arXiv subjects

Marlan O. Scully

Publications and source records attributed to Marlan O. Scully.

At least 55 records · Page 3Linked to original sources

arXiv2019

Enhanced molecular chiral signals via molecular coherence

One of the most widely used chiroptical spectroscopic methods for studying chiral molecules is Raman optical activity; however, the chiral Raman optical activity signal is extremely weak. Here, we theoretically examine enhanced chiral signals in a system with strongly prepared molecular coherence. We show that the enhanced chiral signal due to strong molecular coherence is up to four orders of magnitude higher than that of the spontaneous Raman optical activity. We discuss several advantages of studying the heterodyned signal obtained by combining the anti-Stokes signal with a local oscillator. The heterodyning allows direct measurement of the ratio of the chiral and achiral parameters. Taking advantage of the molecular coherence and heterodyne detection, the coherent anti-Stokes Raman scattering technique opens up a new potential application for investigation of biomolecular chirality.

quant-ph↗

arXiv2019

Coherent Anti-Stokes Raman scattering in optically active medium

Early theoretical works on coherent anti-Stokes Raman scattering in optically active medium consider only heterodyne signal and subsequently, fourth- and fifth-rank tensor averages have been used. In this work, we presented a full signal expression of coherent anti-Stokes Raman scattering in optically active medium with the help of eighth- and ninth-rank tensor averaging for simplest experimental configuration namely, measurements of post-selected circularly polarized components of scattered anti-Stokes field in the presence of three incident laser beams all linearly polarized along the same axis.

quant-ph↗

arXiv2019

On three-dimensional rotational averages of odd-rank tensors

The recent growing interest in nonlinear optical spectroscopy in optically active medium demands the three-dimensional rotational average of high-rank tensors. In the present paper, we present a new method for finding the rotational average of odd-rank tensors in an overcomplete basis of isotropic tensors. The method is successfully applied to the rotational averages of tensors of rank 5,7,9,11.

math-ph↗

arXiv2018

Analytic solution and pulse area theorem for three-level atoms

We report an analytic solution for a three-level atom driven by arbitrary time-dependent electromagnetic pulses. In particular, we consider far-detuned driving pulses and show an excellent match between our analytic result and the numerical simulations. We use our solution to derive a pulse area theorem for three--level $V$ and $Λ$ systems without making the rotating wave approximation. Formulated as an energy conservation law, this pulse area theorem provides a simple picture for a pulse propagation through a three--level media.

quant-ph↗

arXiv2018

Quantum fluctuations in Fröhlich condensate of molecular vibrations driven far from equilibrium

Fröhlich discovered the remarkable condensation of polar vibrations into the lowest frequency mode when the system is pumped externally. For a full understanding of the Fröhlich condensate one needs to go beyond the mean field level to describe critical behavior as well as quantum fluctuations. The energy redistribution among vibrational modes with nonlinearity included is shown to be essential for realizing the condensate and the phonon-number distribution, revealing the transition from quasi-thermal to super-Poissonian statistics with the pump. We further study the spectroscopic properties of the Fröhlich condensate, which are especially revealed by the narrow linewidth. This gives the long-lived coherence and the collective motion of the condensate. Finally we show that the proteins such as Bovine Serum Albumin (BSA) and lysozyme are most likely the candidates for observing such collective modes in THz regime by means of Raman or infrared (IR) spectroscopy.

quant-ph↗

arXiv2018

Local fluctuations of vibrational polaritons monitored by two-dimensional infrared spectroscopy

We study the collective behavior of molecules placed in an infrared (IR) microcavity, incorporating the local fluctuations, i.e., dynamical disorder. The cooperative feature in vibrational polaritons is shown to be dynamically eroded, due to intermolecule coherence. To further resolve such process, we develop a two-dimensional infrared spectroscopy (2D-IR) for molecules interacting with cavity modes. The cooperative feature in correspondence to the spectroscopic signal is specified. The results reveal the dark states by the cross peaks apart from the ones for polaritons, as a result of the breakdown of cooperativity between molecules. We further show that the breakdown of cooperativity profoundly connects to the localization of the vibrational excitations whereas the polariton modes are extended wave over several molecules. Besides, our work offers new physical insight for understanding the recent 2D-IR experiments where the interaction between dark modes and bright polaritons was evident.

quant-ph↗

arXiv2018

Effective spin-spin interactions in bilayers of Rydberg atoms and polar molecules

We show that indirect spin-spin interactions between effective spin-1/2 systems can be realized in two parallel 1D optical lattices loaded with polar molecules and/or Rydberg atoms. The effective spin can be encoded into low-energy rotational states of polar molecules or long-lived states of Rydberg atoms, tightly trapped in a deep optical lattice. The spin-spin interactions can be mediated by Rydberg atoms, placed in a parallel shallow optical lattice, interacting with the effective spins by charge-dipole (for polar molecules) or dipole-dipole (for Rydberg atoms) interaction. Indirect XX, Ising and XXZ interactions with interaction coefficients $J^{\bot}$ and $J^{zz}$ sign varying with interspin distance can be realized, in particular, the $J_{1}-J_{2}$ XXZ model with frustrated ferro-(antiferro-)magnetic nearest (next-nearest) neighbor interactions.

quant-ph↗

arXiv2018

Synthesis of antisymmetric spin exchange interaction and entanglement generation with chiral spin states in a superconducting circuit

We have synthesized the anti-symmetric spin exchange interaction (ASI), which is also called the Dzyaloshinskii-Moriya interaction, in a superconducting circuit containing five superconducting qubits connected to a bus resonator, by periodically modulating the transition frequencies of the qubits with different modulation phases. This allows us to show the chiral spin dynamics in three-, four- and five-spin clusters. We also demonstrate a three-spin chiral logic gate and entangle up to five qubits in Greenberger-Horne-Zeilinger states. Our results pave the way for quantum simulation of magnetism with ASI and quantum computation with chiral spin states.

quant-ph↗

arXiv2017

Quantum statistics of a single-atom Scovil-Schulz-DuBois heat engine

We study the statistics of the lasing output from a single atom quantum heat engine, which was originally proposed by Scovil and Schulz-DuBois (SSDB). In this heat engine model, a single three-level atom is strongly coupled with an optical cavity, and contacted with a hot and a cold heat bath together. We derive a fully quantum laser equation for this heat engine model, and obtain the photon number distribution for both below and above the lasing threshold. With the increase of the hot bath temperature, the population is inverted and lasing light comes out. However, we notice that if the hot bath temperature keeps increasing, the atomic decay rate is also enhanced, which weakens the lasing gain. As a result, another critical point appears at a very high temperature of the hot bath, after which the output light become thermal radiation again. To avoid this double-threshold behavior, we introduce a four-level heat engine model, where the atomic decay rate does not depend on the hot bath temperature. In this case, the lasing threshold is much easier to achieve, and the double-threshold behavior disappears.

quant-ph↗

arXiv2017

Radiation from Atoms Falling into a Black Hole

We show that atoms falling from outside through a cavity into a black hole (BH) emit acceleration radiation which to a distant observer looks much like Hawking BH radiation. In particular, we find the entropy of the acceleration radiation via a simple laser-like analysis. We call this entropy Horizon Brightened Acceleration Radiation (HBAR) entropy to distinguish it from the BH entropy of Bekenstein and Hawking.

quant-ph↗

arXiv2017

Cooperative parametric resonance of the spin one half system of the dense atomic gas

The cooperative resonance for a spin one half system interacting with dc and ac magnetic field is considered. This interaction in the system collective regime can result in parametic resonance and rapid excitation of the excited spin state of the dense atomic gas. The phenomenon is studied using the density matrix approach. We discuss the implementation of this effect and possible applications of the quantum amplification by superradiant emission of radiation.

quant-ph↗

arXiv2017

Entropy of the BEC Ground State: Correlation vs Ground State Entropy

Calculation of the entropy of an ideal Bose Einstein Condensate (BEC) in a three dimensional trap reveals unusual, previously unrecognized, features of the Canonical Ensemble. It is found that, for any temperature, the entropy of the Bose gas is equal to the entropy of the excited particles although the entropy of the particles in the ground state is nonzero. We explain this by considering the correlations between the ground state particles and particles in the excited states. These correlations lead to a correlation entropy which is exactly equal to the contribution from the ground state. The correlations themselves arise from the fact that we have a fixed number of particles obeying quantum statistics. We present results for correlation functions between the ground and excited states in Bose gas, so to clarify the role of fluctuations in the system. We also report the sub-Poissonian nature of the ground state fluctuations.

cond-mat.quant-gas↗

arXiv2017

Controlled Supercontinua via Spatial Beam Shaping

Recently, optimization techniques have had a significant impact in a variety of fields, leading to a higher signal-to-noise and more streamlined techniques. We consider the possibility for using programmable phase-only spatial optimization of the pump beam to influence the supercontinuum generation process. Preliminary results show that significant broadening and rough control of the supercontinuum spectrum are possible without loss of input energy. This serves as a proof-of-concept demonstration that spatial effects can controllably influence the supercontinuum spectrum, leading to possibilities for utilizing supercontinuum power more efficiently and achieving arbitrary spectral control.

physics.optics↗

arXiv2017

Photon-blockade induced photon anti-bunching in photosynthetic Antennas with cyclic structures

One of the important nonclassical effects in quantum optics is the anti-bunching, which has been observed in a large class of physical systems - including light-harvesting antennas with cyclic structures. The units of the ring couple with adjacent ones through dipole-dipole interactions. We show how this strong dipole-dipole interaction leads to photon-blockade resulting in the suppression of double excitation pathway and anti-bunching in photosynthesis systems. The robustness of the photon blockade is demonstrated against the disorder in the ring structures. We hypothesis that the effect may be utilized by light-harvesting systems to avoid damages from excess energy.

physics.chem-ph↗

arXiv2017

Superresolution via Structured Illumination Quantum Correlation Microscopy (SIQCM)

We propose to use intensity correlation microscopy in combination with structured illumination to image quantum emitters that exhibit antibunching with a spatial resolution reaching far beyond the Rayleigh limit. Combining intensity measurements and intensity auto correlations up to order $m$ creates an effective PSF with FWHM shrunk by the factor $\sqrt{m}$. Structured Illumination microscopy on the other hand introduces a resolution improvement of factor 2 by use of the principle of moiré fringes. Here, we show that for linear low-intensity excitation and linear optical detection the simultaneous use of both techniques leads to an in theory unlimited resolution power with the improvement scaling favorably as $m + \sqrt{m}$ in dependence of the correlation order $m$. Hence, yielding this technique to be of interest in microscopy for imaging a variety of samples including biological ones. We present the underlying theory and simulations demonstrating the highly increased spatial superresolution, and point out requirements for an experimental implementation.

physics.optics↗

arXiv2017

Electromagnetically Induced Transparency with Superradiant and Subradiant states

We construct the electromagnetically induced transparency (EIT) by dynamically coupling a superradiant state with a subradiant state. The superradiant and subradiant states with enhanced and inhibited decay rates act as the excited and metastable states in EIT, respectively. Their energy difference determined by the distance between the atoms can be measured by the EIT spectra, which renders this method useful in subwavelength metrology. The scheme can also be applied to many atoms in nuclear quantum optics, where the transparency point due to counter-rotating wave terms can be observed.

physics.atom-ph↗

arXiv2016

Mesoscopic Superposition States Generated by Synthetic Spin-orbit Interaction in Fock-state Lattices

Mesoscopic superposition states of photons can be prepared in three cavities interacting with the same two-level atom. By periodically modulating the three cavity frequencies around the transition frequency of the atom with $2π/3$ phase difference, the time reversal symmetry is broken and an optical circulator is generated with chiralities depending on the quantum state of the atom. A superposition of the atomic states can guide photons from one cavity to a mesoscopic superposition of the other two cavities. The physics can be understood in a finite spin-orbit-coupled Fock-state lattice where the atom and the cavities carry the spin and the orbit degrees of freedom, respectively. This scheme can be realized in circuit QED architectures and provides a new platform for exploring quantum information and topological physics in novel lattices.

quant-ph↗

arXiv2016

Non-Markovianity in a non-thermal bath

We study the dynamics of an open quantum system interacting with a non-thermal bath. Here, "non-thermal" means that the bath modes do not need to have the same temperature, but they have an effective temperature distribution. We find that, when a quantum system is interacting with such a non-thermal bath far from thermal equilibrium, it is no longer proper to use any coarse-grained Markovian description for the system, even when their coupling strength is quite weak. Especially, when there is coherent transition with strong interference strength in the quantum system, the Markovian master equation would bring in a serious problem of negative probability. After we consider some proper non-Markovian corrections, the problem can be naturally resolved.

quant-ph↗