arXiv subjects

Mikhail A. Kats

Publications and source records attributed to Mikhail A. Kats.

At least 37 records · Page 2Linked to original sources

arXiv2024

Giant Modulation of Refractive Index from Picoscale Atomic Displacements

Structural disorder has been shown to enhance and modulate magnetic, electrical, dipolar, electrochemical, and mechanical properties of materials. However, the possibility of obtaining novel optical and optoelectronic properties from structural disorder remains an open question. Here, we show unambiguous evidence of disorder in the form of anisotropic, picoscale atomic displacements modulating the refractive index tensor and resulting in the giant optical anisotropy observed in BaTiS$_3$, a quasi-one-dimensional hexagonal chalcogenide. Single crystal X-ray diffraction studies reveal the presence of antipolar displacements of Ti atoms within adjacent TiS$_6$ chains along the c-axis, and three-fold degenerate Ti displacements in the a-b plane. $^{47/49}$Ti solid-state NMR provides additional evidence for those Ti displacements in the form of a three-horned NMR lineshape resulting from a low symmetry local environment around Ti atoms. We used scanning transmission electron microscopy to directly observe the globally disordered Ti a-b plane displacements and find them to be ordered locally over a few unit cells. First-principles calculations show that the Ti a-b plane displacements selectively reduce the refractive index along the ab-plane, while having minimal impact on the refractive index along the chain direction, thus resulting in a giant enhancement in the optical anisotropy. By showing a strong connection between structural disorder with picoscale displacements and the optical response in BaTiS$_3$, this study opens a pathway for designing optical materials with high refractive index and functionalities such as large optical anisotropy and nonlinearity.

cond-mat.mtrl-sci↗

arXiv2024

Molten flux growth of single crystals of quasi-1D hexagonal chalcogenide BaTiS3

BaTiS3, a quasi-1D complex chalcogenide, has gathered considerable scientific and technological interest due to its giant optical anisotropy and electronic phase transitions. However, the synthesis of high-quality BaTiS3 crystals, particularly those featuring crystal sizes of millimeters or larger, remains a challenge. Here, we investigate the growth of BaTiS3 crystals utilizing a molten salt flux of either potassium iodide, or a mixture of barium chloride and barium iodide. The crystals obtained through this method exhibit a substantial increase in volume compared to those synthesized via the chemical vapor transport method, while preserving their intrinsic optical and electronic properties. Our flux growth method provides a promising route towards the production of high-quality, large-scale single crystals of BaTiS3, which will greatly facilitate advanced characterizations of BaTiS3 and its practical applications that require large crystal dimensions. Additionally, our approach offers an alternative synthetic route for other emerging complex chalcogenides.

cond-mat.mtrl-sci↗

arXiv2024

Infrared Optical Anisotropy in Quasi-1D Hexagonal Chalcogenide BaTiSe3

Polarimetric infrared detection bolsters IR thermography by leveraging the polarization of light. Optical anisotropy, i.e., birefringence and dichroism, can be leveraged to achieve polarimetric detection. Recently, giant optical anisotropy was discovered in quasi-1D narrow-bandgap hexagonal perovskite sulfides, A1+xTiS3, specifically BaTiS3[1,2] and Sr9/8TiS3[3,4]. In these materials, the critical role of atomic-scale structure modulations[4,5] in the unconventional electrical[5,6], optical[7,8], and thermal[7,9] properties raises the broader question of other materials that belong to this family. To address this issue, for the first time, we synthesized high-quality single crystals of a largely unexplored member of the A1+xTiX3 (X = S, Se) family, BaTiSe3. Single-crystal X-ray diffraction determined the room-temperature structure with the P31c space group, which is a superstructure of the earlier reported[10] P63/mmc structure. The crystal structure of BaTiSe3 features antiparallel c-axis displacements similar to BaTiS3,[2] but is of lower symmetry. Polarization-resolved Raman and Fourier transform infrared (FTIR) spectroscopy were used to characterize the optical anisotropy of BaTiSe3, whose refractive index along the ordinary (perpendicular to c) and extraordinary (parallel to c) optical axes was quantitatively determined by combining ellipsometry studies with FTIR. With a giant birefringence Δn~0.9, BaTiSe3 emerges as a new candidate for miniaturized birefringent optics for mid-wave infrared to long-wave infrared imaging.

cond-mat.mtrl-sci↗

arXiv2023

ChatGPT-4 with Code Interpreter can be used to solve introductory college-level vector calculus and electromagnetism problems

We evaluated ChatGPT 3.5, 4, and 4 with Code Interpreter on a set of college-level engineering-math and electromagnetism problems, such as those often given to sophomore electrical engineering majors. We selected a set of 13 problems, and had ChatGPT solve them multiple times, using a fresh instance (chat) each time. We found that ChatGPT-4 with Code Interpreter was able to satisfactorily solve most problems we tested most of the time -- a major improvement over the performance of ChatGPT-4 (or 3.5) without Code Interpreter. The performance of ChatGPT was observed to be somewhat stochastic, and we found that solving the same problem N times in new ChatGPT instances and taking the most-common answer was an effective strategy. Based on our findings and observations, we provide some recommendations for instructors and students of classes at this level.

cs.AI↗

arXiv2023

Colossal optical anisotropy from atomic-scale modulations

In modern optics, materials with large birefringence (Δn, where n is the refractive index) are sought after for polarization control (e.g. in wave plates, polarizing beam splitters, etc.), nonlinear optics and quantum optics (e.g. for phase matching and production of entangled photons), micromanipulation, and as a platform for unconventional light-matter coupling, such as Dyakonov-like surface polaritons and hyperbolic phonon polaritons. Layered "van der Waals" materials, with strong intra-layer bonding and weak inter-layer bonding, can feature some of the largest optical anisotropy; however, their use in most optical systems is limited because their optic axis is out of the plane of the layers and the layers are weakly attached, making the anisotropy hard to access. Here, we demonstrate that a bulk crystal with subtle periodic modulations in its structure -- Sr9/8TiS3 -- is transparent and positive-uniaxial, with extraordinary index n_e = 4.5 and ordinary index n_o = 2.4 in the mid- to far-infrared. The excess Sr, compared to stoichiometric SrTiS3, results in the formation of TiS6 trigonal-prismatic units that break the infinite chains of face-shared TiS6 octahedra in SrTiS3 into periodic blocks of five TiS6 octahedral units. The additional electrons introduced by the excess Sr subsequently occupy the TiS6 octahedral blocks to form highly oriented and polarizable electron clouds, which selectively boost the extraordinary index n_e and result in record birefringence (Δn > 2.1 with low loss). The connection between subtle structural modulations and large changes in refractive index suggests new categories of anisotropic materials and also tunable optical materials with large refractive-index modulation and low optical losses.

physics.optics↗

arXiv2023

Electrically tunable VO2-metal metasurface for mid-infrared switching, limiting, and nonlinear isolation

We demonstrate an electrically controlled metal-VO2 metasurface for the mid-wave infrared that simultaneously functions as a tunable optical switch, an optical limiter with a tunable limiting threshold, and a nonlinear optical isolator with a tunable operating range. The tunability is achieved via Joule heating through the metal comprising the metasurface, resulting in an integrated optoelectronic device. As an optical switch, the device has an experimental transmission ratio of ~100 when varying the bias current. Operating as an optical limiter, we demonstrated tunability of the limiting threshold from 20 mW to 180 mW of incident laser power. Similar degrees of tunability are also achieved for nonlinear optical isolation, which enables asymmetric (nonreciprocal) transmission.

physics.optics↗

arXiv2023

The Effect of Dust and Hotspots on the Thermal Stability of Laser Sails

Laser sails propelled by gigawatt-scale ground-based laser arrays have the potential to reach relativistic speeds, traversing the solar system in hours and reaching nearby stars in years. Here, we describe the danger interplanetary dust poses to the survival of a laser sail during its acceleration phase. We show through multi-physics simulations how localized heating from a single optically absorbing dust particle on the sail can initiate a thermal-runaway process that rapidly spreads and destroys the entire sail. We explore potential mitigation strategies, including increasing the in-plane thermal conductivity of the sail to reduce the peak temperature at hotspots and isolating the absorptive regions of the sail which can burn away individually.

physics.space-ph↗

arXiv2022

Lateral beam shifts and depolarization upon oblique reflection from dielectric mirrors

Dielectric mirrors comprising thin-film multilayers are widely used in optical experiments because they can achieve substantially higher reflectance compared to metal mirrors. Here we investigate potential problems that can arise when dielectric mirrors are used at oblique incidence, in particular for focused beams. We found that light beams reflected from dielectric mirrors can experience lateral beam shifts, beam-shape distortion, and depolarization, and these effects have a strong dependence on wavelength, incident angle, and incident polarization. Because vendors of dielectric mirrors typically do not share the particular layer structure of their products, we designed and simulated several dielectric-mirror stacks, and then also measured the lateral beam shift from two commercial dielectric mirrors and one coated metal mirror. We hope that this paper brings awareness of the tradeoffs between dielectric mirrors and front-surface metal mirrors in certain optics experiments, and suggest that vendors of dielectric mirrors provide information about beam shifts, distortion, and depolarization when their products are used at oblique incidence.

physics.optics↗

arXiv2022

Heavily doped zinc oxide with plasma frequencies in the telecommunication wavelength range

We demonstrate heavy and hyper doping of ZnO by a combination of gallium (Ga) ion implantation using a focused ion beam (FIB) system and post-implantation laser annealing. Ion implantation allows for the incorporation of impurities with nearly arbitrary concentrations, and the laser-annealing process enables dopant activation close to or beyond the solid-solubility limit of Ga in ZnO. We achieved heavily doped ZnO:Ga with free-carrier concentrations of ~10^21 cm^(-3), resulting in a plasma wavelength of 1.02 um, which is substantially shorter than the telecommunication wavelength of 1.55 um. Thus, our approach enables the control of the plasma frequency of ZnO from the far infrared down to 1.02 um, providing a promising plasmonic material for applications in this regime.

physics.app-ph↗

arXiv2022

Tuning carrier density and phase transitions in oxide semiconductors using focused ion beams

We demonstrate spatial modification of the optical properties of thin-film metal oxides, zinc oxide and vanadium dioxide as representatives, using a commercial focused ion beam (FIB) system. Using a Ga+ FIB and thermal annealing, we demonstrated variable doping of a band semiconductor, zinc oxide (ZnO), achieving carrier concentrations from 10^18 cm-3 to 10^20 cm-3. Using the same FIB without subsequent thermal annealing, we defect-engineered a correlated semiconductor, vanadium dioxide (VO2), locally modifying its insulator-to-metal transition (IMT) temperature by range of ~25 degrees C. Such area-selective modification of metal oxides by direct writing using a FIB provides a simple, mask-less route to the fabrication of optical structures, especially when multiple or continuous levels of doping or defect density are required.

cond-mat.mtrl-sci↗

arXiv2022

Wavelength-by-wavelength temperature-independent thermal radiation utilizing an insulator-metal transition

Both the magnitude and spectrum of the blackbody-radiation distribution change with temperature. Here, we designed the temperature-dependent spectral emissivity of a coating to counteract all the changes in the blackbody-radiation distribution over a certain temperature range, enabled by the nonhysteretic insulator-to-metal phase transition of SmNiO3. At each wavelength within the long-wave infrared atmospheric-transparency window, the thermal radiance of our coating remains nearly constant over a temperature range of at least 20 °C. Our approach can conceal thermal gradients and transient temperature changes from infrared imaging systems, including those that discriminate by wavelength, such as multispectral and hyperspectral cameras.

physics.optics↗

arXiv2022

Infrared Optical Spectroscopy of Molten Fluorides: Methods, Electronic and Vibrational Data, Structural Interpretation, and Relevance to Radiative Heat Transfer

To help address the need for predicting radiative heat transfer (RHT) behavior of molten salts, we conducted a comprehensive review of methods and data from infrared optical spectroscopic measurements on molten fluoride salts. Transmittance, reflectance, and trans-reflectance experimental methods are discussed, along with the corresponding data reduction methodology and the limitations of each technique. Optical spectroscopy is a convenient indirect probe for changes in structural parameters with temperature and composition. Electronic and vibrational absorption data for transition-metal, lanthanide, and actinide solutes and vibrational absorption data for alkali and alkaline earth fluoride solvents are compiled, and the corresponding structural interpretation is discussed and compared with other experimental and theoretical work. We find that solvent and solute vibrational absorption can be significant in the mid-infrared, resulting in near-infrared edges of significance to RHT. Extrapolation and averaging of existing edge data leads to estimated gray absorption coefficient values at 700 degrees C of 493 m^(-1) for FLiBe and 148 m^(-1) for FLiNaK, both within the range of 1 to 6000 m^(-1) identified to be of engineering relevance for radiative heat transfer analysis.

cond-mat.soft↗

arXiv2021

Thermal runaway of silicon-based laser sails

Laser sail-based spacecraft -- where a powerful earth-based laser propels a lightweight outer-space vehicle -- have been recently proposed by the Breakthrough Starshot Initiative as a means of reaching relativistic speeds for interstellar spacetravel. The laser intensity at the sail required for this task is at least 1 GW$\cdot$m$^{-2}$ and, at such high intensities, thermal management of the sail becomes a significant challenge even when using materials with low absorption coefficients. Silicon has been proposed as one leading candidate material for the sail due to its low sub-bandgap absorption and high index of refraction, which allows for low-mass-density designs. However, here we show that the temperature-dependent bandgap of silicon combined with two-photon absorption processes can lead to thermal runaway for even the most optimistic viable assumptions of the material quality. From our calculations, we set bounds on the maximum laser intensities that can be used for a thermally stable, Si-based laser sail.

physics.optics↗

arXiv2021

Fast recovery of ion-irradiation-induced defects in Ge2Sb2Te5 thin films at room temperature

Phase-change materials serve a broad field of applications ranging from non-volatile electronic memory to optical data storage by providing reversible, repeatable, and rapid switching between amorphous and crystalline states accompanied by large changes in the electrical and optical properties. Here, we demonstrate how ion irradiation can be used to tailor disorder in initially crystalline Ge2Sb2Te5 (GST) thin films via the intentional creation of lattice defects. We found that continuous Ar ion irradiation at room temperature of GST films causes complete amorphization of GST when exceeding 0.6 (for rock-salt GST) and 3 (for hexagonal GST) displacements per atom (n_dpa). While the transition from rock-salt to amorphous GST is caused by progressive amorphization via the accumulation of lattice defects, several transitions occur in hexagonal GST upon ion irradiation. In hexagonal GST, the creation of point defects and small defect clusters leads to disordering of intrinsic vacancy layers (van der Waals gaps) that drives the electronic metal-insulator transition. Increasing disorder then induces a structural transition from hexagonal to rock-salt and then leads to amorphization. Furthermore, we observed different annealing behavior of defects for rock-salt and hexagonal GST. The higher amorphization threshold in hexagonal GST compared to rock-salt GST is caused by an increased defect-annealing rate, i.e., a higher resistance against ion-beam-induced disorder. Moreover, we observed that the recovery of defects in GST is on the time scale of seconds or less at room temperature.

cond-mat.mtrl-sci↗

arXiv2021

Switchable induced-transmission filters enabled by vanadium dioxide

Abstract: An induced-transmission filter (ITF) uses an ultrathin layer of metal positioned at an electric-field node within a dielectric thin-film bandpass filter to select one transmission band while suppressing other transmission bands that would have been present without the metal layer. Here, we introduce a switchable mid-infrared ITF where the metal film can be "switched on and off", enabling the modulation of the filter response from single-band to multiband. The switching is enabled by a deeply subwavelength film of vanadium dioxide (VO2), which undergoes a reversible insulator-to-metal phase transition. We designed and experimentally demonstrated an ITF that can switch between two states: one broad passband across the long-wave infrared (LWIR, 8 - 12 um) and one narrow passband at ~8.8 um. Our work generalizes the ITF -- previously a niche type of bandpass filter -- into a new class of tunable devices. Furthermore, our unique fabrication process -- which begins with thin-film VO2 on a suspended membrane -- enables the integration of VO2 into any thin-film assembly that is compatible with physical vapor deposition (PVD) processes, and is thus a new platform for realizing tunable thin-film filters.

physics.optics↗

arXiv2021

Efficient generation of optical bottle beams

Optical bottle beams can be used to trap atoms and small low-index particles. We introduce a figure of merit for optical bottle beams, specifically in the context of optical traps, and use it to compare optical bottle-beam traps obtained by three different methods. Using this figure of merit and an optimization algorithm, we identified optical bottle-beam traps based on a Gaussian beam illuminating a metasurface that are superior in terms of power efficiency than existing approaches. We numerically demonstrate a silicon metasurface for creating an optical bottle-beam trap.

physics.optics↗

arXiv2021

Planck spectroscopy

All spectrometers rely on some mechanism to achieve spectral selectivity; common examples include gratings, prisms, and interferometers with moving mirrors. We experimentally demonstrated and validated a spectroscopic technique -- here dubbed Planck spectroscopy -- that measures the spectral emissivity of a surface using only a temperature-controlled stage and a detector, without any wavelength-selective optical components. Planck spectroscopy involves the measurement of temperature-dependent thermally emitted power, where the spectral selectivity is realized via the temperature- and wavelength dependence of Planck's law. We experimentally demonstrated and validated Planck spectroscopy in the mid infrared, for wavelengths from 3 to 13 um -- limited primarily by the bandwidth of our detector -- with resolution of approximately 1 um. The minimalistic setup of Planck spectroscopy can be implemented using infrared cameras to achieve low-cost infrared hyperspectral imaging and imaging ellipsometry.

physics.optics↗

arXiv2021

Passive frequency conversion of ultraviolet images into the visible using perovskite nanocrystals

We demonstrate a passive down-conversion imaging system that converts broadband ultraviolet light to narrow-band green light while preserving the directionality of rays, and thus enabling direct down-conversion imaging. At the same time our system has high transparency in the visible, enabling superimposed visible and ultraviolet imaging. The frequency conversion is performed by a subwavelength-thickness transparent downconverter based on highly efficient CsPbBr3 nanocrystals incorporated into the focal plane of a simple telescope or relay-lens geometry. The resulting imaging performance of this down-conversion system approaches the diffraction limit. This demonstration sets the stage for the incorporation of other high-efficiency perovskite nanocrystal materials to enable passive multi-frequency conversion imaging systems.

physics.optics↗