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Nikolay Zhelev

Publications and source records attributed to Nikolay Zhelev.

9 recordsLinked to original sources

Chiral superfluid helium-3 in the quasi-two-dimensional limit

Anisotropic pair breaking close to surfaces favors the chiral A phase of the superfluid $^3$He over the time-reversal invariant B phase. Confining the superfluid $^3$He into a cavity of height $D$ of the order of the Cooper pair size characterized by the coherence length $\xi_0$ - ranging between 16 nm (34 bar) and 77 nm (0 bar) - extends the surface effects over the whole sample volume, thus allowing stabilization of the A phase at pressures $P$ and temperatures $T$ where otherwise the B phase would be stable. In this Letter, the surfaces of such a confined sample are covered with a superfluid $^4$He film to create specular quasiparticle scattering boundary conditions, preventing the suppression of the superfluid order parameter. We show that the chiral A phase is the stable superfluid phase under strong confinement over the full $P$-$T$ phase diagram down to a quasi-two-dimensional limit $D / \xi_0 = 1$ , where $D = 80$ nm. The planar phase, which is degenerate with the chiral A phase in the weak-coupling limit, is not observed. The gap inferred from measurements over the wide pressure range from 0.2 to 21.0 bar leads to an empirical ansatz for temperature-dependent strong-coupling effects. We discuss how these results pave the way for the realization of the fully gapped two-dimensional $p_x + ip_y$ superfluid under more extreme confinement.

cond-mat.supr-con

Formation and Microwave Losses of Hydrides in Superconducting Niobium Thin Films Resulting from Fluoride Chemical Processing

Superconducting Nb thin films have recently attracted significant attention due to their utility for quantum information technologies. In the processing of Nb thin films, fluoride-based chemical etchants are commonly used to remove surface oxides that are known to affect superconducting quantum devices adversely. However, these same etchants can also introduce hydrogen to form Nb hydrides, potentially negatively impacting microwave loss performance. Here, we present comprehensive materials characterization of Nb hydrides formed in Nb thin films as a function of fluoride chemical treatments. In particular, secondary-ion mass spectrometry, X-ray scattering, and transmission electron microscopy reveal the spatial distribution and phase transformation of Nb hydrides. The rate of hydride formation is determined by the fluoride solution acidity and the etch rate of Nb2O5, which acts as a diffusion barrier for hydrogen into Nb. The resulting Nb hydrides are detrimental to Nb superconducting properties and lead to increased power-independent microwave loss in coplanar waveguide resonators. However, Nb hydrides do not correlate with two-level system loss or device aging mechanisms. Overall, this work provides insight into the formation of Nb hydrides and their role in microwave loss, thus guiding ongoing efforts to maximize coherence time in superconducting quantum devices.

cond-mat.mtrl-sci

Supercooling of the A phase of $^3$He

Because of the extreme purity, lack of disorder, and complex order parameter, the first-order superfluid $^3$He A-B transition is the leading model system for first order transitions in the early universe. Here we report on the path dependence of the supercooling of the A phase over a wide range of pressures below 29.3 bar at nearly zero magnetic field. The A phase can be cooled significantly below the thermodynamic A-B transition temperature. While the extent of supercooling is highly reproducible, it depends strongly upon the cooling trajectory: The metastability of the A phase is enhanced by transiting through regions where the A phase is more stable. We provide evidence that some of the additional supercooling is due to the elimination of B phase seeds formed upon passage through the superfluid transition. A greater understanding of the physics is essential before the $^3$He can be exploited to model transitions in the early universe.

cond-mat.other

Lateral electrodeposition of MoS2 semiconductor over an insulator

Developing novel techniques for depositing transition metal dichalcogenides is crucial for the industrial adoption of 2D materials in optoelectronics. In this work, the lateral growth of molybdenum disulfide (MoS2) over an insulating surface is demonstrated using electrochemical deposition. By fabricating a new type of microelectrodes, MoS2 2D films grown from TiN electrodes across opposite sides have been connected over an insulating substrate, hence, forming a lateral device structure through only one lithography and deposition step. Using a variety of characterization techniques, the growth rate of MoS2 has been shown to be highly anisotropic with lateral to vertical growth ratios exceeding 20-fold. Electronic and photo-response measurements on the device structures demonstrate that the electrodeposited MoS2 layers behave like semiconductors, confirming their potential for photodetection applications. This lateral growth technique paves the way towards room temperature, scalable and site-selective production of various transition metal dichalcogenides and their lateral heterostructures for 2D materials-based fabricated devices.

physics.app-ph

Phase Change Memory by GeSbTe Electrodeposition in Crossbar Arrays

Phase change memories (PCM) is an emerging type of non-volatile memory that has shown a strong presence in the data-storage market. This technology has recently attracted significant research interest in the development of non-Von Neumann computing architectures such as in-memory and neuromorphic computing. Research in these areas has been primarily motivated by the scalability potential of phase change materials and their compatibility with industrial nanofabrication processes. In this work, we are presenting our development of crossbar phase change memory arrays through the electrodeposition of GeSbTe (GST). We show that GST can be electrodeposited in microfabricated TiN crossbar arrays using a scalable process. Our phase switching test of the electrodeposited materials have shown that a SET/RESET resistance ratio of 2-3 orders of magnitude is achievable with a switching endurance of around 80 cycles. These results represent the first phase switching of electrodeposited GeSbTe in microfabricated crossbar arrays. Our work paves the way towards developing large memory arrays involving electrodeposited materials for passive selectors and phase switching devices. It also opens opportunities for developing a variety of different electronic devices using electrodeposited materials.

cond-mat.mtrl-sci

Path-Dependent Supercooling of the $^3$He Superfluid A-B transition

We examine the discontinuous first-order superfluid $^3$He A to B transition in the vicinity of the polycritical point (2.232 mK and 21.22 bar). We find path-dependent transitions: cooling at fixed pressure yields a well defined transition line in the temperature-pressure plane, but this line can be reliably crossed by depressurizing at nearly constant temperature after transiting $T_{\rm c}$ at a higher pressure. This path dependence is not consistent with any of the standard B-phase nucleation mechanisms in the literature. This symmetry breaking transition is a potential simulator for first order transitions in the early universe.

cond-mat.supr-con

Evidence for a Spatially-Modulated Superfluid Phase of $^3$He under Confinement

In superfluid $^3$He-B confined in a slab geometry, domain walls between regions of different order parameter orientation are predicted to be energetically stable. Formation of the spatially-modulated superfluid stripe phase has been proposed. We confined $^3$He in a 1.1 $μ$m high microfluidic cavity and cooled it into the B phase at low pressure, where the stripe phase is predicted. We measured the surface-induced order parameter distortion with NMR, sensitive to the formation of domains. The results rule out the stripe phase, but are consistent with 2D modulated superfluid order.

cond-mat.other

Transfer Printing of CVD Graphene FETs on Patterned Substrates

We describe a simple and scalable method for the transfer of CVD graphene for the fabrication of field effect transistors. This is a dry process that uses a modified RCA cleaning step to improve the surface quality. In contrast to conventional fabrication routes where lithographic steps are performed after the transfer, here graphene is transferred to a pre-patterned substrate. The resulting FET devices display nearly zero Dirac voltage, and the contact resistance between the graphene and metal contacts is on the order of 910 +- 340 Ohm-micrometer. This approach enables formation of conducting graphene channel lengths up to one millimeter. The resist-free transfer process provides a clean graphene surface that is promising for use in high sensitivity graphene FET biosensors.

cond-mat.mes-hall

Study of superfluid $^3$He under nanoscale confinement. A new approach to the investigation of superfluid $^3$He films

We review recent experiments in which superfluid $^3$He has been studied under highly controlled confinement in nanofluidic sample chambers. We discuss the experimental challenges and their resolution. These methods open the way to a systematic investigation of the superfluidity of $^3$He films, and the surface and edge excitations of topological superfluids.

cond-mat.other