arXiv subjects

Mikhail M. Glazov

Publications and source records attributed to Mikhail M. Glazov.

At least 19 recordsLinked to original sources

arXiv2026

Non-radiative energy transfer between boron vacancies in hexagonal boron nitride and other 2D materials

Boron vacancies ($V_B^-$) in hexagonal boron nitride (hBN) have emerged as a promising platform for two-dimensional quantum sensors capable of operating at atomic-scale proximity. However, the mechanisms responsible for photoluminescence quenching in thin hBN sensing layers when placed in contact with absorptive materials remain largely unexplored. In this Letter, we investigate non-radiative Förster resonance energy transfer (FRET) between $V_B^-$ centers and either monolayer graphene or 2D semiconductors. Strikingly, we find that the FRET rate is negligible for hBN sensing layers thicker than 3 nm, highlighting the potential of $V_B^-$ centers for integration into ultra-thin quantum sensors within van der Waals heterostructures. Furthermore, we experimentally extract the intrinsic radiative decay rate of $V_B^-$ defects.

cond-mat.mtrl-sci↗

arXiv2026

Boltzmann transport theory of magnon-exciton drag

We develop a microscopic theory of magnon-exciton drag effect in a bilayer van der Waals antiferromagnetic semiconductor CrSBr. Effective exciton-magnon coupling arises from an orbital mechanism: Magnons tilt the layer magnetizations, enabling charge carrier tunneling that mixes intra- and interlayer excitons and thereby modulate the exciton energy. We derive the effective Hamiltonian of exciton-magnon coupling, based on our calculation of the magnon spectrum taking into account short-range exchange interaction between Cr-ion spins, single-ion anisotropy, and long-range dipole-dipole interactions. The latter produces a negative group velocity of magnons at small wavevectors. We show that despite rather small renormalization of exciton's energy and effective mass by the exciton-magnon interaction, the three key two-magnon processes: exciton-magnon scattering, two-magnon absorption by exciton, and two-magnon emission are highly efficient. By solving the Boltzmann kinetic equation, we evaluate short exciton-magnon scattering time which is in the sub-ps range and strongly decreases with the increase of magnon population. Hence, exciton-magnon scattering is likely to be dominant over other scattering processes related to the exciton-phonon and exciton-disorder interactions. We demonstrate that magnons can efficiently drag excitons, resulting in a large and nearly isotropic exciton propagation that can significantly exceed the intrinsic anisotropic diffusion. Our results provide a theoretical basis for recent observations of anomalous exciton transport in CrSBr [F. Dirnberger, et al., Nat. Nano. (2025)] and establish magnon-exciton drag as a powerful mechanism for controlling exciton propagation in magnetic systems.

cond-mat.mes-hall↗

arXiv2026

Millisecond-long electron spin lifetime in CsPbI$_3$ perovskite nanocrystals revealed by optically detected magnetic resonance

Perovskite nanocrystals are a convenient model system for optical spin orientation and manipulation. However, its real potential might be underestimated due to the incomplete knowledge on spin relaxation times, which are obscured by the limited sensitivity of measurement techniques as well as by the insufficient understanding of the spin relaxation mechanisms in perovskites. In this work, we study the spin relaxation of charge carriers in perovskite nanocrystals both experimentally and theoretically. We address the electron and hole spins in CsPbI$_3$ nanocrystals embedded in a glass matrix by the resonant spin inertia technique based on optically detected magnetic resonance. It allows us to determine the longitudinal spin relaxation time $T_1$ separately for electrons and holes, the $g$ factors, and the effective Overhauser field of the nuclear spin bath. At a temperature of 1.6 K, the $T_1$ time for electrons can be as long as 0.9 ms. We reveal the effect of the time-varying nuclear field fluctuations, which enhances the electron spin relaxation at low magnetic fields, and measure a rather long nuclear spin correlation time of about 60 $μ$s. We develop a model of the spin relaxation in nanocrystals based on a two-LO-phonon Raman process, which explains the observed temperature dependence of the time $T_1$.

cond-mat.mes-hall↗

arXiv2026

Valleytronics in 2D Materials Roadmap

Valleytronics exploits non-equivalent energy extrema in the electronic band structure of crystalline solids -- the valley degree of freedom -- to encode, manipulate, and read out information. The advent of 2D materials, first graphene and then transition-metal dichalcogenides, made valley control practical through optical, electrical, and magnetic routes. This foundation has enabled remarkable progress in recent years spanning established frontiers, such as valley exciton physics and valley Hall effects, as well as emerging directions including lightwave valleytronics, nanophotonic integration, flat-band valleytronics, and spin-valley qubits. In parallel, there are sustained efforts to scale up valleytronic materials and to predict new valleytronic platforms. This Roadmap brings together perspectives from leading experts to chart the key opportunities and challenges at the forefront of 2D material valleytronics. Each section captures a snapshot of progress in a key research area, identifies critical open challenges, and outlines pathways toward future valleytronics breakthroughs.

cond-mat.mes-hall↗

arXiv2025

Long-range ferroelectric order in two dimensional excitonic insulators

It is generally argued that Mermin-Wagner theorem excludes the possibility of long-range order in two dimensional bosonic systems at non-zero temperatures. In contrast, we show here that generic bilayer semiconductors could demonstrate true Bose-Einstein condensation of interlayer excitons. We show that the key requirements include (i) reduction of the interlayer band gap using an applied electric field so that excitons spontaneously appear in the ground state, (ii) band structure that allows for long-range electron-hole exchange interaction, and (iii) a finite magnetic field. Our results indicate that superfluidity and ferroelectric order can co-exist in two dimensional excitonic insulators.

cond-mat.str-el↗

arXiv2025

Interplay of vibrational, electronic, and magnetic states in CrSBr

The van der Waals antiferromagnet CrSBr exhibits coupling of vibrational, electronic, and magnetic degrees of freedom, giving rise to distinctive quasi-particle interactions. We investigate these interactions across a wide temperature range using polarization-resolved Raman spectroscopy at various excitation energies, complemented by optical absorption and photoluminescence excitation (PLE) spectroscopy. Under 1.96 eV excitation, we observe pronounced changes in the A$_g^1$, A$_g^2$, and A$_g^3$ Raman modes near the Néel temperature, coinciding with modifications in the oscillator strength of excitonic transitions and clear resonances in PLE. The distinct temperature evolution of Raman tensor elements and polarization anisotropy for Raman modes indicates that they couple to different excitonic and electronic states. The suppression of the excitonic state's oscillation strength above the Néel temperature could be related to the magnetic phase transition, thereby connecting these excitonic states and Raman modes to a specific spin alignment. These observations make CrSBr a versatile platform for probing quasi-particle interactions in low-dimensional magnets and provide insights for applications in quantum sensing and quantum communication.

cond-mat.mtrl-sci↗

arXiv2025

Exciton transport driven by spin excitations in an antiferromagnet

A new class of optical quasiparticles called magnetic excitons recently emerged in magnetic van der Waals materials. Akin to the highly effective strategies developed for electrons, the strong interactions of these excitons with the spin degree of freedom may provide innovative solutions for long-standing challenges in optics, such as steering the flow of energy and information. Here, we demonstrate transport of excitons by spin excitations in the van der Waals antiferromagnetic semiconductor CrSBr. Key results of our study are the observations of ultrafast, nearly isotropic exciton propagation substantially enhanced at the Neel temperature, transient contraction and expansion of the exciton clouds at low temperatures, as well as superdiffusive behavior in bilayer samples. These signatures largely defy description by commonly known exciton transport mechanisms and are related to the currents of incoherent magnons induced by laser excitation instead. We propose that the drag forces exerted by these currents can effectively imprint characteristic properties of spin excitations onto the motion of excitons. The universal nature of the underlying exciton-magnon scattering promises driving of excitons by magnons in other magnetic semiconductors and even in non-magnetic materials by proximity in heterostructures, merging the rich physics of magneto-transport with optics and photonics.

cond-mat.mes-hall↗

arXiv2025

Control of atomic reconstruction and quasi-1D excitons in strain-engineered moiré heterostructures

In two-dimensional nearly commensurate heterostructures, strain plays a critical role in shaping electronic behavior. While previous studies have focused on random strain introduced during fabrication, achieving controlled structural design has remained challenging. Here, we demonstrate the deterministic creation of one-dimensional arrays from initially zero-dimensional triangular moiré patterns in MoSe$_2$-WSe$_2$ heterobilayers. This transformation, driven by the interplay of uniaxial strain and atomic reconstruction, results in one-dimensional confinement of interlayer excitons within domain walls, exhibiting near-unity linearly polarized emission related to the confinement-induced symmetry breaking. The width of the domain walls--and consequently the degree of exciton confinement--can be precisely tuned by the interlayer twist angle. By applying out-of-plane electric field, the confined excitons exhibit energy shifts exceeding 100~meV and changes in the fine-structure splitting by up to a factor of two. Our work demonstrates the potential of strain engineering for constructing designer moiré systems with programmable quantum properties, paving the way for future optoelectronic applications.

cond-mat.mes-hall↗

arXiv2025

Theory of biexciton-polaritons in transition metal dichalcogenide monolayers

We theoretically investigate a nonlinear optical response of a planar microcavity with an embedded transition metal dicalcogenide monolayer when the energy of a biexcitonic transition is brought in resonance with the energy of a cavity mode. We demonstrate that the emission spectrum of this system strongly depends on an external pump. For small and moderate pumps, we reveal the presence of a doublet in the emission with the corresponding Rabi splitting scaling as a square root of the number of the excitations in the system. Further increase of the pump leads to the reshaping of the spectrum, which demonstrates, at weak damping, the pattern akin a Mollow triplet. An intermediate pumping regime shows a broad irregular spectrum reminiscent of a chaotic dynamics of the system.

cond-mat.mes-hall↗

arXiv2024

Excitons under large pseudomagnetic fields

Excitons in Transition Metal Dichalcogenides (TMDs) acquire a spin-like quantum number, a pseudospin, originating from the crystal's discrete rotational symmetry. Here, we break this symmetry using a tunable uniaxial strain, effectively generating a pseudomagnetic field exceeding 40 Tesla. Under this large field, we demonstrate pseudospin analogs of spintronic phenomena such as the Zeeman effect and Larmor precession. Moreover, we determine previously inaccessible fundamental properties of TMDs, including the strength of the depolarizing field responsible for the loss of exciton coherence. Finally, we uncover the bosonic -- as opposed to fermionic -- nature of many-body excitonic species using the pseudomagnetic equivalent of the $g$-factor spectroscopy. Our work is the first step toward establishing this spectroscopy as a universal method for probing correlated many-body states and realizing pseudospin analogs of spintronic devices.

cond-mat.mes-hall↗

arXiv2024

Raman Polarization Switching in CrSBr

Semiconducting CrSBr is a layered A-type antiferromagnet, with individual layers antiferromagnetically coupled along the stacking direction. Due to its unique orthorhombic crystal structure, CrSBr exhibits highly anisotropic mechanical and optoelectronic properties acting itself as a quasi-1D material. CrSBr demonstrates complex coupling phenomena involving phonons, excitons, magnons, and polaritons. Here we show through polarization-resolved resonant Raman scattering the intricate interaction between the vibrational and electronic properties of CrSBr. For samples spanning from few-layer to bulk thickness, we observe that the polarization of the A$_g^2$ Raman mode can be rotated by 90 degrees, shifting from alignment with the crystallographic a (intermediate magnetic) axis to the b (easy magnetic) axis, depending on the excitation energy. In contrast, the A$_g^1$ and A$_g^3$ modes consistently remain polarized along the b axis, regardless of the laser energy used. We access real and imaginary parts of the Raman tensor in our analysis, uncovering resonant electron-phonon coupling.

cond-mat.mtrl-sci↗

arXiv2024

Doping-control of excitons and magnetism in few-layer CrSBr

Magnetism in two-dimensional materials reveals phenomena distinct from bulk magnetic crystals, with sensitivity to charge doping and electric fields in monolayer and bilayer van der Waals magnet CrI3. Within the class of layered magnets, semiconducting CrSBr stands out by featuring stability under ambient conditions, correlating excitons with magnetic order and thus providing strong magnon-exciton coupling, and exhibiting peculiar magneto-optics of exciton-polaritons. Here, we demonstrate that both exciton and magnetic transitions in bilayer and trilayer CrSBr are sensitive to voltage-controlled field-effect charging, exhibiting bound exciton-charge complexes and doping-induced metamagnetic transitions. Moreover, we demonstrate how these unique properties enable optical probes of local magnetic order, visualizing magnetic domains of competing phases across metamagnetic transitions induced by magnetic field or electrostatic doping. Our work identifies few-layer CrSBr as a rich platform for exploring collaborative effects of charge, optical excitations, and magnetism.

cond-mat.mes-hall↗

arXiv2023

Electron and hole doping of monolayer WSe2 induced by twisted ferroelectric hexagonal boron nitride

For the past few years, 2D ferroelectric materials have attracted strong interest for their potential in future nanoelectronics devices. The recent discovery of 2D ferroelectricity in twisted layers of insulating hexagonal boron nitride, one of the most used 2D materials, has opened the route to its integration into complex van der Waals heterostructures combining hybrid properties. Here we show that opposite polarizations in ferroelectric domains of a folded hBN layer can imprint local n and p doping in a semiconducting transition metal dichalcogenide WSe2 monolayer. We demonstrate that WSe2 can be used as an optical probe of ferroelectricity in hBN and show that the doping density and type can be controlled with the position of the semiconductor with respect to the ferroelectric interface. Our results establish the ferroelectric hBN/WSe2 van der Waals stacking as a promising optoelectronic structure.

cond-mat.mtrl-sci↗

arXiv2023

Non-linear and negative effective diffusivity of optical excitations in moiré-free heterobilayers

Interlayer exciton diffusion is studied in atomically-reconstructed MoSe2/WSe2 heterobilayers with suppressed disorder. Local atomic registry is confirmed by characteristic optical absorption, circularly-polarized photoluminescence, and g-factor measurements. Using transient microscopy we observe propagation properties of interlayer excitons that are independent from trapping at moiré- or disorder-induced local potentials. Confirmed by characteristic temperature dependence for free particles, linear diffusion coefficients of interlayer excitons at liquid helium temperature and low excitation densities are almost 1000 times higher than in previous observations. We further show that exciton-exciton repulsion and annihilation contribute nearly equally to non-linear propagation by disentangling the two processes in the experiment and simulations. Finally, we demonstrate effective shrinking of the light-emission over time across several 100's of picoseconds at the transition from exciton- to the plasma-dominated regimes. Supported by microscopic calculations for bandgap renormalization to identify Mott threshold, this indicates transient crossing between rapidly expanding, short-lived electron-hole plasma and slower, long-lived exciton populations.

cond-mat.mes-hall↗

arXiv2023

Giant optical orientation of exciton spins in lead halide perovskite crystals

Optical orientation of carrier spins by circularly polarized light is the basis of spin physics in semiconductors. Here, we demonstrate strong optical orientation of 85\%, approaching the ultimate limit of unity, for excitons in FA$_{0.9}$Cs$_{0.1}$PbI$_{2.8}$Br$_{0.2}$ lead halide perovskite bulk crystals. Time-resolved photoluminescence allows us to distinguish excitons with 60~ps lifetime from electron-hole recombination in the spin dynamics detected via coherent spin quantum beats in magnetic field. We reveal electron-hole spin correlations through linear polarization beats after circularly polarized excitation. Detuning of the excitation energy from the exciton resonance up to 0.5~eV does not reduce the optical orientation, evidencing clean chiral selection rules in agreement with atomistic calculations, and suppressed spin relaxation of electrons and holes even with large kinetic energies.

cond-mat.mes-hall↗

arXiv2022

Nuclear spin polaron-formation: anisotropy effects and quantum phase transition

We study theoretically the formation of the nuclear-spin polaron state in semiconductor nanosystems within the Lindblad equation approach. To this end, we derive a general Lindblad equation for the density operator that complies with the symmetry of the system Hamiltonian and address the nuclear-spin polaron formation for localized charge carriers subject to an arbitrarily anisotropic hyperfine interaction when optically cooling the nuclei. The steady-state solution of the density matrix for an anisotropic central spin model is presented as a function of the electron and nuclear spin bath temperature. Results for the electron-nuclear spin correlator as well as data for the nuclear spin distribution function serve as a measure of spin-entanglement. The features in both of them clearly indicate the formation of the nuclear polaron state at low temperatures where the crossover regime coincides with an enhancement of quantum fluctuations and agrees with the mean-field prediction of the critical temperature line. We can identify two distinct polaron states dependent upon the hyperfine anisotropy which are separated by a quantum phase transition at the isotropic point. These states are reflected in the temporal spin auto-correlation functions accessible in experiment via spin-noise measurements.

cond-mat.mes-hall↗

arXiv2021

Electron recoil effect in electrically tunable MoSe2 monolayers

Radiative recombination of excitons dressed by the interactions with free charge carriers often occurs under simultaneous excitation of either electrons or holes to unbound states. This phenomenon, known as the electron recoil effect, manifests itself in pronounced, asymmetric spectral lineshapes of the resulting emission. We study the electron recoil effect experimentally in electrically-tunable monolayer semiconductors and derive it theoretically using both trion and Fermi-polaron pictures. Time-resolved analysis of the recoil lineshapes is employed to access transient, non-equilibrium states of the exciton-carrier complexes. We demonstrate cooling of the initially overheated populations on the picosecond timescales and reveal the impact of lattice temperature and free carrier density. Both thermally activated phonons and the presence of free charges are shown to accelerate equilibration. Finally, we find strong correlations between relaxation times from recoil analysis and luminescence rise times, providing a consistent interpretation for the initial dynamics of trion/Fermi-polaron states.

cond-mat.mes-hall↗

arXiv2021

Nonclassical Exciton Diffusion in Monolayer WSe2

We experimentally demonstrate time-resolved exciton propagation in a monolayer semiconductor at cryogenic temperatures. Monitoring phonon-assisted recombination of dark states, we find a highly unusual case of exciton diffusion. While at 5 K the diffusivity is intrinsically limited by acoustic phonon scattering, we observe a pronounced decrease of the diffusion coefficient with increasing temperature, far below the activation threshold of higher-energy phonon modes. This behavior corresponds neither to well-known regimes of semiclassical free-particle transport nor to the thermally activated hopping in systems with strong localization. Its origin is discussed in the framework of both microscopic numerical and semi-phenomenological analytical models illustrating the observed characteristics of nonclassical propagation. Challenging the established description of mobile excitons in monolayer semiconductors, these results open up avenues to study quantum transport phenomena for excitonic quasiparticles in atomically-thin van der Waals materials and their heterostructures.

cond-mat.mes-hall↗