arXiv subjects

Nathan Mayne

Publications and source records attributed to Nathan Mayne.

At least 19 recordsLinked to original sources

arXiv2026

Benchmarking Photolysis Rates with Socrates (24.11): Species for Earth and Exoplanets

Using the Socrates photolysis scheme, we present newly calculated photolysis rates under modern Earth atmospheric conditions for species directly relevant to Earth and species relevant to different atmospheric compositions. We compare to a previous photolysis comparison exercise, namely PhotoComp 2011. Overall, we find good agreement between our results and previous work, with discrepancies usually caused by the implementation of temperature or pressure dependent quantum yields and updated cross-section data. We provide a new set of benchmark photolysis rates for additional species both for Solar irradiance and when irradiated by an M dwarf host star. In general, the higher actinic flux at far-UV and shorter wavelengths of the M dwarf compared to the Sun drives increased photolysis rates for reactions with high threshold energies. This work provides an updated set of benchmark results for further studies of photolysis in the Earth's atmosphere and that of other planets.

astro-ph.EP↗

arXiv2025

The Impact of Different Haze Types on the Atmosphere and Observations of Hot Jupiters: 3D Simulations of HD 189733b, HD209458b and WASP-39b

We present the results from the simulations of the atmospheres of hot-Jupiters HD189733b, HD209458b and WASP-39b, assuming the presence of three different types of haze. Using a 3D General Circulation Model, the Unified Model, we capture the advection, settling and radiative impact of Titan-like, water-world-like and soot-like haze, with a particle radius of 1.5 nm. We show that the radiative impact of haze leads to drastic changes in the thermal structure and circulation in the atmosphere. We then show that in all our simulations, 1) the superrotating jet largely determines the day-to-night haze distribution, 2) eddies drive the latitudinal haze distribution, and 3) the divergent and eddy component of the wind control the finer structure of the haze distribution. We further show that the stronger the absorption strength of the haze, the stronger the superrotating jet, lesser the difference of the day-to-night haze distribution, and larger the transit depth in the synthetic transmission spectrum. We also demonstrate that the presence of such small hazes could result in a stronger haze opacity over the morning terminator in all three planets. This could lead to an observable terminator asymmetry in WASP-39b, with the morning terminator presenting a larger transit depth than the evening terminator. This work suggests that, although it might not be a typical detection feature for hot-Jupiters, an observed increase in transit depth over the morning terminator across the UV and optical wavelength regime could serve as a strong indicator of the presence of haze.

astro-ph.EP↗

arXiv2025

Overcast mornings and clear evenings in hot Jupiter exoplanet atmospheres

Aerosols is an old topic in the young field of exoplanet atmospheres. Understanding what they are, how they form, and where they go has long provided a fertile playground for theorists. For observers, however, aerosols have been a multi-decade migraine, as their chronic presence hides atmospheric features. For hot Jupiters, the large day-night temperature contrast drives inhomogeneous thermal structures and aerosol distribution, leading to different limb properties probed by transit spectra. We present JWST NIRISS/SOSS spectra of morning and evening limbs for nine gas giants with equilibrium temperatures of ~800-1700 K. By measuring feature size of the 1.4 $\mu$m water band for both limbs, we found three planets (WASP-39 b, WASP-94 Ab, and WASP-17 b) show prominent ($>$5$\sigma$) limb-limb atmospheric opacity difference with muted morning and clear evening limbs. The heavily muted water features on morning limbs indicate high-altitude (0.1 to 0.01 mbar) aerosols. To simultaneously have clear evening limbs requires processes with timescales ($\sim$day) comparable to advection to remove these lofted grains, and we found that both downwelling flow and dayside cloud evaporation could be plausible mechanisms. We hypothesize an empirical boundary--termed the "asymmetry horizon"--in temperature-gravity space that marks the transition where inhomogeneous aerosol coverage begins to emerge. Heterogeneous aerosol coverage is common among hot Jupiters. If unrecognized, limb averaging suppresses spectral features, mimicking high-mean-molecular-weight atmospheres, inflating inferred metallicity by up to 2 dex, and underestimating limb temperatures by as much as half. Finally, we introduce the Limb Spectroscopy Metric (LSM) to predict limb spectral feature size based on planet parameters.

astro-ph.EP↗

arXiv2025

Cloudy mornings and clear evenings on a gas giant exoplanet

The spectra of exoplanet atmospheres are affected by aerosols (clouds and hazes) of uncertain origin. Proposed aerosol formation mechanisms include gas condensation or photochemical reactions. We measure the transmission spectrum of the tidally locked gas giant exoplanet WASP-94A b and identify asymmetry in its atmosphere. The morning limb is cooler and cloudy, while the evening limb is hotter and exhibits gaseous H$_2$O absorption features. We interpret this difference as due to the formation of cloud droplets near the morning limb, which evaporate during circulation to the evening limb. The dominant aerosols are clouds cycling between the day and night sides of the atmosphere, not photochemical hazes. The resulting asymmetry can severely bias chemical abundance measurements, unless limb-resolved spectroscopy is available.

astro-ph.EP↗

arXiv2025

Modeling Atmospheric Ion Escape from Kepler-1649 b and c over Time

Rocky planets orbiting M-dwarf stars are prime targets for atmospheric characterization, yet their long-term evolution under intense stellar winds and high-energy radiation remains poorly constrained. The Kepler-1649 system, hosting two terrestrial exoplanets orbiting an M5V star, provides a valuable laboratory for studying atmospheric evolution in the extreme environments typical of M-dwarf systems. In this Letter we show that both planets could have retained atmospheres over gigayear timescales. Using a multi-species magnetohydrodynamic model, we simulate atmospheric ion escape driven by stellar winds and extreme ultraviolet radiation from 0.8 to 4.0 Gyr. The results reveal a clear decline in total ion escape rates with stellar age, as captured by a nonparametric LOWESS regression, with O$^{+}$ comprising 98.3%-99.9% of the total loss. Escape rates at 4.0 Gyr are two to three orders of magnitude lower than during early epochs. At 0.8 Gyr, planet b exhibits 3.79$\times$ higher O$^{+}$ escape rates than planet c, whereas by 4.0 Gyr its O$^{+}$ escape rate becomes 39.5$\times$ lower. This reversal arises from a transition to sub-magnetosonic star-planet interactions, where the fast magnetosonic Mach number, $M_f$, falls below unity. Despite substantial early atmospheric erosion, both planets may have retained significant atmospheres, suggesting potential long-term habitability. These findings offer predictive insight into atmospheric retention in the Kepler-1649 system and inform future JWST observations of similar M-dwarf terrestrial exoplanets aimed at refining habitability assessments.

astro-ph.EP↗

arXiv2024

Inhomogeneous terminators on the exoplanet WASP-39 b

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ \mu$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator.

astro-ph.EP↗

arXiv2024

3D simulations of TRAPPIST-1e with varying CO2, CH4 and haze profiles

Using a 3D General Circulation Model, the Unified Model, we present results from simulations of a tidally-locked TRAPPIST-1e with varying carbon dioxide CO2 and methane CH4 gas concentrations, and their corresponding prescribed spherical haze profiles. Our results show that the presence of CO2 leads to a warmer atmosphere globally due to its greenhouse effect, with the increase of surface temperature on the dayside surface reaching up to ~14.1 K, and on the nightside up to ~21.2 K. Increasing presence of CH4 first elevates the surface temperature on the dayside, followed by a decrease due to the balance of tropospheric warming and stratospheric cooling. A thin layer of haze, formed when the partial pressures of CH4 to CO2 (pCH4/pCO2) = 0.1, leads to a dayside warming of ~4.9K due to a change in the water vapour H2O distribution. The presence of a haze layer that formed beyond the ratio of 0.1 leads to dayside cooling. The haze reaches an optical threshold thickness when pCH4/pCO2 ~0.4 beyond which the dayside mean surface temperature does not vary much. The planet is more favourable to maintaining liquid water on the surface (mean surface temperature above 273.15 K) when pCO2 is high, pCH4 is low and the haze layer is thin. The effect of CO2, CH4 and haze on the dayside is similar to that for a rapidly-rotating planet. On the contrary, their effect on the nightside depends on the wind structure and the wind speed in the simulation.

astro-ph.EP↗

arXiv2024

Modeling Atmospheric Lines By the Exoplanet Community (MALBEC) version 1.0: A CUISINES radiative transfer intercomparison project

Radiative transfer (RT) models are critical in the interpretation of exoplanetary spectra, in simulating exoplanet climates and when designing the specifications of future flagship observatories. However, most models differ in methodologies and input data, which can lead to significantly different spectra. In this paper, we present the experimental protocol of the MALBEC (Modeling Atmospheric Lines By the Exoplanet Community) project. MALBEC is an exoplanet model intercomparison project (exoMIP) that belongs to the CUISINES (Climates Using Interactive Suites of Intercomparisons Nested for Exoplanet Studies) framework which aims to provide the exoplanet community with a large and diverse set of comparison and validation of models. The proposed protocol tests include a large set of initial participating RT models, a broad range of atmospheres (from Hot Jupiters to temperate terrestrials) and several observation geometries, which would allow us to quantify and compare the differences between different RT models used by the exoplanetary community. Two types of tests are proposed: transit spectroscopy and direct imaging modeling, with results from the proposed tests to be published in dedicated follow-up papers. To encourage the community to join this comparison effort and as an example, we present simulation results for one specific transit case (GJ-1214 b), in which we find notable differences in how the various codes handle the discretization of the atmospheres (e.g., sub-layering), the treatment of molecular opacities (e.g., correlated-k, line-by-line) and the default spectroscopic repositories generally used by each model (e.g., HITRAN, HITEMP, ExoMol).

astro-ph.EP↗

arXiv2023

A modern-day Mars climate in the Met Office Unified Model: dry simulations

We present results from the Met Office Unified Model (UM), a world-leading climate and weather model, adapted to simulate a dry Martian climate. We detail the adaptation of the basic parameterisations and analyse results from two simulations, one with radiatively active mineral dust and one with radiatively inactive dust. These simulations demonstrate how the radiative effects of dust act to accelerate the winds and create a mid-altitude isothermal layer during the dusty season. We validate our model through comparison with an established Mars model, the Laboratoire de M\'et\'eorologie Dynamique planetary climate model (PCM), finding good agreement in the seasonal wind and temperature profiles but with discrepancies in the predicted dust mass mixing ratio and conditions at the poles. This study validates the use of the UM for a Martian atmosphere, highlighting how the adaptation of an Earth general circulation model (GCM) can be beneficial for existing Mars GCMs and provides insight into the next steps in our development of a new Mars climate model.

astro-ph.EP↗

arXiv2021

3D radiative-transfer for exoplanet atmospheres. gCMCRT: a GPU accelerated MCRT code

Radiative-transfer (RT) is a key component for investigating atmospheres of planetary bodies. With the 3D nature of exoplanet atmospheres being important in giving rise to their observable properties, accurate and fast 3D methods are required to be developed to meet future multi-dimensional and temporal data sets. We develop an open source GPU RT code, gCMCRT, a Monte Carlo RT forward model for general use in planetary atmosphere RT problems. We aim to automate the post-processing pipeline, starting from direct global circulation model (GCM) output to synthetic spectra. We develop albedo, emission and transmission spectra modes for 3D and 1D input structures. We include capability to use correlated-k and high-resolution opacity tables, the latter of which can be Doppler shifted inside the model. We post-process results from several GCM groups including ExoRad, SPARC/MITgcm THOR, UK Met Office UM, Exo-FMS and the Rauscher model. Users can therefore take advantage of desktop and HPC GPU computing solutions. gCMCRT is well suited for post-processing large GCM model grids produced by members of the community and for high-resolution 3D investigations.

astro-ph.EP↗

arXiv2021

MOVES IV. Modelling the influence of stellar XUV-flux, cosmic rays, and stellar energetic particles on the atmospheric composition of the hot Jupiter HD 189733b

Hot Jupiters provide valuable natural laboratories for studying potential contributions of high-energy radiation to prebiotic synthesis in the atmospheres of exoplanets. In this fourth paper of the MOVES (Multiwavelength Observations of an eVaporating Exoplanet and its Star) programme, we study the effect of different types of high-energy radiation on the production of organic and prebiotic molecules in the atmosphere of the hot Jupiter HD 189733b. Our model combines X-ray and UV observations from the MOVES programme and 3D climate simulations from the 3D Met Office Unified Model to simulate the atmospheric composition and kinetic chemistry with the STAND2019 network. Also, the effects of galactic cosmic rays and stellar energetic particles are included. We find that the differences in the radiation field between the irradiated dayside and the shadowed nightside lead to stronger changes in the chemical abundances than the variability of the host star's XUV emission. We identify ammonium (NH4+) and oxonium (H3O+) as fingerprint ions for the ionization of the atmosphere by both galactic cosmic rays and stellar particles. All considered types of high-energy radiation have an enhancing effect on the abundance of key organic molecules such as hydrogen cyanide (HCN), formaldehyde (CH2O), and ethylene (C2H4). The latter two are intermediates in the production pathway of the amino acid glycine (C2H5NO2) and abundant enough to be potentially detectable by JWST.

astro-ph.EP↗

arXiv2021

Pseudo-2D Modelling of Heat Redistribution Through H$_2$ Thermal Dissociation/Recombination: Consequences for Ultra-Hot Jupiters

Thermal dissociation and recombination of molecular hydrogen, H_2, in the atmospheres of ultra-hot Jupiters (UHJs) has been shown to play an important role in global heat redistribution. This, in turn, significantly impacts their planetary emission, yet only limited investigations on the atmospheric effects have so far been conducted. Here we investigate the heat redistribution caused by this dissociation/recombination reaction, alongside feedback mechanisms between the atmospheric chemistry and radiative transfer, for a planetary and stellar configuration typical of UHJs. To do this, we have developed a time-dependent pseudo-2D model, including a treatment of time-independent equilibrium chemical effects. As a result of the reaction heat redistribution, we find temperature changes of up to $\sim$400 K in the atmosphere. When TiO and VO are additionally considered as opacity sources, these changes in temperature increase to over $\sim$800 K in some areas. This heat redistribution is found to significantly shift the region of peak atmospheric temperature, or hotspot, towards the evening terminator in both cases. The impact of varying the longitudinal wind speed on the reaction heat distribution is also investigated. When excluding TiO/VO, increased wind speeds are shown to increase the impact of the reaction heat redistribution up to a threshold wind speed. When including TiO/VO there is no apparent wind speed threshold, due to thermal stabilisation by these species. We also construct pseudo-2D phase curves from our model, and highlight both significant spectral flux damping and increased phase offset caused by the reaction heat redistribution.

astro-ph.EP↗

arXiv2020

A Library of Self-Consistent Simulated Exoplanet Atmospheres

We present a publicly available library of model atmospheres with radiative-convective equilibrium Pressure-Temperature ($P$-$T$) profiles fully consistent with equilibrium chemical abundances, and the corresponding emission and transmission spectrum with R$\sim$5000 at 0.2 $μ$m decreasing to R$\sim$35 at 30 $μ$m, for 89 hot Jupiter exoplanets, for four re-circulation factors, six metallicities and six C/O ratios. We find the choice of condensation process (local/rainout) alters the $P$-$T$ profile and thereby the spectrum substantially, potentially detectable by JWST. We find H$^-$ opacity can contribute to form a strong temperature inversion in ultra-hot Jupiters for C/O ratios $\geq$ 1 and can make transmission spectra features flat in the optical, alongside altering the entire emission spectra. We highlight how adopting different model choices such as thermal ionisation, opacities, line-wing profiles and the methodology of varying the C/O ratio, effects the $P$-$T$ structure and the spectrum. We show the role of Fe opacity to form primary/secondary inversion in the atmosphere. We use WASP-17b and WASP-121b as test cases to demonstrate the effect of grid parameters across their full range, while highlighting some important findings, concerning the overall atmospheric structure, chemical transition regimes and their observables. Finally, we apply this library to the current transmission and emission spectra observations of WASP-121b, which shows H$_2$O and tentative evidence for VO at the limb, and H$_2$O emission feature indicative of inversion on the dayside, with very low energy redistribution, thereby demonstrating the applicability of library for planning and interpreting observations of transmission and emission spectrum.

astro-ph.EP↗

arXiv2020

A library of ATMO forward model transmission spectra for hot Jupiter exoplanets

We present a grid of forward model transmission spectra, adopting an isothermal temperature-pressure profile, alongside corresponding equilibrium chemical abundances for 117 observationally significant hot exoplanets (Equilibrium Temperatures of 547-2710 K). This model grid has been developed using a 1D radiative-convective-chemical equilibrium model termed ATMO, with up-to-date high temperature opacities. We present an interpretation of observations of ten exoplanets, including best fit parameters and $χ^{2}$ maps. In agreement with previous works, we find a continuum from clear to hazy/cloudy atmospheres for this sample of hot Jupiters. The data for all the 10 planets are consistent with sub-solar to solar C/O ratio, 0.005 to 10 times solar metallicity and water rather than a methane dominated infrared spectra. We then explore the range of simulated atmospheric spectra for different exoplanets, based on characteristics such as temperature, metallicity, C/O-ratio, haziness and cloudiness. We find a transition value for the metallicity between 10 and 50 times solar, which leads to substantial changes in the transmission spectra. We also find a transition value of C/O ratio, from water to carbon species dominated infrared spectra, as found by previous works, revealing a temperature dependence of this transition point ranging from $\sim$0.56 to $\sim$1-1.3 for equilibrium temperatures from $\sim$900 to $\sim$2600 K. We highlight the potential of the spectral features of HCN and C$_2$H$_2$ to constrain the metallicities and C/O ratios of planets, using JWST observations. Finally, our entire grid ($\sim$460,000 simulations) is publicly available and can be used directly with the JWST simulator PandExo for planning observations.

astro-ph.EP↗

arXiv2019

Ozone chemistry on tidally locked M dwarf planets

We use the Met Office Unified Model to explore the potential of a tidally locked M dwarf planet, nominally Proxima Centauri b irradiated by a quiescent version of its host star, to sustain an atmospheric ozone layer. We assume a slab ocean surface layer, and an Earth-like atmosphere of nitrogen and oxygen with trace amounts of ozone and water vapour. We describe ozone chemistry using the Chapman mechanism and the hydrogen oxide (HO$_x$, describing the sum of OH and HO$_2$) catalytic cycle. We find that Proxima Centauri radiates with sufficient UV energy to initialize the Chapman mechanism. The result is a thin but stable ozone layer that peaks at 0.75 parts per million at 25 km. The quasi-stationary distribution of atmospheric ozone is determined by photolysis driven by incoming stellar radiation and by atmospheric transport. Ozone mole fractions are smallest in the lowest 15 km of the atmosphere at the sub-stellar point and largest in the nightside gyres. Above 15 km the ozone distribution is dominated by an equatorial jet stream that circumnavigates the planet. The nightside ozone distribution is dominated by two cyclonic Rossby gyres that result in localized ozone hotspots. On the dayside the atmospheric lifetime is determined by the HO$_x$ catalytic cycle and deposition to the surface, with nightside lifetimes due to chemistry much longer than timescales associated with atmospheric transport. Surface UV values peak at the substellar point with values of 0.01 W/m$^2$, shielded by the overlying atmospheric ozone layer but more importantly by water vapour clouds.

astro-ph.EP↗

arXiv2019

The Acceleration of Superrotation in Simulated Hot Jupiter Atmospheres

Context. Atmospheric superrotating flows at the equator are an almost ubiquitous result of simulations of hot Jupiters, and a theory explaining how this zonally coherent flow reaches an equilibrium has been developed in the literature. However, this understanding relies on the existence of either an initial superrotating or a sheared flow, coupled with a slow evolution such that a linear steady state can be reached. Aims. A consistent physical understanding of superrotation is needed for arbitrary drag and radiative timescales, and the relevance of considering linear steady states needs to be assessed. Methods. We obtain an analytical expression for the structure, frequency and decay rate of propagating waves in hot Jupiter atmospheres around a state at rest in the 2D shallow water beta plane limit. We solve this expression numerically and confirm the robustness of our results with a 3D linear wave algorithm. We then compare with 3D simulations of hot Jupiter atmospheres and study the non linear momentum fluxes. Results. We show that under strong day night heating the dynamics does not transit through a linear steady state when starting from an initial atmosphere in solid body rotation. We further show that non linear effects favour the initial spin up of superrotation and that the acceleration due to the vertical component of the eddy momentum flux is critical to the initial development of superrotation. Conclusions. Overall, we describe the initial phases of the acceleration of superrotation, including consideration of differing radiative and drag timescales, and conclude that eddy-momentum driven superrotating equatorial jets are robust, physical phenomena in simulations of hot Jupiter atmospheres.

astro-ph.EP↗

arXiv2019

Eigenvectors, Circulation and Linear Instabilities for Planetary Science in 3 Dimensions (ECLIPS3D)

Context. The study of linear waves and instabilities is necessary to understand the physical evolution of an atmosphere, and can provide physical interpretation of the complex flows found in simulations performed using Global Circulation Models (GCM). In particular, the acceleration of superrotating flow at the equator of hot Jupiters has mostly been studied under several simplifying assumptions, the relaxing of which may impact final results. Aims. We develop and benchmark a publicly available algorithm to identify the eigenmodes of an atmosphere around any initial steady state. We also solve for linear steady states. Methods. We linearise the hydrodynamical equations of a planetary atmosphere in a steady state with arbitrary velocities and thermal profile. We then discretise the linearised equations on an appropriate staggered grid, and solve for eigenvectors and linear steady solutions with the use of a parallel library for linear algebra: ScaLAPACK. We also implement a posteriori calculation of an energy equation in order to obtain more information on the underlying physics of the mode. Results. Our code is benchmarked against classical wave and instability test cases in multiple geometries. The steady linear circulation calculations also reproduce expected results for the atmosphere of hot Jupiters. We finally show the robustness of our energy equation, and its power to obtain physical insight into the modes. Conclusions. We have developed and benchmarked a code for the study of linear processes in planetary atmospheres, with an arbitrary steady state. The calculation of an a posteriori energy equation provides both increased robustness and physical meaning to the obtained eigenmodes. This code can be applied to various problems, and notably to further study the initial spin up of superrotation of GCM simulations of hot Jupiter.

astro-ph.EP↗

arXiv2019

ESA Voyage 2050 White Paper: Detecting life outside our solar system with a large high-contrast-imaging mission

In this white paper, we recommend the European Space Agency plays a proactive role in developing a global collaborative effort to construct a large high-contrast imaging space telescope, e.g. as currently under study by NASA. Such a mission will be needed to characterize a sizable sample of temperate Earth-like planets in the habitable zones of nearby Sun-like stars and to search for extraterrestrial biological activity. We provide an overview of relevant European expertise, and advocate ESA to start a technology development program towards detecting life outside the Solar system.

astro-ph.EP↗