arXiv subjects

Niall Whiteford

Publications and source records attributed to Niall Whiteford.

At least 19 recordsLinked to original sources

arXiv2026

Sinking Silicates I: Characterizing the benchmark system containing the T0 brown dwarf CWISE J210640.16+250729.0 using JWST

In this study, we present the full (97.3\% complete) 0.8--12.5 $μ$m spectral energy distribution (SED) of an L/T transition object, CWISE J210640.16+250729.0 (CW2106), using the James Webb Space Telescope (JWST). We provide a full characterization of the host star's elemental abundances and age. We empirically derive the bolometric luminosity ($L_{\rm bol}\approx-4.825$ $\textup{L}_\odot$) of CW2106, and obtain estimates of its mass (M$\approx50-62$ M$_{\rm Jup}$), radius (R$\approx0.83-0.87$ R$_{\rm Jup}$), effective temperature ($T_{\rm eff}$$\approx1213$ K), and surface gravity ($\log~g$$\approx5.28$ dex). We find the near-infrared (near-IR) spectrum ($0.8-2.5 ~μ$m) is best reproduced with cloudy atmospheric models while the mid-infrared (mid-IR) spectrum ($5-12.5 ~μ$m) is best reproduced with cloudless models. This suggests a cloud layer restricted to only the deepest observable parts of the atmosphere and is qualified by the lack of a 9 $μ$m silicate feature. Making use of the Mg/Si ratio of the primary, alongside thermochemical models, we predict the clouds in CW2106 to be composed primarily of enstatite (MgSiO$_3$), removing $\sim23\%$ of the bulk oxygen out of the atmosphere. Future retrieval studies will be able to help investigate the existence and full impact of these cloud species.

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arXiv2026

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems VIII: patchy forsterite and enstatite clouds in the atmosphere of VHS 1256 b, retrieval lessons learned and outlook to the future

JWST defines a new era for the data-driven approach of retrieval modelling, which has become a cornerstone tool for the statistical inference of exoplanetary and brown dwarf properties. The Early Release Science program #1386 observations of VHS 1256 b represent a huge jump in data quality, data quantity and spectral coverage for such objects. VHS 1256 b is a young, planetary mass and extremely variable companion that populates the enigmatic L/T cohort of substellar atmospheres. In this first retrieval analysis of the full 1 - 18 micron dataset, we apply the Brewster retrieval framework to the NIRSpec and MIRI spectroscopic observations of VHS 1256 b, exploring a variety of cloud species and structures. Using Delta(BIC) we find that the data is best described by a forsterite (Mg$_{2}$SiO$_{4}$) and enstatite (MgSiO$_{3}$) cloud combination. Our analysis shows a strong preference for patchy silicate cloud coverage, which aligns with VHS 1256 b's extensive and well documented spectral variability. Our retrieval is able to place constraints on the abundances of H$_{2}$O, CO, CO$_{2}$, CH$_{4}$ as well as NH$_{3}$. We also show that the retrieved parameters are sensitive to the data used and the relative signal-to-noise ratios between data from different instruments. We conclude with the next steps for the wider retrieval community to better understand young and cloudy exoplanetary atmospheres.

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arXiv2026

The JWST weather report: Unravelling the atmospheric variability of isolated worlds using principal component analysis

Brown dwarf variability directly probes atmospheric dynamics beyond the Solar System, and recent JWST time-resolved spectroscopy has opened a new window into these processes. Principal component analysis (PCA) offers a data-driven framework to identify the dominant, independent patterns of spectral variability of variable targets without relying on prior atmospheric assumptions. SIMP 0136 is a young, T2.5, brown dwarf at the planetary-mass boundary, making it an ideal analogue for directly imaged exoplanets. We analysed one rotation of JWST/NIRSpec PRISM time-series spectroscopy to investigate the drivers of its variability using PCA. Two principal components are sufficient to reduce the residual spectra to the propagated noise floor, indicating that they capture the detectable coherent spectroscopic variability. The leading principal component captures broadband variability consistent with temperature changes, while the second traces chromatic variability linked to vertical cloud structure. The dominance of two components implies that the spectra can be described as mixtures of three distinct atmospheric states, whose relative contributions we mapped as a function of rotational phase. The observed spectra are described as evolving linear combinations of these states, indicating that the variability arises from the changing visibility of spatially distinct atmospheric regions. By projecting Sonora Diamondback forward models into the same principal component space, we found that the principal components capture a large fraction of the model variance, demonstrating that the same physical processes that govern SIMP-0136's observed variability also capture much of the model grid's variation. Our results establish PCA as a computationally efficient, physically interpretable framework for analysing JWST time-resolved spectroscopy of substellar atmospheres.

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arXiv2026

Photometric Variability and Rotation of Beta Pictoris b from JWST NIRCam Coronagraphic Imaging

We report the detection of photometric variability in the directly imaged super-Jupiter $β$ Pictoris b. Using JWST NIRCam dual-band coronagraphic imaging, we conducted a 16-hour continuous photometric monitoring campaign in the F210M and F410M filters. We developed and validated a time-series photometry framework that combines PSF subtraction, principal component analysis for systematic noise removal, and injection-and-recovery tests to confirm signal fidelity. Both light curves show consistent sinusoidal variability at $\sim$5$σ$ and $\gg 5σ$ significance in the F210M and F410M bands, respectively. A joint sinusoidal fit yields a rotation period of $P_{\rm rot} = 9.00 \pm 0.13$ hr and variability amplitudes of $0.85 \pm 0.07\%$ and $0.89 \pm 0.04\%$ in F210M and F410M, respectively. The near-identical amplitudes and periods in both bands confirm a common astrophysical origin in a heterogeneous atmosphere. Combining $P_{\rm rot}$ with the previously measured projected rotational velocity, we constrain the line-of-sight spin axis inclination of $β$ Pic b. The result favors an equator-on viewing geometry, consistent with line-of-sight spin-orbit alignment: the planetary spin axis, orbital plane, debris disk, and stellar equator are all mutually aligned. This stands in sharp contrast to the large obliquities of wide-separation companions that are likely formed via gravitational fragmentation. Together with the system's young age, this observation provides independent dynamical evidence that $β$ Pic b formed via core accretion. This result constitutes the first detection of rotational modulation in a close-in, high-contrast exoplanet that likely formed via core accretion, demonstrating that time-series coronagraphic imaging with JWST opens a powerful new window onto the rotation, atmospheric dynamics, and spin-orbit architecture of this population.

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arXiv2026

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems. VII. Molecular Mapping Performance with JWST/MIRI MRS: VHS 1256 b as a case study

VHS 1256 b was the first planetary-mass companion to be observed with the James Webb Space Telescope's Mid-Infrared Instrument (JWST/MIRI) using the Medium-Resolution Spectrometer (MRS). The MRS provides high-quality integral-field spectral data in the mid-infrared (IR) wavelengths from 4.9 to 18 um. This dataset serves as a testbed for applying cross-correlation techniques to characterize exoplanet atmospheres. We implement the so-called molecular mapping approach, which consists of performing a spectral cross-correlation between each spectral pixel and atmospheric model templates. We compare these results with those obtained from cross-correlation of the extracted spectrum. Using a self-consistent Exo-REM atmospheric model grid, we constrain the temperature, surface gravity, C/O ratio, and metallicity, finding values consistent with those obtained from other analysis methods. We detect CO (S/N $\sim$ 25) and H2O (S/N $\sim$ 76), with tentative detections of NH3 and CH4 (S/N$\sim$ 3). We test cross-correlation to measure trace-species abundances and isotopic ratios. We measure a volume mixing ratio of [NH3] =-5.73^{+0.15}_{-0.14} and an isotopic ratio $^{12}\mathrm{C}/^{13}\mathrm{C}=77.8^{+13}_{-10}$, both consistent with free-chemistry retrievals. The derived NH3 volume mixing ratio, combined with the measured temperature and radius, is consistent with VHS 1256 b having a mass above the deuterium-burning limit. These results demonstrate the diagnostic power of mid-IR spectroscopy and highlight cross-correlation as a robust method for characterizing directly imaged exoplanets, even in future higher-contrast regimes where spectral extraction becomes challenging. Future MIRI MRS observations across a wider range of temperatures and masses will further expand our understanding of planetary atmospheric chemistry.

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arXiv2025

Large-amplitude Variability Driven by Giant Dust Storms on a Planetary-mass Companion

Large-amplitude variations are commonly observed in the atmospheres of directly imaged exoplanets and brown dwarfs. VHS 1256B, the most variable known planet-mass object, exhibits a near-infrared flux change of nearly 40%, with red color and silicate features revealed in recent JWST spectra, challenging current theories. Using a general circulation model, we demonstrate that VHS 1256B's atmosphere is dominated by planetary-scale dust storms persisting for tens of days, with large patchy clouds propagating with equatorial waves. This weather pattern, distinct from the banded structures seen on solar system giants, simultaneously explains the observed spectra and critical features in the rotational light curves, including the large amplitude, irregular evolution, and wavelength dependence, as well as the variability trends observed in near-infrared color-magnitude diagrams of dusty substellar atmospheres.

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arXiv2025

The Diversity of Cold Worlds: Age and Characterization of the Exoplanet COCONUTS-2b

Studying cold brown dwarfs is key to understanding the diverse characteristics of cold giant exoplanets atmospheres. COCONUTS-2, is a wide binary system composed of a T9 brown dwarf and an M3 star, which presents a unique opportunity to characterize a cold benchmark brown dwarf. As part of a JWST program to study the range of physical and atmospheric properties of the coldest brown dwarfs, we obtained NIRSpec G395H spectra (R~2700, 2.87-5.13 um) and MIRI F1000W, F1280W, and F1800W photometry for COCONUTS-2b. In this work, we find a 99% probability of the system belonging to the Corona of Ursa Major (414+/-23 Myr) using BANYAN Sigma and its full kinematics. We also re-estimate the astrometry of COCONUTS-2b using the MIRI data. We support the membership with a comparison of rotation period, metallicity and C/O ratio of the group with those of the COCONUTS-2 system. We also calculate its bolometric luminosity, which combined with our age estimation, allows us to derive its mass, effective temperature, surface gravity, and radius with high precision. As a result of our analysis, we support the conclusion that COCONUTS-2b is a planetary mass object (7.5+/-0.4 MJup) which was likely formed via the same mechanism as stars. In addition we compare the JWST spectrum to another object in the sample, J082507.35+280548.5 (0825+2805), a Y0.5 brown dwarf, which is a candidate member of the same moving group, but has a lower mass (3.7+/-0.2 MJup). We identify absorption feature differences which could indicate that 0825+2805 has stronger vertical mixing.

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arXiv2025

Diversity of Cold Worlds: Predicted Near- to Mid-infrared Spectral Signatures of a Cold Brown Dwarf with Potential Auroral Heating

Recent JWST/NIRSpec observations have revealed strong methane emission at 3.326 microns in the $\approx$482 K brown dwarf CWISEP J193518.59$-$154620.3 (W1935). Atmospheric modeling suggests the presence of a $\approx$300 K thermal inversion in its upper atmosphere, potentially driven by auroral activity. We present an extension of the retrieved spectra of W1935 with and without inversion spanning 1--20 microns, to identify thermal inversion-sensitive spectral features and explore the origin of the object's peculiar characteristics. Our analysis indicates that atmospheric heating contributes approximately 15% to the bolometric luminosity. The model with inversion predicts an additional similar-strength methane emission feature at 7.7 microns and tentative ammonia emission features in the mid-infrared. Wavelengths beyond $\sim$2 microns are significantly influenced by the inversion, except for the 4.1--5.0 microns CO$_2$ and CO features that originate from atmospheric layers deeper than the region where the inversion occurs. W1935 appears as an outlier in Spitzer/IRAC mid-infrared color-magnitude diagrams (CMDs) based on the $m_{\rm Ch1}-m_{\rm Ch2}$ (IRAC 3.6 microns $-$ 4.5 microns) color, but exhibits average behavior in all other combinations that trace clear sequences. This anomaly is likely due to the Ch2 filter probing vertical mixing-sensitive CO$_2$ and CO features that do not correlate with temperature or spectral type. We find that the thermal inversion tends to produce bluer $m_{\rm Ch1}-m_{\rm Ch2}$ colors, so the overluminous and/or redder position of W1935 in diagrams involving this color cannot be explained by the thermal inversion. This analysis provides insights into the intriguing dispersion of cold brown dwarfs in mid-infrared CMDs and sheds light on their spectral diversity.

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arXiv2025

The JWST Weather Report: retrieving temperature variations, auroral heating, and static cloud coverage on SIMP-0136

SIMP-0136 is a T2.5 brown dwarf whose young age ($200\pm50$~Myr) and low mass ($15\pm3$~M$_{\rm Jup}$) make it an ideal analogue for the directly imaged exoplanet population. With a 2.4 hour period, it is known to be variable in both the infrared and the radio, which has been attributed to changes in the cloud coverage and the presence of an aurora respectively. To quantify the changes in the atmospheric state that drive this variability, we obtained time-series spectra of SIMP-0136 covering one full rotation with both NIRSpec/PRISM and the MIRI/LRS on board JWST. We performed a series of time-resolved atmospheric retrievals using petitRADTRANS in order to measure changes in the temperature structure, chemistry, and cloudiness. We inferred the presence of a ~250 K thermal inversion above 10 mbar of SIMP-0136 at all phases, and propose that this inversion is due to the deposition of energy into the upper atmosphere by an aurora. Statistical tests were performed in order to determine which parameters drive the observed spectroscopic variability. The primary contribution was due to changes in the temperature profile at pressures deeper than 10 mbar, which resulted in variation of the effective temperature from 1243 K to 1248 K. This changing effective temperature was also correlated to observed changes in the abundances of CO2 and H2S, while all other chemical species were consistent with being homogeneous throughout the atmosphere. Patchy silicate clouds were required to fit the observed spectra, but the cloud properties were not found to systematically vary with longitude. This work paints a portrait of an L/T transition object where the primary variability mechanisms are magnetic and thermodynamic in nature, rather than due to inhomogeneous cloud coverage.

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arXiv2025

Characterizing the Time Variability of 2M1207 A+b with JWST NIRSpec/PRISM

We present JWST NIRSpec/PRISM IFU time-resolved observations of 2M1207 A and b (TWA 27), a $\sim 10$ Myr binary system consisting of a $\sim 2500$ K sub-stellar primary hosting a $\sim 1300$ K companion. Our data provide 20 time-resolved spectra over an observation spanning 12.56 hours. We provide an empirical characterization for the spectra of both objects across time. For 2M1207 A, non-linear trend models are statistically favored within the ranges 0.6-2.3 $μ$m and 3.8-5.3 $μ$m. However, most of the periods constrained from sinusoidal models exceed the observing window, setting a lower limit of 12.56 hours. We find the data at H$α$ and beyond 4.35 $μ$m show a moderate time correlation, as well as a pair of light curves at 0.73-0.80 $μ$m and 3.36-3.38 $μ$m. For 2M1207 b, light curves integrated across 0.86-1.77 $μ$m and 3.29-4.34 $μ$m support linear trend models. Following the interpretation of Zhang et. al. (2025), we model the 2M1207 b data with two 1D atmospheric components, both with silicate and iron condensates. The model of time variability as changes to the cloud filling factor shows broad consistency with the variability amplitudes derived from our data. Our amplitudes, however, disagree with the models at $\approx$0.86-1 $μ$m. While an additional model component such as rainout chemistry may be considered here, our analysis is limited by a low signal-to-noise ratio. Our results demonstrate the capability of JWST to simultaneously monitor the spectral variability of a planetary-mass companion and host at low contrast.

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arXiv2025

SO2, silicate clouds, but no CH4 detected in a warm Neptune

WASP-107b is a warm (~740 K) transiting planet with a Neptune-like mass of ~30.5 Earth masses and Jupiter-like radius of ~0.94 Jupiter radius, whose extended atmosphere is eroding. Previous observations showed evidence for water vapour and a thick high-altitude condensate layer in WASP-107b's atmosphere. Recently, photochemically produced sulphur dioxide (SO2) was detected in the atmosphere of a hot (~1200 K) Saturn-mass planet from transmission spectroscopy near 4.05 microns, but for temperatures below 1000 K sulphur is predicted to preferably form sulphur allotropes instead of SO2. Here we report the 9-sigma detection of two fundamental vibration bands of SO2, at 7.35 microns and 8.69 microns, in the transmission spectrum of WASP-107b using the Mid-Infrared Instrument (MIRI) of the JWST. This discovery establishes WASP-107b as the second irradiated exoplanet with confirmed photochemistry, extending the temperature range of exoplanets exhibiting detected photochemistry from ~1200 K down to ~740 K. Additionally, our spectral analysis reveals the presence of silicate clouds, which are strongly favoured (~7-sigma) over simpler cloud setups. Furthermore, water is detected (~12-sigma), but methane is not. These findings provide evidence of disequilibrium chemistry and indicate a dynamically active atmosphere with a super-solar metallicity.

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arXiv2025

On Linking Planet Formation Models, Protoplanetary Disk Properties, and Mature Gas Giant Exoplanet Atmospheres

Measuring a single elemental ratio (e.g., carbon-to-oxygen) provides insufficient information for understanding the formation mechanisms and evolution that affect our observations of gas giant planet atmospheres. Although the fields of planet formation, protoplanetary disks, and exoplanets are well established and interconnected, our understanding of how to self-consistently and accurately link the theoretical and observational aspects of these fields together is lacking. To foster interdisciplinary conversations, the Max-Planck Institut für Astronomie (MPIA) hosted a week-long workshop called, "Challenge Accepted: Linking Planet Formation with Present-Day Atmospheres." Here, we summarize the latest theories and results in planet formation modeling, protoplanetary disk observations, and atmospheric observations of gas giant atmospheres to address one of the challenges of hosting interdisciplinary conferences: ensuring everyone is aware of the state-of-the-art results and technical language from each discipline represented. Additionally, we highlight key discussions held at the workshop. Our main conclusion is that it is unclear what the ideal observable is to make this link between formation scenarios and exoplanet atmospheres, whether it be multiple elemental abundance ratios, measuring refractory budgets, or something else. Based on discussions held throughout the workshop, we provide several key takeaways of what the workshop attendees feel need the most improvement and exploration within each discipline.

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arXiv2025

Diversity of Cold Worlds: A Near Complete Spectral Energy Distribution for 2MASS J04151954-0935066 using JWST

We present the a near complete spectral energy distribution (SED) for an extrasolar world: the T8 brown dwarf 2MASS~J04151954$-$0935066. Spanning from optical to mid-infrared (0.7--20.4 micron) wavelengths, the SED for this substellar atmosphere is constructed from new JWST NIRSpec G395H ($R\sim$2700) and Magellan FIRE echelle ($R\sim$8000) near-infrared spectra, along with MIRI mid-infrared photometry complemented by spectra from Keck I, IRTF, Magellan, AKARI, Spitzer and photometry from various surveys and missions. The NIRSpec G395H spectrum reveals strong molecular absorptions from NH$_{3}$, CH$_{4}$, H$_{2}$S, CO$_{2}$ and H$_{2}$O at approximately 3.00, 3.35, 3.95, 4.25, and 5.00 micron respectively, along with the presence of a CO absorption feature detected mainly at $\sim$ 4.6 micron. We detect no absorption of near-infrared K I doublets in the $R\sim8000$ FIRE spectra. In the mid-infrared IRS spectrum, we tentatively identify a new CO$_{2}$ feature at 14--16 micron. The comprehensive SED allows us to empirically constrain bolometric luminosity, effective temperature, mass and radius. Additionally, we demonstrate that the NIRSpec G395H resolution, the highest allowable by JWST, enables a precise radial velocity measurement of $47.1\pm1.8$ km s$^{-1}$ for the object, in agreement with previous measurements.

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arXiv2025

The JWST weather report from the nearest brown dwarfs II: Consistent variability mechanisms over 7 months revealed by 1-14 $μ$m NIRSpec + MIRI monitoring of WISE 1049AB

We present a new epoch of JWST spectroscopic variability monitoring of the benchmark binary brown dwarf WISE 1049AB, the closest, brightest brown dwarfs known. Our 8-hour MIRI low resolution spectroscopy (LRS) and 7-hour NIRSpec prism observations extended variability measurements for any brown dwarfs beyond 11 $μ$m for the first time, reaching up to 14 $μ$m. Combined with the previous epoch in 2023, they set the longest JWST weather monitoring baseline to date. We found that both WISE 1049AB show wavelength-dependent light curve behaviours. Using a robust k-means clustering algorithm, we identified several clusters of variability behaviours associated with three distinct pressure levels. By comparing to a general circulation model (GCM), we identified the possible mechanisms that drive the variability at these pressure levels: Patchy clouds rotating in and out of view likely shaped the dramatic light curves in the deepest layers between 1-2.5 $μ$m, whereas hot spots arising from temperature / chemical variations of molecular species likely dominate the high-altitude levels between 2.5-3.6 $μ$m and 4.3-8.5 $μ$m. Small-grain silicates potentially contributed to the variability of WISE 1049A at 8.5-11 $μ$m. While distinct atmospheric layers are governed by different mechanisms, we confirmed for the first time that each variability mechanism remains consistent within its layer over the long term. Future multi-period observations will further test the stability of variability mechanisms on this binary, and expanded JWST variability surveys across the L-T-Y sequence will allow us to trace and understand variability mechanisms across a wider population of brown dwarfs and planetary-mass objects.

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arXiv2025

MIRI-JWST mid-infrared direct imaging of the debris disk of HD106906

We report MIRI-JWST coronagraphic observations at 11.3 and 15.5 mic of the debris disk around the young star HD 106906. The observations were made to characterize the structure, temperature and mass of the disk through the thermal emission of the dust heated by the central star. Another goal was also to constrain the size distribution of the grains. The data were reduced and calibrated using the JWST pipeline. The analysis was based on a forward-modeling of the images using a multiparameter radiative transfer model coupled to an optical code for coronagraphy processing. The disk is clearly detected at both wavelengths. The slight asymmetry is geometrically consistent with the asymmetry observed in the near-IR, but it is inconsistent the brightness distribution. The observed structure is well reproduced with a model of a disk (or belt) with a critical radius 70 au, a mildly inward-increasing density (index 2) and a steeper decrease outward (index -6). This indication of a filled disk inside the critical radius is inconsistent with sculpting from an inner massive planet. The size distribution of the grains that cause the mid-IR emission is well constrained by the flux ratio at the two wavelengths : 0.45 10 mic and 0.65 10 mic for silicate and graphite grains, respectively. The minimum size is consistent with predictions of blowout through radiative pressure. We derive a mass of the dust that causes the mid-IR emission of 3.3 5.0 E3 Mearth. When the larger grains (up to 1 cm) that cause the millimeter emission are included, we extrapolate this mass to 0.10 0.16 Mearth. We point out to that this is fully consistent with ALMA observations of the disk in terms of dust mass and of its millimeter flux. We estimate the average dust temperature in the planetesimal belt to be 74 K, and a temperature range within the whole disk from 40 to 130 K.

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arXiv2025

The Diversity of Cold Worlds: a blended-light binary straddling the T/Y transition in brown dwarfs

We present the first brown dwarf spectral binary characterized with JWST: WISE J014656.66+423410.0, the coldest blended-light brown dwarf binary straddling the T/Y transition. We obtained a moderate resolution (R$\sim$2700) G395H spectrum of this unresolved binary with JWST/NIRSpec and we fit it to late-T and Y dwarf spectra from JWST/NIRSpec, and model spectra of comparable temperatures, both as individual spectra and pairs mimicking an unresolved binary system. We find that this tightly-separated binary is likely composed of two unequal-brightness sources with a magnitude difference of $0.50\pm0.08$ mag in IRAC [4.5] and a secondary $1.01\pm0.13$ mag redder than the primary in [3.6]-[4.5]. Despite the large color difference between the best fit primary and secondary, their temperature difference is only $92\pm23$\,K, a feature reminiscing of the L/T transition. Carbon disequilibrium chemistry strongly shapes the mid-infrared spectra of these sources, as a complex function of metallicity and surface gravity. While a larger library of JWST/NIRSpec spectra is needed to conclusively examine the peculiarities of blended-light sources, this spectral binary is a crucial pathfinder to both understand the spectral features of planetary-mass atmospheres and detect binarity in unresolved, moderate-resolution spectra of the coldest brown dwarfs.

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arXiv2025

HCN and C2H2 in the atmosphere of a T8.5+T9 brown dwarf binary

T-type brown dwarfs present an opportunity to explore atmospheres teeming with molecules such as H2O, CH4 and NH3, which exhibit a wealth of absorption features in the mid-infrared. With JWST, we can finally explore this chemistry in detail, including for the coldest brown dwarfs that were not yet discovered in the Spitzer era. This allows precise derivations of the molecular abundances, which in turn informs our understanding of vertical transport in these atmospheres and can provide clues about the formation of cold brown dwarfs and exoplanets. This study presents the first JWST/MRS mid-IR spectrum (R ~ 1500-3000) of a T-dwarf: the T8.5+T9 brown dwarf binary WISE J045853.90+643451.9. We fit the spectrum using a parameterized P-T profile and free molecular abundances (i.e., a retrieval analysis), treating the binary as unresolved. We find a good fit with a cloud-free atmosphere and identify H2O, CH4 and NH3 features. Moreover, we make the first detections of HCN and C2H2 (at 13.4$σ$ and 9.5$σ$ respectively) in any brown dwarf atmosphere. The detection of HCN suggests intense vertical mixing ($K_{zz}\sim10^{11}$cm$^2$s$^{-1}$), challenging previous literature derivations of $K_{zz}$ values for T-type brown dwarfs. Even more surprising is the C2H2 detection, which cannot be explained with existing atmospheric models for isolated objects. This result challenges model assumptions about vertical mixing, and/or our understanding of the C2H2 chemical network, or might hint towards a more complex atmospheric processes such as magnetic fields driving aurorae, or lightning driving ionization. These findings open a new frontier in studying carbon chemistry within brown dwarf atmospheres.

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arXiv2025

First unambiguous detection of ammonia in the atmosphere of a planetary mass companion with JWST/MIRI coronagraphs

The newly accessible mid-infrared (MIR) window offered by the James Webb Space Telescope (JWST) for exoplanet imaging is expected to provide valuable information to characterize their atmospheres. In particular, coronagraphs on board the JWST Mid-InfraRed instrument (MIRI) are capable of imaging the coldest directly imaged giant planets at the wavelengths where they emit most of their flux. The MIRI coronagraphs have been specially designed to detect the NH3 absorption around 10.5 microns, which has been predicted by atmospheric models. We aim to assess the presence of NH3 while refining the atmospheric parameters of one of the coldest companions detected by directly imaging GJ 504 b. Its mass is still a matter of debate and depending on the host star age estimate, the companion could either be placed in the brown dwarf regime or in the young Jovian planet regime. We present an analysis of MIRI coronagraphic observations of the GJ 504 system. We took advantage of previous observations of reference stars to build a library of images and to perform a more efficient subtraction of the stellar diffraction pattern. We detected the presence of NH3 at 12.5 sigma in the atmosphere, in line with atmospheric model expectations for a planetary-mass object and observed in brown dwarfs within a similar temperature range. The best-fit model with Exo-REM provides updated values of its atmospheric parameters, yielding a temperature of Teff = 512 K and radius of R = 1.08 RJup. These observations demonstrate the capability of MIRI coronagraphs to detect NH3 and to provide the first MIR observations of one of the coldest directly imaged companions. Overall, NH3 is a key molecule for characterizing the atmospheres of cold planets, offering valuable insights into their surface gravity. These observations provide valuable information for spectroscopic observations planned with JWST.

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