arXiv subjects

Paola Caselli

Publications and source records attributed to Paola Caselli.

At least 109 records · Page 6Linked to original sources

arXiv2023

Velocity-Coherent Substructure in TMC-1: Inflow and Fragmentation

Filamentary structures have been found nearly ubiquitously in molecular clouds and yet their formation and evolution is still poorly understood. We examine a segment of Taurus Molecular Cloud 1 (TMC-1) that appears as a single, narrow filament in continuum emission from dust. We use the Regularized Optimization for Hyper-Spectral Analysis (ROHSA), a Gaussian decomposition algorithm which enforces spatial coherence when fitting multiple velocity components simultaneously over a data cube. We analyze HC$_5$N (9-8) line emission as part of the Green Bank Ammonia Survey (GAS) and identify three velocity-coherent components with ROHSA. The two brightest components extend the length of the filament, while the third component is fainter and clumpier. The brightest component has a prominent transverse velocity gradient of $2.7 \pm 0.1$ km s$^{-1}$ pc$^{-1}$ that we show to be indicative of gravitationally induced inflow. In the second component, we identify regularly spaced emission peaks along its length. We show that the local minima between pairs of adjacent HC$_5$N peaks line up closely with submillimetre continuum emission peaks, which we argue is evidence for fragmentation along the spine of TMC-1. While coherent velocity components have been described as separate physical structures in other star-forming filaments, we argue that the two bright components identified in HC$_5$N emission in TMC-1 are tracing two layers in one filament: a lower density outer layer whose material is flowing under gravity towards the higher density inner layer of the filament.

astro-ph.GA↗

arXiv2023

Cyanopolyyne chemistry in the L1544 prestellar core: new insights from GBT observations

We report a comprehensive study of the cyanopolyyne chemistry in the prototypical prestellar core L1544. Using the 100m Robert C. Byrd Green Bank Telescope (GBT) we observe 3 emission lines of HC$_3$N, 9 lines of HC$_5$N, 5 lines of HC$_7$N, and 9 lines of HC$_9$N. HC$_9$N is detected for the first time towards the source. The high spectral resolution ($\sim$ 0.05 km s$^{-1}$) reveals double-peak spectral line profiles with the redshifted peak a factor 3-5 brighter. Resolved maps of the core in other molecular tracers indicates that the southern region is redshifted. Therefore, the bulk of the cyanopolyyne emission is likely associated with the southern region of the core, where free carbon atoms are available to form long chains, thanks to the more efficient illumination of the interstellar field radiation. We perform a simultaneous modelling of the HC$_5$N, HC$_7$N, and HC$_9$N lines, to investigate the origin of the emission. To enable this analysis, we performed new calculation of the collisional coefficients. The simultaneous fitting indicates a gas kinetic temperature of 5--12 K, a source size of 80$\arcsec$, and a gas density larger than 100 cm$^{-3}$. The HC$_5$N:HC$_7$N:HC$_9$N abundance ratios measured in L1544 are about 1:6:4. We compare our observations with those towards the the well-studied starless core TMC-1 and with the available measurements in different star-forming regions. The comparison suggests that a complex carbon chain chemistry is active in other sources and it is related to the presence of free gaseous carbon. Finally, we discuss the possible formation and destruction routes in the light of the new observations.

astro-ph.GA↗

arXiv2023

Bombardment of CO ice by cosmic rays: I. Experimental insights into the microphysics of molecule destruction and sputtering

We present a dedicated experimental study of microscopic mechanisms controlling radiolysis and sputtering of astrophysical ices due to their bombardment by cosmic ray ions. Such ions are slowed down due to inelastic collisions with bound electrons, resulting in ionization and excitation of ice molecules. In experiments on CO ice irradiation, we show that the relative contribution of these two mechanisms of energy loss to molecule destruction and sputtering can be probed by selecting ion energies near the peak of the electronic stopping power. We have observed a significant asymmetry, both in the destruction cross section and the sputtering yield, for pairs of ion energies corresponding to same values of the stopping power on either side of the peak. This implies that the stopping power does not solely control these processes, as usually assumed in the literature. Our results suggest that electronic excitations represent a significantly more efficient channel for radiolysis and, possibly, also for sputtering of CO ice. We also show that the charge state of incident ions as well as the rate for CO$^+$ production in the ice have negligible effect on these processes.

astro-ph.IM↗

arXiv2022

First detection of CHD$_{2}$OH towards pre-stellar cores

The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation of methanol, CH$_{3}$OH, towards two starless and two pre-stellar cores. We derive a D/H ratio of 0.8-1.9$\%$ with CH$_{2}$DOH in pre-stellar cores H-MM1 and L694-2, consistent with measurements in more evolved Class 0/I objects and comet 67P/Churyumov-Gerasimenko, suggesting a direct chemical link arising in the pre-stellar stage. Furthermore, the column density ratios of CHD$_{2}$OH/CH$_{2}$DOH are $\sim$50-80$\%$, consistently high as that towards Class 0/I objects, indicating an efficient formation mechanism of CHD$_{2}$OH, possibly through H atom additions to D$_{2}$CO. The CH$_{2}$DOH/CH$_{3}$OH and CHD$_{2}$OH/CH$_{3}$OH column density ratios in the two pre-stellar cores are larger than that in the two starless cores B68 and L1521E, representing an evolutionary trend of methanol deuteration in early-stage cores.

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arXiv2022

The Cosmic-Ray Induced Sputtering Process On Icy Grains

In molecular cloud cores, the cosmic ray (CR) induced sputtering via CR ion-icy grain collision is one of the desorption processes for ice molecules from mantles around dust grains. The efficiency of this process depends on the incident CR ion properties as well as the physicochemical character of the ice mantle. Our main objective is the examination of the sputtering efficiency for H$_2$O and CO ices found in molecular cloud cores. In the calculation routine, we consider a multi-dimensional parameter space that consists of thirty CR ion types, five different CR ion energy flux distributions, two separate ice mantle components (pure H$_2$O and CO), three ice formation states, and two sputtering regimes (linear and quadratic). We find that the sputtering behavior of H$_2$O and CO ices is dominated by the quadratic regime rather than the linear regime, especially for CO sputtering. The sputtering rate coefficients for H$_2$O and CO ices show distinct variations with respect to the adopted CR ion energy flux as well as the grain size-dependent mantle depth. The maximum radius of the cylindrical latent region is quite sensitive to the effective electronic stopping power. The track radii for CO ice are much bigger than H$_2$O ice values. In contrast to the H$_2$O mantle, even relatively light CR ions ($Z \geq 4$) may lead to a track formation within the CO mantle, depending on ${\rm S_{\rm e,eff}}$. We suggest that the latent track formation threshold can be assumed as a separator between the linear and the quadratic regimes for sputtering.

astro-ph.EP↗

arXiv2022

Dust grains cannot grow to millimeter sizes in protostellar envelopes

A big question in the field of star and planet formation is the time at which substantial dust grain growth occurs. The observed properties of dust emission across different wavelength ranges have been used as an indication that millimeter-sized grains are already present in the envelopes of young protostars. However, this interpretation is in tension with results from coagulation simulations, which are not able to produce such large grains in these conditions. In this work, we show analytically that the production of millimeter-sized grains in protostellar envelopes is impossible under the standard assumptions about the coagulation process. We discuss several possibilities that may serve to explain the observed dust emission in the absence of in-situ grain growth to millimeter sizes.

astro-ph.GA↗

arXiv2022

Role of Filamentary Structures in the Formation of Two Dense Cores, L1544 and L694-2

We present mapping results of two prestellar cores, L1544 and L694-2, embedded in filamentary clouds in C$^{18}$O (3-2), $^{13}$CO (3-2), $^{12}$CO (3-2), HCO$^+$ (4-3), and H$^{13}$CO$^+$ (4-3) with the JCMT telescope to examine the role of the filamentary structures in the formation of dense cores in the clouds, with new distance estimates for L1544 ($175_{-3}^{+4}$ pc) and L694-2 ($203_{-7}^{+6}$ pc). From these observations, we found that the non-thermal velocity dispersion of two prestellar cores and their surrounding clouds are smaller than or comparable to the sound speed. This may indicate that the turbulence has already been dissipated for both filaments and cores during their formation time. We also found a $λ/4$ shift between the periodic oscillations in the velocity and the column density distributions implying the possible presence of gravitational core-forming flow motion along the axis of the filament. The mass accretion rates due to these flow motions are estimated to be 2-3 M$_\odot$ Myr$^{-1}$, being comparable to that for Serpens cloud but much smaller than those for the Hub filaments, cluster, or high mass forming filaments by 1 or 2 order of magnitudes. From this study, we suggest that the filaments in our targets might be formed from the shock-compression of colliding clouds, and then the cores are formed by gravitational fragmentation of the filaments to evolve to the prestellar stage. We conclude that the filamentary structures in the clouds play an important role in the entire process of formation of dense cores and their evolution.

astro-ph.GA↗

arXiv2022

Tracking the ice mantle history in the Solar-type Protostars of NGC 1333 IRAS 4

To understand the origin of the diversity observed in exoplanetary systems, it is crucial to characterize the early stages of their formation, represented by Solar-type protostars. Likely, the gaseous chemical content of these objects directly depends on the composition of the dust grain mantles formed before the collapse. Directly retrieving the ice mantle composition is challenging, but it can be done indirectly by observing the major components, such as NH3 and CH3OH at cm wavelengths, once they are released into the gas-phase during the warm protostellar stage. We observed several CH3OH and NH3 lines toward three Class 0 protostars in NGC1333 (IRAS 4A1, IRAS 4A2, and IRAS 4B), at high angular resolution (1"; ~300 au) with the VLA interferometer at 24-26 GHz. Using a non-LTE LVG analysis, we derived a similar NH3/CH3OH abundance ratio in the three protostars (<0.5, 0.015-0.5, and 0.003-0.3 for IRAS 4A1, 4A2, and 4B, respectively). Hence, we infer they were born from pre-collapse material with similar physical conditions. Comparing the observed abundance ratios with astrochemical model predictions, we constrained the dust temperature at the time of the mantle formation to be ~17 K, which coincides with the average temperature of the southern NGC 1333 diffuse cloud. We suggest that a brutal event started the collapse that eventually formed IRAS 4A1, 4A2 and 4B, which,therefore, did not experience the usual pre-stellar core phase. This event could be the clash of a bubble with NGC 1333 south, that has previously been evoked in the literature.

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arXiv2022

Nitrogen fractionation towards a pre-stellar core traces isotope-selective photodissociation

Isotopologue abundance ratios are important to understand the evolution of astrophysical objects and ultimately the origins of a planetary system like our own. Being nitrogen a fundamental ingredient of pre-biotic material, understanding its chemistry and inheritance is of fundamental importance to understand the formation of the building blocks of life. We present here single-dish observations of the ground state rotational transitions of the $^{13}$C and $^{15}$N isotopologues of HCN, HNC and CN with the IRAM 30m telescope. We analyse their column densities and compute the $^{14}$N/$^{15}$N ratio map for HCN. The $^{15}$N-fractionation of CN and HNC is computed towards different offsets across L1544. The $^{15}$N-fractionation map of HCN shows a clear decrease of the $^{14}$N/$^{15}$N ratio towards the southern edge of L1544, where carbon chain molecules present a peak, strongly suggesting that isotope-selective photodissociation has a strong effect on the fractionation of nitrogen across pre-stellar cores. The $^{14}$N/$^{15}$N ratio in CN measured towards four positions across the core also shows a decrease towards the South-East of the core, while HNC shows opposite behaviour. The uneven illumination of the pre-stellar core L1544 provides clear evidence that $^{15}$N-fractionation of HCN and CN is enhanced toward the region more exposed to the interstellar radiation field. Isotope-selective photodissociation of N$_2$ is then a crucial process to understand $^{15}$N fractionation, as already found in protoplanetary disks. Therefore, the $^{15}$N-fractionation in pre-stellar material is expected to change depending on the environment within which pre-stellar cores are embedded. The $^{12}$CN/$^{13}$CN ratio also varies across the core, but its variation does not affect our conclusions on the effect of the environment on the fractionation of nitrogen.

astro-ph.GA↗

arXiv2022

Multi-line observations of CH$_{3}$OH, c-C$_{3}$H$_{2}$ and HNCO towards L1544: Dissecting the core structure with chemical differentiation

Pre-stellar cores are the basic unit for the formation of stars and stellar systems. The anatomy of the physical and chemical structures of pre-stellar cores is critical for understanding the star formation process. L1544 is a prototypical pre-stellar core, which shows significant chemical differentiation surrounding the dust peak. We aim to constrain the physical conditions at the different molecular emission peaks. This study allows us to compare the abundance profiles predicted from chemical models together with the classical density structure of Bonnor-Ebert (BE) sphere. We conducted multi-transition pointed observations of CH$_{3}$OH, c-C$_{3}$H$_{2}$ and HNCO with the IRAM 30m telescope, towards the dust peak and the respective molecular peaks of L1544. With non-LTE radiative transfer calculations and a 1-dimensional model, we revisit the physical structure of L1544, and benchmark with the abundance profiles from current chemical models. We find that the HNCO, c-C$_{3}$H$_{2}$ and CH$_{3}$OH lines in L1544 are tracing progressively higher density gas, from $\sim$10$^{4}$ to several times 10$^{5}$ cm$^{-3}$. Particularly, we find that to produce the observed intensities and ratios of the CH$_{3}$OH lines, a local gas density enhancement upon the BE sphere is required. This suggests that the physical structure of an early-stage core may not necessarily follow a smooth decrease of gas density profile locally, but can be intercepted by clumpy substructures surrounding the gravitational center. Multiple transitions of molecular lines from different molecular species can provide a tomographic view of the density structure of pre-stellar cores. The local gas density enhancement deviating from the BE sphere may reflect the impact of accretion flows that appear asymmetric and are enhanced at the meeting point of large-scale cloud structures.

astro-ph.GA↗

arXiv2022

An Interferometric View of H-MM1. I. Direct Observation of NH3 Depletion

Spectral lines of ammonia, NH$_3$, are useful probes of the physical conditions in dense molecular cloud cores. In addition to advantages in spectroscopy, ammonia has also been suggested to be resistant to freezing onto grain surfaces, which should make it a superior tool for studying the interior parts of cold, dense cores. Here we present high-resolution NH$_3$ observations with the Very Large Array (VLA) and Green Bank Telescope (GBT) towards a prestellar core. These observations show an outer region with a fractional NH$_3$ abundance of X(NH$_3$) = (1.975$\pm$0.005)$\times 10^{-8}$ ($\pm 10\%$ systematic), but it also reveals that after all, the X(NH$_3$) starts to decrease above a H$_2$ column density of $\approx 2.6 \times 10^{22}$ cm$^{-2}$. We derive a density model for the core and find that the break-point in the fractional abundance occurs at the density n(H$_2$) $\sim 2\times10^5$ cm$^{-3}$, and beyond this point the fractional abundance decreases with increasing density, following the power law $n^{-1.1}$. This power-law behavior is well reproduced by chemical models where adsorption onto grains dominates the removal of ammonia and related species from the gas at high densities. We suggest that the break-point density changes from core to core depending on the temperature and the grain properties, but that the depletion power law is anyway likely to be close to $n^{-1}$ owing to the dominance of accretion in the central parts of starless cores.

astro-ph.GA↗

arXiv2022

Astrochemical modelling of infrared dark clouds

Infrared dark clouds (IRDCs) are cold, dense regions of the interstellar medium (ISM) that are likely to represent the initial conditions for massive star formation. It is thus important to study the physical and chemical conditions of IRDCs to provide constraints and inputs for theoretical models of these processes. We aim to determine the astrochemical conditions, especially cosmic ray ionisation rate (CRIR) and chemical age, in different regions of the massive IRDC G28.37+00.07 by comparing observed abundances of multiple molecules and molecular ions with the predictions of astrochemical models. We have computed a series of single-zone astrochemical models with a gas-grain network that systematically explores the parameter space of density, temperature, CRIR, and visual extinction. We have also investigated the effects of choices of CO ice binding energy and temperatures achieved in transient heating of grains when struck by cosmic rays. We selected 10 positions across the IRDC that are known to have a variety of star formation activity. We utilised mid-infrared (MIR) extinction maps and sub-mm emission maps to measure the mass surface densities of these regions, needed for abundance and volume density estimates. The sub-mm emission maps were also used to measure temperatures. We then used IRAM-30m observations of various tracers to estimate column densities and thus abundances. Using estimates of the abundances of CO, HCO$^+$ and N$_2$H$^+$ we find consistency with astrochemical models that have relatively low CRIRs of $ζ\sim10^{-18}$ to $\sim10^{-17}\:{\rm s}^{-1}$, with no evidence for systematic variation with the level of star formation activity. Astrochemical ages are found to be < 1 Myr. We discuss potential sources of systematic uncertainties in these results and the overall implications for IRDC evolutionary history and astrochemical models.(abridged for arXiv)

astro-ph.GA↗

arXiv2022

CH$_3$CN deuteration in the SVS13-A Class I hot-corino. SOLIS XV

We studied the line emission from CH3CN and its deuterated isotopologue CH$_2$DCN towards the prototypical Class I object SVS13-A, where the deuteration of a large number of species has already been reported. Our goal is to measure the CH$_3$CN deuteration in a Class I protostar, for the first time, in order to constrain the CH$_3$CN formation pathways and the chemical evolution from the early prestellar core and Class 0 to the evolved Class I stages. We imaged CH2DCN towards SVS13-A using the IRAM NOEMA interferometer at 3mm in the context of the Large Program SOLIS (with a spatial resolution of 1.8"x1.2"). The NOEMA images have been complemented by the CH$_3$CN and CH$_2$DCN spectra collected by the IRAM-30m Large Program ASAI, that provided an unbiased spectral survey at 3mm, 2mm, and 1.3mm. The observed line emission has been analysed using LTE and non-LTE LVG approaches. The NOEMA/SOLIS images of CH2DCN show that this species emits in an unresolved area centered towards the SVS13-A continuum emission peak, suggesting that methyl cyanide and its isotopologues are associated with the hot corino of SVS13-A, previously imaged via other iCOMs. In addition, we detected 41 and 11 ASAI transitions of CH$_3$CN and CH2DCN, respectively, which cover upper level energies (Eup) from 13 to 442 K and from 18 K to 200 K, respectively. The derived [CH2DCN]/[CH3CN] ratio is $\sim$9\%. This value is consistent with those measured towards prestellar cores and a factor 2-3 higher than those measured in Class 0 protostars. Contrarily to what expected for other molecular species, the CH3CN deuteration does not show a decrease in SVS13-A with respect to measurements in younger prestellar cores and Class 0 protostars. Finally, we discuss why our new results suggest that CH3CN was likely synthesised via gas-phase reactions and frozen onto the dust grain mantles during the cold prestellar phase.

astro-ph.SR↗

arXiv2022

The Central 1000 au of a Pre-stellar Core Revealed with ALMA. II. Almost Complete Freeze-out

Pre-stellar cores represent the initial conditions in the process of star and planet formation. Their low temperatures ($<$10 K) allow the formation of thick icy dust mantles, which will be partially preserved in the future protoplanetary disks, ultimately affecting the chemical composition of planetary systems. Previous observations have shown that carbon- and oxygen-bearing species, in particular CO, are heavily depleted in pre-stellar cores due to the efficient molecular freeze-out onto the surface of cold dust grains. However, N-bearing species such as NH$_3$ and, in particular, its deuterated isotopologues, appear to maintain high abundances where CO molecules are mainly in solid phase. Thanks to ALMA, we present here the first clear observational evidence of NH$_2$D freeze-out toward the L1544 pre-stellar core, suggestive of the presence of a"complete-depletion zone" within a $\simeq$1800 au radius, in agreement with astrochemical pre-stellar core model predictions. Our state-of-the-art chemical model coupled with a non-LTE radiative transfer code demonstrates that NH$_2$D becomes mainly incorporated in icy mantles in the central 2000 au and starts freezing-out already at $\simeq$7000 au. Radiative transfer effects within the pre-stellar core cause the NH$_2$D(1$_{11}$-1$_{01}$) emission to appear centrally concentrated, with a flattened distribution within the central $\simeq$3000 au, unlike the 1.3 mm dust continuum emission which shows a clear peak within the central $\simeq$1800 au. This prevented NH$_2$D freeze-out to be detected in previous observations, where the central 1000 au cannot be spatially resolved.

astro-ph.SR↗

arXiv2022

A train of shocks at 3000 au scale? Exploring the clash of an expanding bubble into the NGC 1333 IRAS 4 region. SOLIS XIV

There is evidence that the star formation process is linked to the intricate net of filaments in molecular clouds, which may be also due to gas compression from external triggers. We studied the southern region of the Perseus NGC 1333 molecular cloud, known to be heavily shaped by similar external triggers, to shed light on the process that perturbed the filament where the Class 0 IRAS4 protostars lie. We use new IRAM-NOEMA observations of SiO and CH3OH, both known to trace violent events as shocks, toward IRAS 4A as part of the Large Program Seeds Of Life in Space (SOLIS). We detected three parallel elongated ($>$6000 au) structures, called fingers, with narrow line profiles (~1.5 $km s^{-1}$) peaked at the cloud systemic velocity, tracing gas with high density (5-20 $10^5 cm^{-3}$) and high temperature (80-160 K). They are chemically different, with the northern finger traced by both SiO and CH3OH ([CH3OH]/[SiO]~160-300), while the other two only by SiO ([CH3OH]/[SiO]$<$ 40). Among various possibilities, a train of three shocks, distanced by $>$5000 yr, would be consistent with the observations if a substantial fraction of silicon, frozen onto the grain mantles, is released by the shocks.We suggest that the shock train is due to an expanding gas bubble, coming behind NGC 1333 from the southwest and clashing against the filament, where IRAS 4A lies. Finally, we propose a solution to the two-decades long debate on the nature and origin of the widespread narrow SiO emission observed in the south part of NGC 1333, namely that it is due to unresolved trains of shocks.

astro-ph.GA↗

arXiv2022

FAUST III. Misaligned rotations of the envelope, outflow, and disks in the multiple protostellar system of VLA 1623$-$2417

We report a study of the low-mass Class-0 multiple system VLA 1623AB in the Ophiuchus star-forming region, using H$^{13}$CO$^+$ ($J=3-2$), CS ($J=5-4$), and CCH ($N=3-2$) lines as part of the ALMA Large Program FAUST. The analysis of the velocity fields revealed the rotation motion in the envelope and the velocity gradients in the outflows (about 2000 au down to 50 au). We further investigated the rotation of the circum-binary VLA 1623A disk as well as the VLA 1623B disk. We found that the minor axis of the circum-binary disk of VLA 1623A is misaligned by about 12 degrees with respect to the large-scale outflow and the rotation axis of the envelope. In contrast, the minor axis of the circum-binary disk is parallel to the large-scale magnetic field according to previous dust polarization observations, suggesting that the misalignment may be caused by the different directions of the envelope rotation and the magnetic field. If the velocity gradient of the outflow is caused by rotation, the outflow has a constant angular momentum and the launching radius is estimated to be $5-16$ au, although it cannot be ruled out that the velocity gradient is driven by entrainments of the two high-velocity outflows. Furthermore, we detected for the first time a velocity gradient associated with rotation toward the VLA 16293B disk. The velocity gradient is opposite to the one from the large-scale envelope, outflow, and circum-binary disk. The origin of its opposite gradient is also discussed.

astro-ph.GA↗

arXiv2022

Seeds of Life in Space (SOLIS). XIII. Nitrogen fractionation towards the protocluster OMC-2 FIR4

Isotopic fractionation is an important tool to investigate the chemical history of our Solar System (SS). In particular, the isotopic fraction of nitrogen (14N/15N) is lower in comets and other pristine SS bodies with respect to the value measured for the protosolar nebula, suggesting a local chemical enrichment of 15N during the SS formation. Therefore, interferometric studies of nitrogen fractionation in SS precursors are imperative for us to obtain clues about our astrochemical origins. In this work, we investigated the variation of the 14N/15N ratio in one of the closest analogues of the environment in which the SS was born: the protocluster OMC-2 FIR4. We present the first comparison at high angular resolution between HCN and N2H+ using interferometric data. We analysed observations of the HCN isotopologues H13CN and HC15N in the OMC-2 FIR4 protocluster, specifically the transitions H13CN (1-0) and HC15N (1-0), from NOEMA within the context of the IRAM Seeds Of Life In Space Large Program. We combined our results with analysis of archival data obtained with ALMA of N2H+ and its 15N isotopologues. Our results show a small regional variation in the ratio for HCN from ~250 to 500. The ratios in the central regions of FIR4, where the candidate protostars are located, are largely consistent (~300). They also show little variation from the part of the protocluster known to harbour a high cosmic-ray ionisation rate, to the portion with lower rate. We also found a small variation in the ratio of N2H+ across different regions from ~200 to ~400. These results suggest that local changes in the physical parameters occurring on small linear scales probed by our observations do not seem to affect the 14N/15N ratio in either HCN or N2H+ and hence that this is independent of the molecule used. Moreover, the high level of irradiation due to cosmic rays does not affect the N-fractionation either.

astro-ph.GA↗

arXiv2021

Methanol Mapping in Cold Cores: Testing Model Predictions

Chemical models predict that in cold cores gas-phase methanol is expected to be abundant at the outer edge of the CO depletion zone, where CO is actively adsorbed. CO adsorption correlates with volume density in cold cores, and, in nearby molecular clouds, the catastrophic CO freeze-out happens at volume densities above 10$^4$ cm$^{-3}$. The methanol production rate is maximized there and its freeze-out rate does not overcome its production rate, while the molecules are shielded from UV destruction by gas and dust. Thus, in cold cores, methanol abundance should generally correlate with visual extinction that depends both on volume and column density. In this work, we test the most basic model prediction that maximum methanol abundance is associated with a local $A_V\simeq$4 mag in dense cores and constrain the model parameters with the observational data. With the IRAM 30 m antenna, we mapped the CH$_3$OH (2-1) and (3-2) transitions toward seven dense cores in the L1495 filament in Taurus to measure the methanol abundance. We use the Herschel/SPIRE maps to estimate visual extinction, and the C$^{18}$O(2-1) maps from Tafalla & Hacar (2015) to estimate CO depletion. We explored the observed and modeled correlations between the methanol abundances, CO depletion, and visual extinction varying the key model parameters. The modeling results show that hydrogen surface diffusion via tunneling is crucial to reproduce the observed methanol abundances, and the needed reactive desorption efficiency matches the one deduced from laboratory experiments.

astro-ph.GA↗