arXiv subjects

Mark S. Marley

Publications and source records attributed to Mark S. Marley.

At least 37 records · Page 2Linked to original sources

arXiv2025

Fractal Aggregate Aerosols in the Virga Cloud Code I: Model Description and Application to a Benchmark Cloudy Exoplanet

We introduce new functionality to treat fractal aggregate aerosol particles within the Virga cloud modeling framework. Previously, the open source cloud modeling code Virga (Batalha et al. 2025), the Python version of EddySed (Ackerman & Marley, 2001), assumed spherical particles to compute particle mass and size distributions throughout the atmosphere. The initial release of Virga also assumed spherical particles to compute Mie scattering properties, which include the single scattering albedo, asymmetry parameter, and optical depth as a function of particle radius and composition. However, extensive evidence from Solar system aerosols, astrophysical disks and dust, and Earth climate studies suggests that non-spherical aggregate particles are common compared to idealized compact spherical particles. Following recent advances in microphysical and opacity modeling, we implement a simple parametrization for dynamical and optical (modified mean field theory) effects of fractal aggregate particles into Virga. We then use this new functionality to perform a case study using basic planetary parameters similar to the well-characterized, aerosol-laden mini-Neptune GJ 1214 b, using KCl clouds made of aggregate particles. We choose KCl to most directly explore comparisons to previous studies. We demonstrate 1) how our method compares to previous fractal aggregate particle treatments and 2) how our new fractal treatment affects theoretical spectra of cloudy atmospheres. Overall, our model is faster and more flexible for a wider range of parameter space than previous studies. We explore the limitations of our modeling set-up and offer guidance for future investigations using our framework.

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arXiv2025

Condensation Clouds in Substellar Atmospheres with Virga

Here we present an open-source cloud model for substellar atmospheres, called Virga. The Virga-v0 series has already been widely adopted in the literature. It is written in Python and has heritage from the Ackerman & Marley (2001) model (often referred to as eddysed), used to study clouds on both exoplanets and brown dwarfs. In the development of the official Virga-v1 we have retained all the original functionality of eddysed and updated/expanded several components including the back-end optical constants data, calculations of the Mie properties, available condensate species, saturation vapor pressure curves and formalism for fall speeds calculations. Here we benchmark Virga by reproducing key results in the literature, including the SiO2 cloud detection in WASP-17 b and the brown dwarf Diamondback-Sonora model series. Development of Virga is ongoing, with future versions already planned and ready for release. We encourage community feedback and collaborations within the GitHub code repository.

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arXiv2025

The HUSTLE Program: The UV to Near-IR Transmission Spectrum of the Hot Jupiter KELT-7b

The ultraviolet and optical wavelength ranges have proven to be a key addition to infrared observations of exoplanet atmospheres, as they offer unique insights into the properties of clouds and hazes and are sensitive to signatures of disequilibrium chemistry. Here we present the 0.2-0.8 $μ$m transmission spectrum of the Teq = 2000 K Jupiter KELT-7b, acquired with HST WFC3/UVIS G280 as part of the HUSTLE Treasury program. We combined this new spectrum with the previously published HST WFC3/IR G141 (1.1-1.7 $μ$m) spectrum and Spitzer photometric points at 3.6$μ$m and 4.5$μ$m, to reveal a generally featureless transmission spectrum between 0.2 and 1.7 $μ$m, with a slight downward slope towards bluer wavelengths, and a asymmetric water feature in the 1.1-1.7 $μ$m band. Retrieval models conclude that the 0.2 - 1.7$μ$m spectrum is primarily explained by a high H- abundance ($\sim 10^{-5}$), significantly above the equilibrium chemistry prediction ($\sim 10^{-12}$), suggesting disequilibrium in KELT-7b's upper atmosphere. Our retrievals also suggest the presence of bright inhomogeneities in the stellar surface, and tentative evidence of CO2 at the Spitzer wavelengths. We demonstrate that with the UV-optical coverage provided by WFC3 UVIS/G280, we are able to confirm the presence and constrain the abundance of H-, and obtain evidence for bright stellar inhomogeneities that would have been overlooked using infrared data alone. Observations redward of 1$μ$m with JWST should be able to further constrain the abundance of H-, as well as confirm the presence of CO2 inferred by the two Spitzer datapoints.

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arXiv2025

ELemental abundances of Planets and brown dwarfs Imaged around Stars (ELPIS): II. The Jupiter-like Inhomogeneous Atmosphere of the First Directly Imaged Planetary-Mass Companion 2MASS 1207 b

2MASS 1207 b, the first directly imaged planetary-mass companion, has been instrumental in advancing our understanding of exoplanets and brown dwarfs over the past 20 years. We have performed extensive atmospheric retrieval analyses of 2MASS 1207 b's JWST/NIRSpec spectrum using petitRADTRANS and a new atmospheric inhomogeneity framework, which characterizes homogeneous atmospheres, patchy clouds, cloud-free hot spots, or the combination of patchy clouds and spots. Among 24 retrieval runs with various assumptions, the most statistically preferred model corresponds to the patchy cloud scheme, with Teff$=1174^{+4}_{-3}$ K, log(g)=$3.62^{+0.03}_{-0.02}$ dex, and R$=1.399^{+0.008}_{-0.010}$ R$_{\rm Jup}$, along with near-solar atmospheric compositions of [M/H]$=-0.05\pm0.03$ dex and C/O$=0.440\pm0.012$. This model suggests ~9% of 2MASS 1207 b's atmosphere is covered by thin iron clouds, producing L-dwarf-like spectra, while the remaining 91% consists of thick silicate and iron clouds, emitting blackbody-like spectra. These thin-cloud and thick-cloud regions resemble Jupiter's belts and zones, respectively; this scenario is consistently supported by other retrieval runs incorporating inhomogeneous atmospheres. We demonstrate that 2MASS 1207 b's weak CO absorption can be explained by the veiling effects of patchy thick clouds; the absence of 3.3um CH4 absorption is attributed to its hot thermal structure, which naturally leads to a CO-dominant, CH4-deficient atmosphere. The retrieved atmospheric models also match the observed variability amplitudes of 2MASS 1207 b. Our analysis reveals that the inferred atmospheric properties show significant scatter in less statistically preferred retrieval runs but converge to consistent values among the preferred ones. This underscores the importance of exploring diverse assumptions in retrievals to avoid biased interpretations of atmospheres and formation.

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arXiv2025

SiO and a super-stellar C/O ratio in the atmosphere of the giant exoplanet WASP-121b

Refractory elements such as iron, magnesium, and silicon can be detected in the atmospheres of ultrahot giant planets. This provides an opportunity to quantify the amount of refractory material accreted during formation, along with volatile gases and ices. However, simultaneous detections of refractories and volatiles have proved challenging, as the most prominent spectral features of associated atoms and molecules span a broad wavelength range. Here, using a single JWST observation of the ultrahot giant planet WASP-121b, we report detections of H$_2$O (5.5-13.5$σ$), CO (10.8-12.8$σ$), and SiO (5.7-6.2$σ$) in the planet's dayside atmosphere, and CH$_4$ (3.1-5.1$σ$) in the nightside atmosphere. We measure super-stellar values for the atmospheric C/H, O/H, Si/H, and C/O ratios, which point to the joint importance of pebbles and planetesimals in giant planet formation. The CH$_4$-rich nightside composition is also indicative of dynamical processes, such as strong vertical mixing, having a profound influence on the chemistry of ultrahot giant planets.

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arXiv2025

The Sonora Substellar Atmosphere Models. V: A Correction to the Disequilibrium Abundance of CO$_2$ for Sonora Elf Owl

To aid the interpretation of observations of substellar atmospheres, Mukherjee et al. (2024) created the Sonora Elf Owl grid of model atmospheres, simulations that accounted for disequilibrium quench chemistry. However, Sonora Elf Owl did not accurately estimate CO$_2$ quenching because the models quenched the gas with respect to the full atmosphere equilibrium, but CO$_2$ should have instead been quenched with respect to the disequilibrium (i.e., quenched) abundance of CO. As a result, Sonora Elf Owl under-predicted the CO$_2$ abundance by several order of magnitude in some instances, an amount that JWST is sensitive to. Here, we release version two of the Sonora Elf Owl grid which has corrected CO$_2$ concentrations. Additionally, in version two we remove PH$_3$ as a spectral contributor since our spectra consistently contained too much PH$_3$ absorption. The new spectra can be found as an update to the original Zenodo postings.

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arXiv2025

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems III: Aperture Masking Interferometric Observations of the star HIP 65426 at 3.8 um

We present aperture masking interferometry (AMI) observations of the star HIP 65426 at $3.8\,\rm{μm}$ as a part of the JWST Direct Imaging Early Release Science (ERS) program obtained using the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument. This mode provides access to very small inner working angles (even separations slightly below the Michelson limit of $0.5λ/D$ for an interferometer), which are inaccessible with the classical inner working angles of the JWST coronagraphs. When combined with JWST's unprecedented infrared sensitivity, this mode has the potential to probe a new portion of parameter space across a wide array of astronomical observations. Using this mode, we are able to achieve a $5σ$ contrast of $Δm{\sim}7.62{\pm}0.13$ mag relative to the host star at separations ${\gtrsim}0.07{"}$, and the contrast deteriorates steeply at separations ${\lesssim}0.07{"}$. However, we detect no additional companions interior to the known companion HIP 65426 b (at separation ${\sim}0.82{"}$ or, $87^{+108}_{-31}\,\rm{au}$). Our observations thus rule out companions more massive than $10{-}12\,\rm{M_{Jup}}$ at separations ${\sim}10{-}20\,\rm{au}$ from HIP 65426, a region out of reach of ground or space-based coronagraphic imaging. These observations confirm that the AMI mode on JWST is sensitive to planetary mass companions at close-in separations (${\gtrsim}0.07{"}$), even for thousands of more distant stars at $\sim$100 pc, in addition to the stars in the nearby young moving groups as stated in previous works. This result will allow the planning and successful execution of future observations to probe the inner regions of nearby stellar systems, opening an essentially unexplored parameter space.

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arXiv2025

Phase-resolved Hubble Space Telescope WFC3 Spectroscopy of Weakly-Irradiated Brown Dwarf GD 1400 and Energy Redistribution-Irradiation Trends in Six WD$-$BD Binaries

Irradiated brown dwarfs offer a unique opportunity to bridge the gap between stellar and planetary atmospheres. We present high-quality $\mathit{HST}$/WFC3/G141 phase-resolved spectra of the white dwarf + brown dwarf binary GD 1400, covering more than one full rotation of the brown dwarf. Accounting for brightness variations caused by ZZ Ceti pulsations, we revealed weak ($\sim$1\%) phase curve amplitude modulations originating from the brown dwarf. Sub-band light curve exploration in various bands showed no significant wavelength dependence on amplitude or phase shift. Extracted day- and night-side spectra indicated chemically similar hemispheres, with slightly higher day-side temperatures, suggesting efficient heat redistribution or dominance of radiative escape over atmospheric circulation. A simple radiative and energy redistribution model reproduced observed temperatures well. Cloud-inclusive models fit the day and night spectra better than cloudless models, indicating global cloud coverage. We also begin qualitatively exploring atmospheric trends across six irradiated brown dwarfs, from the now complete "Dancing with Dwarfs" WD$-$BD sample. The trend we find in the day-side/night-side temperature and irradiation levels is consistent with efficient heat redistribution for irradiation levels less than $\sim$10$^9$ ergs/s/cm$^2$ and decreasing efficiency above that level.

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arXiv2024

Disequilibrium Chemistry, Diabatic Thermal Structure, and Clouds in the Atmosphere of COCONUTS-2b

Located 10.888 pc from Earth, COCONUTS-2b is a planetary-mass companion to a young (150-800 Myr) M3 star, with a wide orbital separation (6471 au) and a low companion-to-host mass ratio ($0.021\pm0.005$). We have studied the atmospheric properties of COCONUTS-2b using newly acquired 1.0-2.5 $μ$m spectroscopy from Gemini/Flamingos-2. The spectral type of COCONUTS-2b is refined to T$9.5 \pm 0.5$ based on comparisons with T/Y dwarf spectral templates. We have conducted an extensive forward-modeling analysis, comparing the near-infrared spectrum and mid-infrared broadband photometry with sixteen state-of-the-art atmospheric model grids developed for brown dwarfs and self-luminous exoplanets near the T/Y transition. The PH$_{3}$-free ATMO2020++, ATMO2020++, and Exo-REM models best match the specific observations of COCONUTS-2b, regardless of variations in the input spectrophotometry. This analysis suggests the presence of disequilibrium chemistry, along with a diabatic thermal structure and/or clouds, in the atmosphere of COCONUTS-2b. All models predict fainter $Y$-band fluxes than observed, highlighting uncertainties in the alkali chemistry models and opacities. We determine a bolometric luminosity of $\log{(L_{\rm bol}/L_{\odot})}=-6.18$ dex, with a 0.5 dex-wide range of $[-6.43,-5.93]$ dex that accounts for various assumptions of models. Using thermal evolution models, we derive an effective temperature of $T_{\rm eff}=483^{+44}_{-53}$ K, a surface gravity of $\log{(g)}=4.19^{+0.18}_{-0.13}$ dex, a radius of $R=1.11^{+0.03}_{-0.04}$ R$_{\rm Jup}$, and a mass of $M=8 \pm 2$ M$_{\rm Jup}$. Various atmospheric model grids consistently indicate that COCONUTS-2b's atmosphere has sub- or near-solar metallicity and C/O. These findings provide valuable insights into COCONUTS-2b's formation history and the potential outward migration to its current wide orbit.

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arXiv2024

JADES: Spectroscopic Confirmation and Proper Motion for a T-Dwarf at 2 Kiloparsecs

Large area observations of extragalactic deep fields with the James Webb Space Telescope (JWST) have provided a wealth of candidate low-mass L- and T-class brown dwarfs. The existence of these sources, which are at derived distances of hundreds of parsecs to several kiloparsecs from the Sun, has strong implications for the low-mass end of the stellar initial mass function, and the link between stars and planets at low metallicities. In this letter, we present a JWST/NIRSpec PRISM spectrum of brown dwarf JADES-GS-BD-9, confirming its photometric selection from observations taken as part of the JWST Advanced Deep Extragalactic Survey (JADES) program. Fits to this spectrum indicate that the brown dwarf has an effective temperature of 800-900K (T5 - T6) at a distance of $1.8 - 2.3$kpc from the Sun, with evidence of the source being at low metallicity ([M/H] $\leq -0.5$). Finally, because of the cadence of JADES NIRCam observations of this source, we additionally uncover a proper motion between the 2022 and 2023 centroids, and we measure a proper motion of $20 \pm 4$ mas yr$^{-1}$ (a transverse velocity of 214 km s$^{-1}$ at 2.25 kpc). At this predicted metallicity, distance, and transverse velocity, it is likely that this source belongs either to the edge of the Milky Way thick disk or the galactic halo. This spectral confirmation demonstrates the efficacy of photometric selection of these important sources across deep extragalactic JWST imaging.

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arXiv2024

The only inflated brown dwarf in an eclipsing white dwarf-brown dwarf binary: WD1032+011B

Due to their short orbital periods and relatively high flux ratios, irradiated brown dwarfs in binaries with white dwarfs offer better opportunities to study irradiated atmospheres than hot Jupiters, which have lower planet-to-star flux ratios. WD1032+011 is an eclipsing, tidally locked white dwarf-brown dwarf binary with a 9950 K white dwarf orbited by a 69.7 M$_{Jup}$ brown dwarf in a 0.09 day orbit. We present time-resolved Hubble Space Telescope Wide Field Camera 3 spectrophotometric data of WD1032+011. We isolate the phase-dependent spectra of WD1032+011B, finding a 210 K difference in brightness temperature between the dayside and nightside. The spectral type of the brown dwarf is identified as L1 peculiar, with atmospheric retrievals and comparison to field brown dwarfs showing evidence for a cloud-free atmosphere. The retrieved temperature of the dayside is $1748^{+66}_{-67}$ K, with a nightside temperature of $1555^{+76}_{-62}$ K, showing an irradiation-driven temperature contrast coupled with inefficient heat redistribution from the dayside to the nightside. The brown dwarf radius is inflated, likely due to the constant irradiation from the white dwarf, making it the only known inflated brown dwarf in an eclipsing white dwarf-brown dwarf binary.

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arXiv2024

Aggregate Cloud Particle Effects in Exoplanet Atmospheres

Aerosol opacity has emerged as a critical factor controlling transmission and emission spectra. We provide a simple guideline for the effects of aerosol morphology on opacity and residence time in the atmosphere, as it pertains to transit observations, particularly those with flat spectra due to high altitude aerosols. This framework can be used for understanding complex cloud and haze particle properties before getting into detailed microphysical modeling. We consider high altitude aerosols to be composed of large fluffy particles that can have large residence times in the atmosphere and influence the deposition of stellar flux and/or the emergence of thermal emission in a different way than compact droplet particles, as generally modeled to date for extrasolar planetary atmospheres. We demonstrate the important influence of aggregate particle porosity and composition on the extent of the wavelength independent regime. We also consider how such fluffy particles reach such high altitudes and conclude that the most likely scenario is their local production at high altitudes via UV bombardment and subsequent blanketing of the atmosphere, rather than some mechanism of lofting or transport from the lower atmosphere.

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arXiv2024

Neglected Silicon Dioxide Polymorphs as Clouds in Substellar Atmospheres

Direct mid-infrared signatures of silicate clouds in substellar atmospheres were first detected in Spitzer observations of brown dwarfs, although their existence was previously inferred from near-infrared spectra. With JWST's Mid-Infrared Instrument (MIRI) instrument, we can now more deeply probe silicate features from 8 to 10 microns, exploring specific particle composition, size, and structure. Recent characterization efforts have led to the identification in particular of silica (silicon dioxide, SiO$_2$) cloud features in brown dwarfs and giant exoplanets. Previous modeling, motivated by chemical equilibrium, has primarily focused on magnesium silicates (forsterite, enstatite), crystalline quartz, and amorphous silica to match observations. Here, we explore the previously neglected possibility that other crystalline structures of silica, i.e. polymorphs, may be more likely to form at the pressure and temperature conditions of substellar upper atmospheres. We evaluate JWST's diagnostic potential for these polymorphs and find that existing published transmission data are only able to conclusively distinguish tridymite, but future higher signal-to-noise transmission observations, directly imaged planet observations, and brown dwarf observations may be able to disentangle all four of the silica polymorphs. We ultimately propose that accounting for the distinct opacities arising from the possible crystalline structure of cloud materials may act as a powerful, observable diagnostic tracer of atmospheric conditions, where particle crystallinity records the history of the atmospheric regions through which clouds formed and evolved. Finally, we highlight that high fidelity, accurate laboratory measurements of silica polymorphs are critically needed to draw meaningful conclusions about the identities and structures of clouds in substellar atmospheres.

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arXiv2024

A Tale of Two Molecules: The Underprediction of CO$_2$ and Overprediction of PH$_3$ in Late T and Y Dwarf Atmospheric Models

The sensitivity and spectral coverage of JWST is enabling us to test our assumptions of ultracool dwarf atmospheric chemistry, especially with regards to the abundances of phosphine (PH$_3$) and carbon dioxide (CO$_2$). In this paper, we use NIRSpec PRISM spectra ($\sim$0.8$-$5.5 $μ$m, $R\sim$100) of four late T and Y dwarfs to show that standard substellar atmosphere models have difficulty replicating the 4.1$-$4.4 $μ$m wavelength range as they predict an overabundance of phosphine and an underabundance of carbon dioxide. To help quantify this discrepancy, we generate a grid of models using PICASO based on the Elf Owl chemical and temperature profiles where we include the abundances of these two molecules as parameters. The fits to these PICASO models show a consistent preference for orders of magnitude higher CO$_2$ abundances and a reduction in PH$_3$ abundance as compared to the nominal models. This tendency means that the claimed phosphine detection in UNCOVER$-$BD$-$3 could instead be explained by a CO$_2$ abundance in excess of standard atmospheric model predictions; however the signal-to-noise of the spectrum is not high enough to discriminate between these cases. We discuss atmospheric mechanisms that could explain the observed underabundance of PH$_3$ and overabundance of CO$_2$, including a vertical eddy diffusion coefficient ($K_{\mathrm{zz}}$) that varies with altitude, incorrect chemical pathways, or elements condensing out in forms such as NH$_4$H$_2$PO$_4$. However, our favored explanation for the required CO$_2$ enhancement is that the quench approximation does not accurately predict the CO$_2$ abundance, as CO$_2$ remains in chemical equilibrium with CO after CO quenches.

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arXiv2024

Precise Bolometric Luminosities and Effective Temperatures of 23 late-T and Y dwarfs Obtained with JWST

We present infrared spectral energy distributions of 23 late-type T and Y dwarfs obtained with the James Webb Space Telescope. The spectral energy distributions consist of NIRSpec PRISM and MIRI LRS spectra covering the $\sim$1--12 $μ$m wavelength range at $λ/ Δλ\approx 100$ and broadband photometry at 15, 18, and 21 $μ$m. The spectra exhibit absorption features common to these objects including H$_2$O, CH$_4$, CO, CO$_2$, and NH$_3$. Interestingly, while the spectral morphology changes relatively smoothly with spectral type at $λ< 3$ $μ$m and $λ> 8$ $μ$m, it shows no clear trend in the 5 $μ$m region where a large fraction of the flux emerges. The broad wavelength coverage of the data enables us to compute the first accurate measurements of the bolometric fluxes of cool brown dwarfs. Combining these bolometric fluxes with parallaxes from Spitzer and HST, we also obtain the first accurate bolometric luminosities of these cool dwarfs. We then used the Sonora Bobcat solar metallicity evolutionary models to estimate the radii of the dwarfs which results in effective temperature estimates ranging from $\sim$1000 to 350 K with a median uncertainty of $\pm$20 K which is nearly an order of magnitude improvement over previous work. We also discuss how various portions of the spectra either do or do not exhibit a clear sequence when ordered by their effective temperatures.

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arXiv2024

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems II: A 1 to 20 Micron Spectrum of the Planetary-Mass Companion VHS 1256-1257 b

We present the highest fidelity spectrum to date of a planetary-mass object. VHS 1256 b is a $<$20 M$_\mathrm{Jup}$ widely separated ($\sim$8\arcsec, a = 150 au), young, planetary-mass companion that shares photometric colors and spectroscopic features with the directly imaged exoplanets HR 8799 c, d, and e. As an L-to-T transition object, VHS 1256 b exists along the region of the color-magnitude diagram where substellar atmospheres transition from cloudy to clear. We observed VHS 1256~b with \textit{JWST}'s NIRSpec IFU and MIRI MRS modes for coverage from 1 $μ$m to 20 $μ$m at resolutions of $\sim$1,000 - 3,700. Water, methane, carbon monoxide, carbon dioxide, sodium, and potassium are observed in several portions of the \textit{JWST} spectrum based on comparisons from template brown dwarf spectra, molecular opacities, and atmospheric models. The spectral shape of VHS 1256 b is influenced by disequilibrium chemistry and clouds. We directly detect silicate clouds, the first such detection reported for a planetary-mass companion.

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arXiv2024

Influence of Orbit and Mass Constraints on Reflected Light Characterization of Directly Imaged Rocky Exoplanets

Survey strategies for upcoming exoplanet direct imaging missions have considered varying assumptions of prior knowledge. Precursor radial velocity surveys could have detected nearby exo-Earths and provided prior orbit and mass constraints. Alternatively, a direct imaging mission performing astrometry could yield constraints on orbit and phase angle of target planets. Understanding the impact of prior mass and orbit information on planetary characterization is crucial for efficiently recognizing habitable exoplanets. To address this question, we use a reflected-light retrieval tool to infer the atmospheric and bulk properties of directly imaged Earth-analogs while considering varying levels of prior information and signal-to-noise ratio (SNR). Because of the strong correlation between the orbit-related parameters and the planetary radius, prior information on the orbital distance and planetary phase yield tight constraints on the planetary radius: from $R_{\rm{p}}=2.95^{+2.69}_{-1.95}~R_{\oplus}$ without prior knowledge, to $R_{\rm{p}}=1.01^{+0.33}_{-0.19}~R_{\oplus}$ with prior determination of the orbit for $\rm{SNR}=20$ in the visible/near-infrared spectral range, thus allowing size determination from reflected light observations. However, additional knowledge of planet mass does not notably enhance radius ($R_{\rm{p}}=0.98^{+0.17}_{-0.14}~R_{\oplus}$) or atmospheric characterization. Also, prior knowledge of the mass alone does not yield a tight radius constraint ($R_{\rm{p}}=1.64^{+1.29}_{-0.80}~R_{\oplus}$) nor improves atmospheric composition inference. By contrast, because of its sensitivity to gas column abundance, detecting a Rayleigh scattering slope or bounding Rayleigh opacity helps to refine gas mixing ratio inferences without requiring prior mass knowledge. Overall, apart from radius determination, increasing the SNR is more beneficial than additional prior observations.

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arXiv2024

Probing the Heights and Depths of Y Dwarf Atmospheres: A Retrieval Analysis of the JWST Spectral Energy Distribution of WISE J035934.06$-$540154.6

We present an atmospheric retrieval analysis of the Y0 brown dwarf WISE J035934.06$-$540154.6 using the low-resolution 0.96--12 $μ$m JWST spectrum presented in \citet{Beiler_2023}. We obtain volume number mixing ratios of the major gas-phase absorbers (H$_2$O, CH$_4$, CO, CO$_2$, PH$_3$, and H$_2$S) that are 3--5$\times$ more precise than previous work that used HST spectra. We also find an order-of-magnitude improvement in the precision of the retrieved thermal profile, a direct result of the broad wavelength coverage of the JWST data. We used the retrieved thermal profile and surface gravity to generate a grid of chemical forward models with varying metallicity, (C/O)$_\textrm{atm}$, and strengths of vertical mixing as encapsulated by the eddy diffusion coefficient $K_\textrm{zz}$. Comparison of the retrieved abundances with this grid of models suggests that the deep atmosphere of WISE 0359$-$54 shows signs of vigorous vertical mixing with $K_\textrm{zz}=10^9$ [cm$^{2}$ s$^{-1}$]. To test the sensitivity of these results to our 5-knot spline thermal profile model, we performed a second retrieval using the \citet{Madhusudhan_2009} thermal profile model. While the results of the two retrievals generally agree well, we do find differences between the retrieved values of mass and volume number mixing ratio of H$_2$S with fractional differences of the median values of $-$0.64 and $-$0.10, respectively. In addition, the 5-knot thermal profile is consistently warmer at pressure between 1 and 70 bar. Nevertheless, our results underscore the power that the broad-wavelength infrared spectra obtainable with the James Webb Space Telescope have to characterize the atmospheres of cool brown dwarfs.

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