use of a hybrid automatic repeat-request (HARQ) protocol with authentication still allows achieving a sufficient level of security. Finally, the secrecy performance of some practical schemes has also been measured in terms of the equivocation rate about the message at the eavesdropper and compared with that of ideal codes.

cs.IT↗

Improving the efficiency of the LDPC code-based McEliece cryptosystem through irregular codes

We consider the framework of the McEliece cryptosystem based on LDPC codes, which is a promising post-quantum alternative to classical public key cryptosystems. The use of LDPC codes in this context allows to achieve good security levels with very compact keys, which is an important advantage over the classical McEliece cryptosystem based on Goppa codes. However, only regular LDPC codes have been considered up to now, while some further improvement can be achieved by using irregular LDPC codes, which are known to achieve better error correction performance than regular LDPC codes. This is shown in this paper, for the first time at our knowledge. The possible use of irregular transformation matrices is also investigated, which further increases the efficiency of the system, especially in regard to the public key size.

cs.IT↗

Surface structure of Bi2Se3(111) determined by low-energy electron diffraction and surface X-ray diffraction

The surface structure of the prototypical topological insulator Bi2Se3 is determined by low-energy electron diffraction and surface X-ray diffraction at room temperature. Both approaches show that the crystal is terminated by an intact quintuple layer. Specifically, an alternative termination by a bismuth bilayer is ruled out. Surface relaxations obtained by both techniques are in good agreement with each other and found to be small. This includes the relaxation of the van der Waals gap between the first two quintuple layers.

cond-mat.mtrl-sci↗

Electron-phonon coupling-induced kinks in the sigma band of graphene

Angle-resolved photoemission spectroscopy reveals pronounced kinks in the dispersion of the sigma band of graphene. Such kinks are usually caused by the combination of a strong electron-boson interaction and the cut-off in the Fermi-Dirac distribution. They are therefore not expected for the $σ$ band of graphene that has a binding energy of more than 3.5 eV. We argue that the observed kinks are indeed caused by the electron-phonon interaction, but the role of the Fermi-Dirac distribution cutoff is assumed by a cut-off in the density of $σ$ states. The existence of the effect suggests a very weak coupling of holes in the $σ$ band not only to the $π$ electrons of graphene but also to the substrate electronic states. This is confirmed by the presence of such kinks for graphene on several different substrates that all show a strong coupling constant of lambda=1.

cond-mat.mes-hall↗

Using LDGM Codes and Sparse Syndromes to Achieve Digital Signatures

In this paper, we address the problem of achieving efficient code-based digital signatures with small public keys. The solution we propose exploits sparse syndromes and randomly designed low-density generator matrix codes. Based on our evaluations, the proposed scheme is able to outperform existing solutions, permitting to achieve considerable security levels with very small public keys.

cs.CR↗

Optimization of the parity-check matrix density in QC-LDPC code-based McEliece cryptosystems

Low-density parity-check (LDPC) codes are one of the most promising families of codes to replace the Goppa codes originally used in the McEliece cryptosystem. In fact, it has been shown that by using quasi-cyclic low-density parity-check (QC-LDPC) codes in this system, drastic reductions in the public key size can be achieved, while maintaining fixed security levels. Recently, some proposals have appeared in the literature using codes with denser parity-check matrices, named moderate-density parity-check (MDPC) codes. However, the density of the parity-check matrices to be used in QC-LDPC code-based variants of the McEliece cryptosystem has never been optimized. This paper aims at filling such gap, by proposing a procedure for selecting the density of the private parity-check matrix, based on the security level and the decryption complexity. We provide some examples of the system parameters obtained through the proposed technique.

cs.IT↗

Low-power Secret-key Agreement over OFDM

Information-theoretic secret-key agreement is perhaps the most practically feasible mechanism that provides unconditional security at the physical layer to date. In this paper, we consider the problem of secret-key agreement by sharing randomness at low power over an orthogonal frequency division multiplexing (OFDM) link, in the presence of an eavesdropper. The low power assumption greatly simplifies the design of the randomness sharing scheme, even in a fading channel scenario. We assess the performance of the proposed system in terms of secrecy key rate and show that a practical approach to key sharing is obtained by using low-density parity check (LDPC) codes for information reconciliation. Numerical results confirm the merits of the proposed approach as a feasible and practical solution. Moreover, the outage formulation allows to implement secret-key agreement even when only statistical knowledge of the eavesdropper channel is available.

cs.IT↗