arXiv subjects

Nikku Madhusudhan

Publications and source records attributed to Nikku Madhusudhan.

At least 19 recordsLinked to original sources

arXiv2026

Stellar Ages of M Dwarf Hosts of Temperate Sub-Neptunes

Measuring M dwarf ages is a central challenge in stellar astrophysics. These stars evolve so slowly that isochrone fitting gives little constraint, requiring alternative methods based on rotation, activity, and kinematics. Reliable ages help constrain the formation and evolution of planetary systems around M dwarfs, including the temperate sub-Neptunes now being characterised with the James Webb Space Telescope (JWST). We present an age analysis of six nearby M dwarf planet hosts (TOI-732, TOI-736, TOI-270, TOI-1468, TOI-1231, and K2-18) using lithium absorption at 6708 Å, rotation periods, and Galactic kinematics. The Li I 6708 Åfeature is absent above 3$σ$ in all targets, implying substantial depletion and ages exceeding 200 Myr. Rotation periods of 39-145 days yield ages of 2.8-8.6 Gyr, calibrated against open cluster M dwarfs and including the intrinsic dispersion of the rotation-age relation. Kinematic ages span 0.8-13 Gyr with uncertainties of 4-6 Gyr. These are less precise per star but help identify outliers such as TOI-1231 (~13 Gyr) and K2-18 ( ~1-2 Gyr) and place the stars in Galactic context. Rotation yields age constraints 2-6 times tighter than kinematics where periods are measured, and comparable constraints where periods must be inferred from chromospheric activity. Combining multiple indicators enables more secure classification of these stars' evolutionary states, providing reference points for future comparative studies.

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arXiv2026

Sea Ice as an Origin of Life Location for Hycean and Ocean Worlds

Water worlds with potential deep oceans are at the forefront of currently observable exoplanetary habitability. The standard requirements for habitability are the presence of an energy source, a source of nutrients, and a solvent, all of which can be met in exoplanets with deep liquid water oceans. Such planets may be numerous, ranging from hycean worlds and ocean worlds to terrestrial-size planets with enhanced water content. However, abiogenesis requires additional conditions, namely a mechanism to accumulate nutrients to the high concentrations required for prebiotic chemistry, and an energy source to drive the chemistry. A deep ocean, and in some cases the high-pressure ice layers underneath, has traditionally been thought to prevent the required concentrations. Here we outline a location where nutrients could be concentrated in sufficiently high quantities to make abiogenesis possible -- at the interface between the open ocean and the surface ice shelf. Using a 3D General Circulation Model, we explore cases corresponding to several candidate habitable exoplanets which might have dayside sea ice. We discuss how the planet's climate influences the nature and behaviour of the sea ice. We investigate the ability of small-scale ice formation and melting processes to concentrate nutrients to prebiotically useful levels, and also explore the potential for meteoritic impactor fragments to provide a platform for prebiotic chemistry. We find that both of these mechanisms may plausibly provide concentrated chemical feedstock for prebiotic chemistry, which adds an important new perspective when evaluating the prospects of habitability in planets with deep oceans.

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arXiv2026

A Homogeneous Survey of JWST MIRI Transmission Spectra of 10 Exoplanets

The launch of JWST has enabled unprecedented atmospheric characterization of exoplanets. In particular, the JWST-MIRI instrument in the mid-infrared enables probing of molecular species that are harder to detect in the near-infrared. This has come to the fore with the first MIRI-LRS observation of a candidate hycean world, K2-18 b, with potential signs of dimethyl sulfide in its atmosphere. The statistical significance of this result has been debated in subsequent works, arguing instead for the possibility of random noise, instrumental systematics, or a different molecule. The same applies to similar spectra reported for several other exoplanets using MIRI-LRS and interpreted with similar retrieval architectures. In this work, we distinguish between these possibilities with a homogeneous survey of MIRI-LRS transmission spectra of 10 diverse exoplanets, from temperate sub-Neptunes to hot rocky planets and gas giants. We first perform a comparative assessment of the spectra, considering fits with featureless models and pairwise correlations, followed by extensive atmospheric retrievals. With the retrievals, we search for over 150 trace species in the atmosphere of each planet. We find hints of complex molecules in the temperate sub-Neptunes and candidate hycean worlds K2-18 b, TOI-732 c and TOI-270 d, similar to previous works, but not in the other seven planets. Our results indicate that the observed spectral features are likely due to molecular absorption rather than instrument systematics or noise, and underscore these temperate sub-Neptunes as a unique class of planets. More observations are required to robustly identify the specific molecules and constrain the underlying chemical processes, biotic or abiotic.

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arXiv2026

A search for narrowband technosignatures from LTT 3780 with the Allen Telescope Array and the Karl G. Jansky Very Large Array

The LTT3780 system hosts two known exoplanets-LTT3780b, a rocky super-Earth, and LTT3780c, a temperate sub-Neptune-orbiting a nearby M dwarf on opposite sides of the radius valley. LTT3780c has been proposed as a candidate Hycean world, making the system an important target for astrobiological investigation, particularly in light of recent JWST atmospheric observations. Although biosignature and technosignature searches both seek evidence of life beyond Earth, these approaches have historically been pursued independently. Well-characterized exoplanet systems provide an opportunity to combine these complementary search strategies. In this work, we conducted radio technosignature observations of the LTT3780 system using both the Allen Telescope Array (ATA) and the Karl G. Jansky Very Large Array (VLA). The two facilities provide complementary observational capabilities, with the ATA optimized for wide-band multi-beam post-processing analyses and the VLA enabling high-sensitivity real-time interferometric searches. Across approx 30 hr of total observing time, we searched for narrowband Doppler-drifting signals in the frequency range approx 1--10 GHz. After applying comprehensive radio-frequency interference mitigation and multi-beam consistency tests, no candidate signals consistent with astrophysical or technosignature origins were identified. We place minimum detectable effective isotropic radiated power limits of 4.7 X 10^12--3.6 X 10^13W across the observed bands and facilities. Although no technosignatures were detected, this work demonstrates how complementary observation and analysis strategies can be applied to exoplanets of astrobiological interest and serves as a pathfinder for future combined biosignature and technosignature investigations.

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arXiv2026

The Mid-Infrared Transmission Spectrum of the Temperate Sub-Neptune TOI-270 d

Observations of temperate sub-Neptunes with JWST have ushered in a new era for atmospheric characterization of small exoplanets. In particular, the MIRI instrument provides a unique opportunity to search for molecules that are not easily accessible in the near-infrared, as demonstrated by recent mid-infrared observations of K2-18 b. In this work, we present the first mid-infrared transmission spectrum of TOI-270 d observed using the JWST MIRI LRS (5-12 $μ$m) instrument. By leveraging archival MIRI LRS data, we establish a new empirical relation between the detector settling timescale and the flux, which helps accurately model the spectral light curves and improve the precision of the transmission spectrum. We find that there is notable evidence of molecular features in the MIRI transmission spectrum of TOI-270 d, favouring the presence of atmospheric absorption at $\ln B$ = 2.8-5.3 when comparing physically plausible atmospheric models with and without molecular line absorption. The data show excess absorption beyond what could be attributed to CH$_4$ and CO$_2$ detected previously, in line with recent near-infrared results. Through an agnostic search for 203 species, we identify several candidate trace molecules, most of which are complex molecules, evaluate their physical plausibility, and compare them against inferences from near-infrared observations. We also compare the MIRI spectrum of TOI-270 d to that of K2-18 b and find that random or systematic noise is unlikely to explain these observations. Future follow-up observations are necessary to definitively identify the additional absorbers beyond CH$_4$ and CO$_2$. These observations demonstrate the unique capability of JWST MIRI for atmospheric characterisation of temperate sub-Neptunes.

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arXiv2026

Transmission Spectrum of the Benchmark Temperate Exo-Neptune TOI-1231 b

The JWST is revolutionizing our understanding of the temperate sub-Neptune population through atmospheric spectroscopy. The nature of these planets remains debated, as their bulk properties are compatible with a range of interior scenarios, including mini-Neptunes, hycean worlds, and gas dwarfs, with different predicted atmospheric compositions. While theoretical studies have predicted compositional diagnostics for shallow- versus deep-atmosphere scenarios, there is a critical need for empirical constraints for a temperate planet that is a priori known to possess a deep H$_2$-rich atmosphere. The temperate exo-Neptune TOI-1231 b provides one such benchmark target. In this work, we present the JWST near-infrared (0.65--5.2 $μ$m) transmission spectrum of TOI-1231 b, observed with NIRISS single-object slitless spectroscopy and NIRSpec G395H, representing the first for a temperate exo-Neptune. The density of TOI-1231 b requires a thick H$_2$-rich atmosphere, making the planet a keystone reference case for testing mini-Neptune scenarios for sub-Neptunes. We report a strong detection of CH$_4$ ($\ln B = 54.5$-$69.6$) and moderate to strong evidence for CO$_2$ ($\ln B = 2.9$-$6.6$). We do not find significant evidence for any other prominent molecule, although we find high 95\% upper limits on the mixing ratios of NH$_3$ and CO, both of which are expected in deep H$_2$-rich atmospheres. We also do not find any significant evidence for sulfur-bearing species that have been inferred for some temperate sub-Neptunes. This composition is consistent with expectations for a temperate Neptune possessing a deep H$_2$-rich atmosphere with no distinct surface. We discuss the implications of our results for the characterization of temperate sub-Neptunes.

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arXiv2026

A Systematic Search for Trace Molecules in the Atmosphere of Exoplanet K2-18 b

The first transmission spectrum of the habitable-zone sub-Neptune K2-18 b with JWST has opened a new avenue for atmospheric characterisation of temperate low-mass exoplanets. The observations led to inferences of methane and carbon dioxide, as well as of dimethyl sulfide (DMS) and/or dimethyl disulfide (DMDS), both potential biosignatures. In the present work we conduct a broad and agnostic search for other chemical species in the atmosphere of K2-18 b. Our exploration includes 661 molecules, spanning a wide range of trace gases, including biotic, abiotic, and anthropogenic gases on Earth. We investigate possible preference for any of these gases, compared to a model only including the previously-detected CH$_4$ and CO$_2$, using three metrics: (a) preference in the JWST mid-infrared (MIR) spectrum, (b) preference in the JWST near-infrared spectrum, for species preferred in MIR and (c) plausible sources of production. We find that only DMS consistently results in Bayes factors $\ln B \geq 2.0$ across the datasets considered independently, though in the near-infrared this depends on detector offsets, as previously reported. The threshold of $\ln B \geq 2.0$ is motivated by the conventional threshold of $\ln B \geq 2.5$ for moderate preference, allowing for an empirical uncertainty of 0.5. A few other gases also provide comparable fits to a subset of the data or only with some of the retrieval codes used, but with limited known plausible sources. Our study highlights the need for further observations to distinguish between possible trace gases in the atmosphere of K2-18 b and theoretical work to establish their plausible sources.

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arXiv2026

Ecological modelling of hycean worlds

New observations are opening the possibility of characterising habitable environments in exoplanetary systems, with the recent example of the candidate hycean world K2-18 b. This motivates an exploration of the possible ecological conditions on such planets to better interpret biosignatures as well as understand the nature of potential life. On Earth, the Lotka-Volterra equations have been used to model numerous coupled populations within ecosystems, from interactions between large vertebrates, to systems with multiple microbial species. In this work, we apply the Lotka-Volterra equations to the ecology of habitable exoplanets for the first time, focusing on hycean worlds. We simulate scenarios in a vertical water column with between 1-5 bacterial species that thrive in anoxic environments on Earth, i.e. similar to predicted hycean conditions. We find that a wide range of ecological diversity is possible for microbial populations under hycean conditions. We demonstrate that dominating phototrophic bacteria at the top of a water column out-compete deeper dwelling phototrophic bacteria, analogous to bacterial blooms on Earth. Incorporating microbial viruses (bacteriophages) within our models can cause ecosystem collapse depending on the time of their introduction, and such phage inclusion can be beneficial to ecological diversity. Finally, our work shows that bacterial populations inhabiting tidally locked exoplanets may be more stable due to constant illumination of the ocean, but can have lower peak population densities in such cases when compared to seasonal scenarios. Our work provides an initial step towards understanding the possible ecological diversity on habitable worlds beyond Earth.

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arXiv2026

Ground-based Atmospheric Characterization of Super-Earth L 98-59 d at High Spectral Resolution

Atmospheric characterization of exoplanets using ground-based high-resolution transmission spectroscopy has traditionally focussed on large and close-in planets, such as hot Jupiters. In this work, we aim to extend this technique to smaller and more temperate planets by studying the atmospheric composition of the temperate super-Earth planet L 98-59 d ($\sim$$1.5\,\mathrm{R_{\oplus}}$; $\sim$$1.9\,\mathrm{M_{\oplus}}$). Using high-resolution transmission spectra obtained using IGRINS on the Gemini-South telescope, we demonstrate the feasibility for atmospheric characterization of super-Earths using ground-based facilities, and confirm the previous tentative JWST inference of hydrogen sulfide (H2S) in the atmosphere of L 98-59 d at $\lesssim$3.9$\,σ$ ($B\sim390$). This is the first ground-based inference of a molecular species in the atmosphere of a super-Earth planet, and reveals the sensitivity of spectrographs on 8m-class telescopes to the atmospheric characterization of such planets. By exploring a grid of atmospheric models, we find that the data favors a cloud-free atmosphere with an abundance of H2S corresponding to $\sim$1-10$\times$ solar metallicity. We additionally place constraints on the atmospheric abundances of other molecular species. Assuming cloud-free models, super-solar abundances for CH4 and NH3 are ruled out at 3.6$σ$ and $4.6σ$, respectively. Our results are consistent with previous suggestions that L 98-59 d is a super-Earth with possible disequilibrium production of H2S driven by volcanic outgassing from the surface. Future studies combining multiple observations with different facilities may be able to further constrain the atmospheric composition of this planet. This work underscores the promise of atmospheric characterization of super-Earth exoplanets using high-resolution spectroscopy with ground-based facilities.

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arXiv2026

A Narrowband Technosignature Search Toward the Hycean Candidate K2-18b Using the VLA and MeerKAT

K2-18b, a sub-Neptune exoplanet located in the habitable zone of its host star, has emerged as an important target for atmospheric characterization and assessments of potential habitability. Motivated by recent interpretations of JWST observations suggesting a hydrogen-rich atmosphere consistent with Hycean-world scenarios, we conducted a coordinated, multi-epoch search for narrowband radio technosignatures using the Karl G. Jansky Very Large Array equipped with the COSMIC backend and the MeerKAT telescope with the BLUSE backend. Our observations span frequencies from 544MHz to 9.8GHz and include multiple epochs that cover at least one full orbital period of the planet. In this work, we outline, create, and apply a comprehensive post-processing framework that incorporates observatory-informed RFI masking, drift-rate filtering based on the expected dynamics of the K2-18 system, multibeam spatial discrimination, primary and secondary transit filtering (when applicable), and SNR-based excision of weak and strong spurious signals. Across all bands and epochs, no signals consistent with an astrophysical or artificial origin were identified at a limit of 10^12 to 10^13W. These non-detections allow us to place upper limits on the presence of persistent, isotropic narrowband transmitters within the K2-18 system, providing the first interferometric technosignature constraints for a Hycean-planet candidate. Our results demonstrate the efficacy of coordinated multiepoch interferometric searches and establish a methodological framework for future technosignature studies of nearby potentially habitable exoplanets.

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arXiv2025

A JWST Transmission Spectrum of the Temperate Sub-Neptune TOI-732 c

In recent years, JWST has facilitated detections of carbon-bearing molecules in the atmospheres of temperate sub-Neptunes orbiting M dwarfs, ushering in a new era in the characterization of this intriguing planetary regime. We report the transmission spectrum of the temperate sub-Neptune TOI-732 c, observed with JWST NIRISS, NIRSpec G395H and MIRI LRS between 0.9-12 $μ$m. The observations provide evidence for methane (CH$_4$) in a H$_2$-rich atmosphere, at a volume mixing ratio of $\sim$1\%, and non-detection of NH$_3$ and HCN, along with nominal constraints on other prominent molecules H$_2$O, CO and CO$_2$, which are typically expected in H$_2$-rich atmospheres. We conduct a comprehensive survey of 250 chemical species and find moderate to strong evidence (up to $\ln B\sim 5.9$, $3.9σ$) for additional absorption due to one or more complex molecules including higher-order hydrocarbons and/or sulfur-bearing molecules. The spectral features are strongly degenerate among these molecules and with methane, which we find at $\ln B=3.2-8.8$ (up to $3.0-4.6$$σ$) significance. Two complex molecules are preferred with at least moderate evidence ($\ln B \gtrsim 2.5$) in both the near- and mid-infrared, while several others show such evidence in at least one of the two wavelength ranges. The preferred molecules are found in trace quantities on Earth, with no significant sources identified in other planetary atmospheres, requiring future work to assess their physical plausibility in this planet. Future observations are required to resolve the degeneracies and place more robust constraints on these species. We highlight the need for further theoretical and experimental work to robustly characterize the atmospheric and internal composition of TOI-732 c and similar sub-Neptunes.

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arXiv2025

The Surface and Interior Conditions of Temperate Sub-Neptune TOI-270 d

Sub-Neptune planets, with no analogue in our solar system, provide a wealth of information about exoplanet diversity, formation & evolution, and habitability. Their robust characterisation requires the coupling of physically informed atmosphere and interior models with precise atmospheric data to break compositional degeneracies. Recent JWST observations of the temperate sub-Neptune TOI-270 d revealed detections of CH$_4$ and CO$_2$ in its H$_2$-rich atmosphere, with tentative inferences of H$_2$O and CS$_2$ and a non-detection of NH$_3$. We conduct a theoretical exploration of the range of possible interiors for TOI-270 d based on the current observational constraints. We carry out internal structure modelling using a coupled atmosphere-interior model, including self-consistent atmospheric temperature structures informed by JWST observations. The bulk properties permit solutions spanning mini-Neptune, gas dwarf and hycean scenarios, with a wide range of possible surface conditions, which are strongly dependent on the atmospheric properties, including the presence of clouds/hazes. We explore the solutions allowing for surface water oceans on TOI-270 d, including under potentially habitable conditions. The atmospheric mass fractions permitting habitable surface conditions are found to be $\lesssim$$3.5\times10^{-5}$ and pressures $\lesssim$100 bar for the envelope temperature structures considered. We consider mini-Neptune interiors that are sufficiently warm for H$_2$O to be mixed with the H$_2$-rich envelope. Finally, we consider possible gas dwarf interiors, finding H$_2$-rich envelope mass fractions of $\sim$$1-5$ % are required to satisfy the bulk properties, with surface pressures $\sim10^4-10^5$ bar. Further theoretical and experimental studies in addition to future atmospheric observations will aid the characterisation of the possible interior and surface conditions on TOI-270 d.

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arXiv2025

The atmospheric composition of TOI-270 d

The first explorations of temperate sub-Neptune exoplanets have been the hallmark of early JWST observations. The bulk properties of such planets are consistent with a range of possible internal structures, which can be distinguished through their interactions with the observable atmospheres. JWST observations of TOI-270 d, a temperate sub-Neptune, have previously led to contrasting conclusions: either a Hycean world, possessing a liquid water ocean, or a mixed-envelope sub-Neptune, where high temperatures prevent a liquid ocean and lead to a high mean molecular weight atmosphere. In order to resolve this uncertainty, we present a comprehensive retrieval analysis of TOI-270 d using recent NIRISS and NIRSpec transit spectroscopy across $\sim$1-5 $μ$m. We find that prior inferences of a mixed envelope were affected by specific modelling choices leading to a high terminator temperature and high mean-molecular weight in the atmosphere. We confirm an H$_2$-rich atmosphere in TOI-270 d and present revised constraints on the molecular log-mixing ratios and maximal detection significances of CH$_4$ at $-1.86^{+0.30}_{-0.29}$ (6.4 $σ$), CO$_2$ at $-1.71^{+0.38}_{-0.66}$ (3.9 $σ$), H$_2$O at $-1.88^{+0.78}_{-4.13}$ (2.1 $σ$) and CS$_2$ at $-4.74^{+0.65}_{-1.10}$ (2.0 $σ$), with a terminator temperature of $323^{+58}_{-52}$ K at 10 mbar. We also find tentative evidence for more complex methyl-bearing species such as C$_2$H$_6$ and/or DMS at a 2.1-2.5 $σ$ level. The present constraints are consistent with TOI-270 d being a Hycean or dark Hycean world, with planet-wide or nightside liquid water oceans. However, more observations are required to verify the present findings and robustly constrain the atmospheric conditions and internal structure of TOI-270 d.

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arXiv2025

General Circulation Models of Hycean Worlds

Sub-Neptunes represent the current frontier of exoplanet atmospheric characterisation. A proposed subset, Hycean planets, would have liquid water oceans and be potentially habitable, but there are many unanswered questions about their atmospheric dynamics and 3D climate states. To explore such climates in detail, we report a General Circulation Model (GCM) for Hycean worlds, building on a modified version of the ExoCAM GCM. Considering the temperate sub-Neptune K2-18 b as a Hycean candidate, we implement GCMs with different surface pressures and albedos. We find dynamical structures similar to those of tidally-locked terrestrial planets as `slow rotators' with either one equatorial or twin mid-latitude zonal jets. We see moist convective inhibition that matches high resolution models, although in hotter cases the inhibited zone is subsaturated. When imposing a top-of-the-atmosphere (TOA) Bond albedo ($A_b$) by modifying the incident stellar flux, we find that the threshold for K2-18~b to not enter a runaway greenhouse state is $A_b \geq 0.55$ for a 1 bar atmosphere, consistent with previous studies, and $A_b \geq 0.8$ for a 5 bar atmosphere. However, a more realistic treatment of the albedo, by modelling scattering within the atmosphere using an enhanced Rayleigh parametrisation, leads to lower lapse rates and stronger thermal inversions. We find that 1 bar atmospheres are stable for an albedo of $A_b \geq 0.27$, 5 bar atmospheres for $A_b \geq 0.35$, and 10 bar atmospheres for $A_b \geq 0.48$. Moderate albedos such as these are typical of the solar system planets and the required scattering is consistent with observational constraints for K2-18~b, supporting its plausibility as a Hycean world.

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arXiv2025

Exploring the Sub-Neptune Frontier with JWST

Sub-Neptune planets, with sizes and masses between those of Earth and Neptune, dominate the exoplanet population. Sub-Neptunes are expected to be the most diverse family of the exoplanet population, potentially including rocky gas dwarfs, water worlds, and mini-Neptunes, with a wide range of atmospheric, surface and interior conditions. With no analogue in the solar system, these planets open fundamental questions in planetary processes, origins, and habitability, and present new avenues in the search for life elsewhere. Atmospheric observations with the James Webb Space Telescope (JWST) are enabling unprecedented characterization of sub-Neptunes, starting with the first detections of carbon-bearing molecules in the habitable zone sub-Neptune K2-18 b. We survey the present landscape of JWST observations and atmospheric inferences of sub-Neptunes, which in turn provide key insights into their atmospheric processes, internal structures, surface conditions, formation pathways and potential habitability. The atmospheric abundance constraints reveal evidence of chemical disequilibria, and insights into the planetary mass-metallicity relation in the sub-Neptune regime. Similarly, for sub-Neptunes with H$_2$O-rich interiors, increasing atmospheric H$_2$O abundances with the equilibrium temperature may indicate the existence of a critical temperature for transition from H$_2$ dominated atmospheres with tropospheric cold traps to those with steamy atmospheres. The chemical abundances also provide initial evidence for diverse planet types, from potentially habitable hycean worlds to steam worlds with super critical water layers. These planet types serve as benchmarks for an emerging taxonomy of volatile-rich sub-Neptunes as a function of their equilibrium temperature and atmospheric extent, heralding a new era of chemical classification of low-mass exoplanets with JWST.

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arXiv2025

A water-rich interior in the temperate sub-Neptune K2-18 b revealed by JWST

Temperate sub-Neptunes are compelling targets for detecting liquid-water oceans beyond the Solar System. If water-rich and lacking massive hydrogen-helium envelopes, these planets could sustain liquid layers beneath their atmospheres despite sizes larger than Earth. Previous observations of the temperate sub-Neptune K2-18 b revealed an H2-dominated atmosphere rich in CH4, with moderate evidence for CO2 and tentative signs of dimethyl sulfide (DMS). Here we present four new JWST/NIRSpec transit observations of K2-18 b. The resulting high-precision transmission spectrum robustly detects both CH4 and CO2, precisely measuring their abundances and firmly establishing the planet's water-rich nature: either a thick envelope with >10% H2O by volume or a thin atmosphere above a liquid-water ocean. The spectrum reveals no detectable H2O, NH3, or CO. The absence of atmospheric water vapor suggests an efficient cold trap, while the nondetections of NH3 and CO support the scenario of a small H2-rich atmosphere overlying a liquid reservoir. However, alternative models that include these gases can also reproduce the spectrum within uncertainties, highlighting the need for deeper observations. The spectrum only contains marginal signals of DMS, methyl mercaptan (CH3SH), and nitrous oxide (N2O), with none exceeding 3 sigma in model preference and all falling below ~2 sigma without imposing a strong super-Rayleigh haze. Meanwhile, our self-consistent photochemical models show that DMS and CH3SH may form abiotically in massive H2-rich atmospheres of high metallicity, making it important to consider additional indicators for their potential use as biosignatures. K2-18 b, a cool, water-rich world, stands out as one of the most promising temperate sub-Neptunes for exploring the emergence of liquid-water environments in non-Earth-like planets, motivating further characterization of its atmosphere and interior.

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arXiv2025

New Constraints on DMS and DMDS in the Atmosphere of K2-18 b from JWST MIRI

The sub-Neptune frontier has opened a new window into the rich diversity of planetary environments beyond the solar system. The possibility of hycean worlds, with planet-wide oceans and H$_2$-rich atmospheres, significantly expands and accelerates the search for habitable environments elsewhere. Recent JWST transmission spectroscopy of the candidate hycean world K2-18 b in the near-infrared led to the first detections of carbon-bearing molecules CH$_4$ and CO$_2$ in its atmosphere, with a composition consistent with predictions for hycean conditions. The observations also provided a tentative hint of dimethyl sulfide (DMS), a possible biosignature gas, but the inference was of low statistical significance. We report a mid-infrared transmission spectrum of K2-18 b obtained using the JWST MIRI LRS instrument in the ~6-12 $μ$m range. The spectrum shows distinct features and is inconsistent with a featureless spectrum at 3.4-$σ$ significance compared to our canonical model. We find that the spectrum cannot be explained by most molecules predicted for K2-18 b with the exception of DMS and dimethyl disulfide (DMDS), also a potential biosignature gas. We report new independent evidence for DMS and/or DMDS in the atmosphere at 3-$σ$ significance, with high abundance ($\gtrsim$10 ppmv) of at least one of the two molecules. More observations are needed to increase the robustness of the findings and resolve the degeneracy between DMS and DMDS. The results also highlight the need for additional experimental and theoretical work to determine accurate cross sections of important biosignature gases and identify potential abiotic sources. We discuss the implications of the present findings for the possibility of biological activity on K2-18 b.

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arXiv2025

Habitability and Biosignatures

The search for life beyond the solar system is a central goal in exoplanetary science. Exoplanet surveys are increasingly detecting potentially habitable exoplanets and large telescopes in space and on ground are aiming to detect possible biosignatures in their atmospheres. At the same time, theoretical studies are expanding the range of habitable environments beyond the conventional focus on Earth-like rocky planets and biosignatures beyond the dominant biogenic gases in the Earth's atmosphere. The present work provides an introductory compendium of key aspects of habitability and biosignatures of importance to the search for life in exoplanetary environments. Basic concepts of planetary habitability are introduced along with essential requirements for life as we know it and the various factors that affect habitability. These include the requirement for liquid water, energy sources, bioessential elements, and geophysical environmental conditions conducive for life. The factors affecting habitability include both astrophysical conditions, such as those due to the host star, as well as planetary processes, such as atmospheric escape, magnetic interactions, and geological activity. A survey of different types of habitable environments possible in exoplanetary systems is presented. The notion of a biosignature is presented along with examples of biosignatures on Earth and their applicability to habitable environments in exoplanetary systems. The desired properties of an ideal biosignature are discussed, along with considerations of the environmental context and chemical disequilibria in the assessment of biosignatures in diverse environments. A discussion of current state-of-the-art and future prospects in the search for habitable conditions and biosignatures on exoplanets is presented.

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