arXiv subjects

Nicola M. Pugno

Publications and source records attributed to Nicola M. Pugno.

At least 55 records · Page 3Linked to original sources

arXiv2018

A 2-D Model for friction of complex anisotropic surfaces

The friction force observed at macroscale is the result of interactions at various lower length scales that are difficult to model in a combined manner. For this reason, simplified approaches are required, depending on the specific aspect to be investigated. In particular, the dimensionality of the system is often reduced, especially in models designed to provide a qualitative description of frictional properties of elastic materials, e.g. the spring-block model. In this paper, we implement for the first time a two dimensional extension of the spring-block model, applying it to structured surfaces and investigating by means of numerical simulations the frictional behaviour of a surface in the presence of features like cavities, pillars or complex anisotropic structures. We show how friction can be effectively tuned by appropriate design of such surface features.

cond-mat.mtrl-sci↗

arXiv2017

Labyrinthine acoustic metamaterials with space-coiling channels for low-frequency sound control

We numerically analyze the performance of labyrinthine acoustic metamaterials with internal channels folded along a Wunderlich space-filling curve to control low-frequency sound in air. In contrast to previous studies, we perform direct modeling of wave propagation through folded channels, not introducing effective theory assumptions. As a result, we reveal that metastructures with channels, which allow wave propagation in the opposite direction to incident waves, have different dynamics as compared to those for straight slits of equivalent length. The differences are attributed to activated tortuosity effects and result in 100% wave reflection at band gap frequencies. This total reflection phenomenon is found to be insensitive to thermo-viscous dissipation in air. For labyrinthine channels generated by iteration levels, one can achieve broadband total sound reflection by using a metamaterial monolayer and efficiently control the amount of absorbed wave energy by tuning the channel width. Thus, the work contributes to a better understanding of labyrinthine metamaterials with potential applications for reflection and filtering of low-frequency airborne sound.

physics.app-ph↗

arXiv2017

Tuning friction with composite hierarchical surfaces

Macroscopic friction coefficients observed in experiments are the result of various types of complex multiscale interactions between sliding surfaces. Therefore, there are several ways to modify them depending on the physical phenomena involved. Recently, it has been demonstrated that surface structure, e.g. artificial patterning, can be used to tune frictional properties. In this paper, we show how the global friction coefficients can also be manipulated using composite surfaces with varying roughness or stiffness values, i.e. by combining geometrical features with the modification of local friction coefficients or stiffnesses. We show that a remarkable reduction of static friction can be achieved by introducing hierarchical arrangements of varying local roughness values, or by introducing controlled material stiffness variations.

cond-mat.mtrl-sci↗

arXiv2017

Spin-orbit coupling in a hexagonal ring of pendula

We consider the mechanical motion of a system of six macroscopic pendula which are connected with springs and arranged in a hexagonal geometry. When the springs are pre-tensioned, the coupling between neighbouring pendula along the longitudinal (L) and the transverse (T) directions are different: identifying the motion along the L and T directions as a spin-like degree of freedom, we theoretically and experimentally verify that the pre-tensioned springs result in a tunable spin-orbit coupling. We elucidate the structure of such a spin-orbit coupling in the extended two-dimensional honeycomb lattice, making connections to physics of graphene. The experimental frequencies and the oscillation patterns of the eigenmodes for the hexagonal ring of pendula are extracted from a spectral analysis of the motion of the pendula in response to an external excitation and are found to be in good agreement with our theoretical predictions. We anticipate that extending this classical analogue of quantum mechanical spin-orbit coupling to two-dimensional lattices will lead to exciting new topological phenomena in classical mechanics.

cond-mat.mes-hall↗

arXiv2017

Bio-inspired hierarchical dissipative metamaterials

Hierarchical structures with constituents over multiple length scales are found in various natural materials like bones, shells, spider silk and others, all of which display enhanced quasi-static mechanical properties, such as high specific strength, stiffness and toughness. At the same time, the role of hierarchy on the dynamic behaviour of metamaterials remains largely unexplored. This study assesses the effect of bio-inspired hierarchical organization as well as of viscoelasticity on the wave attenuation properties of continuous mechanical metamaterials. We consider single-phase metamaterials formed by self-similar unit cells with different hierarchical levels and types of hierarchy. Results highlight a number of advantages through the introduction of structural hierarchy. Band gaps relative to the corresponding non-hierarchical structures are mostly preserved, while additional "hierarchically-induced" band gaps appear. Additionally, the hierarchical configuration allows the tuning of the band gap frequencies of regular metamaterial to lower frequencies, with a simultaneous significant reduction of the global structural weight. We show that even small viscoelastic effects, not treated in the current literature, are essential in determining this behaviour. The approach we propose allows the addition of hierarchical elements to existing metamaterial configurations, with the corresponding improvement of the wave damping properties, thus providing indications for the design of structures for practical applications.

cond-mat.mtrl-sci↗

arXiv2017

Static and dynamic friction of hierarchical surfaces

Hierarchical structures are very common in Nature, but only recently have they been systematically studied in materials physics, in order to understand the specific effects they can have on the mechanical properties of various systems. Structural hierarchy provides a way to tune and optimize macroscopic mechanical properties starting from simple base constituents, and new materials are nowadays designed exploiting this possibility. This can be also true in the field of tribology. In this paper, we study the effect of hierarchical patterned surfaces on the static and dynamic friction coefficients of an elastic material. Our results are obtained by means of numerical simulations using a 1-D spring-block model, which has previously been used to investigate various aspects of friction. Despite the simplicity of the model, we highlight some possible mechanisms that explain how hierarchical structures can significantly modify the friction coefficients of a material, providing a means to achieve tunability.

cond-mat.mtrl-sci↗

arXiv2017

Mechanical Properties and Fracture Patterns of Graphene (Graphitic) Nanowiggles

Graphene nanowiggles (GNW) are graphene-based nanostructures obtained by making alternated regular cuts in pristine graphene nanoribbons. GNW were recently synthesized and it was demonstrated that they exhibit tunable electronic and magnetic properties by just varying their shape. Here, we have investigated the mechanical properties and fracture patterns of a large number of GNW of different shapes and sizes using fully atomistic reactive molecular dynamics simulations. Our results show that the GNW mechanical properties are strongly dependent on its shape and size and, as a general trend narrow sheets have larger ultimate strength and Young's modulus than wide ones. The estimated Young's modulus values were found to be in a range of ~ 100-1000 GPa and the ultimate strength in a range of ~ 20-110 GPa, depending on GNW shape. Also, super-ductile behaviour under strain was observed for some structures.

cond-mat.mtrl-sci↗

arXiv2017

Scale Effects on the Ballistic Penetration of Graphene Sheets

Carbon nanostructures are promising ballistic protection materials, due to their low density and excellent mechanical properties. Recent experimental and computational investigations on the behavior of graphene under impact conditions revealed exceptional energy absorption properties as well. However, the reported numerical and experimental values differ by an order of magnitude. In this work, we combined numerical and analytical modeling to address this issue. In the numerical part, we employed reactive molecular dynamics to carry out ballistic tests on single and double-layered graphene sheets. We used velocity values within the range tested in experiments. Our numerical and the experimental results were used to determine parameters for a scaling law, which is in good agreement with all experimental and simulation results. We find that the specific penetration energy decreases as the number of layers (N) increases, from ~25 MJ/kg for N=1 to ~0.26 MJ/kg as N goes to infinity. These scale effects explain the apparent discrepancy between simulations and experiments.

cond-mat.mtrl-sci↗

arXiv2016

Proof of concept for an ultrasensitive meta-device to detect and localize nonlinear elastic sources

The appearance of nonlinear effects in elastic wave propagation is one of the most reliable and sensitive indicators of the onset of material damage. However, these effects are usually very small and can be detected only using cumbersome digital signal processing techniques. Here, we propose and experimentally validate an alternative approach, using the filtering and focusing properties of elastic metamaterials to naturally select the higher harmonics generated by nonlinear effects and to increase their signal-to noise ratios, enabling the realization of time-reversal procedures for nonlinear elastic source detection. The proposed device demonstrates its potential as an efficient, compact, portable, passive apparatus for nonlinear elastic wave sensing and damage detection.

physics.ins-det↗

arXiv2016

Monte Carlo simulations of measured electron energy-loss spectra of diamond and graphite: role of dielectric-response models

In this work we compare Monte Carlo (MC) simulations of electron transport properties with reflection electron energy loss measurements in diamond and graphite films. We assess the impact of different approximations of the dielectric response on the observables of interest for the characterization of carbon-based materials. We calculate the frequency-dependent dielectric response and energy loss function of these materials in two ways: a full ab initio approach, in which we carry out time-dependent density functional simulations in linear response for different momentum transfers, and a semi-classical model, based on the Drude--Lorentz extension to finite momenta of the optical dielectric function. Ab initio calculated dielectric functions lead to a better agreement with electron energy loss measured spectra with respect the widely used Drude-Lorentz model. This discrepancy is particularly evident for insulators and semiconductors beyond the optical limit ($\mathbf{q} \neq 0$), where single particle excitations become relevant. Furthermore, we show that the behaviour of the energy loss function at different accuracy levels has a dramatic effect on other physical observables, such as the inelastic mean free path and the stopping power in the low energy regime ($< 100$ eV) and thus on the accuracy of MC simulations.

cond-mat.mtrl-sci↗

arXiv2016

Spider-Web Inspired Mechanical Metamaterials

Spider silk is a remarkable example of bio-material with superior mechanical characteristics. Its multilevel structural organization of dragline and viscid silk leads to unusual and tunable properties, extensively studied from a quasi-static point of view. In this study, inspired by the Nephila spider orb web architecture, we propose a novel design for mechanical metamaterials based on its periodic repetition. We demonstrate that spider-web metamaterial structure plays an important role in the dynamic response and wave attenuation mechanisms. The capability of the resulting structure to inhibit elastic wave propagation in sub-wavelength frequency ranges is assessed and parametric studies are performed to derive optimal configurations and constituent mechanical properties. The results show promise for the design of innovative lightweight structures for tunable vibration damping and impact protection, or the protection of large scale infrastructure such as suspended bridges.

cond-mat.mtrl-sci↗

arXiv2016

Wetting theory for small droplets on textured solid surfaces

Conventional wetting theories on rough surfaces with Wenzel, Cassie-Baxter, and Penetrate modes suggest the possibility of tuning the contact angle by adjusting the surface texture. Despite decades of intensive study, there are still many experimental results that are not well understood because conventional wetting theory, which assume an infinite droplet size, has been used to explain measurements of finite-sized droplets. In this study, we suggest a wetting theory that is applicable to any droplet size based on the free energy landscape analysis of various wetting modes of finite-sized droplets on a 2D textured surface. The key finding of our study is that there are many quantized wetting angles with local free energy minima; the implication of this is remarkable. We find that the conventional theories can predict the contact angle at the global free energy minimum if the droplet size is 40 times or larger than the characteristic scale of the surface roughness. Furthermore, we confirm that the pinning origin is the local free energy minima and obtain the energy barriers of pinning as a function of geometric factors. We validate our theory against experimental results on an anisotropic rough surface. In addition, we discuss wetting on a non-uniform rough surface with a rough central region and flat edge. Our findings clarify the extent to which the conventional wetting theory is valid and expand the physical understanding of wetting phenomena of small liquid drops on rough surfaces.

physics.flu-dyn↗

arXiv2016

How graphene flexes and stretches under concomitant bending couples and tractions

We propose a geometrically and physically nonlinear discrete mechanical model of graphene that assigns an energetic cost to changes in bond lengths, bond angles, and dihedral angles. We formulate a variational equilibrium problem for a rectangular graphene sheet with assigned balanced forces and couples uniformly distributed over opposite side pairs. We show that the resulting combination of stretching and bending makes achiral graphene easier to bend and harder (easier) to stretch for small (large) traction loads. Our general developments hold for a wide class of REBO potentials; we illustrate them in detail by numerical calculations performed in the case of a widely used 2nd-generation Brenner potential.

cond-mat.mtrl-sci↗

arXiv2016

Fermentation based carbon nanotube bionic functional composites

The exploitation of the processes used by microorganisms to digest nutrients for their growth can be a viable method for the formation of a wide range of so called biogenic materials that have unique mechanical and physical properties that are not produced by abiotic processes. Based on grape must and bread fermentation, a bionic composite made of carbon nanotubes (CNTs) and single-cell fungi, the Saccharomyces cerevisiae yeast extract, was prepared by fermentation of such microorganisms at room temperature.

cond-mat.mtrl-sci↗

arXiv2015

Towards room-temperature single-layer graphene synthesis by C60 Supersonic Molecular Beam Epitaxy

High-kinetic energy impacts between inorganic surfaces and molecular beams seeded by organics represent a fundamental case study in materials science, most notably when they activate chemical-physical processes leading to nanocrystals growth. Here we demonstrate single-layer graphene synthesis on copper by C60 supersonic molecular beam (SuMBE) epitaxy at 645 °C, with the possibility of further reduction. Using a variety of electron spectroscopy and microscopy techniques, and first-principles simulations, we describe the chemical-physical mechanisms activated by SuMBE resulting in graphene growth. In particular, we find a crucial role of high-kinetic energy deposition in enhancing the organic/inorganic interface interaction, to control the cage openings and to improve the growing film quality. These results, while discussed in the specific case of graphene on copper, are potentially extendable to different metallic or semiconductor substrates and where lower processing temperature is desirable.

cond-mat.mtrl-sci↗

arXiv2013

The Egg of Columbus for making the world toughest fibres

A great flourish of interest in the development of new high-strength and high-toughness materials is taking place in contemporary materials science, with the aim of surpassing the mechanical properties of commercial high-performance fibres. Recently, macroscopic buckypapers, nanotube bundles and graphene sheets have been manufactured. While their macroscopic strength remains 1-2 orders of magnitude lower than their theoretical strength, and is thus comparable to that of current commercial fibres, recent progress has been made in significantly increasing toughness. In particular, researchers have produced extremely tough nanotube fibres with toughness modulus values of up to 570 J/g, 870 J/g and very recently, including graphene, reaching 970 J/g, thus well surpassing that of spider silk (170 J/g, with a record for a giant riverine orb spider of 390 J/g and Kevlar (80 J/g). In this letter, thanks to a new paradigm based on structural mechanics rather than on materials science, we present the Egg of Columbus for making fibres with unprecedented toughness: a slider, in the simplest form just a knot, is introduced as smart frictional element to dissipate energy and in general to reshape the fibre constitutive law, showing evidence of a previously hidden toughness, strictly related to the specific strength of the material. The result is a nearly perfectly plastic constitutive law, with a shape mimicking that of spider silk. The proof of concept is experimentally realized making the world toughest fibre, increasing the toughness modulus of a commercial Endumax fibre from 44 J/g up to 1070 J/g. The maximal achievable toughness is expected for graphene, with an ideal value of 100000 J/g.

cond-mat.mtrl-sci↗

arXiv2009

The Theory of Multiple Peeling

In this paper we solve the multiple peeling problem by applying a fracture mechanics approach to a complex system of films, adhering to the substrate and having a common hinge, where the pulling force is applied. The simplest V-shaped system, consisting of two identical peeling tapes is considered as a case study (to be solved coupling six nonlinear equations); an optimal peeling angle, at which adhesion is maximal, is discovered.

cond-mat.mtrl-sci↗

arXiv2008

Super-Bridges Suspended Over Carbon Nanotube Cables

In this paper the new concept of super-bridges, i.e. kilometre-long bridges suspended over carbon nanotube cables, is introduced. The analysis shows that the use of realistic (thus defective) carbon nanotube bundles as suspension cables can enlarge the current limit main span by a factor of 3.

cond-mat.mtrl-sci↗