arXiv subjects

Paolo Biagioni

Publications and source records attributed to Paolo Biagioni.

At least 19 recordsLinked to original sources

arXiv2026

Robust inverse design of non-periodic Bloch surface wave sensors

One-dimensional photonic crystals supporting Bloch surface waves (BSWs) have emerged as highly sensitive platforms for label-free refractometric sensing. However, the practical performance of these sensors is limited by their vulnerability to fabrication-induced thickness variations. In this Letter, we address this challenge by introducing a robust inverse design framework based on multi-objective genetic optimization. This framework jointly maximizes intensity sensitivity and resilience against manufacturing errors, demonstrating that non-periodic multilayers achieve inherently superior sensitivity-robustness trade-offs, with a pronounced gain in device resilience over conventional periodic designs. By analyzing the optimized designs, we uncover an intrinsic compensation mechanism that physically governs the trade-off and effectively stabilizes the sensor response against structural perturbations. By unlocking the expanded design space of non-periodic multilayers, our optimization strategy paves the way for the practical realization of next-generation BSW sensors.

physics.optics↗

arXiv2026

Polarization-Multiplexed Bloch Surface Wave Sensing of Single-Strand DNA Growth

Refractometric biosensing is a vital label-free tool for the real time detection and interaction analysis of biological and chemical substances. Nanophotonic platforms like Surface Plasmon Resonance (SPR) have played a critical role in providing refractometric sensing capabilities for clinical diagnostics and environmental monitoring. However, traditional systems operating in a single-polarization state cannot fully characterize complex optical properties such as birefringence, which is crucial to resolve many complex biological interactions. Although Bloch Surface Wave (BSW) sensors can support both TE and TM modes, a key capability SPR lacks, they have historically been implemented in single-mode configurations. In this paper, we present a polarization multiplexed BSW refractometric sensing system, simultaneously tracking the resonant wavelength shifts of both TE and TM BSW modes through time. Our technique was applied to investigate single-strand DNA growth during rolling circle amplification (RCA). To accurately recover the time-dependent birefringence, capturing dynamics of the DNA growth and orientation of its chains, we implemented a two-stage modeling approach based on the TMM. First, we utilized a wavelength-dependent surface sensitivity model, confining refractive index changes to the immediate layer above the crystal, to distinguish isotropic background dynamics from birefringent signals. Following the onset of RCA, we transitioned to a model that accounted for the vertical growth of the DNA layers in time. By fitting this model to the TE and TM resonant shifts, we monitor the growth rate of the single-strand DNA layer as well as the refractive index along the two polarization components. Our findings demonstrate the platform's ability to resolve the structural evolution of complex bimolecular interactions associated with conformational changes.

physics.optics↗

arXiv2025

Leveraging Low Index Contrast to Reduce the Polarization Anisotropy in One-Dimensional Photonic Crystals

One-dimensional photonic crystals (1DPCs) are widely used platforms for guiding, filtering, and enhancing light at the nanoscale. Traditionally, designs have favored high refractive index contrast to maximize the photonic band gap (PBG) size. Here, we demonstrate that low-index contrast systems offer a powerful and underexplored route to achieving improved optical functionalities. In particular, we show that low index contrast enables more closely aligned PBGs for transverse electric (TE) and transverse magnetic (TM) polarizations, allowing for broadband superposition of TE and TM Bloch Surface Waves (BSWs). As a demonstration of this functionality, we use this approach to design 1DPCs capable of generating planar superchiral fields for enhanced circular dichroism spectroscopy. To realize such structures, we use an automated design framework based on multi-objective genetic optimization. By comparing optimized designs in both high and low index contrast regimes, we find that low index contrast systems yield significantly greater overlap between the TE and TM BSW dispersion relations and exhibit a pronounced reduction in optical anisotropy - both of which contribute to enhanced optical chirality across the operational bandwidth. Furthermore, simulations reveal that these low index contrast structures offer improved robustness to fabrication tolerances and support a wider dynamic range of chiral analyte concentrations. In addition to their optical performance advantages, low-index contrast systems are naturally compatible with polymeric materials, which offer benefits such as low cost, sustainability, and mechanical flexibility. While this work focuses on mode alignment and its consequences for surface wave behavior, the underlying principles have broader implications for polarization-independent photonic technologies, including optical sensing, computing, and spectral filtering.

physics.optics↗

arXiv2024

All-optical polarization control and routing by nonlinear interferometry at the nanoscale

Optical metasurfaces are rapidly establishing as key-enabling platforms for nanophotonics applications. Along with the ability of taming light in subwavelength thicknesses, they can feature multiple functionalities in one device. The generation and control of light polarization by metasurfaces already provided a route towards ultracompact polarimetry devices in the linear regime. If translated to the nonlinear optical regime it may become a key-enabling tool in nonlinear imaging, optical holography and sensing. Here, we report the experimental ultrafast all-optical polarization modulation of upconverted light by all-dielectric metasurfaces via nonlinear interferometry. By controlling the relative phase between a pump beam at $ω$ and its frequency-double replica at 2$ω$, we can set the phase relation between two frequency-degenerate upconverted processes at 3$ω$ $-$ Sum-Frequency Generation (SFG) and Third-Harmonic Generation (THG) $-$ stemming from an AlGaAs metasurface. By exploiting the opposite parity of the two nonlinear process and tuning their relative powers, we can achieve modulation of the polarization states of the light emitted at 3$ω$ between linear and circular states with a degree of circular polarization (DOCP) up to 83$\%$. In particular, circularly polarized light features opposite handedness symmetrically located in the Fourier space, at coincidence with the first diffraction orders of the metasurface. Moreover, by toggling the phase delay by $π$, the handedness can be fully switched between the diffraction. Our work adds an additional layer of modulation in polarization beyond intensity to all-optical routing with precise phase control. The capability to route circular polarization states in the k-space holds significant potential for chiral sensing and advanced imaging techniques.

physics.optics↗

arXiv2024

Origin of optical nonlinearity in plasmonic semiconductor nanostructures

The development of nanoscale nonlinear elements in photonic integrated circuits is hindered by the physical limits to the nonlinear optical response of dielectrics, which requires that the interacting waves propagate in transparent volumes for distances much longer than their wavelength. Here we present experimental evidence that optical nonlinearities in doped semiconductors are due to free-electron and their efficiency could exceed by several orders of magnitude that of conventional dielectric nonlinearities. Our experimental findings are supported by comprehensive computational results based on the hydrodynamic modeling, which naturally includes nonlocal effects, of the free-electron dynamics in heavily doped semiconductors. By studying third-harmonic generation from plasmonic nanoantenna arrays made out of heavily n-doped InGaAs with increasing levels of free-carrier density, we discriminate between hydrodynamic and dielectric nonlinearities. As a result, the value of maximum nonlinear efficiency as well as its spectral location can now be controlled by tuning the doping level. Having employed the common material platform InGaAs/InP that supports integrated waveguides, our findings pave the way for future exploitation of plasmonic nonlinearities in all-semiconductor photonic integrated circuits.

physics.optics↗

arXiv2023

All-optical free-space routing of upconverted light by metasurfaces via nonlinear interferometry

All-optical modulation yields the promise of high-speed information processing. In this frame, metasurfaces are rapidly gaining traction as ultrathin multifunctional platforms for light management. Among the featured functionalities, they enable light wavefront manipulation and, more recently, demonstrated the ability to perform light-by-light manipulation through nonlinear optical processes. Here, by employing a nonlinear periodic metasurface, we demonstrate all-optical routing of telecom photons upconverted to the visible range. This is achieved via the interference between two frequency-degenerate upconversion processes, namely third-harmonic and sum-frequency generation, stemming from the interaction of a pump pulse with its frequency-doubled replica. By tuning the relative phase and polarization between these two pump beams, and concurrently engineering the nonlinear emission of the individual elements of the metasurfaces (meta-atoms) along with its pitch, we route the upconverted signal among the diffraction orders of the metasurface with a modulation efficiency up to 90%. Thanks to the phase control and the ultrafast dynamics of the underlying nonlinear processes, free-space all-optical routing could be potentially performed at rates close to the employed optical frequencies divided by the quality factor of the optical resonances at play. Our approach adds a further twist to optical interferometry, which is a key-enabling technique in a wide range of applications, such as homodyne detection, radar interferometry, LiDAR technology, gravitational waves detection, and molecular photometry. In particular, the nonlinear character of light upconversion combined with phase sensitivity is extremely appealing for enhanced imaging and biosensing.

physics.optics↗

arXiv2021

Modelling photothermal induced resonance microscopy: the role of interface thermal resistances

Infrared (IR) nanospectroscopy by photothermal induced resonance (PTIR) is a novel experimental technique that combines the nanoscale resolution granted by atomic force microscopy (AFM) and the chemical labelling made possible by IR absorption spectroscopy. While the technique has developed enormously over the last decade from an experimental point of view, the theoretical modelling of the signal still varies significantly throughout the literature and misses a solid benchmark. Here, we report an analysis focused on the electromagnetic and thermal simulations of a PTIR experiment. Thanks to a control experiment where the signal is acquired as a function of the thickness of a polymer film and for different tip geometries, we find clear evidence that the interface thermal resistances play a key role in the determination of the measured signal and should therefore always be accounted for by any quantitative modelling.

cond-mat.mtrl-sci↗

arXiv2020

Tunable broadband light emission from graphene

Graphene is an ideal material for integrated nonlinear optics thanks to its strong light-matter interaction and large nonlinear optical susceptibility. Graphene has been used in optical modulators, saturable absorbers, nonlinear frequency converters, and broadband light emitters. For the latter application, a key requirement is the ability to control and engineer the emission wavelength and bandwidth, as well as the electronic temperature of graphene. Here, we demonstrate that the emission wavelength of graphene$'$ s broadband hot carrier photoluminescence can be tuned by integration on photonic cavities, while thermal management can be achieved by out-of-plane heat transfer to hexagonal boron nitride. Our results pave the way to graphene-based ultrafast broadband light emitters with tunable emission.

physics.optics↗

arXiv2019

Tip-Enhanced Infrared Difference-Nanospectroscopy of the Proton Pump Activity of Bacteriorhodopsin in Single Purple Membrane Patches

Photosensitive proteins embedded in the cell membrane (about 5 nm thickness) act as photoactivated proton pumps, ion gates, enzymes, or more generally, as initiators of stimuli for the cell activity. They are composed of a protein backbone and a covalently bound cofactor (e.g. the retinal chromophore in bacteriorhodopsin (BR), channel rhodopsin, and other opsins). The light-induced conformational changes of both the cofactor and the protein are at the basis of the physiological functions of photosensitive proteins. Despite the dramatic development of microscopy techniques, investigating conformational changes of proteins at the membrane monolayer level is still a big challenge. Techniques based on atomic force microscopy (AFM) can detect electric currents through protein monolayers and even molecular binding forces in single-protein molecules but not the conformational changes. For the latter, Fourier-transform infrared spectroscopy (FTIR) using difference-spectroscopy mode is typically employed, but it is performed on macroscopic liquid suspensions or thick films containing large amounts of purified photosensitive proteins. In this work, we develop AFM-assisted, tip-enhanced infrared difference-nanospectroscopy to investigate light-induced conformational changes of the bacteriorhodopsin mutant D96N in single submicrometric native purple membrane patches. We obtain a significant improvement compared with the signal-to-noise ratio of standard IR nanospectroscopy techniques by exploiting the field enhancement in the plasmonic nanogap that forms between a gold-coated AFM probe tip and an ultraflat gold surface, as further supported by electromagnetic and thermal simulations. IR difference-spectra in the 1450-1800 cm^{-1} range are recorded from individual patches as thin as 10 nm, with a diameter of less than 500 nm, well beyond the diffraction limit for FTIR microspectroscopy...

physics.bio-ph↗

arXiv2019

Plasmonic superchiral lattice resonances in the mid-infrared

Recent efforts in the field of surface-enhanced spectroscopies have focused on the paradigm of superchirality, entailing the engineering of the local electromagnetic fields to boost the enantiospecific interaction between light and chiral molecules. In this framework, approaches based on both metallic and dielectric nanostructures have been proposed and have also recently been extended to vibrational circular dichroism in the mid-infrared. In this work, we design, fabricate and characterize arrays of chiral plasmonic slits featuring enhanced chiral fields in the mid-infrared. We exploit collective lattice resonances to further enhance the local intensity and to generate sharp features in the circular dichroism spectra of the platform. Such features are ideally suited to test the superchiral coupling with the vibrational resonances of chiral molecules.

cond-mat.mes-hall↗

arXiv2019

Evidence for cascaded third harmonic generation in non-centrosymmetric gold nanoantennas

The optimization of nonlinear optical processes at the nanoscale is a crucial step for the development of nanoscale photon sources for quantum-optical networks. The development of innovative plasmonic nanoantenna designs and hybrid nanostructures to enhance optical nonlinearities in very small volumes represents one of the most promising routes. In such systems, the upconversion of photons can be achieved with high efficiencies via third-order processes, such as third harmonic generation (THG), thanks to the resonantly-enhanced volume currents. Conversely, second-order processes, such as second harmonic generation (SHG), are often inhibited by the symmetry of metal lattices and of common nanoantenna geometries. SHG and THG processes in plasmonic nanostructures are generally treated independently, since they both represent a small perturbation in the light-matter interaction mechanisms. In this work, we demonstrate that this paradigm does not hold in general, by providing evidence of a cascaded process in THG, which is fueled by SHG and sizably contributes to the overall yield. We address this mechanism by unveiling an anomalous fingerprint in the polarization state of the nonlinear emission from non-centrosymmetric gold nanoantennas and point out that such cascaded processes may also appear for structures that exhibit only moderate SHG yields - signifying its general relevance in plasmon-enhanced nonlinear optics. The presence of this peculiar mechanism in THG from plasmonic nanoantennas at telecommunication wavelengths allows gaining further insight on the physics of plasmon-enhanced nonlinear optical processes. This could be crucial in the realization of nanoscale elements for photon conversion and manipulation operating at room-temperature.

cond-mat.mes-hall↗

arXiv2018

Superchiral Surface Waves for All-Optical Enantiomer Separation

We introduce the use of superchiral surface waves for the all-optical separation of chiral compounds. Using a combination of electrodynamics modeling and analytical techniques, we show that the proposed approach provides chiral optical forces two orders of magnitude larger than those obtained with circularly polarized plane waves. Superchiral surface waves allow for enantiomer separation on spatial, temporal and size scales than would not be achievable with alternative techniques, thus representing a viable route towards all-optical enantiomer separation.

cond-mat.mes-hall↗

arXiv2018

Mid Infrared Nonlinear Plasmonics using Germanium Nanoantennas on Silicon Substrates

We demonstrate third harmonic generation in plasmonic antennas made of highly doped germanium and designed to be resonant in the mid infrared. Owing to the near-field enhancement, the result is an ultrafast, sub-diffraction, coherent light source tunable between 3 and 5 micrometer wavelength on a silicon substrate. To observe nonlinearity in this challenging spectral region, a high-power femtosecond laser system equipped with parametric frequency conversion in combination with an all-reflective confocal microscope setup is employed. We show spatially resolved maps of the linear scattering cross section and the nonlinear emission of single isolated antenna structures. A clear third order power dependence as well as the mid-infrared emission spectra prove the nonlinear nature of the light emission. Simulations support the observed resonance length of the double rod antenna and demonstrate that the field enhancement inside the antenna material is responsible for the nonlinear frequency mixing.

physics.app-ph↗

arXiv2017

Plasmon-enhanced second harmonic sensing

It has been recently suggested that the nonlinear optical processes in plasmonic nanoantennas allow for a substantial boost in the sensitivity of plasmonic sensing platforms. Here we present a sensing device based on an array of non-centrosymmetric plasmonic nanoantennas featuring enhanced second harmonic generation (SHG) integrated in a microfluidic chip. We evaluate its sensitivity both in the linear and nonlinear regime using a figure of merit (FOM = $(ΔI/I)/Δn$) that accounts for the relative change in the measured intensity, \textit{I}, against the variation of the environmental refractive index \textit{n}. While the signal-to-noise ratio achieved in both regimes allows the detection of a minimum refractive index variation $Δn_{min} \approx 10^{-3}$, the platform operation in the nonlinear regime features a sensitivity (i.e. the FOM) that is at least 3 times higher than the linear one. Thanks to the surface sensitivity of plasmon-enhanced SHG, our results show that the development of such SHG sensing platforms with sensitivity performances exceeding those of their linear counterparts is within reach.

cond-mat.mes-hall↗

arXiv2017

Room-temperature 1.54 $μ$m photoluminescence of Er:O$_x$ centers at extremely low concentration in silicon

The demand for single photon sources at $λ~=~1.54~μ$m, which follows from the consistent development of quantum networks based on commercial optical fibers, makes Er:O$_x$ centers in Si still a viable resource thanks to the optical transition of $Er^{3+}~:~^4I_{13/2}~\rightarrow~^4I_{15/2}$. Yet, to date, the implementation of such system remains hindered by its extremely low emission rate. In this Letter, we explore the room-temperature photoluminescence (PL) at the telecomm wavelength of very low implantation doses of $Er:O_x$ in $Si$. The emitted photons, excited by a $λ~=~792~nm$ laser in both large areas and confined dots of diameter down to $5~μ$m, are collected by an inverted confocal microscope. The lower-bound number of detectable emission centers within our diffraction-limited illumination spot is estimated to be down to about 10$^4$, corresponding to an emission rate per individual ion of about $4~\times~10^{3}$ photons/s.

cond-mat.mtrl-sci↗

arXiv2017

Chiral Surface Waves for Enhanced Circular Dichroism

We present a novel chiral sensing platform that combines a one-dimensional photonic crystal design with a birefringent surface defect. The platform sustains simultaneous transverse electric and transverse magnetic surface modes, which are exploited to generate chiral surface waves. The present design provides homogeneous and superchiral fields of both handednesses over arbitrarily large areas in a wide spectral range, resulting in the enhancement of the circular dichroism signal by two orders of magnitude, thus paving the road toward the successful combination of surface-enhanced spectroscopies and electromagnetic superchirality.

physics.optics↗

arXiv2016

Optical Activation of Germanium Plasmonic Antennas in the Mid Infrared

Impulsive interband excitation with femtosecond near-infrared pulses establishes a plasma response in intrinsic germanium structures fabricated on a silicon substrate. This direct approach activates the plasmonic resonance of the Ge structures and enables their use as optical antennas up to the mid-infrared spectral range. The optical switching lasts for hundreds of picoseconds until charge recombination red-shifts the plasma frequency. The full behavior of the structures is modeled by the electrodynamic response established by an electron-hole plasma in a regular array of antennas.

cond-mat.mes-hall↗

arXiv2016

Local field enhancement: comparing self-similar and dimer nanoantennas

We study the local field enhancement properties of self-similar nanolenses and compare the obtained results with the performance of standard dimer nanoantennas. We report that, despite the additional structural complexity, self-similar nanolenses are unable to provide significant improvements over the field enhancement performance of standard plasmonic dimers.

physics.optics↗