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Martin S. Brandt

Publications and source records attributed to Martin S. Brandt.

At least 19 recordsLinked to original sources

Mitigating the Transition of SiV$^-$ in Diamond to an Optically Dark State

Negatively charged silicon vacancy centers in diamond (SiV$^-$) are promising for quantum photonic technologies. However, when subject to resonant optical excitation, they can inadvertently transfer into a zero-spin optically dark state. We show that this unwanted change of charge state can be quickly reversed by the resonant laser itself in combination with static electric fields. By defining interdigitated metallic contacts on the diamond surface, we increase the steady-state SiV$^-$ photoluminescence under resonant excitation by a factor $\ge3$ for most emitters, making it practically constant for certain individual emitters. We electrically activate single \sivs near the positively biased electrode, which are entirely dark without applying local electric fields. Using time-resolved 3-color experiments, we show that the resonant laser not only excites the SiV$^-$, but also creates free holes that convert SiV$^{2-}$ to SiV$^-$ on a timescale of milliseconds. Through analysis of several individual emitters, our results show that the degree of electrical charge state controllability differs between individual emitters, indicating that their local environment plays a key role. Our proposed electric-field-based stabilization scheme enhances deterministic charge state control in group-IV color centers and improves its understanding, offering a scalable path toward quantum applications such as entanglement generation and quantum key distribution.

quant-ph

Second-order Stark shifts exceeding 10$\,$GHz in electrically contacted SiV$^-$ centers in diamond

Negatively charged silicon vacancy centers (SiV$^-$) in diamond exhibit excellent spin coherence and optical properties, making them promising candidates for quantum technologies. However, the strain-induced inhomogeneous distribution of optical transition frequencies poses a challenge for scalability. We demonstrate electrical tuning of the SiV$^-$ center zero-phonon lines using in-plane contacts to apply moderate electric fields up to 45$\,$MV/m. The second-order Stark shift exceeds 10$\,$GHz, which is of the same order of magnitude as the 15$\,$GHz inhomogeneous distribution of SiV$^-$ observed in emitters embedded in optical nanostructures such as photonic crystal nanocavities. Analysis of individual SiV$^-$ centers shows significant variation in polarizabilities between defects indicating that the polarizability strongly depends on local parameters like strain. The observed polarizabilities are 3-25 times larger than those of tin vacancy centers, which we attribute to valence band resonances that delocalize the $e_u$ wavefunctions. Photoluminescence excitation measurements reveal that optical linewidths increase moderately with applied electric field strength. Our results demonstrate that large electrical Stark shifts can overcome the inhomogeneous distribution of transition frequencies, representing a significant step toward scalable SiV$^-$-based quantum technologies such as quantum repeaters.

quant-ph

Strained Donor-Bound Excitons in $^{28}$Si

We present a comprehensive experimental study of the neutral donor to donor-bound exciton transition (D$^0$$\rightarrow\,$D$^0$X) in isotopically enriched $^{28}$Si, focusing on the group-V donors P, As, and Sb under finely tuned uniaxial stress along the [100] and [110] crystal axes and magnetic fields from 3.5 mT to 1.7 T. From these measurements, donor-specific deformation potentials are extracted. The uniaxial electron deformation potential $Ξ_\mathrm{u}$ is found to be significantly larger than values reported for other states or transitions in silicon and shows a clear dependence on the donor species, indicating an increased sensitivity of the D$^0$X state to strain and central-cell effects. We also observe a magnetic field dependence of the hole shear deformation potential $d$, suggesting a more complex strain coupling mechanism than captured by standard theory. Diamagnetic shift parameters determined from Zeeman spectra show good agreement with earlier measurements. Our results provide a refined parameter set critical for the design of silicon quantum devices based on D$^0$X transitions.

cond-mat.mtrl-sci

Influence of Platinum Thin Films on the Photophysical and Quantum Properties of Near-Surface NV Centers

Nitrogen-vacancy (NV) centers in diamond are optically addressable spin defects with great potential for nanoscale quantum sensing. A key application of NV centers is the detection of external spins at the diamond surface. Among metals, platinum thin films - widely used in spintronics, catalysis and electrochemistry - provide a particularly interesting system for such studies. However, the interaction between NV centers and metals is known to affect their quantum sensing capabilities. In this work, we study five platinum-covered diamond samples containing shallow NVs created via nitrogen implantation with different energies (2.5-60 keV) and investigate the optical and quantum properties of NV ensembles beneath the metal films. We find a substantial reduction of the photoluminescence lifetime and a pronounced decrease of the NV$^{-}$ population for NV ensembles located near the platinum layer. As a result, optically detected magnetic resonance experiments could only be efficiently performed on diamonds implanted with at least 20 keV, where we observed a strong increase in the T$_{2}$ coherence time beneath the platinum thin films. Our study describes the various processes affecting NV centers near platinum films and provides guidance for the integration of thin metal films with near-surface NV centers.

cond-mat.mes-hall

Fast optoelectronic charge state conversion of silicon vacancies in diamond

Group IV vacancy color centers in diamond are promising spin-photon interfaces with strong potential for applications for photonic quantum technologies. Reliable methods for controlling and stabilizing their charge state are urgently needed for scaling to multi-qubit devices. Here, we manipulate the charge state of silicon vacancy (SiV) ensembles by combining luminescence and photo-current spectroscopy. We controllably convert the charge state between the optically active SiV$^-$ and dark SiV$^{2-}$ with MHz rates and 90% contrast by judiciously choosing the local potential applied to in-plane surface electrodes and the laser excitation wavelength. We observe intense SiV$^-$ photoluminescence under hole-capture, measure the intrinsic conversion time from the dark SiV$^{2-}$ to the bright SiV$^-$ to be 36.4(6.7)ms and demonstrate how it can be enhanced by a factor of $10^5$ via optical pumping. Moreover, we obtain new information on the defects that contribute to photo-conductivity, indicating the presence of substitutional nitrogen and divacancies.

quant-ph

Wavelength Dependence of the Electrical and Optical Readout of NV Centers in Diamond

We study the contrast for electrical and optical readout of NV centers in diamond in dependence of the optical excitation wavelength using different excitation schemes. While the optically detected magnetic resonance (ODMR) works efficiently between 480 and 580 nm, electrically detected magnetic resonance (EDMR) shows a strong dependence on the excitation dynamics. The highest, electrically detected contrast of -23% is achieved by resonantly exciting the zero-phonon line of the neutral charge state of NV at 575 nm. EDMR is also enhanced at 521 nm, possibly due to a further excited state of NV$^-$.

cond-mat.mes-hall

The Role of Electrolytes in the Relaxation of Near-Surface Spin Defects in Diamond

Quantum sensing with spin defects in diamond, such as the nitrogen-vacancy (NV) center, enables the detection of various chemical species on the nanoscale. Molecules or ions with unpaired electronic spins are typically probed by their influence on the NV center's spin relaxation. Whereas it is well-known that paramagnetic ions reduce the NV center's relaxation time ($T_1$), here we report on the opposite effect for diamagnetic ions. We demonstrate that millimolar concentrations of aqueous diamagnetic electrolyte solutions increase the $T_1$ time of near-surface NV center ensembles compared to pure water. To elucidate the underlying mechanism of this surprising effect, single and double quantum NV experiments are performed, which indicate a reduction of magnetic and electric noise in the presence of diamagnetic electrolytes. In combination with ab initio simulations, we propose that a change in the interfacial band bending due to the formation of an electric double layer leads to a stabilization of fluctuating charges at the interface of an oxidized diamond. This work not only helps to understand noise sources in quantum systems but could also broaden the application space of quantum sensors towards electrolyte sensing in cell biology, neuroscience and electrochemistry.

physics.app-ph

Magnetic proximity effect on excitonic spin states in Mn-doped layered hybrid perovskites

Materials combining the optoelectronic functionalities of semiconductors with control of the spin degree of freedom are highly sought after for the advancement of quantum technology devices. Here, we report the paramagnetic Ruddlesden-Popper hybrid perovskite Mn:(PEA)2PbI4 (PEA = phenethylammonium) in which the interaction of isolated Mn2+ ions with magnetically brightened excitons leads to circularly polarized photoluminescence. Using a combination of superconducting quantum interference device (SQUID) magnetometry and magneto-optical experiments, we find that the Brillouin-shaped polarization curve of the photoluminescence follows the magnetization of the material. This indicates coupling between localized manganese magnetic moments and exciton spins via a magnetic proximity effect. The saturation polarization of 15% at 4 K and 6 T indicates a highly imbalanced spin population and demonstrates that manganese doping enables efficient control of excitonic spin states in Ruddlesden-Popper perovskites. Our finding constitutes the first example of polarization control in magnetically doped hybrid perovskites and will stimulate research on this highly tuneable material platform that promises tailored interactions between magnetic moments and electronic states.

cond-mat.mtrl-sci

Echo trains in pulsed electron spin resonance of a strongly coupled spin ensemble

We report on a novel dynamical phenomenon in electron spin resonance experiments of phosphorus donors. When strongly coupling the paramagnetic ensemble to a superconducting lumped element resonator, the coherent exchange between these two subsystems leads to a train of periodic, self-stimulated echos after a conventional Hahn echo pulse sequence. The presence of these multi-echo signatures is explained using a simple model based on spins rotating on the Bloch sphere, backed up by numerical calculations using the inhomogeneous Tavis-Cummings Hamiltonian.

cond-mat.mes-hall

Electron nuclear double resonance with donor-bound excitons in silicon

We present Auger-electron-detected magnetic resonance (AEDMR) experiments on phosphorus donors in silicon, where the selective optical generation of donor-bound excitons is used for the electrical detection of the electron spin state. Because of the long dephasing times of the electron spins in isotopically purified $^{28}$Si, weak microwave fields are sufficient, which allow to realize broadband AEDMR in a commercial ESR resonator. Implementing Auger-electron-detected ENDOR, we further demonstrate the optically-assisted control of the nuclear spin under conditions where the hyperfine splitting is not resolved in the optical spectrum. Compared to previous studies, this significantly relaxes the requirements on the sample and the experimental setup, e.g. with respect to strain, isotopic purity and temperature. We show AEDMR of phosphorus donors in silicon with natural isotope composition, and discuss the feasibility of ENDOR measurements also in this system.

physics.ins-det

Multiple-quantum transitions and charge-induced decoherence of donor nuclear spins in silicon

We study single- and multi-quantum transitions of the nuclear spins of ionized arsenic donors in silicon and find quadrupolar effects on the coherence times, which we link to fluctuating electrical field gradients present after the application of light and bias voltage pulses. To determine the coherence times of superpositions of all orders in the 4-dimensional Hilbert space, we use a phase-cycling technique and find that, when electrical effects were allowed to decay, these times scale as expected for a field-like decoherence mechanism such as the interaction with surrounding $^{29}$Si nuclear spins.

quant-ph

Efficient electrical spin readout of NV- centers in diamond

Using pulsed photoionization the coherent spin manipulation and echo formation of ensembles of NV- centers in diamond are detected electrically realizing contrasts of up to 17 %. The underlying spin-dependent ionization dynamics are investigated experimentally and compared to Monte-Carlo simulations. This allows the identification of the conditions optimizing contrast and sensitivity which compare favorably with respect to optical detection.

cond-mat.mes-hall

Measurement of the in-plane thermal conductivity by steady-state infrared thermography

We demonstrate a simple and quick method for the measurement of the in-plane thermal conductance of thin films via steady-state IR thermography. The films are suspended above a hole in an opaque substrate and heated by a homogeneous visible light source. The temperature distribution of the thin films is captured via infrared microscopy and fitted to the analytical expression obtained for the specific hole geometry in order to obtain the in-plane thermal conductivity. For thin films of poly(3,4-ethylenedioxythiophene):polystyrene sulfonate post-treated with ethylene glycol and of polyimide we find conductivities of 1.0 W/mK and 0.4 W/mK at room temperature, respectively. These results are in very good agreement with literature values, validating the method developed.

physics.ins-det

Interaction of Strain and Nuclear Spins in Silicon: Quadrupolar Effects on Ionized Donors

The nuclear spins of ionized donors in silicon have become an interesting quantum resource due to their very long coherence times. Their perfect isolation, however, comes at a price, since the absence of the donor electron makes the nuclear spin difficult to control. We demonstrate that the quadrupolar interaction allows us to effectively tune the nuclear magnetic resonance of ionized arsenic donors in silicon via strain and determine the two nonzero elements of the S tensor linking strain and electric field gradients in this material to $S_{11}=1.5\times10^{22}$ V/m$^2$ and $S_{44}=6\times 10^{22}$ V/m$^2$. We find a stronger benefit of dynamical decoupling on the coherence properties of transitions subject to first-order quadrupole shifts than on those subject to only second-order shifts and discuss applications of quadrupole physics including mechanical driving of magnetic resonance, cooling of mechanical resonators, and strain-mediated spin coupling.

quant-ph

Quadrupolar Effects on Nuclear Spins of Neutral Arsenic Donors in Silicon

We present electrically detected electron nuclear double resonance measurements of the nuclear spins of ionized and neutral arsenic donors in strained silicon. In addition to a reduction of the hyperfine coupling, we find significant quadrupole interactions of the nuclear spin of the neutral donors of the order of 10 kHz. By comparing these to the quadrupole shifts due to crystal fields measured for the ionized donors, we identify the effect of the additional electron on the electric field gradient at the nucleus. This extra component is expected to be caused by the coupling to electric field gradients created due to changes in the electron wavefunction under strain.

cond-mat.mtrl-sci

High cooperativity coupling between a phosphorus donor spin ensemble and a superconducting microwave resonator

We investigate the coupling of an ensemble of phosphorus donors in an isotopically purified $^{28}$Si host lattice interacting with a superconducting coplanar waveguide resonator. The microwave transmission spectrum of the resonator shows a normal mode splitting characteristic for high cooperativity. The evaluated collective coupling strength $g_{\mathrm{eff}}$ is of the same order as the loss rate of the spin system $γ$, indicating the onset of strong coupling. We develop a statistical model to describe the influence of temperature on the coupling strength from $50\,\mathrm{mK}$ to $3.5\,\mathrm{K}$ and find a scaling of the coupling strength with the square root of the number of thermally polarized spins.

quant-ph

Bipolar polaron pair recombination in P3HT/PCBM solar cells

The unique properties of organic semiconductors make them versatile base materials for many applications ranging from light emitting diodes to transistors. The low spin-orbit coupling typical for carbon-based materials and the resulting long spin lifetimes give rise to a large influence of the electron spin on charge transport which can be exploited in spintronic devices or to improve solar cell efficiencies. Magnetic resonance techniques are particularly helpful to elucidate the microscopic structure of paramagnetic states in semiconductors as well as the transport processes they are involved in. However, in organic devices the nature of the dominant spin-dependent processes is still subject to considerable debate. Using multi-frequency pulsed electrically detected magnetic resonance (pEDMR), we show that the spin-dependent response of P3HT/PCBM solar cells at low temperatures is governed by bipolar polaron pair recombination involving the positive and negative polarons in P3HT and PCBM, respectively, thus excluding a unipolar bipolaron formation as the main contribution to the spin-dependent charge transfer in this temperature regime. Moreover the polaron-polaron coupling strength and the recombination times of polaron pairs with parallel and antiparallel spins are determined. Our results demonstrate that the pEDMR pulse sequences recently developed for inorganic semiconductor devices can very successfully be transferred to the study of spin and charge transport in organic semiconductors, in particular when the different polarons can be distinguished spectrally.

cond-mat.mtrl-sci

Ultrafast electronic read-out of diamond NV centers coupled to graphene

Nonradiative transfer processes are often regarded as loss channels for an optical emitter1, since they are inherently difficult to be experimentally accessed. Recently, it has been shown that emitters, such as fluorophores and nitrogen vacancy centers in diamond, can exhibit a strong nonradiative energy transfer to graphene. So far, the energy of the transferred electronic excitations has been considered to be lost within the electron bath of the graphene. Here, we demonstrate that the trans-ferred excitations can be read-out by detecting corresponding currents with picosecond time resolution. We electrically detect the spin of nitrogen vacancy centers in diamond electronically and con-trol the nonradiative transfer to graphene by electron spin resonance. Our results open the avenue for incorporating nitrogen vacancy centers as spin qubits into ultrafast electronic circuits and for harvesting non-radiative transfer processes electronically.

cond-mat.mes-hall