arXiv subjects

Paola Caselli

Publications and source records attributed to Paola Caselli.

At least 127 records · Page 7Linked to original sources

arXiv2021

VLA and NOEMA view of the Bok Globule CB 17: the starless nature of a proposed FHSC candidate

We use 3mm continuum NOEMA and NH$_3$ VLA observations towards the First Hydrostatic Core (FHSC) candidate CB 17 MMS to reveal the dust structure and gas properties down to 600-1,100 au scales and constrain its evolutionary stage. We do not detect any compact source at the previously identified 1.3 mm point source, despite expecting a minimum signal-to-noise of 9. The gas traced by NH$_3$ exhibits subsonic motions, with an average temperature of 10.4 K. A fit of the radial column density profile derived from the ammonia emission finds a flat inner region of radius $\sim$1,800 au and a central density of $\sim$6$\times10^5$ cm$^{-3}$. Virial and density structure analysis reveals the core is marginally bound ($α_{vir}$= 0.73). The region is entirely consistent with a young starless core, hence ruling out CB 17 MMS as a FHSC candidate. Additionally, the core exhibits a velocity gradient aligned with the major axis, showing an arc-like structure in the p-v diagram and an off-center region with high-velocity dispersion caused by two distinct velocity peaks. These features could be due to interaction with the nearby outflow, which appears to deflect due to the dense gas near the NH$_3$ column density peak. We investigate the specific angular momentum profile of the starless core, finding that it aligns closely with previous studies of such radial profiles in Class 0 sources. This similarity to more evolved objects suggests that motions at 1,000 au scales are determined by large-scale dense cloud motions and may be preserved through the early stages of star formation.

astro-ph.GA↗

arXiv2021

The cosmic-ray ionisation rate in the pre-stellar core L1544

Context. Cosmic rays (CRs) play an important role in the chemistry and dynamics of the interstellar medium. In dense environments, they represent the main ionising agent, driving the rich chemistry of molecular ions and determining the ionisation fraction, which regulates the degree of coupling between the gas and magnetic fields. Estimates of the CR ionisation rate ($ζ_2$) span several orders of magnitude, depending on the targeted sources and on the used method. Aims. Recent theoretical models have characterised the CR attenuation with increasing density. We aim to test these models for the attenuation of CRs in the low-mass pre-stellar core L1544. Methods. We use a state-of-the-art gas-grain chemical model, which accepts the CR ionisation rate profile as input, to predict the abundance profiles of four ions: $\rm N_2H^+$, $\rm N_2D^+$, $\rm HC^{18}O^+$, and $\rm DCO^+$. Non-LTE radiative transfer is performed to produce synthetic spectra based on the derived abundances. These are compared with observations obtained with the Institut de Radioastronomie Millimétrique (IRAM) 30m telescope. Results. Our results indicate that a model with $ζ_2 > 10^{-16} \rm \, s^{-1}$ is excluded by the observations. Also the model with the standard $ζ_2 = 1.3 \times 10^{-17} \rm \, s^{-1}$ produces a worse agreement with respect to the attenuation model based on Voyager observations, which has an average $ζ_2 = 3 \times 10^{-17} \rm \, s^{-1}$ at the column densities typical of L1544. The single-dish data, however, are not sensitive to the attenuation of the CR profile, which changes only by a factor of two in the range of column densities spanned by the core model. Interferometric observations at higher spatial resolution, combined with observations of transitions with lower critical density are needed to observe a decrease of $ζ_2$ with density.

astro-ph.GA↗

arXiv2021

TRAO Survey of the nearby filamentary molecular clouds, the universal nursery of stars (TRAO FUNS). II. Filaments and Dense cores in IC 5146

We present the results on the physical properties of filaments and dense cores in IC 5146, as a part of the TRAO FUNS project. We carried out On-The-Fly mapping observations using the Taeduk Radio Astronomy Observatory (TRAO) 14m telescope covering about 1 square degree of the area of IC 5146 using various molecular lines. We identified 14 filaments (24 in total, including sub-filaments) from the C$^{18}$O (1-0) data cube and 22 dense cores from the $\rm N_{2}H^{+}$ (1-0) data. We examined the filaments' gravitational criticality, turbulence properties, accretion rate from filaments to dense cores, and relative evolutionary stages of cores. Most filaments in IC 5146 are gravitationally supercritical within the uncertainty, and most dense cores are formed in them. We found that dense cores in the hubs show a systemic velocity shift of ~0.3 km/s between the $\rm N_{2}H^{+}$ and C$^{18}$O gas. Besides, these cores are subsonic or transonic, while the surrounding filament gas is transonic or supersonic, indicating that the cores in the hubs are likely formed by the turbulence dissipation in the colliding turbulent filaments and the merging is still ongoing. We estimated the mass accretion rate of $15 - 35~M_{\odot}~\rm Myr^{-1}$ from the filaments to the dense cores, and the required time scales to collect the current core mass are consistent with the lifetime of the dense cores. The structures of filaments and dense cores in the hub can form by a collision of turbulent converging flows, and mass flow along the filaments to the dense cores may play an important role in forming dense cores.

astro-ph.GA↗

arXiv2021

The young protostellar disk in IRAS16293-2422 B is hot and shows signatures of gravitational instability

Deeply embedded protostars are actively fed from their surrounding envelopes through their protostellar disk. The physical structure of such early disks might be different from that of more evolved sources due to the active accretion. We present 1.3 and 3\,mm ALMA continuum observations at resolutions of 6.5\,au and 12\,au respectively, towards the Class 0 source IRAS 16293-2422 B. The resolved brightness temperatures appear remarkably high, with $T_{\rm b} >$ 100\,K within $\sim$30\,au and $T_{\rm b}$ peak over 400\,K at 3\,mm. Both wavelengths show a lopsided emission with a spectral index reaching values less than 2 in the central $\sim$ 20\,au region. We compare these observations with a series of radiative transfer calculations and synthetic observations of magnetohydrodynamic and radiation hydrodynamic protostellar disk models formed after the collapse of a dense core. Based on our results, we argue that the gas kinematics within the disk may play a more significant role in heating the disk than the protostellar radiation. In particular, our radiation hydrodynamic simulation of disk formation, including heating sources associated with gravitational instabilities, is able to generate the temperatures necessary to explain the high fluxes observed in IRAS 16293B. Besides, the low spectral index values are naturally reproduced by the high optical depth and high inner temperatures of the protostellar disk models. The high temperatures in IRAS 16293B imply that volatile species are mostly in the gas phase, suggesting that a self-gravitating disk could be at the origin of a hot corino.

astro-ph.SR↗

arXiv2021

Ice mantles on dust grains: dramatic variation of thickness with grain size

We compute the desorption rate of icy mantles on dust grains as a function of the size and composition of both the grain and the mantle. We combine existing models of cosmic ray (CR) related desorption phenomena with a model of CR transport to accurately calculate the desorption rates in dark regions of molecular clouds. We show that different desorption mechanisms dominate for grains of different sizes, and in different regions of the cloud. We then use these calculations to investigate a simple model of the growth of mantles, given a distribution of grain sizes. We find that modest variations of the desorption rate with grain size lead to a strong dependence of mantle thickness on grain size. Furthermore, we show that freeze-out is almost complete in the absence of an external UV field, even when photodesorption from CR produced UV is taken into consideration. Even at gas densities of $10^4$ ${\rm cm^{-3}}$, less than 30\% of the CO remains in the gas phase after $3\times 10^5$ years for standard values of the CR ionization rate.

astro-ph.GA↗

arXiv2021

Are massive dense clumps truly sub-virial? A new analysis using Gould Belt ammonia data

Dynamical studies of dense structures within molecular clouds often conclude that the most massive clumps contain too little kinetic energy for virial equilibrium, unless they are magnetized to an unexpected degree. This raises questions about how such a state might arise, and how it might persist long enough to represent the population of massive clumps. In an effort to re-examine the origins of this conclusion, we use ammonia line data from the Green Bank Ammonia Survey and Planck-calibrated dust emission data from Herschel to estimate the masses and kinetic and gravitational energies for dense clumps in the Gould Belt clouds. We show that several types of systematic error can enhance the appearance of low kinetic-to-gravitational energy ratios: insufficient removal of foreground and background material; ignoring the kinetic energy associated with velocity differences across a resolved cloud; and over-correcting for stratification when evaluating the gravitational energy. Using an analysis designed to avoid these errors, we find that the most massive Gould Belt clumps harbor virial motions, rather than sub-virial ones. As a byproduct, we present a catalog of masses, energies, and virial energy ratios for 85 Gould Belt clumps.

astro-ph.GA↗

arXiv2021

Impact of magneto-rotational instability on grain growth in protoplanetary disks: II. Increased grain collisional velocities

Turbulence is the dominant source of collisional velocities for grains with a wide range of sizes in protoplanetary disks. So far, only Kolmogorov turbulence has been considered for calculating grain collisional velocities, despite the evidence that turbulence in protoplanetary disks may be non-Kolmogorov. In this work, we present calculations of grain collisional velocities for arbitrary turbulence models characterized by power-law spectra and determined by three dimensionless parameters: the slope of the kinetic energy spectrum, the slope of the auto-correlation time, and the Reynolds number. The implications of our results are illustrated by numerical simulations of the grain size evolution for different turbulence models. We find that for the modeled cases of the Iroshnikov-Kraichnan turbulence and the turbulence induced by the magneto-rotational instabilities, collisional velocities of small grains are much larger than those for the standard Kolmogorov turbulence. This leads to faster grain coagulation in the outer regions of protoplanetary disks, resulting in rapid increase of dust opacity in mm-wavelength and possibly promoting planet formation in very young disks.

astro-ph.EP↗

arXiv2021

SiO Outflows as Tracers of Massive Star Formation in Infrared Dark Clouds

To study the early phases of massive star formation, we present ALMA observations of SiO(5-4) emission and VLA observations of 6 cm continuum emission towards 32 Infrared Dark Cloud (IRDC) clumps, spatially resolved down to $\lesssim 0.05$ pc. Out of the 32 clumps, we detect SiO emission in 20 clumps, and in 11 of them the SiO emission is relatively strong and likely tracing protostellar outflows. Some SiO outflows are collimated, while others are less ordered. For the six strongest SiO outflows, we estimate basic outflow properties. In our entire sample, where there is SiO emission, we find 1.3 mm continuum and infrared emission nearby, but not vice versa. We build the spectral energy distributions (SEDs) of cores with 1.3 mm continuum emission and fit them with radiative transfer (RT) models. The low luminosities and stellar masses returned by SED fitting suggest these are early stage protostars. We see a slight trend of increasing SiO line luminosity with bolometric luminosity, which suggests more powerful shocks in the vicinity of more massive YSOs. We do not see a clear relation between the SiO luminosity and the evolutionary stage indicated by $L/M$. We conclude that as a protostar approaches a bolometric luminosity of $\sim 10^2 \: L_{\odot}$, the shocks in the outflow are generally strong enough to form SiO emission. The VLA 6 cm observations toward the 15 clumps with the strongest SiO emission detect emission in four clumps, which is likely shock ionized jets associated with the more massive ones of these protostellar cores.

astro-ph.GA↗

arXiv2021

Star Formation in a Strongly Magnetized Cloud

We study star formation in the Center Ridge 1 (CR1) clump in the Vela C giant molecular cloud, selected as a high column density region that shows the lowest level of dust continuum polarization angle dispersion, likely indicating that the magnetic field is relatively strong. We observe the source with the ALMA 7m-array at 1.05~mm and 1.3~mm wavelengths, which enable measurements of dust temperature, core mass and astrochemical deuteration. A relatively modest number of eleven dense cores are identified via their dust continuum emission, with masses spanning from 0.17 to 6.7 Msun. Overall CR1 has a relatively low compact dense gas fraction compared with other typical clouds with similar column densities, which may be a result of the strong magnetic field and/or the very early evolutionary stage of this region. The deuteration ratios, Dfrac, of the cores, measured with N2H+(3-2) and N2D+(3-2) lines, span from 0.011 to 0.85, with the latter being one of the highest values yet detected. The level of deuteration appears to decrease with evolution from prestellar to protostellar phase. A linear filament, running approximately parallel with the large scale magnetic field orientation, is seen connecting the two most massive cores, each having CO bipolar outflows aligned orthogonally to the filament. The filament contains the most deuterated core, likely to be prestellar and located midway between the protostars. The observations permit measurement of the full deuteration structure of the filament along its length, which we present. We also discuss the kinematics and dynamics of this structure, as well as of the dense core population.

astro-ph.GA↗

arXiv2021

The complex organic molecular content in the L1498 starless core

Observations carried out toward starless and pre-stellar cores have revealed that complex organic molecules are prevalent in these objects, but it is unclear what chemical processes are involved in their formation. Recently, it has been shown that complex organics are preferentially produced at an intermediate-density shell within the L1544 pre-stellar core at radial distances of ~4000 au with respect to the core center. However, the spatial distribution of complex organics has only been inferred toward this core and it remains unknown whether these species present a similar behaviour in other cores. We report high-sensitivity observations carried out toward two positions in the L1498 pre-stellar core, the dust peak and a position located at a distance of ~11000 au from the center of the core where the emission of CH$_3$OH peaks. Similarly to L1544, our observations reveal that small O-bearing molecules and N-bearing species are enhanced by factors ~4-14 toward the outer shell of L1498. However, unlike L1544, large O-bearing organics such as CH3CHO, CH3OCH3 or CH3OCHO are not detected within our sensitivity limits. For N-bearing organics, these species are more abundant toward the outer shell of the L1498 pre-stellar core than toward the one in L1544. We propose that the differences observed between O-bearing and N-bearing species in L1498 and L1544 are due to the different physical structure of these cores, which in turn is a consequence of their evolutionary stage, with L1498 being younger than L1544.

astro-ph.SR↗

arXiv2021

Neutral vs Ion Linewidths in Barnard 5: Evidence for Penetration by MHD Waves

Dense cores are the final place where turbulence is dissipated. It has been proposed from theoretical arguments that the non-thermal velocity dispersion should be narrower both for molecular ions (compared to neutrals) and for transitions with higher critical densities. To test these hypotheses, we compare the velocity dispersion of N$_2$H$^+$ (1--0) (n$_{\rm crit}$ = $6\times10^4$ cm$^{-3}) and NH$_3$ (n$_{\rm crit}=2\times10^3$ cm$^{-3}), in the dense core Barnard 5. We analyse well resolved and high signal-to-noise observations of NH$_3$ (1,1) and (2,2) obtained with combining GBT and VLA data, and N$_2$H$^+$ (1--0) obtained with GBT Argus, which present a similar morphology. % Surprisingly, the non-thermal velocity dispersion of the ion is systematically higher than that of the neutral by 20\%. The derived sonic Mach number, $\mathcal{M}_s = σ_{\rm NT}/c_s$, has peak values $\mathcal{M}_{s, {\rm N_2H^+}} = 0.59$ and $\mathcal{M}_{s, {\rm NH}_3} = 0.48$ for N$_2$H$^+$ and NH$_3$, respectively. % This observed difference may indicate that the magnetic field even deep within the dense core is still oscillating, as it is in the turbulent region outside the core. The ions should be more strongly dynamically coupled to this oscillating field than the neutrals, thus accounting for their broader linewidth. If corroborated by further observations, this finding would shed additional light on the transition to quiescence in dense cores.

astro-ph.GA↗

arXiv2021

Transition from Coherent Cores to Surrounding Cloud in L1688

Stars form in cold dense cores showing subsonic velocity dispersions. The parental molecular clouds display higher temperatures and supersonic velocity dispersions. The transition from core to cloud has been observed in velocity dispersion, but temperature and abundance variations are unknown. We aim to study the transition from cores to ambient cloud in temperature and velocity dispersion using a single tracer. We use NH3 (1,1) and (2,2) maps in L1688 from the Green Bank Ammonia Survey, smoothed to 1', and determine the physical properties from fits. We identify the coherent cores and study the changes in temperature and velocity dispersion from cores to the surrounding cloud. We obtain a kinetic temperature map tracing the extended cloud, improving from previous maps tracing mostly the cores. The cloud is 4-6 K warmer than the cores, and shows a larger velocity dispersion (diff. = 0.15-0.25 km/s). Comparing to Herschel-based measurements, we find that cores show kinetic temperature $\approx$1.8 K lower than the dust temperature; while the gas temperature is higher than the dust temperature in the cloud. We find an average p-NH3 fractional abundance (with respect to H2) of $(4.2\pm0.2) \times 10^{-9}$ towards the coherent cores, and $(1.4\pm0.1) \times 10^{-9}$ outside the core boundaries. Using stacked spectra, we detect two components, one narrow and one broad, towards cores and their neighbourhoods. We find the turbulence in the narrow component to be correlated to the size of the structure (Pearson-r=0.54). With these unresolved regional measurements, we obtain a turbulence-size relation of $σ_{v,NT}\propto r^{0.5}$, similar to previous findings using multiple tracers. We discover that the subsonic component extends up to 0.15 pc beyond the typical coherent boundaries, unveiling larger extents of the coherent cores and showing gradual transition to coherence over ~0.2 pc.

astro-ph.GA↗

arXiv2021

A New Method for Simulating Photoprocesses in Astrochemical Models

We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal) species is explicitly considered. In addition, we have included non-thermal, non-diffusive chemistry to account for the low-temperature characteristic of cold cores. As an initial test of our method, we have simulated two previous experimental studies involving the UV irradiation of pure solid O$_2$. In contrast to previous solid-state astrochemical model calculations which have used gas-phase photoabsorption cross-sections, we have employed solid-state cross-sections in our calculations. This method allows the model to be tested using well-constrained experiments rather than poorly constrained gas-phase abundances in ISM regions. Our results indicate that inclusion of non-thermal reactions and suprathermal species allows for reproduction of low-temperature solid-phase photoprocessing that simulate interstellar ices within cold ($\sim$ 10 K) dense cores such as TMC-1.

astro-ph.GA↗

arXiv2021

FAUST II. Discovery of a Secondary Outflow in IRAS 15398-3359: Variability in Outflow Direction during the Earliest Stage of Star Formation?

We have observed the very low-mass Class 0 protostar IRAS 15398-3359 at scales ranging from 50 au to 1800 au, as part of the ALMA Large Program FAUST. We uncover a linear feature, visible in H2CO, SO, and C18O line emission, which extends from the source along a direction almost perpendicular to the known active outflow. Molecular line emission from H2CO, SO, SiO, and CH3OH further reveals an arc-like structure connected to the outer end of the linear feature and separated from the protostar, IRAS 15398-3359, by 1200 au. The arc-like structure is blue-shifted with respect to the systemic velocity. A velocity gradient of 1.2 km/s over 1200 au along the linear feature seen in the H2CO emission connects the protostar and the arc-like structure kinematically. SO, SiO, and CH3OH are known to trace shocks, and we interpret the arc-like structure as a relic shock region produced by an outflow previously launched by IRAS 15398-3359. The velocity gradient along the linear structure can be explained as relic outflow motion. The origins of the newly observed arc-like structure and extended linear feature are discussed in relation to turbulent motions within the protostellar core and episodic accretion events during the earliest stage of protostellar evolution.

astro-ph.SR↗

arXiv2021

Deuterium Chemodynamics of Massive Pre-Stellar Cores

High levels of deuterium fractionation of $\rm N_2H^+$ (i.e., $\rm D_{frac}^{N_2H^+} \gtrsim 0.1$) are often observed in pre-stellar cores (PSCs) and detection of $\rm N_2D^+$ is a promising method to identify elusive massive PSCs. However, the physical and chemical conditions required to reach such high levels of deuteration are still uncertain, as is the diagnostic utility of $\rm N_2H^+$ and $\rm N_2D^+$ observations of PSCs. We perform 3D magnetohydrodynamics simulations of a massive, turbulent, magnetised PSC, coupled with a sophisticated deuteration astrochemical network. Although the core has some magnetic/turbulent support, it collapses under gravity in about one freefall time, which marks the end of the simulations. Our fiducial model achieves relatively low $\rm D_{frac}^{N_2H^+} \sim 0.002$ during this time. We then investigate effects of initial ortho-para ratio of $\rm H_2$ ($\rm OPR^{H_2}$), temperature, cosmic ray (CR) ionization rate, CO and N-species depletion factors and prior PSC chemical evolution. We find that high CR ionization rates and high depletion factors allow the simulated $\rm D_{frac}^{N_2H^+}$ and absolute abundances to match observational values within one freefall time. For $\rm OPR^{H_2}$, while a lower initial value helps the growth of $\rm D_{frac}^{N_2H^+}$, the spatial structure of deuteration is too widespread compared to observed systems. For an example model with elevated CR ionization rates and significant heavy element depletion, we then study the kinematic and dynamic properties of the core as traced by its $\rm N_2D^+$ emission. The core, undergoing quite rapid collapse, exhibits disturbed kinematics in its average velocity map. Still, because of magnetic support, the core often appears kinematically sub-virial based on its $\rm N_2D^+$ velocity dispersion.

astro-ph.GA↗

arXiv2021

Dissecting the super-critical filaments embedded in the 0.5 pc subsonic region of Barnard 5

We characterize in detail the two ~0.3 pc long filamentary structures found within the subsonic region of Barnard 5. We use combined GBT and VLA observations of the molecular lines NH$_3$(1,1) and (2,2) at a resolution of 1800 au, as well as JCMT continuum observations at 850 and 450 $μ$m at a resolution of 4400 au and 3000 au, respectively. We find that both filaments are highly super-critical with a mean mass per unit length, $M/L$, of ~80 M$_\odot$ pc$^{-1}$, after background subtraction, with local increases reaching values of ~150 M$_\odot$ pc$^{-1}$. This would require a magnetic field strength of ~500 $μ$G to be stable against radial collapse. We extract equidistant cuts perpendicular to the spine of the filament and fit a modified Plummer profile as well as a Gaussian to each of the cuts. The filament widths (deconvolved FWHM) range between 6500-7000 au (~0.03 pc) along the filaments. This equals ~2.0 times the radius of the flat inner region. We find an anti-correlation between the central density and this flattening radius, suggestive of contraction. Further, we also find a strong correlation between the power-law exponent at large radii and the flattening radius. We note that the measurements of these three parameters fall in a plane and derive their empirical relation. Our high-resolution observations provide direct constraints of the distribution of the dense gas within super-critical filaments showing pre- and protostellar activity.

astro-ph.GA↗

arXiv2020

Carbon Chain Chemistry in Hot-Core Regions around Three Massive Young Stellar Objects Associated with 6.7 GHz Methanol Masers

We have carried out observations of CCH ($N=1-0$), CH$_{3}$CN ($J=5-4$), and three $^{13}$C isotopologues of HC$_{3}$N ($J=10-9$) toward three massive young stellar objects (MYSOs), G12.89+0.49, G16.86--2.16, and G28.28--0.36, with the Nobeyama 45-m radio telescope. Combined with previous results on HC$_{5}$N, the column density ratios of $N$(CCH)/$N$(HC$_{5}$N), hereafter the CCH/HC$_{5}$N ratios, in the MYSOs are derived to be $\sim 15$. This value is lower than that in a low-mass warm carbon chain chemistry (WCCC) source by more than one order of magnitude. We compare the observed CCH/HC$_{5}$N ratios with hot-core model calculations (Taniguchi et al. 2019). The observed ratios in the MYSOs can be best reproduced by models when the gas temperature is $\sim 85$ K, which is higher than in L1527, a low-mass WCCC source ($\sim 35$ K). These results suggest that carbon-chain molecules detected around the MYSOs exist at least partially in higher temperature regions than those in low-mass WCCC sources. There is no significant difference in column density among the three $^{13}$C isotopologues of HC$_{3}$N in G12.89+0.49 and G16.86-2.16, while HCC$^{13}$CN is more abundant than the others in G28.28--0.36. We discuss carbon-chain chemistry around the three MYSOs based on the CCH/HC$_{5}$N ratio and the $^{13}$C isotopic fractionation of HC$_{3}$N.

astro-ph.GA↗

arXiv2020

UV resistance of nucleosides -- an experimental approach

The emergence of life on Earth is a highly discussed but still unsolved question. Current research underlines the importance of environments within close proximity to the Earth's surface as they can solve long-standing problems such as polymerization of nucleotides and phosphorylation of nucleosides. However, near-surface settings, for example, ponds or ice shields, are prone to UV irradiation. We investigated the photosensitivity of uracil, uridine, adenosine, cytidine, and guanosine by using Raman microscopy. The samples were irradiated by a UV source with 150~mW/cm\textsuperscript{2} for 10 min. Uracil and uridine showed the highest photosensitivity, while adenosine, cytidine, and guanosine remained stable. The change of spectral features and ab initio quantum calculations indicate the formation of uracil's trans-syn cyclobutane dimer during UV irradiation.

physics.chem-ph↗