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Mark S. Marley

Publications and source records attributed to Mark S. Marley.

At least 55 records · Page 3Linked to original sources

Time-resolved Hubble Space Telescope Wide Field Camera 3 Spectrophotometry Reveals Inefficient Day-to-Night Heat Redistribution in the Highly Irradiated Brown Dwarf SDSS 1557B

Brown dwarfs in ultra-short period orbits around white dwarfs offer a unique opportunity to study the properties of tidally-locked, fast rotating (1-3 hr), and highly-irradiated atmospheres. Here, we present phase-resolved spectrophotometry of the white dwarf-brown dwarf (WD-BD) binary SDSS 1557, which is the fifth WD-BD binary in our six-object sample. Using the Hubble Space Telescope Wide Field Camera 3 Near-infrared G141 instrument, the 1.1 to 1.7 $μ$m phase curves show rotational modulations with semi-amplitudes of 10.5$\pm$0.1%. We observe a wavelength dependent amplitude, with longer wavelengths producing larger amplitudes, while no wavelength dependent phase shifts were identified. The phase-resolved extracted BD spectra exhibit steep slopes and are nearly featureless. A simple radiative energy redistribution atmospheric model recreates the hemisphere integrated brightness temperatures at three distinct phases and finds evidence for weak redistribution efficiency. Our model also predicts a higher inclination than previously published. We find that SDSS 1557B, the second most irradiated BD in our sample, is likely dominated by clouds on the night side, whereas the featureless day side spectrum is likely dominated by H$^-$ opacity and a temperature inversion, much like the other highly-irradiated BD EPIC2122B.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems IV: NIRISS Aperture Masking Interferometry Performance and Lessons Learned

We present a performance analysis for the aperture masking interferometry (AMI) mode on board the James Webb Space Telescope Near Infrared Imager and Slitless Spectrograph (JWST/NIRISS). Thanks to self-calibrating observables, AMI accesses inner working angles down to and even within the classical diffraction limit. The scientific potential of this mode has recently been demonstrated by the Early Release Science (ERS) 1386 program with a deep search for close-in companions in the HIP 65426 exoplanetary system. As part of ERS 1386, we use the same data set to explore the random, static, and calibration errors of NIRISS AMI observables. We compare the observed noise properties and achievable contrast to theoretical predictions. We explore possible sources of calibration errors and show that differences in charge migration between the observations of HIP 65426 and point-spread function calibration stars can account for the achieved contrast curves. Lastly, we use self-calibration tests to demonstrate that with adequate calibration NIRISS F380M AMI can reach contrast levels of $\sim9-10$ mag at $\gtrsim λ/D$. These tests lead us to observation planning recommendations and strongly motivate future studies aimed at producing sophisticated calibration strategies taking these systematic effects into account. This will unlock the unprecedented capabilities of JWST/NIRISS AMI, with sensitivity to significantly colder, lower-mass exoplanets than lower-contrast ground-based AMI setups, at orbital separations inaccessible to JWST coronagraphy.

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The Sonora Substellar Atmosphere Models. III. Diamondback: Atmospheric Properties, Spectra, and Evolution for Warm Cloudy Substellar Objects

We present a new grid of cloudy atmosphere and evolution models for substellar objects. These models include the effect of refractory cloud species, including silicate clouds, on the spectra and evolution. We include effective temperatures from 900 to 2400 K and surface gravities from log g=3.5-5.5, appropriate for a broad range of objects with masses between 1 and 84 Jupiter masses. Model pressure-temperature structures are calculated assuming radiative-convective and chemical equilibrium. We consider the effect of both clouds and metallicity on the atmospheric structure, resulting spectra, and thermal evolution of substellar worlds. We parameterize clouds using the Ackerman & Marley (2001) cloud model, including cloud parameter fsed values from 1-8; we include three metallicities (-0.5, 0.0, and +0.5). Refractory clouds and metallicity both alter the evolution of substellar objects, changing the inferred temperature at a given age by up to 100-200 K. We compare to the observed photometry of brown dwarfs, finding broad agreement with the measured photometry. We publish the spectra, evolution, and other data products online with open access.

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The Sonora Substellar Atmosphere Models. IV. Elf Owl: Atmospheric Mixing and Chemical Disequilibrium with Varying Metallicity and C/O Ratios

Disequilibrium chemistry due to vertical mixing in the atmospheres of many brown dwarfs and giant exoplanets is well-established. Atmosphere models for these objects typically parameterize mixing with the highly uncertain $K_{\rm zz}$ diffusion parameter. The role of mixing in altering the abundances of C-N-O-bearing molecules has mostly been explored for solar composition atmospheres. However, atmospheric metallicity and the C/O ratio also impact atmospheric chemistry. Therefore, we present the \texttt{Sonora Elf Owl} grid of self-consistent cloud-free 1D radiative-convective equilibrium model atmospheres for JWST observations, which includes a variation of $K_{\rm zz}$ across several orders of magnitude and also encompasses sub-solar to super-solar metallicities and C/O ratios. We find that the impact of $K_{\rm zz}$ on the $T(P)$ profile and spectra is a strong function of both $T_{\rm eff}$ and metallicity. For metal-poor objects $K_{\rm zz}$ has large impacts on the atmosphere at significantly higher $T_{\rm eff}$ compared to metal-rich atmospheres where the impact of $K_{\rm zz}$ is seen to occur at lower $T_{\rm eff}$. We identify significant spectral degeneracies between varying $K_{\rm zz}$ and metallicity in multiple wavelength windows, in particular at 3-5 $μ$m. We use the \texttt{Sonora Elf Owl} atmospheric grid to fit the observed spectra of a sample of 9 early to late T- type objects from $T_{\rm eff}=550-1150$ K. We find evidence for very inefficient vertical mixing in these objects with inferred $K_{\rm zz}$ values lying in the range between $\sim$ 10$^1$-10$^4$ cm$^2$s$^{-1}$. Using self-consistent models, we find that this slow vertical mixing is due to the observations probing mixing in the deep detached radiative zone in these atmospheres.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems V: Do Self-Consistent Atmospheric Models Represent JWST Spectra? A Showcase With VHS 1256 b

The unprecedented medium-resolution (R~1500-3500) near- and mid-infrared (1-18um) spectrum provided by JWST for the young (140+/-20Myr) low-mass (12-20MJup) L-T transition (L7) companion VHS1256b gives access to a catalogue of molecular absorptions. In this study, we present a comprehensive analysis of this dataset utilizing a forward modelling approach, applying our Bayesian framework, ForMoSA. We explore five distinct atmospheric models to assess their performance in estimating key atmospheric parameters: Teff, log(g), [M/H], C/O, gamma, fsed, and R. Our findings reveal that each parameter's estimate is significantly influenced by factors such as the wavelength range considered and the model chosen for the fit. This is attributed to systematic errors in the models and their challenges in accurately replicating the complex atmospheric structure of VHS1256b, notably the complexity of its clouds and dust distribution. To propagate the impact of these systematic uncertainties on our atmospheric property estimates, we introduce innovative fitting methodologies based on independent fits performed on different spectral windows. We finally derived a Teff consistent with the spectral type of the target, considering its young age, which is confirmed by our estimate of log(g). Despite the exceptional data quality, attaining robust estimates for chemical abundances [M/H] and C/O, often employed as indicators of formation history, remains challenging. Nevertheless, the pioneering case of JWST's data for VHS1256b has paved the way for future acquisitions of substellar spectra that will be systematically analyzed to directly compare the properties of these objects and correct the systematics in the models.

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Optical Properties of Organic Haze Analogues in Water-rich Exoplanet Atmospheres Observable with JWST

JWST has begun its scientific mission, which includes the atmospheric characterization of transiting exoplanets. Some of the first exoplanets to be observed by JWST have equilibrium temperatures below 1000 K, which is a regime where photochemical hazes are expected to form. The optical properties of these hazes, which controls how they interact with light, are critical for interpreting exoplanet observations, but relevant experimental data are not available. Here we measure the density and optical properties of organic haze analogues generated in water-rich exoplanet atmosphere experiments. We report optical constants (0.4 to 28.6 μm) of organic haze analogues for current and future observational and modeling efforts covering the entire wavelength range of JWST instrumentation and a large part of Hubble. We use these optical constants to generate hazy model atmospheric spectra. The synthetic spectra show that differences in haze optical constants have a detectable effect on the spectra, impacting our interpretation of exoplanet observations. This study emphasizes the need to investigate the optical properties of hazes formed in different exoplanet atmospheres, and establishes a practical procedure to determine such properties.

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Probing reflection from aerosols with the near-infrared dayside spectrum of WASP-80b

The presence of aerosols is intimately linked to the global energy budget and the composition of a planet's atmospheres. Their ability to reflect incoming light prevents energy from being deposited into the atmosphere, and they shape spectra of exoplanets. We observed five near-infrared secondary eclipses of WASP-80b with the Wide Field Camera 3 (WFC3) aboard the \textit{Hubble Space Telescope} to provide constraints on the presence and properties of atmospheric aerosols. We detect a broadband eclipse depth of $34\pm10$\,ppm for WASP-80b. We detect a higher planetary flux than expected from thermal emission alone at $1.6σ$, which hints toward the presence of reflecting aerosols on this planet's dayside, indicating a geometric albedo of $A_g<0.33$ at 3$σ$. We paired the WFC3 data with Spitzer data and explored multiple atmospheric models with and without aerosols to interpret this spectrum. Albeit consistent with a clear dayside atmosphere, we found a slight preference for near-solar metallicities and for dayside clouds over hazes. We exclude soot haze formation rates higher than $10^{-10.7}$ g cm$^{-2}$s$^{-1}$ and tholin formation rates higher than $10^{-12.0}$ g cm$^{-2}$s$^{-1}$ at $3σ$. We applied the same atmospheric models to a previously published WFC3/Spitzer transmission spectrum for this planet and found weak haze formation. A single soot haze formation rate best fits both the dayside and the transmission spectra simultaneously. However, we emphasize that no models provide satisfactory fits in terms of the chi-square of both spectra simultaneously, indicating longitudinal dissimilarity in the atmosphere's aerosol composition.

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ELemental abundances of Planets and brown dwarfs Imaged around Stars (ELPIS): I. Potential Metal Enrichment of the Exoplanet AF Lep b and a Novel Retrieval Approach for Cloudy Self-luminous Atmospheres

AF Lep A+b is a remarkable planetary system hosting a gas-giant planet that has the lowest dynamical mass among directly imaged exoplanets. We present an in-depth analysis of the atmospheric composition of the star and planet to probe the planet's formation pathway. Based on new high-resolution spectroscopy of AF Lep A, we measure a uniform set of stellar parameters and elemental abundances (e.g., [Fe/H] = $-0.27 \pm 0.31$ dex). The planet's dynamical mass ($2.8^{+0.6}_{-0.5}$ M$_{\rm Jup}$) and orbit are also refined using published radial velocities, relative astrometry, and absolute astrometry. We use petitRADTRANS to perform chemically-consistent atmospheric retrievals for AF Lep b. The radiative-convective equilibrium temperature profiles are incorporated as parameterized priors on the planet's thermal structure, leading to a robust characterization for cloudy self-luminous atmospheres. This novel approach is enabled by constraining the temperature-pressure profiles via the temperature gradient $(d\ln{T}/d\ln{P})$, a departure from previous studies that solely modeled the temperature. Through multiple retrievals performed on different portions of the $0.9-4.2$ $μ$m spectrophotometry, along with different priors on the planet's mass and radius, we infer that AF Lep b likely possesses a metal-enriched atmosphere ([Fe/H] $> 1.0$ dex). AF Lep b's potential metal enrichment may be due to planetesimal accretion, giant impacts, and/or core erosion. The first process coincides with the debris disk in the system, which could be dynamically excited by AF Lep b and lead to planetesimal bombardment. Our analysis also determines $T_{\rm eff} \approx 800$ K, $\log{(g)} \approx 3.7$ dex, and the presence of silicate clouds and dis-equilibrium chemistry in the atmosphere. Straddling the L/T transition, AF Lep b is thus far the coldest exoplanet with suggested evidence of silicate clouds.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems I: High Contrast Imaging of the Exoplanet HIP 65426 b from 2-16 $μ$m

We present JWST Early Release Science (ERS) coronagraphic observations of the super-Jupiter exoplanet, HIP 65426 b, with the Near-Infrared Camera (NIRCam) from 2-5 $μ$m, and with the Mid-Infrared Instrument (MIRI) from 11-16 $μ$m. At a separation of $\sim$0.82" (86$^{+116}_{-31}$ au), HIP 65426 b is clearly detected in all seven of our observational filters, representing the first images of an exoplanet to be obtained by JWST, and the first ever direct detection of an exoplanet beyond 5 $μ$m. These observations demonstrate that JWST is exceeding its nominal predicted performance by up to a factor of 10, depending on separation and subtraction method, with measured 5$σ$ contrast limits of $\sim$1$\times10^{-5}$ and $\sim$2$\times10^{-4}$ at 1" for NIRCam at 4.4 $μ$m and MIRI at 11.3 $μ$m, respectively. These contrast limits provide sensitivity to sub-Jupiter companions with masses as low as 0.3$M_\mathrm{Jup}$ beyond separations of $\sim$100 au. Together with existing ground-based near-infrared data, the JWST photometry are well fit by a BT-SETTL atmospheric model from 1-16 $μ$m, and span $\sim$97% of HIP 65426 b's luminous range. Independent of the choice of model atmosphere we measure an empirical bolometric luminosity that is tightly constrained between $\mathrm{log}\!\left(L_\mathrm{bol}/L_{\odot}\right)$=-4.31 to $-$4.14, which in turn provides a robust mass constraint of 7.1$\pm$1.2 $M_\mathrm{Jup}$. In totality, these observations confirm that JWST presents a powerful and exciting opportunity to characterise the population of exoplanets amenable to high-contrast imaging in greater detail.

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Spherical Harmonics for the 1D Radiative Transfer Equation II: Thermal Emission

Approximate methods to estimate solutions to the radiative transfer equation are essential for the understanding of atmospheres of exoplanets and brown dwarfs. The simplest and most popular choice is the "two-stream method" which is often used to produce simple yet effective models for radiative transfer in scattering and absorbing media. Toon et al. (1989) (Toon89) outlined a two-stream method for computing reflected light and thermal spectra and was later implemented in the open-source radiative transfer model PICASO. In Part~I of this series, we developed an analytical spherical harmonics method for solving the radiative transfer equation for reflected solar radiation (Rooney et al. 2023), which was implemented in PICASO to increase the accuracy of the code by offering a higher-order approximation. This work is an extension of this spherical harmonics derivation to study thermal emission spectroscopy. We highlight the model differences in the approach for thermal emission and benchmark the 4-term method (SH4) against Toon89 and a high-stream discrete-ordinates method, CDISORT. By comparing the spectra produced by each model we demonstrate that the SH4 method provides a significant increase in accuracy, compared to Toon89, which can be attributed to the increased order of approximation and to the choice of phase function. We also explore the trade-off between computational time and model accuracy. We find that our 4-term method is twice as slow as our 2-term method, but is up to five times more accurate, when compared with CDISORT. Therefore, SH4 provides excellent improvement in model accuracy with minimal sacrifice in numerical expense.

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Spherical Harmonics for the 1D Radiative Transfer Equation I: Reflected Light

A significant challenge in radiative transfer theory for atmospheres of exoplanets and brown dwarfs is the derivation of computationally efficient methods that have adequate fidelity to more precise, numerically demanding solutions. In this work, we extend the capability of the first open-source radiative transfer model for computing the reflected light of exoplanets at any phase geometry, PICASO: Planetary Intensity Code for Atmospheric Spectroscopy Observations. Until now, PICASO has implemented two-stream approaches to the solving the radiative transfer equation for reflected light, in particular following the derivations of Toon et al. (1989) (Toon89). In order to improve the model accuracy, we have considered higher-order approximations of the phase functions, namely, we have increased the order of approximation from 2 to 4, using spherical harmonics. The spherical harmonics approximation decouples spatial and directional dependencies by expanding the intensity and phase function into a series of spherical harmonics, or Legendre polynomials, allowing for analytical solutions for low-order approximations to optimize computational efficiency. We rigorously derive the spherical harmonics method for reflected light and benchmark the 4-term method (SH4) against Toon89 and two independent and higher-fidelity methods (CDISORT & doubling-method). On average, the SH4 method provides an order of magnitude increase in accuracy, compared to Toon89. Lastly, we implement SH4 within PICASO and observe only modest increase in computational time, compared to two-stream methods (20% increase).

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The puzzle of the formation of T8 dwarf Ross 458c

At the lowest masses, the distinction between brown dwarfs and giant exoplanets is often blurred and literature classifications rarely reflect the deuterium burning boundary. Atmospheric characterisation may reveal the extent to which planetary formation pathways contribute to the population of very-low mass brown dwarfs, by revealing if their abundance distributions differ from those of the local field population or, in the case of companions, their primary stars. The T8 dwarf Ross 458c is a possible planetary mass companion to a pair of M dwarfs, and previous work suggests that it is cloudy. We here present the results of the retrieval analysis of Ross 458c, using archival spectroscopic data in the 1.0 to 2.4 micron range. We test a cloud free model as well as a variety of cloudy models and find that the atmosphere of Ross 458c is best described by a cloudy model (strongly preferred). The CH4/H2O is higher than expected at 1.97 +0.13 -0.14. This value is challenging to understand in terms of equilibrium chemistry and plausible C/O ratios. Comparisons to thermochemical grid models suggest a C/O of ~ 1.35, if CH4 and H2O are quenched at 2000 K, requiring vigorous mixing. We find a [C/H] ratio of +0.18, which matches the metallicity of the primary system, suggesting that oxygen is missing from the atmosphere. Even with extreme mixing, the implied C/O is well beyond the typical stellar regime, suggesting a either non-stellar formation pathway, or the sequestration of substantial quantities of oxygen via hitherto unmodeled chemistry or condensation processes.

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Hotter Than Expected: HST/WFC3 Phase-resolved Spectroscopy of a Rare Irradiated Brown Dwarf with Strong Internal Heat Flux

With infrared flux contrasts larger than typically seen in hot Jupiter, tidally-locked white dwarf-brown dwarf binaries offer a superior opportunity to investigate atmospheric processes in irradiated atmospheres. NLTT5306 is such a system, with a M$_{BD}$ = 52 $\pm$ 3 M$_{Jup}$ brown dwarf orbiting a T$_{eff}$ = 7756 $\pm$ 35 K white dwarf with an ultra-short period of $\sim$102 min. We present HST/WFC3 spectroscopic phase curves of NLTT5306, consisting of 47 spectra from 1.1 to 1.7 microns with an average S/N=65 per wavelength. We extracted the phase-resolved spectra of the brown dwarf NLTT5306B, finding a small (<100 K) day/night temperature difference ($\sim$5 percent of the average day-side temperature). Our best-fit model phase curves revealed a complex wavelength-dependence on amplitudes and relative phase offsets, suggesting longitudinal-vertical atmospheric structure. The night-side spectrum was well-fit by a cloudy, non-irradiated atmospheric model while the day-side was best-matched by a cloudy, weakly irradiated model. Additionally, we created a simple radiative energy redistribution model of the atmosphere and found evidence for efficient day-to-night heat redistribution and a moderately high Bond albedo. We also discovered an internal heat flux much higher than expected given the published system age, leading to an age reassessment that resulted in NLTT5306B most likely being much younger. We find that NLTT5306B is the only known significantly irradiated brown dwarf where the global temperature structure is not dominated by external irradiation, but rather its own internal heat. Our study provides an essential insight into the drivers of global circulation and day-to-night heat transport as a function of irradiation, rotation rate, and internal heat.

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Improved companion mass limits for Sirius A with thermal infrared coronagraphy using a vector-apodizing phase plate and time-domain starlight-subtraction techniques

We use observations with the infrared-optimized MagAO system and Clio camera in 3.9 $μ$m light to place stringent mass constraints on possible undetected companions to Sirius A. We suppress the light from Sirius A by imaging it through a grating vector-apodizing phase plate coronagraph with 180-degree dark region (gvAPP-180). To remove residual starlight in post-processing, we apply a time-domain principal-components-analysis-based algorithm we call PCA-Temporal (PCAT), which uses eigen-time-series rather than eigen-images to subtract starlight. By casting the problem in terms of eigen-time-series, we reduce the computational cost of post-processing the data, enabling the use of the fully sampled dataset for improved contrast at small separations. We also discuss the impact of retaining fine temporal sampling of the data on final contrast limits. We achieve post-processed contrast limits of $1.5 \times 10^{-6}$ to $9.8 \times 10^{-6}$ outside of 0.75 arcsec which correspond to planet masses of 2.6 to 8.0 $M_J$. These are combined with values from the recent literature of high-contrast imaging observations of Sirius to synthesize an overall completeness fraction as a function of mass and separation. After synthesizing these recent studies and our results, the final completeness analysis rules out 99% of $\ge 9 \ M_J$ planets from 2.5-7 AU.

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Testing the Interaction Between a Substellar Companion and a Debris Disk in the HR 2562 System

The HR 2562 system is a rare case where a brown dwarf companion resides in a cleared inner hole of a debris disk, offering invaluable opportunities to study the dynamical interaction between a substellar companion and a dusty disk. We present the first ALMA observation of the system as well as the continued GPI monitoring of the companion's orbit with 6 new epochs from 2016 to 2018. We update the orbital fit and, in combination with absolute astrometry from GAIA, place a 3$σ$ upper limit of 18.5 $M_J$ on the companion's mass. To interpret the ALMA observations, we used radiative transfer modeling to determine the disk properties. We find that the disk is well resolved and nearly edge on. While the misalignment angle between the disk and the orbit is weakly constrained due to the short orbital arc available, the data strongly support a (near) coplanar geometry for the system. Furthermore, we find that the models that describe the ALMA data best have an inner radius that is close to the companion's semi-major axis. Including a posteriori knowledge of the system's SED further narrows the constraints on the disk's inner radius and place it at a location that is in reasonable agreement with, possibly interior to, predictions from existing dynamical models of disk truncation by an interior substellar companion. HR\,2562 has the potential over the next few years to become a new testbed for dynamical interaction between a debris disk and a substellar companion.

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Probing the Extent of Vertical Mixing in Brown Dwarf Atmospheres with Disequilibrium Chemistry

Evidence of disequilibrium chemistry due to vertical mixing in the atmospheres of many T and Y-dwarfs has been inferred due to enhanced mixing ratios of CO and reduced NH$_3$. Atmospheric models of planets and brown dwarfs typically parameterize this vertical mixing phenomenon with the vertical eddy diffusion coefficient, $K_{\rm zz}$. While $K_{\rm zz}$ can perhaps be approximated in the convective regions in the atmosphere with mixing length theory, in radiative regions the strength of vertical mixing is uncertain by many orders of magnitude. With a new grid of self-consistent 1D model atmospheres from $T_{\rm eff}$ of 400 - 1000 K, computed with a new radiative-convective equilibrium python code PICASO 3.0, we aim to assess how molecular abundances and corresponding spectra can be used as a probe of depth-dependent $K_{\rm zz}$. At a given surface gravity, we find non-monotonic behavior in the CO abundance as a function of $T_{\rm eff}$, as chemical abundances are sometimes quenched in either of two potential atmospheric convective zones, or quenched in either of two possible radiative zones. The temperature structure and chemical quenching behavior also changes with gravity. We compare our models with available near-infrared and M-band spectroscopy of several T and Y-dwarfs and assess their atmospheric vertical mixing profiles. We also compare to color-magnitude diagrams and make predictions for JWST spectra. This work yields new constraints, and points the way to significant future gains, in determining $K_{\rm zz}$, a fundamental atmospheric parameter in substellar atmospheres, with significant implications for chemistry and cloud modeling.

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PICASO 3.0: A One-Dimensional Climate Model for Giant Planets and Brown Dwarfs

Upcoming James Webb Space Telescope (JWST) observations will allow us to study exoplanet and brown dwarf atmospheres in great detail. The physical interpretation of these upcoming high signal-to-noise observations requires precise atmospheric models of exoplanets and brown dwarfs. While several one-dimensional and three-dimensional atmospheric models have been developed in the past three decades, these models have often relied on simplified assumptions like chemical equilibrium and are also often not open-source, which limits their usage and development by the wider community. We present a python-based one-dimensional atmospheric radiative-convective equilibrium model. This model has heritage from the Fortran-based code (Marley et al.,1996} which has been widely used to model the atmospheres of Solar System objects, brown dwarfs, and exoplanets. In short, the basic capability of the original model is to compute the atmospheric state of the object under radiative-convective equilibrium given its effective or internal temperature, gravity, and host--star properties (if relevant). In the new model, which has been included within the well-utilized code-base PICASO, we have added these original features as well as the new capability of self-consistently treating disequilibrium chemistry. This code is widely applicable to Hydrogen-dominated atmospheres (e.g., brown dwarfs and giant planets).

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Ring Seismology of the Ice Giants Uranus and Neptune

We assess the prospect of using ring seismology to probe the interiors of the ice giants Uranus and Neptune. We do this by calculating normal mode spectra for different interior models of Uranus and Neptune using the stellar oscillation code GYRE. These spectra provide predictions of where in these planets' ring systems the effects of interior oscillations might be detected. We find that f-mode resonances with azimuthal order $m=2$ or $7 \leq m \leq 19$ fall among the inner rings (6, 5, 4, $α$, and $β$) of Uranus, while f-mode resonances with $2 \leq m \leq 12$ fall in the tenuous $ζ$ ring region. In addition, f-mode resonances with $m=2$ or $6 \leq m \leq 13$ may give azimuthal structure to Neptune's tenuous Galle ring. We also find that g-mode resonances may fall in the middle to outer rings of these planets. Although an orbiter is most likely required to confirm the association between any waves in the rings and planetary normal modes, the diversity of normal mode spectra implies that identification of just one or two modes in the rings of Uranus or Neptune would eliminate a variety of interior models, and thus aid in the interpretation of Voyager observations and future spacecraft measurements.

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