arXiv subjects

Maria Teresa Mercaldo

Publications and source records attributed to Maria Teresa Mercaldo.

At least 19 recordsLinked to original sources

arXiv2026

Spin selectivity induced by non-collinear spins in Rashba wires

We report a previously overlooked general mechanism to obtain highly efficient spin selectivity in conventional time-reversal symmetric one-dimensional systems without invoking phase decoherence. We reveal that Rashba quantum wires featuring non-collinear spin states at the Fermi level inherently possess spin-selective transport properties. We show that this spin noncollinearity can be systematically designed and engineered by introducing an additional pseudospin degree of freedom - such as valley, sublattice, or orbital angular momentum - into spin-orbit coupled systems. By applying this framework to multi-subband semiconducting quantum wires and oxide nanowires, we establish a generalized route toward quantum-coherent spin selectivity up to 10 %. Our findings offer practical design principles for spin-selective transport devices.

cond-mat.mes-hall↗

arXiv2026

Quantum metric quadrupoles in elemental bismuth thin films

The nonlinear transport properties of solids are deeply rooted in the quantum geometry of their electronic wavefunctions, which is encoded in the quantum geometric tensor. Its real part, known as the quantum metric, has been recently identified as a primary origin of nonlinear transport in quantum materials where time-reversal and inversion symmetries are not simultaneously present. Consequently, the influence of the quantum metric on the largest class of materials -- non-magnetic and centrosymmetric systems -- has remained entirely elusive. Here, we demonstrate that third-order transport in centrosymmetric materials hosting relativistic fermions is governed by quantum metric quadrupoles (QMQs). We show that these QMQs can originate from both the non-Abelian quantum geometry of bulk three-dimensional Dirac fermions and the Abelian quantum geometry of spin-orbit-coupled surface states. In stark contrast to all zero-field nonlinear transport signatures known to date, the current driven by these QMQs persists as a robust, non-vanishing observable even in highly scalable polycrystalline thin films. We experimentally validate this quantum metric footprint by measuring nonlinear transport in thin films of elemental bismuth, observing a robust, surface-dominated, and broadband third-harmonic generation that persists up to room temperature. Our findings uncover a hidden role of the quantum metric in polycrystalline systems, establishing third-order nonlinear transport as a high-precision diagnostic tool of wavefunction geometry under ambient conditions.

cond-mat.mes-hall↗

arXiv2026

Transverse Magnetic Response from Orbitally Polarized Cooper Pairs in Elemental Superconductors

We demonstrate how crystalline symmetry lowering, as for instance through strain, allows elemental superconductors such as vanadium and niobium to realize spin-singlet orbitally polarized Cooper pairs composed of electrons with identical orbital moments. Using superconducting density functional theory, we show that lowering of trigonal symmetry to $C_s$, thus keeping only a single mirror plane, activates interorbital pairing in bulk and (111) surfaces, with a pronounced surface enhancement. In a magnetic field, the resulting orbitally polarized superconducting state leads to a novel transverse magnetic response. For in--plane field orientations that break the remaining mirror symmetry, a sizable orbital magnetization emerges perpendicular to the applied field. We show that this effect is a direct consequence of equal--orbital-moment Cooper pairing, providing an experimentally accessible signature of this state. Our results establish strained elemental superconductors as a minimal material platform for superconducting orbitronics.

cond-mat.supr-con↗

arXiv2026

Curvature-induced nonlinear anomalous Hall effect in thin magnetic shells

Optoelectronic and nonlinear transport experiments probe the quantum geometric tensor of Bloch states, whose real and imaginary components -- the quantum metric and the Berry curvature -- are typically constrained by symmetry. Here, we show that geometric bending provides a route to engineer such responses in centrosymmetric ferromagnets. Curvature-induced strain gradients across the shell thickness break inversion symmetry and activate an orbital Rashba coupling. In the presence of in-plane magnetization and spin-orbit coupling, this generates spin textures with a nontrivial quantum geometry, leading to an intrinsic nonlinear anomalous Hall effect (NAHE) governed by the quantum metric and maximized when the magnetization aligns with the applied electric field. When geometric deformations further break twofold rotational symmetry around the out-of-plane axis, an additional NAHE emerges, maximal for magnetization perpendicular to the driving electric field and governed by the Berry curvature dipole, thus giving access to the imaginary component of the quantum geometric tensor. These results establish curved ferromagnetic shells as a platform for engineering anisotropic nonlinear transport and for selectively probing both components of the quantum geometric tensor.

cond-mat.mes-hall↗

arXiv2026

Probing the quantum metric of 3D topological insulators

The surface states of 3D topological insulators possess geometric structures that imprint distinctive signatures on electronic transport. A prime example is the Berry curvature, which controls, for instance, electric frequency doubling via its higher order moments. In addition to the Berry curvature, topological surface states are expected to exhibit a nontrivial quantum metric, which plays a key role in governing nonlinear magnetotransport. However, its manifestation has yet to be experimentally observed and controlled in 3D topological insulators. Here, we provide evidence for a nonlinear response activated by the quantum metric of the topological surface states of Sb$_2$Te$_3$. We measure a time-reversal odd, nonlinear magnetoresistance that is independent from the temperature and the scattering time below 30 K, and is thus of intrinsic geometrical origin. This quantum metric magnetoresistance can be controlled by tuning the contributions of the top and bottom topological surface states by voltage gating. Our measurements thus demonstrate the existence and tunability of quantum geometry-induced transport in topological phases of matter and provide strategies for designing novel functionalities in topological devices.

cond-mat.mes-hall↗

arXiv2025

Supercurrent diode with high winding vortex

Nonreciprocal supercurrent refers to the phenomenon where the maximum dissipationless current in a superconductor depends on its direction of flow. This asymmetry underlies the operation of superconducting diodes and is often associated with the presence of vortices. Here, we investigate supercurrent nonreciprocal effects in a superconducting weak-link hosting distinct types of vortices. We demonstrate how the winding number of the vortex, its spatial configuration, and the shape of the superconducting lead can steer the sign and amplitude of the supercurrent rectification. We identify a general criterion for optimizing the rectification amplitude based on vortex patterns, focusing on configurations where the first harmonic of the supercurrent vanishes. We prove that supercurrent nonreciprocal effects can be used to diagnose high-winding vortex and to distinguish between different types of vorticity. Our results provide a toolkit for controlling supercurrent rectification through vortex phase textures and detecting unconventional vortex states.

cond-mat.supr-con↗

arXiv2025

The quantum metric of electrons with spin-momentum locking

Quantum materials are characterized by electromagnetic responses intrinsically linked to the geometry and topology of electronic wavefunctions, encoded in the quantum metric and Berry curvature. Whereas Berry curvature-mediated transport effects have been identified in several magnetic and nonmagnetic systems, quantum metric-induced transport phenomena remain limited to topological antiferromagnets. Here we show that spin-momentum locking -- a general characteristic of the electronic states at surfaces and interfaces of spin-orbit coupled materials -- leads to a finite quantum metric. This metric activates a nonlinear in-plane magnetoresistance that we measure and electrically control in 111-oriented LaAlO$_3$/SrTiO$_3$ interfaces. These findings demonstrate the existence of quantum metric effects in a vast class of materials and enable previously unexplored strategies to design functionalities based on quantum geometry.

cond-mat.mes-hall↗

arXiv2025

Filtering Spin and Orbital Moment in Centrosymmetric Systems

The control of spin and orbital angular momentum without relying on magnetic materials is commonly accomplished by breaking of inversion symmetry, which enables charge-to-spin conversion and spin selectivity in electron transfer processes occurring in chiral media. In contrast to this perspective, we show that orbital moment filtering can be accomplished in centrosymmetric systems: the electron states can be selectively manipulated allowing for the preferential transfer of electrons with a particular orbital momentum orientation. We find that orbital moment filtering is indeed efficiently controlled through orbital couplings that break both mirror and rotational symmetries. We provide the symmetry conditions required for the electron transmission to achieve orbital filtering and relate them to the orientation of the orbital moment. The presence of atomic spin-orbit interaction in the centrosymmetric transmission medium leads to the selective filtering of spin and orbital moments. Our findings allow to identify optimal regimes for having highly efficient simultaneous spin and orbital moment filtering.

cond-mat.other↗

arXiv2025

Triplet superconductivity by the orbital Rashba effect at surfaces of elemental superconductors

It is often assumed that in a superconductor without spin-triplet pairing, the formation of unconventional spin-triplet densities requires the spin-orbit interaction in combination with either broken inversion symmetry or broken time-reversal symmetry. Here, we show from first principles the existence of supercurrent-driven spin triplet densities on the surface of a variety of simple superconducting materials without spin-orbit coupling. We are able to attribute this phenomenon to the superconducting non-relativistic orbital Rashba Edelstein effect. Furthermore, we find that the spin-orbit induced spin moment is one order of magnitude smaller than the orbital moment, and has a vanishing effect on the total magnitude of the induced triplet density. Our findings imply the existence of a route to generate spin-currents without the use of heavy metals. Additionally, as an orbital moment can couple directly to a magnetic field, it shows that orbital physics is the dominant term that drives the superconducting diode effect.

cond-mat.supr-con↗

arXiv2025

Topological phase transitions in superconductors with chiral symmetry

We study topological transitions in one dimensional superconductors that can harbor multiple edge Majorana bound states protected by chiral symmetry. The chiral symmetry arises due to the structure of the internal spin degrees of freedom of the superconductor and it can be guided by the coupling of the superconductor with sources of time-reversal symmetry breaking. We then consider distinct regions of the phase diagram in the parameters space that are marked by gapless excitations in the spectrum and evaluate the conditions for inducing a topological transition. We show that for gapless chiral symmetric superconductors one can identify a class of physical perturbations that enable a gap opening in the spectrum, without breaking chirality, and turn the system into a topological state. This type of superconductor is dubbed marginal topological superconductor because an infinitesimally small perturbation is able to induce a transition into a topological nontrivial phase. To explicitly demonstrate and evaluate the character of the transitions from gapless to topological gapfull phases we explore different physical cases including p-wave superconductor in the presence of an applied magnetic field or proximity-coupled to a ferromagnet, and s-wave superconductor in a noncollinear magnetic ordering.

cond-mat.supr-con↗

arXiv2025

Nonlinear planar magnetotransport as a probe of the topology of surface states

It has been recently established that transport measurements in the nonlinear regime can give direct access to the quantum metric (QM): the real part of the quantum geometric tensor characterizing the geometry of the electronic wavefunctions in a solid. In topological materials, the QM has been so far revealed in thin films of the topological antiferromagnet MnBi$_2$Te$_4$ where it provides a direct contribution to longitudinal currents quadratic in the driving electric field. Here we show that the Dirac surface states of strong three-dimensional topological insulators have a QM that can be accessed from the nonlinear transport characteristics in the presence of an externally applied planar magnetic field. A previously unknown intrinsic part of the longitudinal magnetoconductivity carries the signature of the QM while coexisting with the extrinsic part responsible for the so-called bilinear magnetoelectric resistance. We prove that the QM-induced nonlinear magnetotransport carries specific signatures of single Dirac cones. This allows to use it as an efficient diagnostic tool of the bulk topology of three-dimensional non-magnetic insulators.

cond-mat.mes-hall↗

arXiv2025

Anomalous spin-optical helical effect in Ti-based kagome metal

The kagome lattice stands as a rich platform for hosting a wide array of correlated quantum phenomena, ranging from charge density waves and superconductivity to electron nematicity and loop current states. Direct detection of loop currents in kagome systems has remained a formidable challenge due to their intricate spatial arrangements and the weak magnetic field signatures they produce. This has left their existence and underlying mechanisms a topic of intense debate. In this work, we uncover a hallmark reconcilable with loop currents: spin handedness-selective signals that surpass conventional dichroic, spin, and spin-dichroic responses. We observe this phenomenon in the kagome metal CsTi$_3$Bi$_5$ and we call it the anomalous spin-optical helical effect. This effect arises from the coupling of light' s helicity with spin-orbital electron correlations, providing a groundbreaking method to visualize loop currents in quantum materials. Our discovery not only enriches the debate surrounding loop currents but also paves the way for new strategies to exploit the electronic phases of quantum materials via light-matter interaction.

cond-mat.str-el↗

arXiv2025

Colossal orbital-Edelstein effect in non-centrosymmetric superconductors

In superconductors that lack inversion symmetry, the flow of supercurrent can induce a non-vanishing magnetization, a phenomenon which is at the heart of non-dissipative magneto-electric effects, also known as Edelstein effects. For electrons carrying spin and orbital moments a question of fundamental relevance deals with the orbital nature of magneto-electric effects in conventional spin-singlet superconductors with Rashba coupling. Remarkably, we find that the supercurrent-induced orbital magnetization is more than one order of magnitude greater than that due to the spin, giving rise to a colossal magneto-electric effect. The induced orbital magnetization is shown to be sign tunable, with the sign change occurring for the Fermi level lying in proximity of avoiding crossing points in the Brillouin zone. In the presence of superconducting phase inhomogeneities, a modulation of the Edelstein signal on the scale of the superconducting coherence length appears, leading to domains with opposite orbital moment orientations. These hallmarks are robust to real-space self-consistent treatment of the superconducting order parameter. The orbital-dominated magneto-electric phenomena, hence, have clear-cut marks for detection both in the bulk and at the edge of the system and are expected to be a general feature of multi-orbital superconductors with inversion symmetry breaking.

cond-mat.supr-con↗

arXiv2025

Back-action supercurrent diodes

Back-action refers to a response that retro-acts on a system to tailor its properties with respect to an external stimulus. This effect is at the heart of many electronic devices such as amplifiers, oscillators, and sensors. Here, we demonstrate that back-action can be exploited to achieve non-reciprocal transport in superconducting circuits. In our devices, dissipationless current flows in one direction whereas dissipative transport occurs in the opposite direction. Supercurrent diodes presented so far rely on magnetic elements or vortices to mediate charge transport or external magnetic fields to break time-reversal symmetry. Back-action solely turns a conventional reciprocal superconducting weak link with no asymmetry between the current bias directions into a rectifier, where the critical current amplitude depends on the bias sign. The self-interaction of the supercurrent stems from the gate tunability of the critical current in metallic and semiconducting systems, which promotes nearly ideal magnetic field-free rectification with selectable polarity.

cond-mat.mes-hall↗

arXiv2024

Spin and orbital Edelstein effect in spin-orbit coupled noncentrosymmetric superconductor

Superconductors without inversion symmetry can exhibit a non-zero magnetization when a supercurrent is present, leading to non-dissipative magnetoelectric effects. Here, we focus on understanding the relation between the spin and orbital properties of these effects in conventional spin-singlet noncentrosymmetric superconductors with orbital Rashba coupling, particularly for multiorbital electronic systems with coupled spin and orbital moments. We investigate how atomic spin-orbit coupling influences the magnitude and direction of the spin and orbital Edelstein effect. Our findings indicate that the correlation between spin and orbital moments induced by supercurrents is generally not determined by the sign of atomic spin-orbit coupling, but rather by the number of bands at the Fermi level and the orbital characteristics of those bands with respect to the mirror parity. We investigate the character of the spin and orbital Edelstein effect by examining its dependence in momentum space and the role of avoiding crossings in determining the induced magnetization. The outcomes demonstrate that the sign change of the orbital Edelstein effect near avoiding crossing bands remains robust despite modifications to the atomic spin-orbit amplitude. Furthermore, we observe that the spin Edelstein effect is typically one order of magnitude smaller than the orbital Edelstein effect, but can be significantly enhanced in certain scenarios with increased atomic spin-orbit coupling. These results indicate that by manipulating the orbital degrees of freedom in noncentrosymmetric materials, the relationship between the spin and orbital Edelstein moments can be effectively controlled.

cond-mat.supr-con↗

arXiv2024

Unveiling unconventional magnetism at the surface of Sr$_2$RuO$_4$

Materials with strongly correlated electrons exhibit physical properties that are often difficult to predict as they result from the interactions of large numbers of electrons combined with several quantum degrees of freedom. The layered oxide perovskite Sr$_2$RuO$_4$ is a strongly correlated electron material that has been intensively investigated since its discovery due to its unusual physical properties. Whilst recent experiments have reopened the debate on the exact symmetry of the superconducting state in Sr$_2$RuO$_4$, a deeper understanding of the Sr$_2$RuO$_4$ normal state appears crucial as this is the background in which electron pairing occurs. Here, by using low-energy muon spin spectroscopy we discover the existence of magnetism at the surface of Sr$_2$RuO$_4$ in its normal state. We detect static weak dipolar fields yet manifesting below a relatively high onset temperature larger than 50 K, which reveals the unconventional nature of the observed magnetism. We relate the origin of this phase breaking time reversal symmetry to electronic ordering in the form of orbital loop currents that originate at the reconstructed Sr$_2$RuO$_4$ surface. Our observations set a reference for the discovery of the same magnetic phase in other materials and unveil an electronic ordering mechanism that can influence unconventional electron pairing with broken time reversal symmetry in those materials where the observed magnetic phase coexists with superconductivity.

cond-mat.str-el↗

arXiv2024

Signatures of a surface spin-orbital chiral metal

The relation between crystal symmetries, electron correlations, and electronic structure steers the formation of a large array of unconventional phases of matter, including magneto-electric loop currents and chiral magnetism. Detection of such hidden orders is a major goal in condensed matter physics. However, to date, nonstandard forms of magnetism with chiral electronic ordering have been experimentally elusive. Here, we develop a theory for symmetry-broken chiral ground states and propose a methodology based on circularly polarized spin-selective angular-resolved photoelectron spectroscopy to probe them. We exploit the archetypal quantum material Sr2RuO4 and reveal spectroscopic signatures which, even though subtle, may be reconciled with the formation of spin-orbital chiral currents at the material surface. As we shed light on these chiral regimes, our findings pave the way for a deeper understanding of ordering phenomena and unconventional magnetism.

cond-mat.str-el↗

arXiv2023

Sign reversal diode effect in superconducting Dayem nanobridges

Supercurrent diodes are nonreciprocal electronic elements whose switching current depends on their flow direction. Recently, a variety of composite systems combining different materials and engineered asymmetric superconducting devices have been proposed. Yet, ease of fabrication and tunable sign of supercurrent rectification joined to large efficiency have not been assessed in a single platform so far. We demonstrate that all-metallic superconducting Dayem nanobridges naturally exhibit nonreciprocal supercurrents under an external magnetic field, with a rectification efficiency up to $\sim 27\%$. Our niobium nanostructures are tailored so that the diode polarity can be tuned by varying the amplitude of an out-of-plane magnetic field or the temperature in a regime without magnetic screening. We show that sign reversal of the diode effect may arise from the high-harmonic content of the current phase relation in combination with vortex phase windings present in the bridge or an anomalous phase shift compatible with anisotropic spin-orbit interactions.

cond-mat.supr-con↗