arXiv subjects

Patrice Bertet

Publications and source records attributed to Patrice Bertet.

At least 19 recordsLinked to original sources

arXiv2026

Strongly anisotropic non-Kramers electron spin as a quantum coherence probe of angular fluctuations

Strongly anisotropic non-Kramers rare-earth ions combine giant longitudinal g-factors with a vanishing transverse component imposed by time-reversal symmetry, a combination that makes their spin transitions exquisitely sensitive to the orientation of the applied magnetic field. We show that this sensitivity carries a dual identity: it is simultaneously an overlooked decoherence channel and the basis for a spin-coherence-based angular probe. Using pulsed electron paramagnetic resonance at X-band, we report the first measurements of the quantum coherence of Tb$^{3+}$ in a native-doped CaWO$_4$ crystal (15 ppb) and map the Hahn-echo coherence time $T_2$ as a function of temperature (2 to 10 K) and resonant field ($10^3$ to $10^4$ G). A parameter-free model combining spin-lattice relaxation, instantaneous diffusion and spectral diffusion from all independently quantified impurities overestimates $T_2$ by an order of magnitude at low temperature and wrongly predicts the field dependence of $T_2$, inconsistent with the observed monotonic decrease of $T_2$ with $B_r$. A two-parameter extension, including dynamical angular fluctuations of the crystal axis, reproduces the full dataset across multiple setups and laboratories. Two controlled experiments nominally identical except for different mechanical configuration of the setup establish the mechanical origin of the dominant contribution. The two-parameter extension corresponds to an angular amplitude noise spectral density of overall order 36 n{\deg}/$\sqrt{Hz}$ from global external vibrations (ranging from 10 to 66 n{\deg}/$\sqrt{Hz}$ depending on the exact setup mechanical configuration) estimated at $\sim$ 2.5 kHz plus a temperature-dependent contribution assumed to come from local phonon-driven angular jitter. It identifies and highlights a decoherence pathway of practical relevance to any anisotropic solid-state spin system.

cond-mat.mes-hall↗

arXiv2026

Superconducting Parallel-Plate Resonators for the Detection of Single Electron Spins

We introduce a multilayer superconducting microwave resonator with sub-Ohm impedance optimized for high coupling strength to single electron spins. The design minimizes the magnetic far-field and therefore achieves a Purcell factor $F_P > 10^{15}$. We show several ways to fabricate this type of resonator and present resonators with an intrinsic $Q$-factor exceeding $2 \cdot 10^4$ at the single-photon level. We further characterize these resonators in magnetic fields up to $500 \, \text{mT}$. Finally, we evaluate the impact of the achievable Purcell factor on single-spin detection through photon counting and dispersive readout.

quant-ph↗

arXiv2025

Noise Mitigation in Single Microwave Photon Counting by Cascaded Quantum Measurements

While single-photon counting is routinely achieved in the optical domain, operational single microwave photon detectors (SMPDs) have only recently been demonstrated. SMPDs are critical for sensing weak signals from incoherent emitters, with applications ranging from the detection of individual electron spins and dark-matter candidates to advancements in hybrid quantum devices and superconducting quantum computing. These detectors offer a substantial advantage over quantum-limited amplification schemes by bypassing the standard quantum limit for power detection, therefore further reductions in their intrinsic noise are essential for advancing quantum sensing at microwave frequencies. Several SMPD designs utilize the state of a superconducting qubit to encode the detection of an itinerant photon, and rely on a non-destructive photon-qubit interaction. Here, we leverage this Quantum-Non-Demolition feature by repeatedly measuring the impinging photon with cascaded Four-Wave-Mixing processes and encoding the detection on several qubits. This cascaded detector mitigates the intrinsic local noise of individual qubits, achieving a two-order-of-magnitude reduction in intrinsic detector noise at the cost of halving the efficiency. We report an intrinsic sensitivity of $8(1)\times10^{-24}\text{W}/\sqrt{\text{Hz}}$, with an operational sensitivity of $5.9(6)\times 10^{-23}\text{W}/\sqrt{\text{Hz}}$ limited by thermal photons in the input line.

quant-ph↗

arXiv2025

Analytical solutions for optimal photon absorption into inhomogeneous spin memories

We investigate for optimal photon absorption a quantum electrodynamical model of an inhomogeneously-broadened spin ensemble coupled to a single-mode cavity. Solutions to this problem under experimental assumptions are developed in the Schrödinger picture without using perturbation theory concerning the cavity-spin interactions. Furthermore, we exploit the possibility of modulating the frequency and coupling rate of the resonator. We consider a one-photon input pulse and show some optimal scenarios, where exact formulas and numerical results are obtained for the absorption probabilities and the optimal pulse shapes. In particular, if the external loss dominates the internal loss of the cavity, we find the optimal cooperativity for different parameters and identify cases where absorption with a success probability larger than $99\%$ is achieved.

quant-ph↗

arXiv2025

Enhancing the sensitivity of single microwave photon detection with bandwidth tunability

We report on the characteristics of a microwave photon counter device based on a superconducting transmon qubit. Its design is similar to [arXiv:2307.03614], with an additional bandwidth tuning circuit that allows optimizing the device efficiency and noise. Owing to this new feature and to improvements in device fabrication, a power sensitivity of $3 \cdot 10^{-23} \mathrm{W}/\sqrt{\mathrm{Hz}}$ is reached. We confirm the high performance of the device by measuring single spin microwave fluorescence.

quant-ph↗

arXiv2024

Individual solid-state nuclear spin qubits with coherence exceeding seconds

The ability to coherently control and read out qubits with long coherence times in a scalable system is a crucial requirement for any quantum processor. Nuclear spins in the solid state have shown great promise as long-lived qubits. Control and readout of individual nuclear spin qubit registers has made major progress in the recent years using individual electron spin ancilla addressed either electrically or optically. Here, we present a new platform for quantum information processing, consisting of $^{183}$W nuclear spin qubits adjacent to an Er$^{3+}$ impurity in a CaWO$_4$ crystal, interfaced via a superconducting resonator and detected using a microwave photon counter at 10mK. We study two nuclear spin qubits with $T_2^*$ of $0.8(2)~$s and $1.2(3)~$s, $T_2$ of $3.4(4)~$s and $4.4(6)~$ s, respectively. We demonstrate single-shot quantum non-demolition readout of each nuclear spin qubit using the Er$^{3+}$ spin as an ancilla. We introduce a new scheme for all-microwave single- and two-qubit gates, based on stimulated Raman driving of the coupled electron-nuclear spin system. We realize single- and two-qubit gates on a timescale of a few milliseconds, and prepare a decoherence-protected Bell state with 88% fidelity and $T_2^*$ of $1.7(2)~$s. Our results are a proof-of-principle demonstrating the potential of solid-state nuclear spin qubits as a promising platform for quantum information processing. With the potential to scale to tens or hundreds of qubits, this platform has prospects for the development of scalable quantum processors with long-lived qubits.

quant-ph↗

arXiv2024

Incoherent Measurement of Sub-10 kHz Optical Linewidths

Quantum state lifetimes $T_2$, or equivalently homogeneous linewidths $\Gamma_h = 1/\pi T_2$, are a key parameter for understanding decoherence processes in quantum systems and assessing their potential for applications in quantum technologies. The most common tool for measuring narrow optical homogeneous linewidths, i.e. long $T_2$, is the measurement of coherent photon echo emissions, which however gives very weak signal when the number of emitters is small. This strongly hampers the development of nano-materials, such as those based on rare earth ions, for quantum communication and processing. In this work we propose, and demonstrate in an erbium doped crystal, a measurement of photon echoes based on incoherent fluorescence detection and its variance analysis. It gives access to $T_2$ through a much larger signal than direct photon echo detection, and, importantly, without the need for a highly coherent laser. Our results thus open the way to efficiently assess the properties of a broad range of emitters and materials for applications in quantum nano-photonics.

quant-ph↗

arXiv2024

Month-long-lifetime microwave spectral holes in an erbium-doped scheelite crystal at millikelvin temperature

Rare-earth-ion (REI) ensembles in crystals have remarkable optical and spin properties characterized by narrow homogeneous linewidths relative to the inhomogeneous ensemble broadening. This makes it possible to precisely tailor the ensemble spectral density and therefore the absorption profile by applying narrow-linewidth radiation to transfer population into auxiliary levels, a process broadly known as spectral hole burning (SHB). REI-doped crystals find applications in information processing, both classical (pattern recognition, filtering, spectral analysis) and quantum (photon storage), all protocols requiring suitable ensemble preparation by SHB as a first step. In Er$^{3+}$-doped materials, the longest reported hole lifetime is one minute, and longer lifetimes are desirable. Here, we report SHB and accumulated echo measurements in a scheelite crystal of CaWO$_4$ by pumping the electron spin transition of Er$^{3+}$ ions at microwave frequencies and millikelvin temperatures, with nuclear spin states of neighboring $^{183}$W atoms serving as the auxiliary levels. The lifetime of the holes and accumulated echoes rises steeply as the sample temperature is decreased, exceeding a month at 10 mK. Our results demonstrate that millikelvin temperatures can be beneficial for signal processing applications requiring long spectral hole lifetimes.

quant-ph↗

arXiv2024

Opto-RF transduction in Er$^{3+}$:CaWO$_4$

We use an erbium doped CaWO$_4$ crystal as a resonant transducer between the RF and optical domains at 12 GHz and 1532 nm respectively. We employ a RF resonator to enhance the spin coupling but keep a single-pass (non-resonant) optical setup. The overall efficiency is low but we carefully characterize the transduction process and show that the performance can be described by two different metrics that we define and distinguish: the electro-optics and the quantum efficiencies. We reach an electro-optics efficiency of -84 dB for 15.7 dBm RF power. The corresponding quantum efficiency is -142 dB for 0.4 dBm optical power. We develop the Schrödinger-Maxwell formalism, well-known to describe light-matter interactions in atomic systems, in order to model the conversion process. We explicitly make the connection with the cavity quantum electrodynamics (cavity QED) approach that are generally used to describe quantum transduction.

quant-ph↗

arXiv2024

Cyclically operated Single Microwave Photon Counter with $10^\mathrm{-22}$ $\mathrm{W/\sqrt{Hz}}$ sensitivity

Single photon detection played an important role in the development of quantum optics. Its implementation in the microwave domain is challenging because the photon energy is 5 orders of magnitude smaller. In recent years, significant progress has been made in developing single microwave photon detectors (SMPDs) based on superconducting quantum bits or bolometers. In this paper we present a practical SMPD based on the irreversible transfer of an incoming photon to the excited state of a transmon qubit by a four-wave mixing process. This device achieves a detection efficiency $η= 0.43$ and an operational dark count rate $α= 85$ $\mathrm{s^{-1}}$, mainly due to the out-of-equilibrium microwave photons in the input line. The corresponding power sensitivity is $\mathcal{S} = 10^{-22}$ $\mathrm{W/\sqrt{Hz}}$, one order of magnitude lower than the state of the art. The detector operates continuously over hour timescales with a duty cycle $η_\mathrm{D}=0.84$, and offers frequency tunability of at least 50 MHz around 7 GHz.

quant-ph↗

arXiv2023

Roadmap on Nanoscale Magnetic Resonance Imaging

The field of nanoscale magnetic resonance imaging (NanoMRI) was started 30 years ago. It was motivated by the desire to image single molecules and molecular assemblies, such as proteins and virus particles, with near-atomic spatial resolution and on a length scale of 100 nm. Over the years, the NanoMRI field has also expanded to include the goal of useful high-resolution nuclear magnetic resonance (NMR) spectroscopy of molecules under ambient conditions, including samples up to the micron-scale. The realization of these goals requires the development of spin detection techniques that are many orders of magnitude more sensitive than conventional NMR and MRI, capable of detecting and controlling nanoscale ensembles of spins. Over the years, a number of different technical approaches to NanoMRI have emerged, each possessing a distinct set of capabilities for basic and applied areas of science. The goal of this roadmap article is to report the current state of the art in NanoMRI technologies, outline the areas where they are poised to have impact, identify the challenges that lie ahead, and propose methods to meet these challenges. This roadmap also shows how developments in NanoMRI techniques can lead to breakthroughs in emerging quantum science and technology applications.

cond-mat.mes-hall↗

arXiv2023

Single electron-spin-resonance detection by microwave photon counting

Electron spin resonance (ESR) spectroscopy is the method of choice for characterizing paramagnetic impurities, with applications ranging from chemistry to quantum computing, but it gives access only to ensemble-averaged quantities due to its limited signal-to-noise ratio. Single-electron-spin sensitivity has however been reached using spin-dependent photoluminescence, transport measurements, and scanning-probe techniques. These methods are system-specific or sensitive only in a small detection volume, so that practical single spin detection remains an open challenge. Here, we demonstrate single electron magnetic resonance by spin fluorescence detection, using a microwave photon counter at cryogenic temperatures. We detect individual paramagnetic erbium ions in a scheelite crystal coupled to a high-quality factor planar superconducting resonator to enhance their radiative decay rate, with a signal-to-noise ratio of 1.9 in one second integration time. The fluorescence signal shows anti-bunching, proving that it comes from individual emitters. Coherence times up to 3 ms are measured, limited by the spin radiative lifetime. The method has the potential to apply to arbitrary paramagnetic species with long enough non-radiative relaxation time, and allows single-spin detection in a volume as large as the resonator magnetic mode volume ( 10 um^3 in the present experiment), orders of magnitude larger than other single-spin detection techniques. As such, it may find applications in magnetic resonance and quantum computing.

quant-ph↗

arXiv2022

Microwave fluorescence detection of spin echoes

Counting the microwave photons emitted by an ensemble of electron spins when they relax radiatively has recently been proposed as a sensitive method for electron paramagnetic resonance (EPR) spectroscopy, enabled by the development of operational Single Microwave Photon Detectors (SMPD) at millikelvin temperature. Here, we report the detection of spin echoes in the spin fluorescence signal. The echo manifests itself as a coherent modulation of the number of photons spontaneously emitted after a $π/2_X - τ- π_Y - τ- π/2_Φ$ sequence, dependent on the relative phase $Φ$. We demonstrate experimentally this detection method using an ensemble of $\mathrm{Er}^{3+}$ ion spins in a scheelite crystal of $\mathrm{CaWO}_4$. We use fluorescence-detected echoes to measure the erbium spin coherence time, as well as the echo envelope modulation due to the coupling to the $^{183}\mathrm{W}$ nuclear spins surrounding each ion. We finally compare the signal-to-noise ratio of inductively-detected and fluorescence-detected echoes, and show that it is larger with the fluorescence method.

quant-ph↗

arXiv2022

Electron-spin spectral diffusion in an erbium doped crystal at millikelvin temperatures

Erbium-doped crystals offer a versatile platform for hybrid quantum devices because they combine magnetically-sensitive electron-spin transitions with telecom-wavelength optical transitions. At the high doping concentrations necessary for many quantum applications, however, strong magnetic interactions of the electron-spin bath lead to excess spectral diffusion and rapid decoherence. Here we lithographically fabricate a 4.4 GHz superconducting planar micro-resonator on a $\text{CaWO}_{4}$ crystal doped with Er ions at a concentration of twenty parts per million relative to Ca. Using the microwave resonator, we characterize the spectral diffusion processes that limit the electron-spin coherence of Er ions at millikelvin temperatures by applying 2- and 3-pulse echo sequences. The coherence time shows a strong temperature dependence, reaching 1.3 ms at 23 mK for an electron-spin transition of $^{167}\text{Er}$.

quant-ph↗

arXiv2021

Twenty-three millisecond electron spin coherence of erbium ions in a natural-abundance crystal

Erbium ions doped into crystals have unique properties for quantum information processing, because of their optical transition at 1.5 $μ$m and of the large magnetic moment of their effective spin-1/2 electronic ground state. Most applications of erbium require however long electron spin coherence times, and this has so far been missing. Here, by selecting a host matrix with a low nuclear-spin density (CaWO$_4$) and by quenching the spectral diffusion due to residual paramagnetic impurities at millikelvin temperatures, we obtain an Er$^{3+}$ electron spin coherence time of 23 ms. This is the longest electron spin coherence time measured in a material with a natural abundance of nuclear spins and on a magnetically-sensitive transition. Our results establish Er$^{3+}$:CaWO$_4$ as a leading platform for quantum networks.

quant-ph↗

arXiv2021

Detecting spins with a microwave photon counter

Quantum emitters respond to resonant illumination by radiating electromagnetic fields. A component of these fields is phase-coherent with the driving tone, while another one is incoherent, consisting of spontaneously emitted photons and forming the fluorescence signal. Atoms and molecules are routinely detected by their fluorescence at optical frequencies, with important applications in quantum technology and microscopy. Spins, on the other hand, are usually detected by {their coherent response} at radio- or microwave frequencies, either in continuous-wave or pulsed magnetic resonance. Indeed, fluorescence detection of spins is hampered {by their low spontaneous emission rate} and by the lack of single-photon detectors in this frequency range. Here, using superconducting quantum devices, we demonstrate the detection of a small ensemble of donor spins in silicon by their fluorescence at microwave frequency and millikelvin temperatures. We enhance the spin radiative decay rate by coupling them to a high-quality-factor and small-mode-volume superconducting resonator, and we connect the device output to a newly-developed microwave single-photon counter based on a superconducting qubit. We discuss the potential of fluorescence detection as a novel method for magnetic resonance spectroscopy of small numbers of spins.

quant-ph↗

arXiv2020

Donor spins in silicon for quantum technologies

Dopant atoms are ubiquitous in semiconductor technologies, providing the tailored electronic properties that underpin the modern digital information era. Harnessing the quantum nature of these atomic-scale objects represents a new and exciting technological revolution. In this article we describe the use of ion-implanted donor spins in silicon for quantum technologies. We review how to fabricate and operate single-atom spin qubits in silicon, obtaining some of the most coherent solid-state qubits, and we discuss pathways to scale up these qubits to build large quantum processors. Heavier group-V donors with large nuclear spins display electric quadrupole couplings that enable nuclear electric resonance, quantum chaos and strain sensing. Donor ensembles can be coupled to microwave cavities to develop hybrid quantum Turing machines. Counted, deterministic implantation of single donors, combined with novel methods for precision placement, will allow the integration of individual donors spins with industry-standard silicon fabrication processes, making implanted donors a prime physical platform for the second quantum revolution.

quant-ph↗

arXiv2020

Electron Spin Resonance spectroscopy with femtoliter detection volume

We report electron spin resonance measurements of donors in silicon at millikelvin temperatures using a superconducting $LC$ planar micro-resonator and a Josephson Parametric Amplifier. The resonator includes a nanowire inductor, defining a femtoliter detection volume. Due to strain in the substrate, the donor resonance lines are heavily broadened. Single-spin to photon coupling strengths up to $\sim 3~\text{kHz}$ are observed. The single shot sensitivity is $120 \pm 24~$spins/Hahn echo, corresponding to $\approx 12 \pm 3$~spins$/\sqrt{\text{Hz}}$ for repeated acquisition.

quant-ph↗