arXiv subjects

Nikku Madhusudhan

Publications and source records attributed to Nikku Madhusudhan.

At least 37 records · Page 2Linked to original sources

arXiv2025

Characterising M dwarf host stars of two candidate Hycean worlds

Planetary systems orbiting M dwarf host stars are promising targets for atmospheric characterisation of low-mass exoplanets. Accurate characterisation of M dwarf hosts is important for detailed understanding of the planetary properties and physical processes, including potential habitability. Recent studies have identified several candidate Hycean planets orbiting nearby M dwarfs as promising targets in the search for habitability and life on exoplanets. In this study, we characterise two such M dwarf host stars, K2-18 and TOI-732. Using archival photometric and spectroscopic observations, we estimate their effective temperatures (T$_{\mathrm{eff}}$) and metallicities through high-resolution spectral analyses and ages through gyrochronology. We assess the stellar activity of the targets by analysing activity-sensitive chromospheric lines and X-ray luminosities. Additionally, we predict activity cycles based on measured rotation periods and utilise photometric data to estimate the current stellar activity phase. We find K2-18 to be 2.9-3.1 Gyr old with T$_{\mathrm{eff}}$ = 3645$\pm$52 K and metallicity of [Fe/H] = 0.10$\pm$0.12 dex, and TOI-732 to be older (6.7-8.6 Gyr), cooler (3213$\pm$92 K), and more metal-rich ([Fe/H] = 0.22$\pm$0.13 dex). Both stars exhibit relatively low activity making them favourable for atmospheric observations of their planets. The predicted activity cycle and analysis of available high-precision photometry for K2-18 suggest that it might have been near an activity minimum during recent JWST observations, though some residual activity may be expected at such minima. We predict potential activity levels for both targets to aid future observations, and highlight the importance of accurate characterisation of M dwarf host stars for exoplanet characterisation.

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arXiv2025

A new convection scheme for GCMs of temperate sub-Neptunes

Atmospheric characterisation of temperate sub-Neptunes is the new frontier of exoplanetary science with recent JWST observations of possible Hycean world K2-18b. Accurate modelling of atmospheric processes is essential to interpreting high-precision spectroscopic data given the wide range of possible conditions in the sub-Neptune regime, including on potentially habitable planets. Notably, convection is an important process which can operate in different modes across sub-Neptune conditions. Convection can act very differently in atmospheres with a high condensible mass fraction (non-dilute atmospheres) or with a lighter background gas, e.g. water convection in a H$_2$-rich atmosphere, and can be much weaker or even shut down entirely in the latter case. We present a new mass-flux scheme which can capture these variations and simulate convection over a wide range of parameter space for use in 3D general circulation models (GCMs). We validate our scheme for two representative cases, a terrestrial-like atmosphere and a mini-Neptune atmosphere. In the terrestrial case, considering TRAPPIST-1e with an Earth-like atmosphere, the model performs near-identically to Earth-tuned models in an Earth-like convection case. In the mini-Neptune case, considering the bulk properties of K2-18b and assuming a deep H$_2$-rich atmosphere, we demonstrate the capability of the scheme to reproduce non-condensing convection. We find convection occurring at pressures greater than 0.3 bar and the dynamical structure shows high-latitude prograde jets. Our convection scheme will aid in the 3D climate modelling of a wide range of exoplanet atmospheres, and enable further exploration of temperate sub-Neptune atmospheres.

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arXiv2025

Prospects for biological evolution on Hycean worlds

Recent detections of carbon-bearing molecules in the atmosphere of a candidate Hycean world, K2-18 b, with JWST are opening the prospects for characterising potential biospheres on temperate exoplanets. Hycean worlds are a recently theorised class of habitable exoplanets with ocean covered surfaces and hydrogen-rich atmospheres. Hycean planets are thought to be conducive for hosting microbial life under conditions similar to those in the Earth's oceans. In the present work we investigate the potential for biological evolution on Hycean worlds and their dependence on the thermodynamic conditions. We find that a large range of evolutionary rates and origination times are possible for unicellular life in oceanic environments for a relatively marginal range in environmental conditions. For example, a relatively small (10 K) increase in the average ocean temperature can lead to over twice the evolutionary rates, with key unicellular groups originating as early as $\sim$1.3 billion years from origin of life. On the contrary, similar decreases in temperatures can also significantly delay the origination times by several billion years. This delay in turn could affect their observable biomarkers such as dimethylsulfide, which is known to be produced predominantly by Eukaryotic marine phytoplankton in Earth's oceans. Therefore, Hycean worlds that are significantly cooler than Earth may be expected to host simpler microbial life than Earth's oceans and may show weaker biosignatures, unless they orbit significantly older stars than the Sun. Conversely, Hycean worlds with warmer surface temperatures than Earth are more likely to show stronger atmospheric biosignatures due to microbial life if present.

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arXiv2024

The Origin and Evolution of Saturn: A Post-Cassini Perspective

The Saturn System has been studied in detail by the Cassini-Huygens Mission. A major thrust of those investigations has been to understand how Saturn formed and evolved and to place Saturn in the context of other gas giants and planetary systems in general. Two models have been proposed for the formation of the giant planets,the core accretion model and the disk instability model. The heavy element enrichment, core size, and internal structure of Saturn, compared to Jupiter strongly favor the core accretion model as for Jupiter. Two features of the core accretion model that are distinct from the disk instability model are the growth of a core with a mass several times that of the Earth, followed by runaway collapse of gas onto the core once a mass threshold is reached. The heavy element core grows slowly over millions of years through accretion of cm-m sized pebbles, even larger bodies, and moon sized embryos in the gaseous disk. The abundance pattern of heavy elements is thus a key constraint on formation models. C, N, S, and P at Saturn are presently known to varying degree of uncertainty. The He to H ratio in the atmosphere is crucial for understanding heat balance, interior processes, and planetary evolution, but present values at Saturn range from low to high, allowing for a wide range of possibilities. While the very low values are favored to explain excess luminosity, high values might indicate presence of layered convection in the interior, resulting in slow cooling. Additional insight into Saturn's formation comes from the unique data on the rings from Cassini's Grand Finale orbits. While the solar system is the only analog for the extra solar systems, detection of the alkali metals and water in giant exoplanets is useful for understanding the formation and evolution of Saturn, where such data are presently lacking.

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arXiv2024

Considerations for Photochemical Modeling of Possible Hycean Worlds

JWST is revolutionising the study of temperate sub-Neptunes, starting with the first detection of carbon-bearing molecules in the habitable-zone sub-Neptune K2-18 b. The retrieved abundances of CH$_4$ and CO$_2$ and non-detection of NH$_3$ and CO in K2-18 b are consistent with prior predictions of photochemical models for a Hycean world with a habitable ocean. However, recent photochemical modeling raised the prospect that the observed abundances may be explained by a mini-Neptune scenario instead. In this study, we explore these scenarios using independent photochemical modeling with K2-18 b as a case study. We find the previous results to be sensitive to a range of model assumptions, such as the photochemical cross sections, incident stellar spectrum, surface pressure, UV albedo, and metallicity, significantly affecting the resulting abundances. We explore a wide model space to investigate scenarios that are compatible with the retrieved molecular abundances for K2-18 b. Our analysis shows that the previously favoured mini-Neptune scenario is not compatible with most of the retrieved abundances, while the Hycean scenarios, both inhabited and uninhabited, provide better agreement. An uninhabited Hycean scenario explains most of the abundance constraints, except CH$_4$ which is generally underabundant but dependent on the model assumptions. The inhabited Hycean scenario is compatible with all the abundances if the observed CH$_4$ is assumed to be predominantly biogenic. Our results underscore the importance of systematic photochemical modeling and accurate interpretation of chemical abundance constraints for candidate Hycean worlds.

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arXiv2024

Towards a self-consistent evaluation of gas dwarf scenarios for temperate sub-Neptunes

The recent JWST detections of carbon-bearing molecules in a habitable-zone sub-Neptune have opened a new era in the study of low-mass exoplanets. The sub-Neptune regime spans a wide diversity of planetary interiors and atmospheres not witnessed in the solar system, including mini-Neptunes, super-Earths, and water worlds. Recent works have investigated the possibility of gas dwarfs, with rocky interiors and thick H$_2$-rich atmospheres, to explain aspects of the sub-Neptune population, including the radius valley. Interactions between the H$_2$-rich envelope and a potential magma ocean may lead to observable atmospheric signatures. We report a coupled interior-atmosphere modelling framework for gas dwarfs to investigate the plausibility of magma oceans on such planets and their observable diagnostics. We find that the surface-atmosphere interactions and atmospheric composition are sensitive to a wide range of parameters, including the atmospheric and internal structure, mineral composition, volatile solubility and atmospheric chemistry. While magma oceans are typically associated with high-temperature rocky planets, we assess if such conditions may be admissible and observable for temperate sub-Neptunes. We find that a holistic modelling approach is required for this purpose and to avoid unphysical model solutions. We find using our model framework and considering the habitable-zone sub-Neptune K2-18 b as a case study that its observed atmospheric composition is incompatible with a magma ocean scenario. We identify key atmospheric molecular and elemental diagnostics, including the abundances of CO$_2$, CO, NH$_3$ and, potentially, S-bearing species. Our study also underscores the need for fundamental material properties for accurate modelling of such planets.

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arXiv2024

On the Application of Bayesian Leave-One-Out Cross-Validation to Exoplanet Atmospheric Analysis

Over the last decade, exoplanetary transmission spectra have yielded an unprecedented understanding about the physical and chemical nature of planets outside our solar system. Physical and chemical knowledge is mainly extracted via fitting competing models to spectroscopic data, based on some goodness-of-fit metric. However, current employed metrics shed little light on how exactly a given model is failing at the individual data point level and where it could be improved. As the quality of our data and complexity of our models increases, there is an urgent need to better understand which observations are driving our model interpretations. Here we present the application of Bayesian leave-one-out cross-validation to assess the performance of exoplanet atmospheric models and compute the expected log pointwise predictive density (elpd$_\text{LOO}$). elpd$_\text{LOO}$ estimates the out-of-sample predictive accuracy of an atmospheric model at data point resolution providing interpretable model criticism. We introduce and demonstrate this method on synthetic HST transmission spectra of a hot Jupiter. We apply elpd$_\text{LOO}$ to interpret current observations of HAT-P-41b and assess the reliability of recent inferences of H$^-$ in its atmosphere. We find that previous detections of H$^{-}$ are dependent solely on a single data point. This new metric for exoplanetary retrievals complements and expands our repertoire of tools to better understand the limits of our models and data. elpd$_\text{LOO}$ provides the means to interrogate models at the single data point level, a prerequisite for robustly interpreting the imminent wealth of spectroscopic information coming from JWST.

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arXiv2024

The Hycean Paradigm in the Search for Life Elsewhere

The search for habitable conditions and signs of life on exoplanets is a major frontier in modern astronomy. Detecting atmospheric signatures of Earth-like exoplanets is challenging due to their small sizes and relatively thin atmospheres. Recently, a new class of habitable sub-Neptune exoplanets, called Hycean worlds, has been theorized. Hycean worlds are planets with H2-rich atmospheres and planet-wide oceans with thermodynamic conditions similar to those in the Earth's oceans. Their large sizes and extended atmospheres, compared to rocky planets of similar mass, make Hycean worlds significantly more accessible to atmospheric observations. These planets open a new avenue in the search for planetary habitability and life elsewhere using spectroscopic observations with the James Webb Space Telescope (JWST). We observed the transmission spectrum of a candidate Hycean world, K2-18 b, recently with JWST in its first year of operations. The spectrum reveals multiple spectral features of carbon bearing molecules in the planetary atmosphere, leading to the first detections of methane (CH4) and carbon dioxide (CO2) in a habitable-zone exoplanet. We discuss inferences of the atmospheric chemical composition and its implications for the atmospheric, interior and surface conditions on the planet, along with the possibility of a habitable ocean underneath the atmosphere. We discuss new observational and theoretical developments in this emerging frontier and their implications for exoplanetary habitability and search for life elsewhere.

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arXiv2024

Exoplanet Transit Spectroscopy with JWST NIRSpec: Diagnostics and Homogeneous Case Study of WASP-39 b

The JWST has ushered in a new era of exoplanet transit spectroscopy. Among the JWST instruments, the Near-Infrared Spectrograph (NIRSpec) has the most extensive set of configurations for exoplanet time series observations. The NIRSpec Prism and G395H grating represent two extremes in NIRSpec instrument modes, with the Prism spanning a wider spectral range (0.6-5.3 $μ$m at lower resolution (R$\sim$100) compared to G395H (2.87-5.14 $μ$m; R$\sim$2700). In this work, we develop a new data reduction framework, JexoPipe, to conduct a homogeneous assessment of the two NIRSpec modes for exoplanet spectroscopy. We use observations of the hot Saturn WASP-39 b obtained as part of the JWST Transiting Exoplanets ERS program to assess the spectral quality and stability between the two instrument modes at different epochs. We explore the noise sources, effect of saturation, and offsets in transmission spectra between the different instrument modes and also between the two G395H NRS detectors. We find an inter-detector offset in G395H of $\sim$ 40-50 ppm, consistent with recent studies. We find evidence for correlated noise in the Prism white light curve. We find the G395H spectrum to be of higher precision compared to the Prism at the same resolution. We also compare the JexoPipe spectra with those reported from other pipelines. Our work underscores the need for robust assessment of instrument performance and identification of optimal practices for JWST data reduction and analyses.

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arXiv2024

Revealing H$_2$O dissociation in WASP-76~b through combined high- and low-resolution transmission spectroscopy

Numerous chemical constraints have been possible for exoplanetary atmospheres thanks to high-resolution spectroscopy (HRS) from ground-based facilities as well as low-resolution spectroscopy (LRS) from space. These two techniques have complementary strengths, and hence combined HRS and LRS analyses have the potential for more accurate abundance constraints and increased sensitivity to trace species. In this work we retrieve the atmosphere of the ultra-hot Jupiter WASP-76~b, using high-resolution CARMENES/CAHA and low-resolution HST WFC3 and Spitzer observations of the primary eclipse. As such hot planets are expected to have a substantial fraction of H$_2$O dissociated, we conduct retrievals including both H$_2$O and OH. We explore two retrieval models, one with self-consistent treatment of H$_2$O dissociation and another where H$_2$O and OH are vertically-homogeneous. Both models constrain H$_2$O and OH, with H$_2$O primarily detected by LRS and OH through HRS, highlighting the strengths of each technique and demonstrating the need for combined retrievals to fully constrain chemical compositions. We see only a slight preference for the H$_2$O-dissociation model given that the photospheric constraints for both are very similar, indicating $\log(\mathrm{OH/H_2O}) = 0.7^{+0.3}_{-0.3}$ at 1.5~mbar, showing that the majority of the H$_2$O in the photosphere is dissociated. However, the bulk O/H and C/O ratios inferred from the models differs significantly, and highlights the challenge of constraining bulk compositions from photospheric abundances with strong vertical chemical gradients. Further observations with JWST and ground-based facilities may help shed more light on these processes.

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arXiv2024

High-resolution Spectroscopic Reconnaissance of a Temperate Sub-Neptune

The study of temperate sub-Neptunes is the new frontier in exoplanetary science. A major development in the past year has been the first detection of carbon-bearing molecules in the atmosphere of a temperate sub-Neptune, K2-18 b, a possible Hycean world, with the James Webb Space Telescope (JWST). The JWST is poised to characterise the atmospheres of several other such planets with important implications for planetary processes in the temperate regime. Meanwhile, ground-based high-resolution spectroscopy has been highly successful in detecting chemical signatures of giant exoplanets, though low-mass planets have remained elusive. In the present work, we report the atmospheric reconnaissance of a temperate sub-Neptune using ground-based high-resolution transmission spectroscopy. The long orbital period and the low systemic velocity results in a low planetary radial velocity during transit, making this system a valuable testbed for high-resolution spectroscopy of temperate sub-Neptunes. We observe high-resolution time-series spectroscopy in the H- and K-bands during the planetary transit with the IGRINS instrument (R$\sim$45,000) on Gemini-South. Using observations from a single transit we find marginal evidence (2.2$σ$) for the presence of methane (CH$_4$) in the atmosphere and no evidence for ammonia (NH$_3$) despite its strong detectability for a cloud-free H$_2$-rich atmosphere. We assess our findings using injection tests with different atmospheric scenarios, and find them to be consistent with a high CH$_4$/NH$_3$ ratio and/or the presence of high-altitude clouds. Our results demonstrate the capability of Gemini-S/IGRINS for atmospheric characterization of temperate sub-Neptunes, and the complementarity between space- and ground-based facilities in this planetary regime.

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arXiv2024

Feasibility of High-Resolution Transmission Spectroscopy for Low-Velocity Exoplanets

In recent years, high-resolution transmission spectroscopy in the near-infrared has led to detections of prominent molecules in several giant exoplanets on close-in orbits. This approach has traditionally relied on the large Doppler shifts of the planetary spectral lines induced by the high velocities of the close-in planets, which were considered necessary for separating them from the quasi-static stellar and telluric lines. In this work we demonstrate the feasibility of high-resolution transmission spectroscopy for chemical detections in atmospheres of temperate low-mass exoplanets around M dwarfs with low radial velocity variation during transit. We pursue this goal using model injection and recovery tests with H- and K- band high-resolution spectroscopy of the temperate sub-Neptune TOI-732 c, observed using the IGRINS spectrograph on Gemini-S. We show that planetary signals in transit may be recovered when the change in the planet's radial velocity is very small, down to sub-pixel velocities. This is possible due to the presence of the planetary signal in only a subset of the observed spectra. A sufficient number of out-of-transit spectra can create enough contrast between the planet signal and telluric/stellar contaminants that the planet signal does not constitute a principal component of the time-series spectra and can therefore be isolated using PCA-based detrending without relying on a significant Doppler shift. We additionally explore novel metrics for finding such signals, and investigate trends in their detectability. Our work extends the scope of high-resolution transmission spectroscopy and creates a pathway towards the characterisation of habitable sub-Neptune worlds with ground-based facilities.

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arXiv2024

VIRA: An Exoplanet Atmospheric Retrieval Framework for JWST Transmission Spectroscopy

JWST observations are leading to important new insights into exoplanetary atmospheres through transmission spectroscopy. In order to harness the full potential of the broad spectral range and high sensitivity of JWST, atmospheric retrievals of exoplanets require a high level of robustness and accuracy in the underlying models. We present the VIRA retrieval framework which implements a range of modelling and inference capabilities motivated by early JWST observations of exoplanet transmission spectra. This includes three complementary approaches to modelling atmospheric composition, three atmospheric aerosol models, including a physically-motivated Mie scattering approach, and consideration of correlated noise. VIRA enables a cascading retrieval architecture involving a sequence of retrievals with increasing sophistication. We demonstrate VIRA using a JWST transmission spectrum of the hot Saturn WASP-39 b in the $\sim$1-5 $μ$m range. In addition to confirming prior chemical inferences, we retrieve molecular abundances for H$_2$O, CO, CO$_2$, SO$_2$ and H$_2$S, resulting in super-solar elemental abundances of log(O/H)=$-2.0\pm0.2$, log(C/H)=$-2.1\pm0.2$ and log(S/H)=$-3.6\pm0.2$, along with C/O and S/O ratios of $0.83^{+0.05}_{-0.07}$ and $0.029^{+0.012}_{-0.009}$, respectively, in the free chemistry case. The abundances correspond to $20.1^{+10.5}_{-8.1}\times$, $28.2^{+16.3}_{-12.1}\times$ and $20.8^{+10.3}_{-7.5}\times$ solar values for O/H, C/H and S/H, respectively, compared to C/H $= 8.67\pm0.35 \times$ solar for Saturn. Our results demonstrate how JWST transmission spectroscopy combined with retrieval frameworks like VIRA can measure multi-elemental abundances for giant exoplanets and enable comparative characterisation with solar system planets.

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arXiv2024

Possible Hycean conditions in the sub-Neptune TOI-270 d

The JWST has ushered in a new era in atmospheric characterisations of temperate low-mass exoplanets with recent detections of carbon-bearing molecules in the candidate Hycean world K2-18 b. We investigated JWST observations of the TOI-270 system, with two sub-Neptunes simultaneously transiting the nearby M dwarf during the visit. We report our atmospheric characterisation of the outer planet TOI-270 d, a candidate Hycean world, with JWST transmission spectroscopy using the NIRSpec G395H instrument in the 2.7-5.2 $μ$m range, combined with previous observations obtained with the HST WFC3 spectrograph (1.1-1.6 $μ$m). The spectrum reveals strong signatures of CH4 and CO2 at 3.8-4.9$σ$ and 2.9-3.9$σ$ confidence, respectively, and no evidence of NH3. The abundant CH4 and CO2, at ~0.1-1% mixing ratios, and the non-detection of NH3 are similar to the findings reported for K2-18 b and consistent with predictions for a Hycean world with a planet-wide ocean under a H2-rich atmosphere. We also report evidence of CS2 at a 2.3-3.0$σ$ confidence and a potential inference of H2O at 1.6-4.4$σ$, depending on the data analysis approach, and discuss possible interpretations of these results. The spectrum does not provide strong constraints on the presence of clouds or hazes in the observable atmosphere, nor any evidence for the effects of stellar heterogeneities, which is consistent with previous studies. For the smaller inner planet TOI-270 b, we find that the spectrum is inconsistent with a featureless spectrum at ~3$σ$, showing some preference for an H2-rich atmosphere in a super-Earth. We discuss the implications of our findings and future prospects.

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arXiv2024

On the Ocean Conditions of Hycean Worlds

Recent studies have suggested the possibility of Hycean worlds, characterised by deep liquid water oceans beneath H$_2$-rich atmospheres. These planets significantly widen the range of planetary properties over which habitable conditions could exist. We conduct internal structure modelling of Hycean worlds to investigate the range of interior compositions, ocean depths and atmospheric mass fractions possible. Our investigation explicitly considers habitable oceans, where the surface conditions are limited to those that can support potential life. The ocean depths depend on the surface gravity and temperature, confirming previous studies, and span 10s to $\sim$1000 km for Hycean conditions, reaching ocean base pressures up to $\sim$6$\times$10$^4$ bar before transitioning to high-pressure ice. We explore in detail test cases of five Hycean candidates, placing constraints on their possible ocean depths and interior compositions based on their bulk properties. We report limits on their atmospheric mass fractions admissible for Hycean conditions, as well as those allowed for other possible interior compositions. For the Hycean conditions considered, across these candidates we find the admissible mass fractions of the H/He envelopes to be $\lesssim$10$^{-3}$. At the other extreme, the maximum H/He mass fractions allowed for these planets can be up to $\sim$4-8$\%$, representing purely rocky interiors with no H$_2$O layer. These results highlight the diverse conditions possible among these planets and demonstrate their potential to host habitable conditions under vastly different circumstances to the Earth. Upcoming JWST observations of candidate Hycean worlds will allow for improved constraints on the nature of their atmospheres and interiors.

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arXiv2023

Carbon-bearing Molecules in a Possible Hycean Atmosphere

The search for habitable environments and biomarkers in exoplanetary atmospheres is the holy grail of exoplanet science. The detection of atmospheric signatures of habitable Earth-like exoplanets is challenging due to their small planet-star size contrast and thin atmospheres with high mean molecular weight. Recently, a new class of habitable exoplanets, called Hycean worlds, has been proposed, defined as temperate ocean-covered worlds with H2-rich atmospheres. Their large sizes and extended atmospheres, compared to rocky planets of the same mass, make Hycean worlds significantly more accessible to atmospheric spectroscopy with the JWST. Here we report a transmission spectrum of the candidate Hycean world, K2-18 b, observed with the JWST NIRISS and NIRSpec instruments in the 0.9-5.2 $μ$m range. The spectrum reveals strong detections of methane (CH4) and carbon dioxide (CO2) at 5$σ$ and 3$σ$ confidence, respectively, with high volume mixing ratios of ~1% each in a H2-rich atmosphere. The abundant CH4 and CO2 along with the non-detection of ammonia (NH3) are consistent with chemical predictions for an ocean under a temperate H2-rich atmosphere on K2-18 b. The spectrum also suggests potential signs of dimethyl sulfide (DMS), which has been predicted to be an observable biomarker in Hycean worlds, motivating considerations of possible biological activity on the planet. The detection of CH4 resolves the long-standing missing methane problem for temperate exoplanets and the degeneracy in the atmospheric composition of K2-18 b from previous observations. We discuss possible implications of the findings, open questions, and future observations to explore this new regime in the search for life elsewhere.

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arXiv2023

Chemical Conditions on Hycean Worlds

Traditionally, the search for life on exoplanets has been predominantly focused on rocky exoplanets. Hycean worlds are a class of habitable sub-Neptunes with planet-wide oceans and H2-rich atmospheres. Their broad range of possible sizes and temperatures lead to a wide habitable zone and high potential for discovery and atmospheric characterization using transit spectroscopy. Over a dozen candidate Hycean planets are already known to be transiting nearby M dwarfs, making them promising targets for atmospheric characterization with the James Webb Space Telescope (JWST). In this work, we investigate possible chemical conditions on a canonical Hycean world, focusing on (a) the present and primordial molecular composition of the atmosphere, and (b) the inventory of bioessential elements for the origin and sustenance of life in the ocean. Based on photochemical and kinetic modeling for a range of conditions, we discuss the possible chemical evolution and observable present-day composition of its atmosphere. In particular, for reduced primordial conditions the early atmospheric evolution passes through a phase that is rich in organic molecules that could provide important feedstock for prebiotic chemistry. We investigate avenues for delivering bioessential metals to the ocean, considering the challenging lack of weathering from a rocky surface and the ocean separated from the rocky core by a thick icy mantle. Based on ocean depths from internal structure modelling and elemental estimates for the early Earth's oceans, we estimate the requirements for bioessential metals in such a planet. We find that the requirements can be met for plausible assumptions about impact history and atmospheric sedimentation, and supplemented by other steady state sources. We discuss the observational prospects for atmospheric characterisation of Hycean worlds.

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arXiv2023

Exoplanet Spectroscopy with JWST NIRISS: Diagnostics and Case Studies

The James Webb Space Telescope (JWST) is ushering in a new era in remote sensing of exoplanetary atmospheres. Atmospheric retrievals of exoplanets can be highly sensitive to high-precision JWST data. It is, therefore, imperative to characterise the instruments and noise sources using early observations to enable robust characterisation of exoplanetary atmospheres using JWST-quality spectra. The present work is a step in that direction, focusing on the NIRISS SOSS instrument mode, with a wavelength coverage of 0.6 - 2.8 μm and R ~ 700. Using a custom-built pipeline, JExoRes, we investigate key diagnostics of NIRISS SOSS with observations of two giant exoplanets, WASP-39 b and WASP-96 b, as case studies. We conduct a detailed evaluation of the different aspects of the data reduction and analysis, including sources of contamination, 1/f noise, and system properties such as limb darkening. The slitless nature of NIRISS SOSS makes it susceptible to contamination due to background sources. We present a method to model and correct for dispersed field stars which can significantly improve the accuracy of the observed spectra. In doing so, we also report an empirically determined throughput function for the instrument. We find significant correlated noise in the derived spectra, which may be attributed to 1/f noise, and discuss its implications for spectral binning. We quantify the covariance matrix which would enable the consideration of correlated noise in atmospheric retrievals. Finally, we conduct a comparative assessment of NIRISS SOSS spectra of WASP-39 b reported using different pipelines and highlight important lessons for exoplanet spectroscopy with JWST NIRISS.

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