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Mikhail A. Kats

Publications and source records attributed to Mikhail A. Kats.

At least 19 recordsLinked to original sources

Lower bound on the thickness of broadband dielectric mirrors

We present a lower bound on the total physical thickness of a lossless, non-dispersive dielectric mirror for a given minimum reflectance across a wavelength band. The bound is based on a causality-based sum rule translated from a known result in acoustics, that expresses the wavelength integral of the logarithmic transmission of any lossless one-dimensional refractive-index profile as a function of the total thickness of each material comprising the profile, independent of how the layers are arranged. Calculating the thickness bound for a dielectric mirror, given some incident medium and substrate, requires only the lowest and highest refractive indices used in the thin-film stack and the minimum desired reflectance for a given wavelength span. We find that (1) the bound is set by the wavelength span so, for example, a 400-700 nm and an 800-1100 nm mirror have the same bound; (2) the figure of merit for materials minimizing the necessary thickness is $(n_H-n_L)^2/(n_H+n_L)$, where $n_H$ and $n_L$ are the indices of the high- and low-index materials; and (3) each additional "nine" of reflectance (e.g., from 99% to 99.9%) requirement adds a fixed amount of additional thickness to the bound. Non-exhaustive numerical calculations show that the readily achievable thickness is about twice our bound.

physics.optics

Anti-reflection coatings for highly anisotropic materials in the mid infrared

We develop and optimize thin anti-reflection coatings (ARCs) for highly anisotropic materials in the mid infrared. Unlike conventional ARCs that assume nearly isotropic refractive indices, this work fully integrates the anisotropic nature of materials into the design process. We describe two designs of thin ARCs for highly anisotropic materials: a single form-birefringent layer, and a planar bilayer. We realized the planar bilayer ARC experimentally, demonstrating excellent mid-infrared anti-reflectance across over a broad range of angles for all polarizations.

physics.optics

Visible Imaging of Incoherent 1200-nm Light via Triplet--Triplet Annihilation Upconversion

Upconversion of low-energy photons to higher-energy photons provides an opportunity to surpass traditional limitations in fields such as 3D printing, photovoltaics, and photocatalysis. Triplet--triplet annihilation upconversion (TTA-UC) is particularly appealing for such applications as it can efficiently upconvert low-intensity, incoherent light. However, previously demonstrated thin-film TTA systems are simultaneously constrained by modest efficiencies and limited reach into the near infrared (NIR). Here, we design a single-layer thin-film bulk heterojunction that integrates PbS quantum dots (QDs) as tunable NIR absorbers within an organic semiconductor matrix of TES-ADT, achieving large anti-Stokes shifts up to 500 nm and high internal quantum efficiencies across the NIR-I and NIR-II windows (800-1200 nm). Through the incorporation of 5-tetracene carboxylic acid ligands on the PbS QD surface, the yield of sensitized triplets was boosted, as confirmed by transient absorption and time-resolved photoluminescence measurements. The resulting films demonstrated a 15-fold improvement in UC efficiency. Furthermore, we demonstrate visible imaging of incoherent 1200 nm light via thin-film TTA-UC at incident intensities at the imaging mask as low as 20 mWcm$^2$, marking a significant advance toward practical implementation of solid-state NIR-to-visible upconversion.

physics.optics

Material selection for mid-infrared thin-film coatings and windows

We summarized the room-temperature optical properties for infrared-transparent materials, defining transparency windows for two different applications: thin-film coatings (absorption coefficient $α< 10 cm^{-1}$) and windows ($α< 1 cm^{-1}$). The transparency requirements for thin films are substantially less stringent, enabling the use of many more optical materials for a given wavelength range. To make an easy-to-use reference, we categorized materials by chemical group, crystallinity, and typical deposition technique, and discussed practical pros and cons such as chemical and thermal stability, mechanical hardness, and cost. The datasets and plotting scripts are provided so that users can regenerate transparency-window maps for different applications. If you do optical design at infrared wavelengths, we recommend that you print out the figures and stick them on your wall.

physics.optics

Silicon-on-sapphire metasurfaces generate arrays of dark and bright traps for neutral atoms

We demonstrated crystalline silicon-on-sapphire (c-SOS) metasurfaces that convert a Gaussian beam into arrays of complex optical traps, including arrays of optical bottle beams that trap atoms in dark regions interleaved with bright tweezer arrays. The high refractive index and indirect band gap of crystalline silicon makes it possible to design high-resolution near-infrared ($λ>700$ nm) metasurfaces that can be manufactured at scale using CMOS-compatible processes. Compared with active components like spatial light modulators (SLMs) that have become widely used to generate trap arrays, metasurfaces provide an indefinitely scalable number of pixels, enabling large arrays of complex traps in a very small form factor, as well as reduced dynamic noise. To design metasurfaces that can generate three-dimensional bottle beams to serve as dark traps, we modified the Gerchberg-Saxton algorithm to enforce complex-amplitude profiles at the focal plane of the metasurface and to optimize the uniformity of the traps across the array. We fabricated and measured c-SOS metasurfaces that convert a Gaussian laser beam into arrays of bright traps, dark traps, and interleaved bright/dark traps.

physics.optics

Cool windows: simultaneously engineering high visible transparency and strong solar rejection

For window applications in hot climates, it is desirable to have windows with high visible transparency, while maintaining strong reflectance in both the ultraviolet and near infrared, to minimize unwanted heat gain. Given that more than 70% of incident solar energy is at wavelengths shorter than 1000 nm, achieving spectrally abrupt transitions from transparent to reflecting at the boundaries of the visible is essential. Such abrupt transitions at multiple wavelengths typically would require tens of dielectric layers, which is impractical for most window applications. Here, we propose and realize a structure comprising only eight planar layers that achieves sharp reflectance changes at ~390 and ~680 nm, resulting in high visible transmittance (>70%), and high near-infrared (>80%) and UV (>60%) reflectance, as well as high mid-infrared emissivity (>90%) for additional radiative cooling. We demonstrate that our engineered window reduces air temperature by up to 3.8 °C inside an enclosed box simulating a vehicle, compared to a box with a reference window.

physics.optics

All-passive upconversion of incoherent near-infrared light at intensities down to 10$^{-7}$ W/cm$^2$

Frequency upconversion, which converts low-energy photons into higher-energy ones, typically requires intense coherent illumination to drive nonlinear processes or the use of externally driven optoelectronic devices. Here, we demonstrate an upconversion system that converts low-intensity (down to ~10-7 W/cm$^2$) incoherent near-infrared (NIR) light into the visible, reaching intensities perceptible by the human eye, without the use of any external power input. Our upconverting element is enabled by the following ingredients: (1) photon upconversion via triplet-triplet annihilation in a bulk heterojunction of the organic semiconductors Y6 and rubrene; (2) plasmonic enhancement of absorption and field intensity in the heterojunction layer; (3) collection enhancement using a dichroic thin-film assembly. To enable high-resolution imaging, the upconverting element is inserted at an intermediate image plane of a dual-wavelength telescope system, which preserves the relative directionality of rays between the incident NIR light and output visible light. Our all-passive upconversion imaging system will enable NIR imaging and sensing in low-light environments under energy constraints.

physics.optics

Preventing overfitting in infrared ellipsometry using temperature dependence: fused silica as a case study

Fitting oscillator models to variable-angle spectroscopic ellipsometry (VASE) data can lead to non-unique, unphysical results. We demonstrate using temperature-dependent trends to prevent overfitting and ensure model physicality. As a case study, we performed mid-infrared VASE measurements on fused silica (SiO2) of various grades, from room temperature to 600 °C. We fitted oscillator models independently at each temperature, and confirmed the model's physical validity by observing the expected monotonic trends in vibrational oscillator parameters. Using this technique, we generated a highly accurate dataset for the temperature-dependent complex refractive index of fused silica for modeling mid-infrared optical components such as thermal emitters.

physics.optics

Self-referencing photothermal common-path interferometry to measure absorption of Si3N4 membranes for laser-light sails

Laser-light sails are a spacecraft concept wherein lightweight "sails" are propelled by high-intensity lasers. We investigated the near-infrared absorption of free-standing membranes of stoichiometric silicon nitride (Si$_3$N$_4$), a candidate sail material. To resolve the small but non-zero optical loss, we used photothermal common-path interferometry (PCI), for which we developed a self-referencing modality where a PCI measurement is performed twice: once on a bare membrane, and a second time with monolayer graphene deposited on the membrane. The graphene increases the absorption of the sample by orders of magnitude, such that it can be measured by ellipsometry, without significantly affecting the thermal properties. We measured the absorption coefficient of Si$_3$N$_4$ to be (1.5-3) $\times$ 10$^{-2}$ cm$^{-1}$ at 1064 nm, making it a suitable sail material for laser intensities as high as ~10 GW/m$^2$. By comparison, silicon-rich "low stress" SiN$_x$ (x~1), with a measured absorption coefficient of approximately 8 cm$^{-1}$, is unlikely to survive such high laser intensities. Our self-referencing technique enables testing of low-loss membranes of various materials for laser sails and other applications.

physics.optics

Passive radiative cooling using temperature-dependent emissivity can sometimes outperform static emitters

In passive sky-facing radiative cooling, wavelength-selective thermal emitters in the atmospheric transparency window of 8-13 $μ$m can reach lower temperatures compared to broadband emitters, but broadband emitters always have higher cooling power when the emitter is warmer than the ambient. Here, we propose a temperature-tunable thermal emitter that switches between a wavelength-selective state -- with high emissivity only in the atmospheric transparency window of 8-13 $μ$m -- and a broadband-emissive state with high emissivity in the 3-25 $μ$m range, thus maintaining high cooling potential across all temperatures. We also propose a realization of such a temperature-tunable emitter using the phase transition of vanadium dioxide (VO$_2$), which can be tuned to the ambient temperature using a combination of doping and defect engineering.

physics.optics

Interleaved dual-species arrays of single atoms using a passive optical element and one trapping laser

We demonstrate trapping of individual rubidium (Rb) and cesium (Cs) atoms in an interleaved array of bright tweezers and dark bottle-beam traps, using a microfabricated optical element illuminated by a single laser beam and a 4F system with spatial filtering. Our approach exploits the opposite-sign dynamic polarizabilities of Rb and Cs, ensuring each species is exclusively trapped in either bright or dark sites. The passive optical mask creates optimal trap depths for both species using three transmittance levels while minimizing the optical phase difference, implemented using a variable-thickness absorbing layer of amorphous germanium. This trapping architecture achieves atom loading rates close to 50% while reducing system complexity compared to conventional methods using active optoelectronic components and/or multiple laser wavelengths.

physics.atom-ph

A gradient atmospheric model reveals enhanced radiative cooling potential and demonstrates the advantages of broadband emitters

Passive radiative cooling toward the sky is a developing technology for adaptation in hot climates. Previous calculations of cooling performance have generally used uniform atmospheric models that assume a single sky temperature and atmospheric transmittance spectrum. Here, we introduce a gradient atmospheric model that accounts for altitude-dependent temperature and gas composition, revealing that uniform models underestimate cooling power by 10 - 40%. Using our improved model, we systematically compared broadband emitters (BEs) and wavelength-selective emitters (SEs) for sky-facing radiative cooling at various locations on Earth. We find that the differences in cooling power between the two types of emitters in the sub-ambient temperature range are generally small, even under ideal conditions. Furthermore, in practice, BEs actually have superior performance than realistic SEs, because they have fewer design degrees of freedom and thus can be engineered to have lower solar absorption. Our analysis suggests that large-scale deployment of sky-facing passive radiative cooling technologies should prioritize the development of scalable, low-cost surfaces with minimal solar absorption, rather than focusing on achieving selective thermal emission.

physics.optics

Broadband light extraction from near-surface NV centers using crystalline-silicon antennas

We use crystalline silicon (Si) antennas to efficiently extract broadband single-photon fluorescence from shallow nitrogen-vacancy (NV) centers in diamond into free space. Our design features relatively easy-to-pattern high-index Si resonators on the diamond surface to boost photon extraction by overcoming total internal reflection and Fresnel reflection at the diamond-air interface, and providing modest Purcell enhancement, without etching or otherwise damaging the diamond surface. In simulations, ~17 times more single photons are collected from a single NV center compared to the case without the antenna; in experiments, we observe an enhancement of ~9 times, limited by spatial alignment between the NV and the antenna. Our approach can be readily applied to other color centers in diamond, and more generally to the extraction of light from quantum emitters in wide-bandgap materials.

physics.optics

Large tuning of the optical properties of nanoscale NdNiO3 via electron doping

We synthesized crystalline films of neodymium nickel oxide (NdNiO3), a perovskite quantum material, switched the films from a metal phase (intrinsic) into an insulator phase (electron-doped) by field-driven lithium-ion intercalation, and characterized their structural and optical properties. Time-of-flight secondary-ion mass spectrometry (ToF-SIMS) showed that the intercalation process resulted in a gradient of the dopant concentration along the thickness direction of the films, turning the films into insulator-metal bilayers. We used variable-angle spectroscopic ellipsometry to measure the complex refractive indices of the metallic and insulating phases of NdNiO3. The insulator phase has a refractive index of n ~ 2 and low absorption in the visible and near infrared, and analysis of the complex refractive indices indicated that the band gap of the insulating phase is roughly 3-4 eV. Electrical control of the optical band gap, with corresponding large changes to the optical refractive indices, creates new opportunities for tunable optics.

cond-mat.mtrl-sci

Enhanced biochemical sensing with high-Q transmission resonances in free-standing membrane metasurfaces

Optical metasurfaces provide novel solutions to label-free biochemical sensing by localizing light resonantly beyond the diffraction limit, thereby selectively enhancing light-matter interactions for improved analytical performance. However, high-Q resonances in metasurfaces are usually achieved in the reflection mode, which impedes metasurface integration into compact imaging systems. Here, we demonstrate a novel metasurface platform for advanced biochemical sensing based on the physics of the bound states in the continuum (BIC) and electromagnetically induced transparency (EIT) modes, which arise when two interfering resonances from a periodic pattern of tilted elliptic holes overlap both spectrally and spatially, creating a narrow transparency window in the mid-infrared spectrum. We experimentally measure these resonant peaks observed in transmission mode (Q~734 at ~8.8 um) in free-standing silicon membranes and confirm their tunability through geometric scaling. We also demonstrate the strong coupling of the BIC-EIT modes with a thinly coated PMMA film on the metasurface, characterized by a large Rabi splitting (32 cm-1) and biosensing of protein monolayers in transmission mode. Our new photonic platform can facilitate the integration of metasurface biochemical sensors into compact and monolithic optical systems while being compatible with scalable manufacturing, thereby clearing the way for on-site biochemical sensing in everyday applications.

physics.optics

Electrostatic Steering of Thermal Emission with Active Metasurface Control of Delocalized Modes

We theoretically describe and experimentally demonstrate a graphene-integrated metasurface structure that enables electrically-tunable directional control of thermal emission. This device consists of a dielectric slab that acts as a Fabry-Perot (F-P) resonator supporting long-range delocalized modes bounded on one side by an electrostatically tunable metal-graphene metasurface. By varying the Fermi level of the graphene, the accumulated phase of the F-P mode is shifted, which changes the direction of absorption and emission at a fixed frequency. We directly measure the frequency- and angle-dependent emissivity of the thermal emission from a fabricated device heated to 250$^{\circ}$. Our results show that electrostatic control allows the thermal emission at 6.61 $μ$m to be continuously steered over 16$^{\circ}$, with a peak emissivity maintained above 0.9. We analyze the dynamic behavior of the thermal emission steerer theoretically using a Fano interference model, and use the model to design optimized thermal steerer structures.

physics.optics

Atomic magnetometry using a metasurface polarizing beamsplitter in silicon on sapphire

We demonstrate atomic magnetometry using a metasurface polarizing beamsplitter fabricated on a silicon-on-sapphire (SOS) platform. The metasurface splits a beam that is near-resonant with the rubidium atoms (795 nm) into orthogonal linear polarizations, enabling measurement of magnetically sensitive circular birefringence in a rubidium vapor through balanced polarimetry. We incorporated the metasurface into an atomic magnetometer based on nonlinear magneto-optical rotation and measured sub-nanotesla sensitivity, which is limited by low-frequency technical noise and transmission loss through the metasurface. To our knowledge, this work represents the first demonstration of SOS nanophotonics for atom-based sensing and paves the way for highly integrated, miniaturized atomic sensors with enhanced sensitivity and portability.

physics.optics